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KNa2Cd crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two KNa2Cd ribbons oriented in the (0, 1, 0) direction. K is bonded in a linear geometry to two equivalent Na atoms. Both K–Na bond lengths are 4.07 Å. Na is bonded in a linear geometry to one K and one Cd atom. The Na–Cd bond length is 3.12 Å. Cd is bonded in a linear geometry to two equivalent Na atoms.
K2NaCd crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two K2NaCd ribbons oriented in the (0, 1, 0) direction. K is bonded in a linear geometry to one Na and one Cd atom. The K–Na bond length is 3.73 Å. The K–Cd bond length is 3.75 Å. Na is bonded in a linear geometry to two equivalent K atoms. Cd is bonded in a linear geometry to two equivalent K atoms.