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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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17 records

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NASA NTRS1981

Development of CdO-graphite-Ag coatings for gas bearings to 427 C

Graphite is one of the most commonly known lubricants. Its effectiveness in a range between room temperature (RT) and 540 C is reportedly improved by adding cadmium oxide. CdO-graphite powder in a gas carrier has been used in numerous applications that rely on dry lubrication. A coating of this composition was developed and successfully tested in foil air bearings for long periods up to a temperature of 427 C and at a normal contacting load (during starting and stopping) of 14 kPa based on bearing projected area. The addition of ultra-fine silver to the CdO-graphite has improved the coating endurance. At 427 C, the CdO-graphite-Ag coating performed better than CdO-graphite without silver, both for extended periods at 14 kPa loading and for limited periods at 35 kPa. At 288 C, the coating was tested for an extended period up to 28 kPa and has also successfully completed high-speed shock tests to an acceleration level of 100g.

Bhushan, B.↗

NASA NTRS1989

CdO Pretreatment For Graphite Lubricant Films

Lubrication of rubbing steel surfaces with graphite improved by sputtering cadmium oxide onto surfaces, according to report. Lubricating films consisting of mixtures of cadmium oxide and graphite did not perform as well as films of graphite alone on surfaces pretreated with cadmium oxide. Primary beneficial effect obtained by sputtering pretreatment with cadmium oxide, which apparently improves bond between metallic substrate and graphite.

Fusaro, Robert L.↗

NASA NTRS1986

Sputtered cadmium oxide as a surface pretreatment for graphite solid lubricant films

Sputtered films of cadmium oxide were applied to sand blasted AISI 440C HT stainless steel disks as a surface pretreatment for the application of rubbed graphite films. Mixtures of cadmium oxide and graphite were applied to the nonpretreated sandblasted metal and evaluated. The results were compared to graphite films applied to other commercially available surface pretreatments. It is found that sputtered CdO pretreated surfaces increase the endurance lives of the graphite films and decrease the counterface steady state wear rate of the pins almost an order of magnitude compared to commercially available pretreatments. The CdO additions in general improved the tribological properties of graphite. The greatest benefit occurred when it was applied to the substrate rather than mixing it with the graphite and that sputtered films of CdO perform much better than rubbed CdO films.

Fusaro, R. L.↗

NASA NTRS1987

Sputtered cadmium oxide as a surface pretreatment for graphite solid-lubricant films

Fusaro, Robert L.↗

NASA NTRS1990

Controlled decomposition and oxidation: A treatment method for gaseous process effluents

The safe disposal of effluent gases produced by the electronics industry deserves special attention. Due to the hazardous nature of many of the materials used, it is essential to control and treat the reactants and reactant by-products as they are exhausted from the process tool and prior to their release into the manufacturing facility's exhaust system and the atmosphere. Controlled decomposition and oxidation (CDO) is one method of treating effluent gases from thin film deposition processes. CDO equipment applications, field experience, and results of the use of CDO equipment and technological advances gained from the field experiences are discussed.

Mckinley, Roger J. B., Sr.↗

NASA NTRS1978

Static evaluation of surface coatings for compliant gas bearings in an oxidizing atmosphere to 650 C

Hard wear-resistant coatings and soft low shear strength coatings were developed for an air-lubricated compliant journal bearing for a future automotive gas turbine engine. The coatings were expected to function in either 540 or 650 C ambient. Soft lubricant coatings were generally limited in temperature. Therefore emphasis was on the hard wear-resistant coatings. The coating materials covered were TiC, B4C, Cr3C2, WC, SiC, CrB2, TiB2, Cr2O3, Al2O3, Si3N4, Tribaloy 800, CaF2, CaF2-BaF2 eutectic, Ni-Co, silver, CdO-graphite and proprietary compounds. The coatings on test coupons were subjected to static oven screening tests. The test consisted of exposure of material samples in an oven for 300 h at the maximum temperature (540 or 650 C) and ten temperature cycles from room temperature to the maximum service temperature. On the basis of the specimen examinations the following coatings were recommended for future wear tests: TiC (sputtered), Cr2O3 (sputtered), Si3N4 (sputtered), CdO and graphite (fused), Kaman DES (a proprietary coating), CrB2 (plasma sprayed), Cr3C2 (detonation gun) and NASA PS-106 (plasma sprayed).

Bhushan, B.↗

NASA NTRS1938

Correction of Profile-Drag Results from Variable-Density Tunnel and the Effect on the Choice of Wing-Section Thickness

Profile-drag coefficients published from tests in the N.A.C.A. variable-density tunnel (Technical Reports Nos. 460, 537, 586, and 610, references 1 to 4) have tended to appear high as compared with results from the N.A.C.A. full-scale tunnel (Technical Report No. 530, reference 5) and from foreign sources (references 6 to 8). Such discrepancies were considered in Technical Report No. 586, and corrections for turbulence and tip effects were derived that tended to reduce the profile-drag coefficients, particularly for the thicker airfoils. The corrected profile-drag coefficients, designated by the lower-case symbol cdo as contrasted with the older CDO, have been employed in the airfoil reports published since Technical Report No. 460, but even these corrected results continued to appear high, particularly for the thicker sections. The important practical result is that a smaller increase of drag with airfoil thickness is indicated, which may be of primary importance to the airplane designer in choosing the optimum airfoil sections for actual wings. Further investigations of this subject were, of course, undertaken, one of the most important being an investigation of three symmetrical sections N.A.C A. 0009, 0012, and 0018 under conditions of low turbulence in the full-scale tunnel. Preliminary results from this investigation also indicate a smaller increase in drag with airfoil thickness than the results from the variable-density tunnel. Furthermore, comparative tests made in the two tunnels by applying strings to the surface of the N.A.C.A. 0012 airfoil to move the transition point to a predetermined position indicated that the effective reynolds Number concept would account approximately for the drag as affected by the position of transition from laminar to turbulent flow in the boundary layer.

Jacobs, Eastman N.↗

NASA NTRS1972

Cadmium poisoning of oxygen reduction on platinum electrode in potassium hydroxide

Experiment with a rotating disk and ring apparatus showed no poisoning by cadmium in 8.5 M KOH, alone or with Cl(-) or CO3(=). Poisoning does not occur either in 0.1 M KOH supernatant at CdO, but a partially reversible poisoning results from .0001 M CdCl2 and traces of fatty acid are present. Evidence indicates that the catastrophic poisoning affects the four-electron O2 reduction more than it does the one-electron H3O(+) discharge.

Miller, R. O.↗

NASA NTRS1977

Friction and wear behavior of graphite fiber reinforced polyimide composites

The friction and wear rate characteristics of 50/50 (weight per cent) graphite fiber-polyimide composites were studied by sliding metallic hemispherically tipped riders against disks made from the composites. Two different polyimides and two different graphite fibers were evaluated. Also studied were such variables as the effect of adding 10 per cent weight additions of powdered (CF-1.1)n, CdI2, or CdO, the effect of moisture in an air atmosphere, the effect of temperature, and the effect of different sliding speeds. In general, wear to the metallic riders was negligible and composite wear increased at a constant rate as a function of number of sliding cycles.

Fusaro, R. L.↗

NASA NTRS1978

Some effects of composition on friction and wear of graphite-fiber-reinforced polyimide liners in plain spherical bearings

Oscillating, plain spherical bearings with graphite-fiber-reinforced polyimide (GFRPI) liners were tested for friction and wear from 25 to 315 C. A condensation polymer was compared with an addition polymer, and a high-modulus fiber was compared with a lower cost, low-modulus fiber. All polymer-fiber combinations gave friction coefficients from 0.05 to 0.18 and low wear. Adding CdO and CdI2 reduced the wear of degassed bearings in dry air. These additives were not needed when the bearing liners contained adsorbed moisture. Although, at 25 C, MoS2 reduced the friction and wear of the base composite at unit loads above 70,000,000 N/m squared (10,000 psi), it had no beneficial effect at lighter loads.

Sliney, H. E.↗

NASA NTRS1978

Hydrodynamic air lubricated compliant surface bearing for an automotive gas turbine engine. 2: Materials and coatings

Material coatings for an air-lubricated, compliant journal bearing for an automotive gas turbine engine were exposed to service test temperatures of 540 C or 650 C for 300 hours, and to 10 temperature cycles from room temperatures to the service test temperatures. Selected coatings were then put on journal and partial-arc foils and tested in start-stop cycle tests at 14 kPa (2 psi) loading for 2000 cycles. Half of the test cycles were performed at a test chamber service temperature of 540 C (1000 F) or 650 C (1200 F); the other half were performed at room temperature. Based on test results, the following combinations and their service temperature limitations are recommended: HL-800 TM (CdO and graphite) on foil versus chrome carbide on journal up to 370 C (700 F); NASA PS 120 (Tribaloy 400, silver and CaF2 on journal versus uncoated foil up to 540 C (1000 F); and Kaman DES on journal and foil up to 640 C (1200 F). Kaman DES coating system was further tested successfully at 35 kPa (5 psi) loading for 2000 start-stop cycles.

Bhushan, B.↗

NASA NTRS1978

Graphite-fiber-reinforced polyimide liners of various compositions in plain spherical bearings

Composites made of graphite-fiber-reinforced polyimide (GFRPI) with a fiber-resin ratio (by weight) of about 1 were evaluated as molded outer-race liners in plain spherical bearings. Several compositions were examined: two types of polyimide (addition and condensation polymers), two types of graphite fiber (high and low modulus) and four powder additives (CdO, CdI2, (CF1.1)n, and MoS2). Friction and wear were measured during oscillation at 25, 200, and 315 C. It is shown that all compositions provided good lubrication in dry air, that neither type of polyimide or graphite fiber nor the additives gave a clear advantage, and that wear rates were always higher during run-in, before conditions stabilized. It is concluded that GFRPI composites are self-lubricating under all but the most extreme moisture-free conditions at 25 C. The additives are helpful only with very high loads or extremely dry environments.

Sliney, H. E.↗

NASA NTRS1978

Development of surface coatings for air-lubricated, compliant journal bearings to 650 C

Surface coatings for an air-lubricated, compliant journal for an automotive gas turbine engine were tested to find those capable of withstanding temperatures of either 540 C (1000 F) or 650 C (1200 F). Also, the coatings have to be capable of surviving the start-stop sliding contact cycles prior to rotor lift-off and at touchdown. Selected coating combinations were tested in start-stop tests at 14 kPa (2 psi) loading for 2000 cycles at room and maximum temperatures. Specific coating recommendations are: Cdo and graphite on foil versus chrome carbide on journal up to 370 C (700 F); NASA PS-120 (Tribaloy 400, silver, and CaF2) on journal versus uncoated foil up to 540 C (1000 F); and chemically adherent Cr2O3 on journal and foil up to 650 C (1200 F). The chemically adherent Cr2O3 coating system was further tested successfully at 35 kPa (5 psi) loading for 2000 start-stop cycles.

Bhushan, B.↗

NASA NTRS1980

High temperature self-lubricating coatings for air lubricated foil bearings for the automotive gas turbine engine

coating combinations were developed for compliant surface bearings and journals to be used in an automotive gas turbine engine. The coatings were able to withstand the sliding start/stops during rotor liftoff and touchdown and occasional short time, high speed rubs under representative loading of the engine. Some dozen coating variations of CdO-graphite, Cr2O3 (by sputtering) and CaF2 (plasma sprayed) were identified. The coatings were optimized and they were examined for stoichiometry, metallurgical condition, and adhesion. Sputtered Cr2O3 was most adherent when optimum parameters were used and it was applied on an annealed (soft) substrate. Metallic binders and interlayers were used to improve the ductility and the adherence.

Bhushan, B.↗

NASA NTRS1987

Control-System Design Program

Control-theory design package, Optimal Regulator Algorithms for Control of Linear Systems (ORACLS), developed to aid in design of controllers and optimal filters for systems modeled by linear, time-invariant differential and difference equations. Optimal linear quadratic regulator theory, Linear-Quadratic-Gaussian (LQG) problem, most widely accepted method of determining optimal control policy. Provides for solution to time-in-variant continuous or discrete LQG problems. Attractive to control-system designer providing rigorous tool for dealing with multi-input and multi-output dynamic systems in continuous and discrete form. CDO version written in FORTRAN IV. VAX version written in FORTRAN 77.

Frisch, Harold P.↗

NASA NTRS2002

Hurricane Erin September 10, 2001: Comparison of TRMM, AMSU-A and QUIKSCAT Data with an Extensive Aircraft Data Set, and Some Preliminary Results

A main purpose of this study is to compare satellite products from TRMM, AMSU-A and QuikSCAT with a unique, extensive aircraft data set in Category 3 Hurricane Erin on September 10,2001, and to draw some preliminary conclusions from the data. For the first time, dropwinsondes were obtained by the NASA ER-2 aircraft. There were 8 soundings in the eye, core and surroundings radially out to the edge of the Central Dense Overcast (CDO). Additionally, 11 dropwinsondes from the DC-8 aircraft at about 12 km documented the storm outskirts and environment. TRMM made a direct overpass of the eye as did both NOAA-15 and NOM-16 with AMSU on board. Among the most interesting results: Contours of the tropopause height (a first). As expected from earlier fragmentary results, the tropopause was approximately 1 km higher in the core than in the environment. The highest tropopause was about 2 km above the tallest towers in the eyewall, south-southeast of the eye center, suggesting that earlier convective towers had been higher than those measured by EDOP and TRMM during the flights. Surprisingly, the heaviest precipitation was on the opposite side of the eyewall from the tallest convective towers. The warm core was elongated in the vertical, and poorly retrieved from the AMSU-A data by the NESDIS profile retrieval algorithm. The eye of Erin was "dirty". A CCN/CN counter flown on the NOAA P3 at 14.3 km showed a concentration of 1500 aerosol particles per cubic centimeter. This is an order of magnitude higher than a sample in the hurricane environment. TRMM data are used to hypothesize an explanation.

Simpson, J.↗

NASA NTRS2014

Carbon Dioxide Gas Sensors and Method of Manufacturing and Using Same

A gas sensor comprises a substrate layer; a pair of interdigitated metal electrodes, said electrodes include upper surfaces, the electrodes selected from the group consisting of Pt, Pd, Au, Ir, Ag, Ru, Rh, In, Os, and their alloys. A first layer of solid electrolyte staying in between electrode fingers and partially on said upper surfaces of said electrodes, said first layer selected from NASICON, LISICON, KSICON and.beta.''-Alumina. A second layer of metal carbonate(s) as an auxiliary electrolyte engaging said upper surfaces of the electrodes and the first solid electrolyte. The metal carbonates selected from the group consisting of the following ions Na.sup.+, K.sup.+, Li.sup.+, Ag.sup.+, H.sup.+, Pb.sup.2+, Sr.sup.2+, Ba.sup.2+, and any combination thereof. An extra layer of metal oxide selected from the group consisting of SnO.sub.2, In.sub.2O.sub.3, TiO.sub.2, WO.sub.3, ZnO, Fe.sub.2O.sub.3, ITO, CdO, U.sub.3O.sub.8, Ta.sub.2O.sub.5, BaO, MoO.sub.2, MoO.sub.3, V.sub.2O.sub.5, Nb.sub.2O.sub.5, CuO, Cr.sub.2O.sub.3, La.sub.2O.sub.3, RuO.sub.3, RuO.sub.2, ReO.sub.2, ReO.sub.3, Ag.sub.2O, CoO, Cu.sub.2O, SnO, NiO, Pr.sub.2O.sub.3, BaO, PdO.sub.2, HfO.sub.3, HfO.sub.3 or other metal oxide and their mixtures residing above and in engagement with the second electrolyte to improve sensor performance and/or to reduce sensor heating power consumption.

Hunter, Gary W.↗