Materials Data on S(ClO)2 by Materials Project
SO2Cl2 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfuryl chloride molecules. S6+ is bonded in a distorted tetrahedral geometry to two equivalent O2- and two equivalent Cl1- atoms. Both S–O bond lengths are 1.43 Å. Both S–Cl bond lengths are 2.03 Å. O2- is bonded in a single-bond geometry to one S6+ atom. Cl1- is bonded in a single-bond geometry to one S6+ atom.