Materials Data on RePCl9 by Materials Project
ReCl5PCl4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and one pentachlororhenium molecule.
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Materials Data on Re2PCl by Materials Project
Re2PCl crystallizes in the cubic F-43m space group. The structure is three-dimensional. there are two inequivalent Re sites. In the first Re site, Re is bonded in a 4-coordinate geometry to four equivalent Re, four equivalent P, and six equivalent Cl atoms. All Re–Re bond lengths are 2.71 Å. All Re–P bond lengths are 2.71 Å. All Re–Cl bond lengths are 3.12 Å. In the second Re site, Re is bonded to four equivalent Re and four equivalent Cl atoms to form distorted edge-sharing ReRe4Cl4 tetrahedra. All Re–Cl bond lengths are 2.71 Å. P is bonded in a distorted body-centered cubic geometry to four equivalent Re and four equivalent Cl atoms. All P–Cl bond lengths are 2.71 Å. Cl is bonded in a distorted body-centered cubic geometry to ten Re and four equivalent P atoms.
36 MATERIALS SCIENCE↗