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5 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 is Tungsten structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of three PtCl2 clusters. Pt2+ is bonded in a rectangular see-saw-like geometry to four Cl1- atoms. All Pt–Cl bond lengths are 2.33 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 crystallizes in the orthorhombic Pnnm space group. The structure is one-dimensional and consists of two PtCl2 ribbons oriented in the (1, 0, 0) direction. Pt2+ is bonded in a square co-planar geometry to four equivalent Cl1- atoms. All Pt–Cl bond lengths are 2.32 Å. Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl4 by Materials Project

PtCl4 is Silicon tetrafluoride-like structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of twenty-four platinum(iv) chloride molecules. Pt4+ is bonded in a tetrahedral geometry to four Cl1- atoms. All Pt–Cl bond lengths are 2.27 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt4+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt4+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of one PtCl2 ribbon oriented in the (1, 0, 0) direction. Pt2+ is bonded in a rectangular see-saw-like geometry to four Cl1- atoms. There are a spread of Pt–Cl bond distances ranging from 2.27–2.52 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Pt2+ atom. In the second Cl1- site, Cl1- is bonded in a distorted T-shaped geometry to three equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on PtCl2 by Materials Project

PtCl2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of four PtCl2 ribbons oriented in the (0, 1, 0) direction. Pt2+ is bonded in a square co-planar geometry to four Cl1- atoms. All Pt–Cl bond lengths are 2.32 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Pt2+ atoms.

36 MATERIALS SCIENCE↗