Materials Data on SCl2 by Materials Project
SCl2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight sulfur dichloride molecules. S2+ is bonded in a water-like geometry to two Cl1- atoms. There are one shorter (2.03 Å) and one longer (2.06 Å) S–Cl bond lengths. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one S2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one S2+ atom.
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