Materials Data on InCoO3 by Materials Project
CoInO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Co3+ is bonded to six O2- atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedra tilt angles range from 36–39°. There is four shorter (1.94 Å) and two longer (1.97 Å) Co–O bond length. In3+ is bonded in a 8-coordinate geometry to eight O2- atoms. There are a spread of In–O bond distances ranging from 2.15–2.69 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded to two equivalent Co3+ and two equivalent In3+ atoms to form distorted corner-sharing OIn2Co2 trigonal pyramids. In the second O2- site, O2- is bonded in a 4-coordinate geometry to two equivalent Co3+ and three equivalent In3+ atoms.