Materials Data on CoPPd by Materials Project
CoPdP is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Co1+ is bonded to four equivalent P3- atoms to form a mixture of corner and edge-sharing CoP4 tetrahedra. All Co–P bond lengths are 2.22 Å. Pd2+ is bonded in a 1-coordinate geometry to five equivalent P3- atoms. There are one shorter (2.35 Å) and four longer (2.72 Å) Pd–P bond lengths. P3- is bonded in a 9-coordinate geometry to four equivalent Co1+ and five equivalent Pd2+ atoms.
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