Recent progress in atom-atom collision theory.
Atom-atom collision theory, comparing velocity criterion for inelastic scattering, Massey parameter and Landau-Zener parameter
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Atom-atom collision theory, comparing velocity criterion for inelastic scattering, Massey parameter and Landau-Zener parameter
Collisions between comparable-sized planetary bodies are a special class of collisions, rarer than other collisions, but producing interesting products, such as unfractured dumbbell-shaped contact binaries, partly brecciated elongated bodies, totally brecciated spheroidal bodies, and perhaps co-orbiting binary pairs or swarms. Qualitative and rough quantitative theories are presented to indicate collision outcomes. Contact binaries or fractured elongated bodies as large as tens or hundreds of kilometers across can be produced - larger than hitherto considered. Lengths about 20 to 200 km are most probable for igneous or ordinary chondritic elongated objects formed by collision, but other lengths could result from tidal evolution of pairs. Though most elongated asteroids are probably collision fragments, as usually assumed, some may instead be accretionary products. Trojan asteroid 624 Hektor is a candidate. Some polymict, genomict, and monomict brecciated meteorites may be better explained by large-scale fragmentation and immediate gravitational re-assembly of parent bodies than by local-scale processes of cratering on parent-body surfaces.
Hard sphere model for reactive molecular collisions based on energy and momentum of reactants and products
Theory of excitation and charge exchange in proton-hydrogen collisions
Collision focusing effect on monocrystalline sputtering yield theory
Collision integrals for nonelastic processes in plasma kinetic theory
Theory and analysis of relative motion and internal excitation in molecular collisions
Quantum mechanical theory of spectral line broadening which incorporates doppler and collision broadening in a natural way
Quantum mechanical treatment of atomic center of mass motion in theory of collision effects on line shapes
A new on-line control strategy for sensor-based collision avoidance of manipulators and supporting experimental results are presented in this article. This control strategy is based on nullification of virtual forces applied to the end-effector by a hypothetical spring-plus-damper attached to the object's surface. In the proposed approach, the real-time arm control software continuously monitors the object distance measured by the arm-mounted proximity sensors. When this distance is less than a preset threshold, the collision avoidance control action is initiated to inhibit motion toward the object and thus prevent collision. This is accomplished by employing an outer feedback loop to perturb the end-effector nominal motion trajectory in real-time based on the sensory data. The perturbation is generated by a proportional-plus-integral (PI) collision avoidance controller acting on the difference between the sensed distance and the preset threshold. This approach is computationally very fast, requires minimal modification to the existing manipulator positioning system, and provides the manipulator with an on-line collision avoidance capability to react autonomously and intelligently. A dexterous RRC robotic arm is instrumented with infrared proximity sensors and is operated under the proposed collision avoidance strategy. Experimental results are presented to demonstrate end-effector collision avoidance both with an approaching object and while reaching inside a constricted opening.
This paper describes a new approach to the study of atom-diatom reactive collisions in three dimensions employing wave packets and the time-dependent Schroedinger equation. The method uses a projection operator approach to couple the inelastic and reactive portions of the total wave function and optical potentials to circumvent the necessity of using product arrangement coordinates. Reactive transition probabilities are calculated from the state resolved flux of the wave packet as it leaves the interaction region in the direction of the reactive arrangement channel. The present approach is used to obtain such vibrationally resolved probabilities for the three-dimensional H + H2 (J = 0) hydrogen exchange reaction, using a body-fixed system of coordinates.
Collision effects on atomic spectral line profiles, using quantum mechanical description of atomic center-of-mass motion with particular application to lasers
Collision effects on line shapes using quantum mechanical description of atomic center of mass motion, considering pressure effects in gas lasers
Partial differential equations for theory of atomic collisions
Attenuation cross section and refractive index using collision theory, calculating resonance profiles of autoionizing lines based on scattering theory
A theoretical model for the pressure dependence of the intensity of a gas laser is presented in which only velocity-changing collisions with foreign-gas atoms are included. This is a special case where the phase shifts are the same for the two atomic-laser levels or are so small that deflections are the dominant effect of collisions. A collision model for hard-sphere repulsive interactions is derived and the collision parameters, persistence of velocity and collision frequency, are assumed to be independent of velocity. The collision theory is applied to a third-order expansion of the polarization in powers of the cavity electric field (weak-signal theory). The resulting expression for the intensity shows strong pressure dependence. The collisions reduce the amount of saturation and the laser intensity increases with pressure in a characteristic fashion.
The temperature dependence of the rate constants for model reacting systems was studied to understand some recent experimental measurements which imply the existence of negative activation energies. A collision theory model and classical trajectory calculations are used to demonstrate that the reaction probability can vary inversely with collision energy for bimolecular reactions occurring on attractive potential energy surfaces. However, this is not a sufficient condition to ensure that the rate constant has a negative temperature dependence. On the basis of these calculations, it seems unlikely that a true bimolecular reaction between neutral molecules will have a negative activation energy.
Under typical solar chromospheric conditions for hydrogen radiators, strong collisions due to both electrons and ions are well separated in time, so that a binary collision theory for collisional redistribution is applicable. However, a simple impact approximation may not be used, but rather a unified type theory is required in which frequency dependent line shape parameters are used to describe both impact and quasi-static regions of the spectrum. In addition, correlated terms which describe absorption and emission during a collision are important, and, in fact, without correlated terms describing both transfer of excitation and emission during the same collision unphysical predictions (such as negative intensities) would be obtained. In this paper theory is specifically developed for the coupled Lyman-alpha, Lyman-beta, Hydrogen-alpha system, and equations of statistical equilibrium and absorption and emission coefficients are given. All correlated events are examined and emission during a collision is found to be important in the line wings. Stimulated emission and absorption is also included within a broadband approximation. The major approximation is to ignore lower state interaction. It is found that for Lyman-beta Raman-coupling with Hydrogen-alpha occurs and the overall scattering of radiation in the line wings is mostly coherent. In contrast, for Hydrogen-alpha, incoherent redistribution due to lower state radiative decay (which occurs even in the absence of collisions) is found to dominate the coherent scattering. Finally, in the Lyman series the dominant incoherent contribution is associated with cascade transitions and inelastic collisions between different principal quantum states.