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Results for “Collision-induced absorption”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Collision-induced absorption in the far infrared spectrum of Titan

The effects of collision-induced absorption on the far infrared spectrum of Titan have been investigated. After a review of the procedure for the theoretical calculation of the N2 translation-rotational spectrum, new results for the temperature range o 70 to 120 K are reported. These are used as input data for a simple atmospheric model in order to compute the far infrared radiance, brightness temperature, and specral limb function. This source of opacity alone is not capable of explaining the Voyager results. When the collision-induced methane is included, the results are in closer agreement in the range between 200 and 300/cm, suggesting that a more complete treatment of collision-induced absorption including particularly CH4-N2, N2-H2, and H2-H2 results, may provide sufficient opacity to reduce or obviate the need for opacities due to clouds or aerosols in order to explain the observed spectra.

Hunt, J. L.↗
NASA NTRS1982

Stratospheric measurements of collision-induced absorption by molecular oxygen

High-resolution stratospheric solar absorption spectra recorded at sunset with a balloon-borne interferometer, from an altitude of 33 km, are used in a study of collision-induced absorption by the fundamental vibration-rotation band of O2, whose continuum has been identified in the 1400-1700/cm region in spectra obtained at tangent altitudes below 22 km. It is found that transmittance measurements in intervals free of atmospheric line absorption agree with values calculated with the O2 absorption coefficients of Timofeyev and Tonkov (1978), and that the measurements indicate a 20% upper limit for the uncertainty of the available O2 absorption coefficients at lower stratospheric temperatures, on the order of 220 K.

Rinsland, C. P.↗
NASA NTRS1977

Collision-induced absorption of O2 in the Herzberg continuum

Using a one meter normal incidence grating monochromator, the total absorption of radiation for O2 has been reinvestigated between 2000-2500 A. The absorption cross sections of O2 and O4 are then derived from total absorption measurements and compared with other available data. Additional measurements of O2 absorption have been made in the presence of Ar which does not absorb in this spectral region and is chemically inactive with O2. It is found that the absorption of oxygen increases in the presence of Ar, which is interpreted as due to the formation of O2-Ar dimers.

SHARDANAND↗
NASA NTRS1984

Theory of collision-induced translation-rotation spectra: H2-He

An adiabatic quantal theory of spectral line shapes in collision-induced absorption and emission is presented which incorporates the induced translation-rotation and translation-vibration spectra. The generalization to account for the anisotropy of the scattering potential is given. Calculations are carried out of the collision-induced absorption spectra of He in collisions with H2 with ab initio electric dipole functions and realistic potentials. The anisotropy of the interaction potential is small and is not included in the calculations. The predicted spectra are in satisfactory agreement with experimental data though some deviations occur which may be significant. The rotational line shapes have exponential wings and are not Lorentzian. The connection between the quantal and classical theories is written out explicitly for the isotropic overlap induction.

Birnbaum, G.↗
NASA NTRS1978

Far-infrared absorption in H2 and H2-He mixtures

Collision-induced absorption in the translation-rotation band of H2 and H2-He mixtures has been measured from 20 to 900 kaysers at 77.4, 195, and 292 K. To establish the accuracy of the results, various sources of error are investigated. The zeroth and first spectral moments are evaluated from experiment and theory for H2 at the various temperatures. To obtain theoretical moments consistent with the experimental values, the quantum pair-distribution function must be used. The major portion of the experimental moments can be accounted for by quadrupole-induced dipoles in H2 pairs. The remaining portion is attributable to an anisotropic overlap interaction, although its magnitude depends on the value of the molecular parameters required to calculate the quadrupole contribution.

Birnbaum, G.↗
NASA NTRS1987

Measurement and analysis of the far infrared absorption spectrum of the gaseous mixture H2-CH4

The collision-induced absorption of H2-CH4 mixtures was measured from 20 to 900/cm at 195 and 297 K. By subtracting the absorption due to H2-H2 and CH4-CH4 collisions from that of the mixture, the absorption due to H2-CH4 collisions was obtained. This spectrum was analyzed using the BC model line shape to provide a way of estimating the far-IR spectrum of H2-CH4 for various concentrations of H2 and CH4. Theoretical spectral moments were computed with different potential functions and compared with experimental values.

Birnbaum, George↗
NASA NTRS1987

The spectra of Uranus and Neptune at 8-14 and 17-23 microns

The 3-m NASA Infrared Telescope Facility was used to observe the disks of Uranus and Neptune between May 30 and June 1, 1985 in the 7-14 and 17-23 micron spectral regions. Maximum stratospheric mixing ratios of 9 x 10 to the -9th for C2H2, and of 2 x 10 to the -8th for C2H6, are found for Uranus, and the spectrum is otherwise smooth, consistent with the opacity provided by H2 collision-induced absorption and spectrally continuous stratospheric emission. Strong emission features of CH4 and C2H6 are found in the short-wavelength spectrum of Neptune, and the spectrum near 13.5 microns is consistent with C2H2 emission in local saturation equilibrium with a maximum mixing ratio of 9 x 10 to the -7th.

Orton, Glenn S.↗
NASA NTRS1987

Experimental and theoretical investigation of the far-infrared spectrum of H2-He mixtures

New measurements of the rototranslational collision-induced absorption spectra in the far-infrared (FIR) frequency region of gaseous mixtures of hydrogen and helium are reported. The frequency range extends up to 1500/cm at the temperature of 195 K, and 1700/cm at 296 K. The uncertainties of the measurement are assessed. Comparison with previous measurements shows substantial agreement at frequencies where the measurements overlap. For comparison with the measurement, spectra are computed from the fundamental theory using a state of the art ab initio dipole function and an isotropic potential surface as input. The observed agreement suggests that, for important applications, such as the analysis of the FIR spectra of the outer planets, the spectra can be obtained reliably as a function of frequency and temperature from quantum calculations of the kind presented here.

Birnbaum, George↗
NASA NTRS1982

Airborne spectroscopy and spacecraft radiometry of Venus in the far infrared

The first spectral observations of the Venus disk in the 110 to 270 per cm spectral range are reported, made from the Kuiper Airborne Observatory in mid-March 1979, some three months following the start of the Pioneer Venus Orbiter mission. The instrumentation and its differences from earlier flight hardware is discussed. The brightness temperature was 275 K near 110/cm, dropping to 230 K near 270/cm. Radiance calculations, using temperature and cloud structure formation from the Pioneer Venus mission and including gaseous absorption by the collision-induced dipole of CO2, yield results consistently brighter than the observations. The atmospheric environment is reviewed with regard to the FIR opacity and possible particle distribution modifications are discussed. It is concluded that the most likely possibility for supplementing the FIR opacity is a population of large particles in the upper cloud with number densities less than one particle per cu cm which has remained undetected by in situ measurements.

Aumann, H. H.↗
DOE OSTI2024

Exploring direct photodetachment and photodissociation–photodetachment dynamics of platinum iodide anions (PtI n - , n = 2–5) using cryogenic photoelectron spectroscopy

The direct photodetachment and two-photon photodissociation–photodetachment processes of a series of PtI n - (n = 2–5) anions were systematically studied using cryogenic anion photoelectron spectroscopy and first-principles electronic structure calculations. The adiabatic/vertical detachment energies (ADEs/VDEs) of these anions were determined from their 193 nm photoelectron (PE) spectra, i.e., 3.54/3.63, 4.04/4.09, 4.33/4.36, and 4.37/4.41 eV for n = 2–5, respectively, and well reproduced by B3LYP-D3(BJ)/aug-cc-pVTZ-pp calculations. As the coordination number increases, the electron affinity (EA) of PtI n • (n = 2–5) neutrals (equivalent to the corresponding anion’s ADE) gradually increases, exceeding the EA of Cl at n = 3 and exhibiting superhalogen characteristics for n ≥ 3. Meanwhile, the ground state transition contributed from detaching electrons in the highest occupied molecular orbital gradually evolves from the central metal Pt to the iodine ligands. For the PtI 3 - anion, besides one-photon direct detachment, four distinct two-photon photodissociation–photodetachment channels were identified, and the competition between them was discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1985

Modeling of pressure-induced far-infrared absorption spectra Molecular hydrogen pairs

Meyer et al. (1985) have calculated the accurate induced dipole moment function of H2-H2 from first principles, using highly correlated wave functions for the first time in such work. The present paper is concerned with the collision-induced translational-rotational absorption coefficient for molecular hydrogen pairs, taking into account computations on the basis of the fundamental theory considered by Meyer et al. Data have been obtained for temperatures in the range from 40 to 300 K. Criteria are developed for choosing among various model line shapes. It is found that certain models are capable of approximating the quantum profiles closely, with rms errors of only a few percent.

Borysow, J.↗
NASA NTRS1985

Measurement of collision-induced shift and broadening of the ultraviolet transitions of OH

Using a CW tunable laser, absorption measurements were made to determine for the first time the shift and broadening of the ultraviolet transitions of OH induced by collisions with molecular nitrogen and oxygen. Similar measurements were also made for collisions with air and inert gases He, Ne, Ar, and Kr. Both the shift and broadening due to these collisions were found to depend linearly upon pressures in the range from 50 Torr up to 1 atm. The homogeneous linewidth for the P2(2) transition of OH in ambient air is determined to be 0.20 + or - 0.005/cm. Results with Ar and Kr show contributions not accounted for by the polarizability of the colliding species.

Shirinzadeh, B.↗
NASA NTRS1984

Hydrogen dimer structures in the far-infrared spectra of Jupiter and Saturn

On the basis of a spectral line shape computation and radiative transfer calculations, it is shown that the unexplained, diminutive structures seen in the Voyager IRIS Jovian spectra near the hydrogen S0(0) and S0(1) rotational frequencies are due to bound-free transitions involving hydrogen dimers. The absorption intensities of these transitions, as well as of the collision-induced background, are given. These dimer structures may possibly prove to be useful for determining the helium/hydrogen ratio and the para-hydrogen fraction in the atmospheres of the outer planets.

Frommhold, L.↗
NASA NTRS1971

Infrared Absorption of Carbon Dioxide at High Densities With Application to the Atmosphere of Venus

Several new infrared absorptions were found in carbon dioxide. All are normally forbidden, and were collision-induced in an absorbing cell whose combination of pressure and path length has a unique sensitivity for induced absorptions. The new absorptions in the 2.3 micron region are attributed to transitions from ground to the 3(1)1 Fermi pair at 4248 and 4391/cm. Other absorptions are attributed to simultaneous CO2-N2 transitions and to the 00(0)0-00(0)2 transition in CO2 polarizability derivatives and regular progressions in strength versus increasing quantum number. The spectra were used to predict the radiative transfer in a dry CO2 model of the lower Venus atmosphere. The results indicate that the radiation balance in the lower atmosphere is adequately explained by a dry massive atmosphere of CO2 with a layer of infrared-opaque clouds. The absorptions in the 2.3 micron region are significant in accounting for the opacity to sustain Venus' 768 K surface temperature.

John Fitzallen Moore↗
NASA NTRS1988

Laboratory studies of irradiated nitrogen-methane mixtures - Applications to Triton

The characteristics of the near-IR spectrum of Triton is addressed in view of 0.8-2.5 micron laboratory transmission spectra obtained for methane dissolved in liquid nitrogen. It is found that, for methane concentrations greater than 3 percent of the saturation value, the collision-induced, 2.152-micron first-overtone band of molecular nitrogen is overshadowed by the methane band centered at 2.3 microns. While gamma-radiolysis of nitrogen-methane mixtures generates an unstable precipitate whose yellowish color is qualitatively similar to the yellow color of Triton, no specific absorption band in the precipitate can be unambiguously identified on Triton.

Piscitelli, J. R.↗