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At least 19 records

REVISITING THE CHLORINE ABUNDANCE IN DIFFUSE INTERSTELLAR CLOUDS FROM MEASUREMENTS WITH THE COPERNICUS SATELLITE

We reanalyzed interstellar Cl I and Cl II spectra acquired with the Copernicus satellite. The directions for this study come from those of Crenny and Federman and sample the transition from atomic to molecular-rich clouds where the unique chemistry leading to molecules containing chlorine is initiated. Our profile syntheses relied on up-to-date laboratory oscillator strengths and component structures derived from published high-resolution measurements of K I absorption that were supplemented with Ca II and Na I D results. We obtain self-consistent results for the Cl I lines at 1088, 1097, and 1347 A from which precise column densities are derived. The improved set of results reveals clearer correspondences with H{sub 2} and total hydrogen column densities. These linear relationships arise from rapid conversion of Cl{sup +} to Cl{sup 0} in regions where H{sub 2} is present.

79 ASTRONOMY AND ASTROPHYSICS↗

Global anthropogenic emissions (CAMS-GLOB-ANT) for the Copernicus Atmosphere Monitoring Service simulations of air quality forecasts and reanalyses

Anthropogenic emissions are the result of many different economic sectors, including transportation, power generation, industrial, residential and commercial activities, waste treatment and agricultural practices. Air quality models are used to forecast the atmospheric composition, analyze observations and reconstruct the chemical composition of the atmosphere during the previous decades. In order to drive these models, gridded emissions of all compounds need to be provided. This paper describes a new global inventory of emissions called CAMS-GLOB-ANT, developed as part of the Copernicus Atmosphere Monitoring Service (CAMS; https://doi.org/10.24380/eets-qd81, Soulie et al., 2023). The inventory provides monthly averages of the global emissions of 36 compounds, including the main air pollutants and greenhouse gases, at a spatial resolution of 0.1° × 0.1° in latitude and longitude, for 17 emission sectors. The methodology to generate the emissions for the 2000–2023 period is explained, and the datasets are analyzed and compared with publicly available global and regional inventories for selected world regions. Depending on the species and regions, good agreements as well as significant differences are highlighted, which can be further explained through an analysis of different sectors as shown in the figures in the Supplement.

54 ENVIRONMENTAL SCIENCES↗

Using Atmospheric Inverse Modelling of Methane Budgets with Copernicus Land Water and Wetness Data to Detect Land Use-Related Emissions

Climate change mitigation requires countries to report their annual greenhouse gas (GHG) emissions and sinks, including those from land use, land use change, and forestry (LULUCF). In Finland, the LULUCF sector plays a crucial role in achieving net-zero GHG emissions, as the sector is expected to be a net sink. However, accurate estimates of LULUCF-related GHG emissions, such as methane (CH 4 ), remain challenging. We estimated LULUCF-related CH 4 emissions in Finland in 2013–2020 by combining national land cover and remote-sensed surface wetness data with CH 4 emissions estimated by an inversion model. According to our inversion model, most of Finland’s CH 4 emissions were attributed to natural sources such as open pristine peatlands. However, our research indicated that forests with thin tree cover surrounding open peatlands may also be a significant source of CH 4 . Unlike open pristine peatlands and pristine peatlands with thin tree cover, surrounding transient forests are included in the Finnish GHG inventory if they meet the criteria used for forest land. The current Finnish national GHG inventory may therefore underestimate CH 4 emissions from forested organic soils surrounding open peatlands, although more precise methods and data are needed to verify this. Given the potential impact on net GHG emissions, CH 4 emissions from transitional forests on organic soils should be further investigated. Furthermore, the results demonstrate the potential of combining atmospheric inversion modelling of GHGs with diverse data sources and highlight the need for methods to more easily combine atmospheric inversions with national GHG inventories.

54 ENVIRONMENTAL SCIENCES↗

The Worldwide C3S CORDEX Grand Ensemble: A Major Contribution to Assess Regional Climate Change in the IPCC AR6 Atlas

The collaboration between the Coordinated Regional Climate Downscaling Experiment (CORDEX) and the Earth System Grid Federation (ESGF) provides open access to an unprecedented ensemble of regional climate model (RCM) simulations, across the 14 CORDEX continental-scale domains, with global coverage. These simulations have been used as a new line of evidence to assess regional climate projections in the latest contribution of the Working Group I (WGI) to the IPCC Sixth Assessment Report (AR6), particularly in the regional chapters and the Atlas. Here, we present the work done in the framework of the Copernicus Climate Change Service (C3S) to assemble a consistent worldwide CORDEX grand ensemble, aligned with the deadlines and activities of IPCC AR6. This work addressed the uneven and heterogeneous availability of CORDEX ESGF data by supporting publication in CORDEX domains with few archived simulations and performing quality control. It also addressed the lack of comprehensive documentation by compiling information from all contributing regional models, allowing for an informed use of data. In addition to presenting the worldwide CORDEX dataset, we assess here its consistency for precipitation and temperature by comparing climate change signals in regions with overlapping CORDEX domains, obtaining overall coincident regional climate change signals. The C3S CORDEX dataset has been used for the assessment of regional climate change in the IPCC AR6 (and for the interactive Atlas) and is available through the Copernicus Climate Data Store (CDS).

54 ENVIRONMENTAL SCIENCES↗

GE Renewable Energy: Perdigao wind dataset from Large Eddy Simulation and ERA5

Perdigao wind research dataset including ERA5 data, high resolution and low resolution Large Eddy Simulations for the year 2020 at 1 hour frequency. Generated using Copernicus Climate Change Service information 2022[1] [1] Hersbach, H., Bell, B., Berrisford, P., Biavati, G., Horányi, A., Muñoz Sabater, J., Nicolas, J., Peubey, C., Radu, R., Rozum, I., Schepers, D., Simmons, A., Soci, C., Dee, D., Thépaut, J-N. (2018): ERA5 hourly data on single levels from 1979 to present. Copernicus Climate Change Service (C3S) Climate Data Store (CDS). (Accessed on 05-04-2022), 10.24381/cds.adbb2d47

17 WIND ENERGY↗

The G2 erosion model: An algorithm for month-time step assessments

Highlights: • G2 is a soil erosion model for developing monthly erosion maps at regional scale. • G2 enhances the spatio-temporal variability of cover management and erosivity factors. • The V-factor models the impact of vegetation cover, land use and imperviousness layer. • G2 uses data from ESDAC, LUCAS, COPERNICUS, CORINE, SENTINEL and EU-DEM databases. • G2 has been applied in Strymonas Catchment, Crete, Cyprus and Albania catchments. A detailed description of the G2 erosion model is presented, in order to support potential users. G2 is a complete, quantitative algorithm for mapping soil loss and sediment yield rates on month-time intervals. G2 has been designed to run in a GIS environment, taking input from geodatabases available by European or other international institutions. G2 adopts fundamental equations from the Revised Universal Soil Loss Equation (RUSLE) and the Erosion Potential Method (EPM), especially for rainfall erosivity, soil erodibility, and sediment delivery ratio. However, it has developed its own equations and matrices for the vegetation cover and management factor and the effect of landscape alterations on erosion. Provision of month-time step assessments is expected to improve understanding of erosion processes, especially in relation to land uses and climate change. In parallel, G2 has full potential to decision-making support with standardised maps on a regular basis. Geospatial layers of rainfall erosivity, soil erodibility, and terrain influence, recently developed by the Joint Research Centre (JRC) on a European or global scale, will further facilitate applications of G2.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of regional CO2 mole fractions in the ECMWF CAMS real-time atmospheric analysis and NOAA CarbonTracker Near-Real Time reanalysis with airborne observations from ACT-America field campaigns

This study systematically examines the regional uncertainties and biases in carbon dioxide (CO2) mole fractions from two of the state-of-the-art global analysis products, namely the Copernicus Atmosphere Monitoring Service (CAMS) real-time atmospheric analysis from the European Centre for Medium-Range Weather Forecasts and the Carbon- Tracker Near-Real Time (CT-NRT) reanalysis from the National Oceanic and Atmospheric Administration, by evaluation against hundreds of hours of airborne in situ measurements from the summer 2016 and winter 2017 Atmospheric Carbon and Transport (ACT) { America eld campaigns. Both the CAMS and CT-NRT analyses agree reasonably well with the independent ACT-America airborne CO2 measurements in the free troposphere, with root-mean-square deviations (RMSDs) between analyses and observations generally between 1{2 ppm, but show considerably larger uncertainties in the atmospheric boundary layer where the RMSDs are as large as 10 ppm in the lowermost 500 m of the boundary layer. There are strong variations in accuracy and bias between seasons, and across three different sub-regions in the United States (Mid-Atlantic, Midwest and South), with the largest uncertainties in the Mid-Atlantic region in summer. Overall, the RMSDs of the CAMS and CT-NRT analyses against airborne data are comparable to each other, and grossly consistent with the difference between the two analyses. The current study provides uncertainty estimates for both analysis products over North America and suggests that these two independent estimates can be used to approximate regional CO2 analysis uncertainties. Both statistics are important in future studies in quantifying the uncertainties in regional CO2 mole fraction and flux estimates.

Chen, Hans↗

Assessment of Extinction‐, Satellite‐, and Model‐Based Vertical Cloud Condensation Nuclei (CCN) Retrieval Methods Using Airborne CCN Measurements Over the Southern Great Plains

Abstract Accurate estimates of the vertical profile of cloud condensation nuclei (CCN) concentration are crucial to better quantify aerosol‐cloud interactions. We assessed the correlation between the vertical CCN concentrations obtained from extinction‐, satellite‐, and model‐based retrieval methods and airborne CCN concentrations collected at 0.24% supersaturation within the 3, 9, 27, and 81 km regions centered over the U.S. Department of Energy's Atmospheric Radiation Measurement User Facility Southern Great Plains (SGP) site during the spring and summer of 2016. The extinction profiles at a wavelength 355 nm were provided by the ground‐based Raman lidar. Our analysis showed moderate correlation between dry‐corrected extinction and airborne CCN data. We found the retrieved number concentration of CCN (RNCCN) method showed regression best‐fit slopes close to unity and consistent prediction errors for the majority of the data. The Lenhardt et al. (2023, https://doi.org/10.5194/amt‐16‐2037‐2023 ) method showed similar conclusions but only during spring, whereas the Mamouri and Ansmann (2016, https://doi.org/10.5194/acp‐16‐5905‐2016 ) method showed poor correlation. The Shinozuka et al. (2015, https://doi.org/10.5194/acp‐15‐7585‐2015 ) satellite‐based method exhibited reasonable agreement during summer but poor correlation during periods where both high (∼1,400 #/cm 3 ) and low (∼50 #/cm 3 ) airborne CCN concentrations were observed. The Copernicus Atmosphere Monitoring Service reanalysis modeled 3‐D CCN data set showed a moderate to weak positive correlation but performed poorly at high airborne CCN concentrations. Our analysis suggests the extinction‐based RNCCN method performed better than other methods across most observation periods under the diverse meteorological conditions observed at the SGP site.

54 ENVIRONMENTAL SCIENCES↗

The detection of marine microseismic activity with the CUORE tonne-scale cryogenic experiment

Vibrations from experimental setups and the environment are a persistent source of noise for low-temperature calorimeters searching for rare events, including neutrinoless double beta ( 0νββ ) decay or dark matter interactions. Such noise can significantly limit experimental sensitivity to the physics case under investigation. Here, we report the detection of marine microseismic vibrations using mK-scale calorimeters. This study employs a multi-device analysis correlating data from CUORE, the leading experiment in the search for 0νββ decay with mK-scale calorimeters, and the Copernicus Earth Observation program, revealing the seasonal impact of Mediterranean Sea activity on CUORE’s energy thresholds, resolution, and sensitivity over four years. The detection of marine microseisms underscores the need to address faint environmental noise in ultra-sensitive experiments. Understanding how such noise couples to the detector and developing mitigation strategies is essential for next-generation experiments. We demonstrate one such strategy: a noise decorrelation algorithm implemented in CUORE using auxiliary sensors, which reduces vibrational noise and improves detector performance. Enhancing sensitivity to 0νββ decay and to rare events with low-energy signatures requires identifying unresolved noise sources, advancing noise reduction methods, and improving vibration suppression systems, all of which inform the design of next-generation rare event experiments.

experimental nuclear physics↗

Moving beyond the Aerosol Climatology of WRF-Solar: A Case Study over the North China Plain

Numerical weather prediction (NWP), when accessible, is a crucial input to short-term solar power forecasting. WRF-Solar, the first NWP model specifically designed for solar energy applications, has shown promising predictive capability. Nevertheless, few attempts have been made to investigate its performance under high aerosol loading, which attenuates incoming radiation significantly. The North China Plain is a polluted region due to industrialization, which constitutes a proper testbed for such investigation. Here, in this paper, aerosol direct radiative effect (DRE) on three surface shortwave radiation components (i.e., global, beam, and diffuse) during five heavy pollution episodes is studied within the WRF-Solar framework. Results show that WRF-Solar overestimates instantaneous beam radiation up to 795.3 W m -2 when the aerosol DRE is not considered. Although such overestimation can be partially offset by an underestimation of the diffuse radiation of about 194.5 W m -2 , the overestimation of the global radiation still reaches 160.2 W m -2 . This undesirable bias can be reduced when WRF-Solar is powered by Copernicus Atmosphere Monitoring Service (CAMS) aerosol forecasts, which then translates to accuracy improvements in photovoltaic (PV) power forecasts. This work also compares the forecast performance of the CAMS-powered WRF-Solar with that of the European Centre for Medium-Range Weather Forecasts model. Under high aerosol loading conditions, the irradiance forecast accuracy generated by WRF-Solar increased by 53.2% and the PV power forecast accuracy increased by 6.8%.

54 ENVIRONMENTAL SCIENCES↗

Towards provision of regularly updated climate data from the Coupled Model Intercomparison Project

The Coupled Model Intercomparison Project (CMIP) is a flagship of the World Climate Research Programme (WCRP). CMIP has become a recognised ‘brand’ in climate circles evolving over the last thirty years from a targeted research activity by a small number of climate modelling centres intercomparing their Earth System Model (ESM) simulations to a broad international coordinated research effort (Durack et al, 2025). CMIP is organized as a research activity leveraging funded and in-kind contributions from experts within modelling centres and the broader scientific community supported more recently by a fully-funded International Project Office. Within CMIP, Model Intercomparison Projects (MIPs) are community-designed to understand past, present and future climate. CMIP data provides a valuable resource for climate research and is routinely used to assess model representation of climate processes and test scientific hypotheses in the context of model uncertainty and (forced and internal) variability as evident from its prolific use in scientific publications1 . The impact relies on enabling infrastructure (most prominently via the Earth System Grid Federation (ESGF)), which allows sharing of simulation output, provision of the boundary conditions used in each simulation, and definition of the data standards that are essential to facilitating wide use of the data. The impact is supplemented by the wide-ranging scrutiny to which model simulations are subjected. Beyond its use in research, CMIP data is a key resource for communities producing derived climate information from downscaling and impact studies, such as the Coordinated Regional Downscaling Experiment (CORDEX; Gutowski et al., 2016) and the Intersectoral Impacts MIP (ISIMIP; Frieler et al., 2024). Government, academic and commercial entities also increasingly rely on CMIP and its downstream data for climate risk assessments and climate services (for example, Copernicus Climate Change Service and World Bank portal). This means that, although CMIP is a research activity, it increasingly serves a secondary and very relevant role as a provider of climate data – a long-recognised dichotomy (Stevens, 2024). Research and applications have distinct needs, with the former requiring flexibility and generality and the latter consistency. Here we explain how the design of the research activity has been adapted to reduce the burdens imposed by applications and how the research infrastructure might evolve to further enable scientific inquiry. We propose one possible approach to consistently providing model information and projections for applications in the future.

Environmental sciences↗

Evaluation of VEGETATION and PROBA-V Phenology Using PhenoCam and Eddy Covariance Data

High-quality retrieval of land surface phenology (LSP) is increasingly important for understanding the effects of climate change on ecosystem function and biosphere–atmosphere interactions. We analyzed four state-of-the-art phenology methods: threshold, logistic-function, moving-average and first derivative based approaches, and retrieved LSP in the North Hemisphere for the period 1999–2017 from Copernicus Global Land Service (CGLS) SPOT-VEGETATION and PROBA-V leaf area index (LAI) 1 km V2.0 time series. We validated the LSP estimates with near-surface PhenoCam and eddy covariance FLUXNET data over 80 sites of deciduous forests. Results showed a strong correlation (R 2 > 0.7) between the satellite LSP and ground-based observations from both PhenoCam and FLUXNET for the timing of the start (SoS) and R 2 > 0.5 for the end of season (EoS). The threshold-based method performed the best with a root mean square error of ~9 d with PhenoCam and ~7 d with FLUXNET for the timing of SoS (30th percentile of the annual amplitude), and ~12 d and ~10 d, respectively, for the timing of EoS (40th percentile).

47 OTHER INSTRUMENTATION↗

Impact of Aerosol and Cloud on the Solar Energy Potential over the Central Gangetic Himalayan Region

We examine the impact of atmospheric aerosols and clouds on the surface solar radiation and solar energy at Nainital, a high-altitude remote location in the central Gangetic Himalayan region (CGHR). For this purpose, we exploited the synergy of remote-sensed data in terms of ground-based AERONET Sun Photometer and satellite observations from the MODerate Resolution Imaging Spectroradiometer (MODIS) and the Meteosat Second Generation (MSG), with radiative transfer model (RTM) simulations and 1 day forecasts from the Copernicus Atmosphere Monitoring Service (CAMS). Clouds and aerosols are one of the most common sources of solar irradiance attenuation and hence causing performance issues in the photovoltaic (PV) and concentrated solar power (CSP) plant installations. The outputs of RTM results presented with high accuracy under clear, cloudy sky and dust conditions for global horizontal (GHI) and beam horizontal irradiance (BHI). On an annual basis the total aerosol attenuation was found to be up to 105 kWh m –2 for the GHI and 266 kWh m –2 for BHI, respectively, while the cloud effect is much stronger with an attenuation of 245 and 271 kWh m –2 on GHI and BHI. The results of this study will support the Indian solar energy producers and electricity handling entities in order to quantify the energy and financial losses due to cloud and aerosol presence.

54 ENVIRONMENTAL SCIENCES↗

Long-Term Dynamics of Atmospheric Sulfur Dioxide in Urban and Rural Regions of China: Urbanization and Policy Impacts

High levels of sulfur dioxide (SO 2 ) due to human activities pose a serious air pollution issue in China, especially in urban agglomerations. However, limited research has investigated the impact of anthropogenic emissions on higher SO 2 concentrations in urban regions compared to rural areas in China. Here, we analyzed the trends in SO 2 concentrations from 1980 to 2021 in China using the Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2) dataset. SO 2 column concentrations from the Copernicus Atmosphere Monitoring Service (CAMS) and the Ozone Monitoring Instrument (OMI) during the years 2007–2021 were also examined for validation and comparison purposes. Eight representative areas, including four urban regions (Pearl River Delta [PRD], Beijing-Tianjin-Hebei [BTH], Yangtze River Delta [YRD], and Sichuan Basin [SCB]) and four rural regions (Northeast Region [NER], Mongolian Region [MR], West Region [WR], and Tibetan Plateau Region [TR]) were selected for the analysis. Overall, a significant but fluctuating increase in SO 2 concentrations over China was observed during 1980–2021. During 1980–1997 and 2000–2010, there was an increase in SO 2 concentration, while during 1997–2000 and 2010–2021, a decreasing trend was observed. The average increase in SO 2 concentration was approximately 16 times higher in urban regions than in the rural background. We also found that SO 2 dynamics were highly associated with expansion of urban areas, population density, and gross domestic product. Nonetheless, since 2007, SO 2 concentrations have exhibited a downward trend, which is mainly attributed to the air pollution policies implemented by the Chinese government. Our findings highlight the need for further studies on the impact of SO 2 on regional climate change in China.

54 ENVIRONMENTAL SCIENCES↗

A STUDY OF THE ELEMENTS COPPER THROUGH URANIUM IN SIRIUS A: CONTRIBUTIONS FROM STIS AND GROUND-BASED SPECTRA

We determine abundances or upper limits for all of the 55 stable elements from copper to uranium for the A1 Vm star Sirius. The purpose of the study is to assemble the most complete picture of elemental abundances with the hope of revealing the chemical history of the brightest star in the sky, apart from the Sun. We also explore the relationship of this hot metallic-line (Am) star to its cooler congeners, as well as the hotter, weakly- or non-magnetic Mercury-manganese (HgMn) stars. Our primary observational material consists of Hubble Space Telescope ( HST ) spectra taken with the Space Telescope Imaging Spectrograph in the ASTRAL project. We have also used archival material from the COPERNICUS satellite, and from the HST Goddard High-Resolution Spectrograph, as well as ground-based spectra from Furenlid, Westin, Kurucz, Wahlgren, and their coworkers, ESO spectra from the UVESPOP project, and NARVAL spectra retrieved from PolarBase. Our analysis has been primarily by spectral synthesis, and in this work we have had the great advantage of extensive atomic data unavailable to earlier workers. We find most abundances as well as upper limits range from 10 to 100 times above solar values. We see no indication of the huge abundance excesses of 1000 or more that occur among many chemically peculiar stars of the upper main sequence. The picture of Sirius as a hot Am star is reinforced.

79 ASTRONOMY AND ASTROPHYSICS↗

Evaluating high-resolution forecasts of atmospheric CO and CO 2 from a global prediction system during KORUS-AQ field campaign

Accurate and consistent monitoring of anthropogenic combustion is imperative because of its significant health and environmental impacts, especially at city-to-regional scale. Here, we assess the performance of the Copernicus Atmosphere Monitoring Service (CAMS) global prediction system using measurements from aircraft, ground sites, and ships during the Korea-United States Air Quality (KORUS-AQ) field study in May to June 2016. Our evaluation focuses on CAMS CO and CO 2 analyses as well as two higher-resolution forecasts (16 and 9km horizontal resolution) to assess their capability in predicting combustion signatures over east Asia. Our results show a slight overestimation of CAMS CO 2 with a mean bias against airborne CO 2 measurements of 2.2, 0.7, and 0.3ppmv for 16 and 9km CO 2 forecasts, and analyses, respectively. The positive CO 2 mean bias in the 16km forecast appears to be consistent across the vertical profile of the measurements. In contrast, we find a moderate underestimation of CAMS CO with an overall bias against airborne CO measurements of -19.2 (16km), -16.7 (9km), and -20.7 ppbv (analysis). This negative CO mean bias is mostly seen below 750 hPa for all three forecast/analysis configurations. Despite these biases, CAMS shows a remarkable agreement with observed enhancement ratios of CO with CO 2 over the Seoul metropolitan area and over the West (Yellow) Sea, where east Asian outflows were sampled during the study period. More efficient combustion is observed over Seoul (dCO dCO 2 Combining double low line 9 ppbvppmv -1 ) compared to the West Sea (dCO dCO 2 Combining double low line 28 ppbvppmv -1 ). This "combustion signature contrast" is consistent with previous studies in these two regions. CAMS captured this difference in enhancement ratios (Seoul: 8-12 ppbvppmv -1 , the West Sea: ~ 30 ppbvppmv- 1 ) regardless of forecast/analysis configurations. The correlation of CAMS CO bias with CO2 bias is relatively high over these two regions (Seoul: 0.64-0.90, the West Sea: ~ 0.80) suggesting that the contrast captured by CAMS may be dominated by anthropogenic emission ratios used in CAMS. However, CAMS shows poorer performance in terms of capturing local-to-urban CO and CO 2 variability. Along with measurements at ground sites over the Korean Peninsula, CAMS produces too high CO and CO 2 concentrations at the surface with steeper vertical gradients (~ 0.4 ppmvhPa-1 for CO 2 and 3.5 ppbvhPa -1 for CO) in the morning samples than observed (~ 0.25 ppmvhPa -1 for CO 2 and 1.7 ppbvhPa -1 for CO), suggesting weaker boundary layer mixing in the model. Lastly, we find that the combination of CO analyses (i.e., improved initial condition) and use of finer resolution (9km vs. 16km) generally produces better forecasts.

54 ENVIRONMENTAL SCIENCES↗

Impacts of long-range transport of aerosols on marine-boundary-layer clouds in the eastern North Atlantic

Vertical profiles of aerosols are inadequately observed and poorly represented in climate models, contributing to the current large uncertainty associated with aerosol–cloud interactions. The US Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) aircraft field campaign near the Azores islands provided ample observations of vertical distributions of aerosol and cloud properties. Here we utilize the in situ aircraft measurements from the ACE-ENA and ground-based remote-sensing data along with an aerosol-aware Weather Research and Forecast (WRF) model to characterize the aerosols due to long-range transport over a remote region and to assess their possible influence on marine-boundary-layer (MBL) clouds. The vertical profiles of aerosol and cloud properties measured via aircraft during the ACE-ENA campaign provide detailed information revealing the physical contact between transported aerosols and MBL clouds. The European Centre for Medium-Range Weather Forecasts Copernicus Atmosphere Monitoring Service (ECMWF-CAMS) aerosol reanalysis data can reproduce the key features of aerosol vertical profiles in the remote region. The cloud-resolving WRF sensitivity experiments with distinctive aerosol profiles suggest that the transported aerosols and MBL cloud interactions (ACIs) require not only aerosol plumes to get close to the marine-boundary-layer top but also large cloud top height variations. Based on those criteria, the observations show that the occurrence of ACIs involving the transport of aerosol over the eastern North Atlantic (ENA) is about 62 % in summer. For the case with noticeable long-range-transport aerosol effects on MBL clouds, the susceptibilities of droplet effective radius and liquid water content are -0.11 and +0.14, respectively. When varying by a similar magnitude, aerosols originating from the boundary layer exert larger microphysical influence on MBL clouds than those entrained from the free troposphere.

54 ENVIRONMENTAL SCIENCES↗

Spatial distributions of X CO 2 seasonal cycle amplitude and phase over northern high-latitude regions

Satellite-based observations of atmospheric carbon dioxide (CO 2 ) provide measurements in remote regions, such as the biologically sensitive but undersampled northern high latitudes, and are progressing toward true global data coverage. Recent improvements in satellite retrievals of total column-averaged dry air mole fractions of CO 2 (X CO 2 ) from the NASA Orbiting Carbon Observatory 2 (OCO-2) have allowed for unprecedented data coverage of northern high-latitude regions, while maintaining acceptable accuracy and consistency relative to ground-based observations, and finally providing sufficient data in spring and autumn for analysis of satellite-observed X CO 2 seasonal cycles across a majority of terrestrial northern high-latitude regions. Here, we present an analysis of X CO 2 seasonal cycles calculated from OCO-2 data for temperate, boreal, and tundra regions, subdivided into 5° latitude by 20° longitude zones. We quantify the seasonal cycle amplitudes (SCAs) and the annual half drawdown day (HDD). OCO-2 SCAs are in good agreement with ground-based observations at five high-latitude sites, and OCO-2 SCAs show very close agreement with SCAs calculated for model estimates of X CO 2 from the Copernicus Atmosphere Monitoring Services (CAMS) global inversion-optimized greenhouse gas flux model v19r1 and the CarbonTracker2019 model (CT2019B). Model estimates of X CO 2 from the GEOS-Chem CO 2 simulation version 12.7.2 with underlying biospheric fluxes from CarbonTracker2019 (GC-CT2019) yield SCAs of larger magnitude and spread over a larger range than those from CAMS, CT2019B, or OCO-2; however, GC-CT2019 SCAs still exhibit a very similar spatial distribution across northern high-latitude regions to that from CAMS, CT2019B, and OCO-2. Zones in the Asian boreal forest were found to have exceptionally large SCA and early HDD, and both OCO-2 data and model estimates yield a distinct longitudinal gradient of increasing SCA from west to east across the Eurasian continent. In northern high-latitude regions, spanning latitudes from 47 to 72° N, longitudinal gradients in both SCA and HDD are at least as pronounced as latitudinal gradients, suggesting a role for global atmospheric transport patterns in defining spatial distributions of X CO2 seasonality across these regions. GEOS-Chem surface contact tracers show that the largest X CO 2 SCAs occur in areas with the greatest contact with land surfaces, integrated over 15–30d. The correlation of X CO 2 SCA with these land surface contact tracers is stronger than the correlation of X CO 2 SCA with the SCA of CO 2 fluxes or the total annual CO 2 flux within each 5° latitude by 20° longitude zone. This indicates that accumulation of terrestrial CO 2 flux during atmospheric transport is a major driver of regional variations in X CO 2 SCA.

54 ENVIRONMENTAL SCIENCES↗