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At least 19 records

Seismic Ambient Noise Analyses Reveal Changing Temperature and Water Signals to 10s of Meters Depth in the Critical Zone

The critical zone sustains terrestrial life, but we have few tools to explore it efficiently beyond the first few meters of the subsurface. Using analyses of high-frequency ambient seismic noise from densely spaced seismometers deployed in the forested Shale Hills subcatchment of the Susquehanna Shale Hills Critical Zone Observatory (SSHCZO), we show that temporal changes in seismic velocities at depths from ~1 m to tens of m can be detected. Furthermore, these changes are driven by variations at the land surface. The Moving-Window Cross-Spectral (MWCS) method was employed to measure seismic-velocity changes in coda waves at hourly resolution in 10 different frequency bands. We observed a diurnal signal, a seasonal signal, and a meteorological-event-based signal. These signals were compared to time-series measurements of precipitation, well water levels, soil moisture, soil temperature, air temperature, latent heat flux, and air pressure in the heavily instrumented catchment. Most of the velocity changes can be explained by variations in temperature that result in thermoelastic strains that propagate to depth. But some double minima in seismic velocity time-series observed after large rain events were attributed in part to the effects of water infiltration. These results show that high-frequency ambient noise data may in some locations be used to detect changes in the critical zone from ~1 to ~100 m or greater depth with hourly resolution. But interpretation of such data requires multiple environmental data sets to deconvolve the complex interrelationships among thermoelastic and hydrological effects in the subsurface critical zone.

54 ENVIRONMENTAL SCIENCES↗

Early Career Perspectives to Broaden the Scope of Critical Zone Science

Abstract Critical Zone (CZ) scientists have advanced understanding of Earth's surface through process‐based research that quantifies water, energy, and mass fluxes in predominantly undisturbed systems. However, the CZ is being increasingly altered by humans through climate and land use change. Expanding the scope of CZ science to include both human‐ and non‐human controls on the CZ is important for understanding anthropogenic impacts to Earth's surface processes and ecosystem services. Here, we share perspectives from predominantly U.S.‐based, early career CZ scientists centered around broadening the scope of CZ science to focus on societally relevant science through a transdisciplinary science framework. We call for increased training on transdisciplinary methods and collaboration opportunities across disciplines and with stakeholders to foster a scientific community that values transdisciplinary science alongside physical science. Here, we build on existing transdisciplinary research frameworks by highlighting the need for institutional support to include and educate graduate students throughout the research processes. We also call for graduate‐student‐led initiatives to increase their own exposure to transdisciplinary science through activities such as transdisciplinary‐focused seminars and symposiums, volunteering with local conservation groups, and participating in internships outside academia.

Warix, Sara [University of Utah Department of Geol↗

Soil Organic Matter Dynamics in the Critical Zone

Soil is the thin, vital layer of Earth’s surface that forms the foundation of the Critical Zone and sustains life. This chapter explores the intricate dynamics of soil organic matter within the critical zone, focusing on three key thematic areas: deep soil organic matter, wildfire organic matter interactions, and organic matter erosion. Soil organic matter, although a small fraction of soil mass, plays a crucial role in soil function and ecosystem stability. The complexity of soil organic matter arises from its diverse chemical composition and interactions with minerals, which influence its persistence in the environment. This chapter begins by examining deep soil organic matter, which constitutes a significant portion of global carbon storage. We discuss how deep soil organic matter, typically isolated from surface processes, may become vulnerable to decomposition and carbon release due to disturbances. Next, we explore the impacts of fire on soil organic matter, particularly the formation and stability of pyrolyzed organic matter. The decomposition of pyrolyzer organic matter is influenced by its chemical composition and the surrounding environmental conditions, with implications for carbon cycling and soil fertility in post-fire ecosystems. Finally, the chapter addresses the role of erosion in soil organic matter dynamics. Erosion, accelerated by human activities, redistributes soil organic matter across landscapes, affecting its turnover and the broader biogeochemical cycles. We consider how micro-topographic features and erosion processes interact to influence soil OM stability and carbon sequestration. By synthesizing recent advances in these areas, this chapter provides a comprehensive overview of the complex and dynamic nature of soil organic matter in the critical zone, highlighting its importance in understanding the critical zone in the face of environmental change.

Moreland, Kimber↗

AmeriFlux FLUXNET-1F US-SSH Susquehanna Shale Hills Critical Zone Observatory

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-SSH Susquehanna Shale Hills Critical Zone Observatory. This is the FLUXNET version of the carbon flux data for the site US-SSH Susquehanna Shale Hills Critical Zone Observatory produced by applying the standard ONEFlux (1F) software. Site Description - The Susquehanna Shale Hills Critical Zone Observatory is comprised of one first-order catchment in the Susquehanna River basin. This catchment, known as Shale Hills, is about 8 hectares in total area. The stream that defines the Shale Hills catchment flows into Shavers Creek in the Juniata River sub-basin. The vegetation cover at Shale Hills is dominated by deciduous broadleaf forest, with some evergreen needleleaf trees along the stream.

Forsythe, Brandon R.↗

AmeriFlux US-SSH Susquehanna Shale Hills Critical Zone Observatory

This is the AmeriFlux version of the carbon flux data for the site US-SSH Susquehanna Shale Hills Critical Zone Observatory. Site Description - The Susquehanna Shale Hills Critical Zone Observatory is comprised of one first-order catchment in the Susquehanna River basin. This catchment, known as Shale Hills, is about 8 hectares in total area. The stream that defines the Shale Hills catchment flows into Shavers Creek in the Juniata River sub-basin. The vegetation cover at Shale Hills is dominated by deciduous broadleaf forest, with some evergreen needleleaf trees along the stream.

Forsythe, Brandon R.↗

Ambient field seismology in critical zone hydrological sciences

Passive ambient noise monitoring is an emerging tool in environmental seismology, leveraging the ambient seismic field to assess temporal variations in shallow subsurface properties. This review focuses on the potential and challenges of using scattered coda waves from noise correlation functions to monitor critical zone dynamics. The sensitivity of seismic velocities to various environmental factors, including precipitation, snowmelt, atmospheric pressure, and groundwater fluctuations, underscores the method’s versatility. While coda waves excel in detecting subtle changes due to their scattered nature, ballistic waves provide higher spatial resolution, albeit with challenges in source stability. Advances in seismic sensing, including distributed acoustic sensing and low-cost geophone networks, have enabled high-resolution monitoring of hydrological processes, subsurface deformation, and seismic hazards. Integrating seismic data with hydrological models provides insights into water storage, pore pressure changes, and soil moisture dynamics. However, limitations in spatial resolution, calibration with ground truth data, and coupled effects between environmental factors remain key challenges. This review emphasizes the importance of interdisciplinary approaches in refining methodologies, enhancing sensor deployments, and addressing data gaps. Passive seismic monitoring offers opportunities to understand critical zone processes and their broader impacts on seismic hazards and environmental sustainability.

58 GEOSCIENCES↗

Seeing the Disturbed Forest for the Trees: Remote Sensing Is Underutilized to Quantify Critical Zone Response to Unprecedented Disturbance

Understanding the severity and extent of near surface critical zone (CZ) disturbances and their ecosystem response is a pressing concern in the face of increasing human and natural disturbances. Predicting disturbance severity and recovery in a changing climate requires comprehensive understanding of ecosystem feedbacks among vegetation and the surrounding environment, including climate, hydrology, geomorphology, and biogeochemistry. Field surveys and satellite remote sensing have limited ability to effectively capture the spatial and temporal variability of disturbance and CZ properties. Technological advances in remote sensing using new sensors and new platforms have improved observations of changes in vegetation canopy structure and productivity; however, integrating measures of forest disturbance from various sensing platforms is complex. By connecting the potential for remote sensing technologies to observe different CZ disturbance vectors, we show that lower severity disturbance and slower vegetation recovery are more difficult to quantify. Case studies in montane forests from the western United States highlight new opportunities, including evaluating post-disturbance forest recovery at multiple scales, shedding light on understory vegetation regrowth, detecting specific physiological responses, and refining ecohydrological modeling. Learning from regional CZ disturbance case studies, we propose future directions to synthesize fragmented findings with (a) new data analysis using new or existing sensors, (b) data fusion across multiple sensors and platforms, (c) increasing the value of ground-based observations, (d) disturbance modeling, and (e) synthesis to improve understanding of disturbance.

54 ENVIRONMENTAL SCIENCES↗

Distinct Depth-Discrete Profiles of Microbial Communities and Geochemical Insights in the Subsurface Critical Zone

Microbial assembly and metabolic potential in the subsurface critical zone (SCZ) are substantially impacted by subsurface geochemistry and hydrogeology, selecting for microbes distinct from those in surficial soils. In this study, we integrated metagenomics and geochemistry to elucidate how microbial composition and metabolic potential are shaped and impacted by vertical variations in geochemistry and hydrogeology in terrestrial subsurface sediment. A sediment core from an uncontaminated, pristine well at Oak Ridge Field Research Center in Oak Ridge, Tennessee, including the shallow subsurface, vadose zone, capillary fringe, and saturated zone, was used in this study. Our results showed that subsurface microbes were highly localized and that communities were rarely interconnected. Microbial community composition as well as metabolic potential in carbon and nitrogen cycling varied even over short vertical distances. Further analyses indicated a strong depth-related covariation of community composition with a subset of 12 environmental variables. An analysis of dissolved organic carbon (DOC) quality via ultrahigh resolution mass spectrometry suggested that the SCZ was generally a low-carbon environment, with the relative portion of labile DOC decreasing and that of recalcitrant DOC increasing along the depth, selecting microbes from copiotrophs to oligotrophs and also impacting the microbial metabolic potential in the carbon cycle. Our study demonstrates that sediment geochemistry and hydrogeology are vital in the selection of distinct microbial populations and metabolism in the SCZ.

59 BASIC BIOLOGICAL SCIENCES↗

Deep in the Sierra Nevada critical zone: saprock represents a large terrestrial organic carbon stock

Large uncertainty remains in the spatial distribution of deep soil organic carbon (OC) storage and how climate controls belowground OC. This research aims to quantify OC stocks, characterize soil OC age and chemical composition, and evaluate climatic impacts on OC storage from the soil surface through the deep critical zone to bedrock. These objectives were carried out at four sites along a bio-climosequence in the Sierra Nevada, California. On average, 74% of OC was stored below the A horizon, and up to 30% of OC was stored in saprock (friable weakly weathered bedrock). Radiocarbon, spectroscopic, and isotopic analyses revealed the coexistence of very old organic matter (OM) (mean radiocarbon age = 20 300 years) with relatively recent OM (mean radiocarbon age = 4800 years) and highly decomposed organic compounds with relatively less decomposed material in deep soil and saprock. This co-mingling of OM suggests OC is prone to both active cycling and long-term protection from degradation. In addition to having direct effects on OC cycling, climate indirectly controls deep OC storage through its impact on the degree of regolith weathering (e.g. thickening). Although deep OC concentrations are low relative to soil, thick saprock represents a large, previously unrealized OC pool.

58 GEOSCIENCES↗

Lead isotopic compositions of airborne particulates collected from snow and from dry deposition in the East River Watershed, Colorado and at the Southern Sierra Critical Zone Observatory, California

The data set consists of lead (Pb) isotopic ratios (206Pb/207Pb and 208Pb/207Pb, as well as 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb) for particulate samples collected from snow and dry deposition. This was part of a study (O’Day et al. 2020) that was looking at the speciation of phosphorous in splits of these samples to evaluate the flux and bio-availability of phosphorous to the mountain sites in the study. The Pb isotopic data allow sourcing of long-range transported Pb, specifically the fraction of Pb sourced in Asia, and so a comparison of the relative distances of PM sources between the high and low elevation sites. Samples were collected at the East River Watershed, CO (dry deposition collected over Sept.-Oct. 2016, show sampling winter 2017) and at the Southern Sierra Critical Zone Observatory (dry deposition collected over Sept-Nov 2016, July-Sept 2017, June-July 2017). The data includes Pb concentration data, as well as calculated fraction of the Pb sourced in Asia. This data set was published in part in O’Day et al. (2020) Phosphorus Speciation in Atmospherically Deposited Particulate Matter and Implications for Terrestrial Ecosystem Productivity. ES&T, https://dx.doi.org/10.1021/acs.est.9b06150

54 ENVIRONMENTAL SCIENCES↗

Bonneville basin critical zones: Spring chemistry and gastropod ecology in playa-margin wetlands

Playa margin wetlands in the Bonneville basin are sustained by groundwater-fed brackish springs, which transport salts and other solutes into the playa basin. These wetlands are sensitive to changing water availability and quality, which are impacted by changing climate and land use, and whose sediments also provide important records of changing environmental conditions. Gastropods building their shells in these springs provide important recorders of water chemistry and may reflect changing aqueous conditions. In this paper, we analyze spring water chemistry, gastropod ecology and gastropod shell chemistry of Blue Lake (BL) and Horseshoe Springs (HRS), two groundwater-fed wetlands in the Great Salt Lake watershed. Here, we report the physical parameters including pH, temperature, and specific conductivity across the spring pond at Horseshoe springs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Science Area 1: Standard Award: Model-Data Fusion to Examine Multiscale Dynamical Controls on Snow Cover and Critical Zone Moisture Inputs (Final Report)

In many mountain watersheds of the world, seasonal snowpacks play an important role as natural reservoirs of water. Seasonal snowpacks accumulate water during cold, wet winter months that subsequently melts. Downstream communities depend on water from melting seasonal snowpacks to support agricultural, industrial, and municipal water needs. Rapidly melting snowpacks can also present a flooding hazard, particularly if snowpacks melt at rates faster than anticipated and where adequate reservoir capacity is unavailable to buffer river flows associated with melt. The spatial and temporal dynamics of snow accumulation and melt also play an important role in supporting upland ecosystems in mountain landscapes. Snowmelt provides soil moisture that enable terrestrial ecosystem productivity and exert control on soil microorganisms that play important roles in global carbon cycles. Climate warming is gradually decreasing the amount of precipitation in mountain watersheds arriving as snow, presenting potentially profound disruptions to mountain ecosystems, as well as downstream delivery of water. The overarching goal of this project was to understand how interactions between the near-surface atmosphere and surface topography control the input, accumulation, retention, and release of water from mountain snowpacks. Over a 5-year period, this project pursued an approach combining high-resolution regional climate modeling, satellite and airborne remote sensing data, and ground-based observations to develop and analyze benchmark datasets to address overarching science questions and hypotheses. Key products include a continuous, long-term, high spatiotemporal resolution (1 km/1 hr) dataset characterizing key climate variables in the Upper Colorado River Basin. The dataset included historical estimates of precipitation, temperature, humidity, solar and longwave radiation, and wind speeds. Additionally, the project developed a 20+ year long, 30 m spatial, daily temporal multi-sensor dataset characterizing snow presence/absence in the East/Taylor River watersheds in the Central Rocky Mountains of Colorado. The project supported training of 1 postdoctoral scholar, 1 Ph.D. student, and 1 M.S. student.

54 ENVIRONMENTAL SCIENCES↗

WHONDRS Surface Water and Sediment Geochemistry and Organic Matter Characterization Data from Streams across HJ Andrews Experimental Forest, Oregon (v2)

This dataset supports a broader study developing conceptual models for river corridor critical zone processes across spatial scales and was generated in collaboration with the HJ Andrews River Corridor Critical Zone Workshop in 2025. The dataset provides surface water geochemistry (dissolved organic carbon, total dissolved nitrogen) from 48 sites across the HJ Andrews Experimental Forest, Oregon (https://andrewsforest.oregonstate.edu). Some of the sites have been impacted by the Holiday Farm Fire and the Lookout Fire in 2020 and 2023, respectively. Related data were collected as part of the workshop and will be published separately in collaboration with other workshop attendees and available at http://www.hydroshare.org/resource/b274c4a234bf4b12b7cb8a54a696c629. Related genomic data can be found on the National Center for Biotechnology Information (NCBI) under BioProject PRJNA1503030 (see critical details section below for more information). Additional related data collected in 2016 from a similar effort can be found at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/3377027 and http://www.hydroshare.org/resource/ea6c0832885a46c3939e7bb22e48e754 and are described within https://doi.org/10.5194/essd-11-1-2019 (Ward et al., 2019). This data package was originally published in March 2026. It was updated in August 2026 (v2; new and modified files). See the change history section in the readme for more details. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) a folder of field photos, (2) a folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data, (3) a data checks report, (4) a folder of sample data, (5) file-level metadata, (6) data dictionary, (7) field metadata, (8) readme, (9) international generic sample number (IGSN) mapping file; and (10) field protocol. The sample data subfolder contains surface water and sediment (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages, (2) total dissolved nitrogen data and averages, (3) methods codes, (4) FTICR-MS methods; and (5) a subfolder of 9.4 Tesla (9.4T) FTICR-MS data. This folder contains the CoreMS processed data and seven subfolders, thee containing .xml files for each sample type (sediment, surface water and blank samples), three containing the sediment CoreMS output files for each sample type (sediment, surface water and blank samples), and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .Rmd, .py, .cal, .json, .jpg, or .jpeg.

Biogeochemistry↗

Vegetation water sources in California's Sierra Nevada (USA) are young and change over time, a multi-isotope ( δ 18 O, δ 2 H, 3 H) tracer approach.

Sierra Nevada forests transpire a significant amount of California's water resources, sparking interest in applying forest management to improve California's water supply. Determining the source water of evapotranspiration enables forest managers to make informed decisions. To this end, a significant interest in critical zone science is to develop new methods to work across time scales to predict subsurface water storage and use. Here, forest vegetation accessed young water and switched sources depending on availability, suggesting that forest drought vulnerability may depend on the range of water sources available (rain, snowmelt and deeply stored water). This finding also suggests that changes in transpiration rates may have immediate effects on water sources in close proximity to vegetation, and delayed effects on storage and runoff. New δ 18 O, δ 2 H and 3 H data were used to track precipitation, runoff, evapotranspiration and storage through the critical zone seasonally, including seasons where evapotranspiration and snowmelt were in phase (winter snowmelt) and out of phase (seasonally dry summer). The main source of this headwater catchment's runoff is derived from its meadow saturated zone water, which was dominated by snowmelt. Water that originated as snowmelt contributed to transpiration, unless other sources, such as recent rain, became available. In cases where xylem δ 18 O and δ 2 H signatures matched those of deeper saturated zone water, 3 H data showed that xylem water was distinctly younger than the deep saturated zone water. During 2016, which experienced relatively normal snowpack in winter and seasonally dry summer conditions, mean summer saturated zone water and vegetation water were similar in δ 18 O, –12.4 ± 0.04 ‰ and – 12.5 ± 0.3 ‰, respectively, but were distinctly different in 3 H, 5.5 ± 0.2 pCi/L and 13.7 ± 1.1 pCi/L, respectively. While δ 18 O shows that vegetation and meadow saturated zone water have similar origins, 3 H shows they have dissimilar ages.

58 GEOSCIENCES↗

Reactive Transport Modeling of Mineral Precipitation and Carbon Trapping in Discrete Fracture Networks

In this study we use numerical experiments to analyze reactive flow and transport behavior in discrete intersecting fracture networks, focusing on (a) how reaction-induced changes in physical and chemical properties affect flow connectivity and (b) how fracture networks developed in the Earth's critical zone contribute to carbon sequestration via mineral weathering reactions. In the first part of the study, we used two-dimensional reactive flow and transport simulations to analyze the impacts of mixing in a natural discrete fracture network. We concluded that reaction-induced changes can substantially alter the flow connectivity, especially at fracture intersections. The second set of simulations considered the problem of natural weathering of fractured mafic and ultramafic rocks in the partially saturated Earth's critical zone as a function of infiltration rates, fracture permeability, and partially saturated flow parameters. As a model system, we considered an incongruent reaction network with dissolution of forsterite and precipitation of magnesite. The behavior is complex in terms of the rate-controlling processes because of the multicomponent nature of the system as shown by the grid Peclet number: the CO 2 behavior is gas diffusion-controlled in the partially saturated zone, while the rate of water flow via the Damkӧhler number controls Mg 2+ transport through the fracture network. The amounts of carbon that can be trapped are modest, but the naturally fractured domain considered here provides a useful “base case” against which various engineered solutions can be compared.

58 GEOSCIENCES↗