Materials Data on CsMnSb by Materials Project
CsMnSb is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is two-dimensional and consists of one CsMnSb sheet oriented in the (0, 0, 1) direction. Cs1+ is bonded in a 4-coordinate geometry to four equivalent Sb3- atoms. All Cs–Sb bond lengths are 3.81 Å. Mn2+ is bonded to four equivalent Sb3- atoms to form a mixture of edge and corner-sharing MnSb4 tetrahedra. All Mn–Sb bond lengths are 2.83 Å. Sb3- is bonded in a 8-coordinate geometry to four equivalent Cs1+ and four equivalent Mn2+ atoms.
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