Materials Data on Cs2SiP2 by Materials Project
(Cs)2SiP2 crystallizes in the orthorhombic Ibam space group. The structure is one-dimensional and consists of eight cesium molecules and two SiP2 ribbons oriented in the (1, 0, 0) direction. In each SiP2 ribbon, Si4- is bonded in a 4-coordinate geometry to four equivalent P1+ atoms. All Si–P bond lengths are 2.30 Å. P1+ is bonded in an L-shaped geometry to two equivalent Si4- atoms.
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