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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on CuSnF6 by Materials Project

CuSnF6 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Cu2+ is bonded to six equivalent F1- atoms to form CuF6 octahedra that share corners with six equivalent SnF6 octahedra. The corner-sharing octahedral tilt angles are 35°. All Cu–F bond lengths are 2.03 Å. Sn4+ is bonded to six equivalent F1- atoms to form SnF6 octahedra that share corners with six equivalent CuF6 octahedra. The corner-sharing octahedral tilt angles are 35°. All Sn–F bond lengths are 2.01 Å. F1- is bonded in a bent 150 degrees geometry to one Cu2+ and one Sn4+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Materials Data on CuSnF6 by Materials Project

CuSnF6 crystallizes in the triclinic P-1 space group. The structure is one-dimensional and consists of one CuSnF6 ribbon oriented in the (1, 1, 1) direction. Cu2+ is bonded in a distorted square co-planar geometry to six F1- atoms. There are a spread of Cu–F bond distances ranging from 1.93–2.70 Å. Sn4+ is bonded in a linear geometry to two equivalent F1- atoms. Both Sn–F bond lengths are 1.18 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Cu2+ atom. In the second F1- site, F1- is bonded in a 2-coordinate geometry to one Cu2+ and one Sn4+ atom. In the third F1- site, F1- is bonded in a 1-coordinate geometry to one Cu2+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on CuSn3F6 by Materials Project

Cu(SnF2)3 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one cuprum molecule and three tin difluoride molecules.

36 MATERIALS SCIENCE↗