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New prospects for PV powered water desalination plants: case studies in Saudi Arabia: New prospects for PV powered water desalination plants
Increased water demand and increased drought episodes in the Middle East and other regions necessitate an expansion in desalination projects and create a great market opportunity for photovoltaics (PV). PV-powered desalination has previously been regarded as not being a cost-competitive solution when compared with conventionally powered desalination; however, the decline in PV costs over the last few years has changed this outlook. Here, this article presents up-to-date performance and cost analysis of reverse osmosis (RO) desalination powered with PV connected to the Saudi Arabian grid. Reference cases include relatively small (i.e., producing 6550 m 3 water per day) and large (i.e., 190 000 m 3 /day) desalination plants using seawater at a salinity of 40 000 ppm. We used data from a King Abdullah University for Science and Technology presentation and Hybrid Optimization Model for Electric Renewables 2.81 Energy Modeling Software (HOMER Energy LLC) in tandem with Desalination Economic Evaluation Program 4.0 (International Atomic Energy Agency) desalination software to analyze the techno-economic feasibility of these plants. The first phase of our work entailed a comparison between dual-axis high concentration PV (CPV) equipped with triple junction III/V solar cells and CdTe PV-powered RO systems. The estimated levelized cost of electricity from CPV is 0.16/kWh dollars, whereas that from CdTe PV is $0.10/kWh dollars and 0.09/kWh dollars for fixed-tilt and one-axis tracking systems, respectively. These costs are higher than the price of diesel-based grid electricity in the region because diesel fuel is heavily subsidized in Saudi Arabia.
Looking Beyond Energy Efficiency: An Applied Review of Water Desalination Technologies and an Introduction to Capillary-Driven Desalination
Most notable emerging water desalination technologies and related publications, as examined by the authors, investigate opportunities to increase energy efficiency of the process. In this paper, the authors reason that improving energy efficiency is only one route to produce more cost-effective potable water with fewer emissions. In fact, the grade of energy that is used to desalinate water plays an equally important role in its economic viability and overall emission reduction. This paper provides a critical review of desalination strategies with emphasis on means of using low-grade energy rather than solely focusing on reaching the thermodynamic energy limit. Herein, it is argued that large-scale commercial desalination technologies have by-and-large reached their engineering potential. They are now mostly limited by the fundamental process design rather than process optimization, which has very limited room for improvement without foundational change to the process itself. The conventional approach toward more energy efficient water desalination is to shift from thermal technologies to reverse osmosis (RO). However, RO suffers from three fundamental issues: (1) it is very sensitive to high-salinity water, (2) it is not suitable for zero liquid discharge and is therefore environmentally challenging, and (3) it is not compatible with low-grade energy. From extensive research and review of existing commercial and lab-scale technologies, the authors propose that a fundamental shift is needed to make water desalination more affordable and economical. Future directions may include novel ideas such as taking advantage of energy localization, surficial/interfacial evaporation, and capillary action. Here, some emerging technologies are discussed along with the viability of incorporating low-grade energy and its economic consequences. Finally, a new process is discussed and characterized for water desalination driven by capillary action. The latter has great significance for using low-grade energy and its substantial potential to generate salinity/blue energy.
Conducting thermal energy to the membrane/water interface for the enhanced desalination of hypersaline brines using membrane distillation
Membrane distillation (MD) is a membrane-based thermal desalination process capable of treating hypersaline brines. Standard MD systems rely on preheating the feed to drive the desalination process. However, relying on the feed to carry thermal energy is limited by a decline of the thermal driving force as the water moves across the membrane, and temperature polarization. In contrast, supplying heat directly into the feed channel, either through the membrane or other channel surfaces, has the potential of minimizing temperature polarization, increasing single-pass water recoveries, and decreasing the number of heat exchangers in the system. When solar thermal energy can be utilized, particularly if the solar heat is optimally delivered to enhance water evaporation and process performance, MD processes can potentially be improved in terms of energy efficiency, environmental sustainability, or operating costs. Here we describe an MD process using layered composite membranes that include a high-thermal-conductivity layer for supplying heat directly to the membrane-water interface and the flow channel. Here, the MD system showed stable performance with water flux up to 9 L/m 2 /hr, and salt rejection >99.9% over hours of desalinating hypersaline feed (100 g/L NaCl). In addition to bench-scale system, we developed a computational fluid dynamics model that successfully described the transport phenomena in the system.
Desalinating a Real Hyper-Saline Pre-Treated Produced Water via Direct-Heat Vacuum Membrane Distillation
Membrane distillation (MD) is an emerging thermal desalination technology capable of desalinating waters of any salinity. During typical MD processes, the saline feedwater is heated and acts as the thermal energy carrier; however, temperature polarization (as well as thermal energy loss) contributes to low distillate fluxes, low single-pass water recovery and poor thermal efficiency. An alternative approach is to integrate an extra thermal energy carrier as part of the membrane and/or module assembly, which can channel externally provided heat directly to the membrane-feedwater interface and/or along the feed channel length. This direct-heat delivery has been demonstrated to increase single-pass water recovery and enhance the overall thermal efficiency. We developed a bench-scale direct-heated vacuum MD (DHVMD) process to desalinate pre-treated oil and gas "produced water" with an initial total dissolved solids of 115,500 ppm at a feed temperature ranging between 24 and 32 degrees C. We evaluated both water flux and specific energy consumption (SEC) as a function of water recovery. The system achieved a 50% water recovery without significant scaling, with an average flux >6 kg m-2 hr-1 and a SEC as low as 2,530 kJ kg-1. The major species of mineral scales (i.e., NaCl, CaSO4, and SrSO4) that limited the water recovery to 68% were modeled in terms of thermodynamics and identified by scanning electron microscopy and energy-dispersive X-ray spectroscopy. In addition, we further developed and employed a physics-based process model to estimate temperature, salinity, water transport and energy flows for full-scale vacuum MD and DHVMD modules. Model results show that a direct-heat input rate of 3,600 W can increase single-pass water recovery from 2.1% to 3.1% while lowering the thermal SEC from 7,800 kJ kg-1 to 6,517 kJ kg-1 in an unoptimized module. Finally, the scaling up potential of DHVMD process is briefly discussed.
Uranium Resource Recovery from Desalination Plant Feed and Reject Water Using Amidoxime Functionalized Adsorbent
With global demand for nuclear power expected to rise, new nuclear fuel resources must be explored to ensure the viability and sustainability of nuclear power. Uranium recovery from seawater is one potential source, though the low concentration of uranium in seawater is a significant obstacle. As a concentrate of seawater, desalination brine reject would have a significantly higher uranyl concentration. In this work, the adsorption of uranium and competing ions in brine reject is investigated. Adsorption experiments were performed over 84 days in 5-gallon batch tanks with amidoxime adsorbents and samples taken from the feed seawater and reverse osmosis brine reject of the Tampa Bay Desalination Plant. The aqueous concentration and adsorbed mass of uranium, zinc, copper, iron, vanadium, calcium, and magnesium were determined through inductively coupled plasma mass spectroscopy. Aqueous adsorption modeling was used to simulate speciation and adsorption of these ions under the experimental conditions. The adsorbed mass of uranium in seawater was 6.22 mg/g adsorbent which declined to 3.95 mg/g in brine. This is a result of increased competition from iron and vanadium whose adsorbed masses increased from 1.06 to 3.00 mg/g and 1.05 to 2.67 mg/g, respectively. Good agreement between experimental and predicted results was obtained for all ions in seawater. Uranium adsorption was overpredicted in brine which may be attributed to the presence of other competing ions and the system not being at equilibrium. Furthermore, results demonstrate that the influence of competing ions, such as those of iron and vanadium, on uranium adsorption would need to be reduced for brine reject to become a significant uranium resource.
Mineral Recovery Enhanced Desalination (MRED) process: An innovative technology for desalinating hard brackish water
Desalination of water containing high concentrations of calcium, dissolved carbon dioxide, sulfate, silica and other sparingly soluble salts is difficult because of the scaling potential. An innovative pre-treatment scheme was investigated at bench scale that selectively removes these constituents and produces a soft water to enable desalination with high feed water recovery. The process first removes dissolved carbon dioxide by air stripping at low pH. Magnesium is removed by precipitation at high pH. Calcium is removed by ion exchange (IX), and sulfate is removed by nanofiltration (NF). Cation regenerant from IX, containing calcium, and concentrate from NF, containing sulfate, is combined to precipitate gypsum. Concentrate from the desalination process consisting of a concentrated NaCl solution is used to regenerate the IX resins. The selective precipitation, IX, and NF processes were tested in laboratory experiments and produced magnesium hydroxide and gypsum at greater than 90% and 95% purity respectively. A process model was developed to calculate process performance, mass and liquid flow rates. Finally, the MRED process offers the following benefits: 1) greater recovery of brackish feedwater by a desalination process, 2) recovery of marketable commodities and 3) reduction in the volume and mass of waste products from the treatment process.
Unconventional desalination: The use of cyclone separators in HDH desalination to achieve zero liquid discharge
Research in water desalination technologies is constantly growing to meet global demands for freshwater. Though acting to meet these demands, the rapid growth and spread of desalination technologies poses environmental issues due to the increasing brine concentrates that are ultimately discharged back to nature. This article presents a cyclone separator to transform a humidification-dehumidification (HDH) cycle to a dual-product cycle to produce freshwater and solid salt crystals for highly saline streams. A desalination cycle equipped with a cyclone separator is used to treat water with 3.5%–81% salinity. The separation efficiency is well above 99% and can produce potable water from hyper saline feed in a once-through process. Further, the cyclone separator performance was tested under different conditions including humidity ratios, relative humidities, and feed stream's salinities. The cyclone separator is self-cleaning and overcomes salt scaling. This behavior is a direct function of the walls' temperature and the carrier air dew point. Self-cleaning capability allows the cyclone separator to treat feed water of extreme salinities (up to 810,000ppm) down to freshwater salinity with zero liquid discharge. The cyclone separator was utilized in a novel HDH desalination technology to treat different salinities. The product was freshwater of salinity <500ppm.
Utilizing waste heat in wastewater treatment plants for water desalination: Modeling and Multi-Objective optimization of a Multi-Effect desalination system using Decision Tree Regression and Pelican optimization algorithm
This paper examines the feasibility of using waste heat from wastewater treatment plants (WWTPs) for water desalination. A model was developed to utilize waste heat from the gensets at As Samra WWTP in Jordan, using real data and TRNSYS® software to calculate available waste heat. The desalination process was then modeled with ASPEN PLUS® software, focusing on multi-effect desalination (MED). Both series and parallel configurations for the MED system were compared. The study investigated the effects of system feeding flow rate, feeding pressure, and heat input on productivity, performance ratio, and recovery ratio. The study also introduces a novel optimization technique combining machine learning and modern optimization algorithms to maximize system productivity and performance. Initially, a decision tree regression (DTR) model is developed to establish relationships between key independent variables (flow rate, feed pressure, and heat input) and dependent variables (productivity, performance ratio, and recovery ratio). The Pelican Optimization Algorithm (POA) is then used to identify the optimal values of the independent variables for maximum productivity and performance. The results show that using a series configuration yields a system productivity of 3984.2 kg/hr, a performance ratio of 3.78, and a recovery ratio of 0.991 at a feed flow rate of 4000 kg/hr, feed pressure of 3 bars, and heat input of 719 kW. Optimal productivity (4421 kg/hr), performance ratio (3.81), and recovery ratio (0.851) are achieved at a feed flow rate of 5166 kg/hr, feed pressure of 3.2 bars, and heat input of 794 kW. In conclusion, the techno-economic assessment indicates a levelized cost of water of 1.63 USD/m 3 for parallel configurations and 1.65 USD/m 3 for series configurations, with a payback period of less than two years.
Mapping of a Novel Zero-Liquid Discharge Desalination System Based on Humidification–Dehumidification onto the Field of Existing Desalination Technologies
It is well-established that increasing demands for fresh water are paving the way for desalination technologies. However, this correlates with an increase in brine production whose treatment and disposal can be complicated and expensive. This paper presents a thermodynamic model to bound the operation and development of a novel Humidification–Dehumidification-based system featuring Zero-Liquid Discharge and off-grid capabilities. The model employs conservation laws to find feasible state points to meet a baseline operation of 10 kg/h of product water separated from a hypersaline feed stream with 100 g/kg salt concentration. The system incurs in a 1039 kWh/m3 energy intensity that can be supplied completely by an electric source or in combination with heating steam. Follow-up sensitivity analysis highlights the robustness of the system in handling variations of 25% in product flowrate and 75% in feed salinity, practically without incurring any additional energy demands. The proposed system operating costs between 72 USD/m3 and 96 USD/m3 are comparable to those of existing brine disposal techniques. Furthermore, an operational map of existing desalination technologies suggests a niche characterized by high recovery rates and high feed salinities that are generally unfulfilled by conventional desalination methods. Overall, the proposed system shows potential for off-grid hypersaline brine treatment. This study sets the stage for future development of physics-based and data-driven predictive models as the proposed system iterates into a pilot plant deployment.
Delivery of a Solar-Powered Forward Osmosis Seawater Desalination Plant: Trevi’s 500 m3/day Zero-Carbon FO Seawater Desalination Plant at NELHA
This paper presents an account of Trevi’s delivery of a 500 m3/day solar powered forward osmosis (FO) seawater desalination plant at the Ocean Science and Technology Park of the Natural Energy Laboratory of Hawaii Authority (NELHA). The project aimed to demonstrate the viability of solar thermal-powered desalination for agricultural applications through the integration of a 2MW micro-dish solar thermal array with a state-of-the-art FO system. Highlighted in the paper are the three distinct project phases; Planning and Design, System Construction, Installation & Testing followed finally by System Operation and Optimization. Results and decisions which led to the final plant design will be shared, highlighting how Trevi Systems succeeded in producing a zero-carbon FO seawater desalination plant with a projected Levelized Cost of Water (LCOW) estimate competitive with existing carbon-intensive RO technologies (based on some assumptions and the cost of heat which is required for FO.
Energy efficient supercritical water desalination using a high-temperature heat pump: A zero liquid discharge desalination
Supercritical water desalination (SCWD) is zero liquid discharge technology that can potentially control the solubility of different electrolytes. However, SCWD is an energy-intensive process and requires high-quality thermal heat (> 450 °C). This study proposes the integration of a high-temperature heat pump to reduce the SCWD energy requirement. The integrated system energy consumption improves by 36% for 3.5% feed concentration and 14% for 20% feed, and the distillate cost reduces by 15% and 10%. Another benefit of the proposed integration is the system can be operated using only electricity as a heat source, as is the case with commonly used high-recovery thermal desalination technology. The integrated SCWD-heat pump system shows superior performance compared to the commercially used brine concentrator and crystallizer system. It is approximately 20% more energy-efficient for 25% feed concentration and 8% cheaper. Hence, the integrated SCWD-heat pump has the potential to outperform the pre-existing high-recovery desalination technology.
Optimal design of multi-stage vacuum membrane distillation and integration with supercritical water desalination for improved zero liquid discharge desalination
Herein this paper proposes a novel concept for the optimal design of multi-stage vacuum membrane distillation (VMD). Generally, a multi-stage VMD is designed with an equal temperature difference between each stage. However, such a design is energy inefficient and increases VMD area. An analytical methodology for calculating the optimal stage temperature is proposed. By selecting the optimal stage temperature, the energy efficiency and required membrane area can be potentially improved by 16% and 30%, respectively. The proposed concept applies to all heat sources, including latent, sensible, and waste heat. To illustrate the method, multi-stage VMD is integrated with the waste heat from a supercritical water desalination (SCWD) system to achieve zero liquid discharge. SCWD is an energy-intensive process, requires high-quality thermal heat (>450 °C), and exhibits high waste heat rejection. The integrated VMD-SCWD approach is approximately 50% more energy-efficient and 35% more cost-efficient than the standalone SCWD system. Compared to the commercially used brine concentrator and crystallizer, the multi-stage VMD-SCWD system is more energy efficient for feed concentrations >5%. VMD-SCWD system is 30% cheaper, due to less expensive membrane distillation modules compared to a brine concentrator. The proposed design concept can replace the brine concentrator and crystallizer as an improved alternative for a zero-liquid discharge desalination system.
A salt-rejecting floating solar still for low-cost desalination
A floating, low-cost solar desalination system was constructed, capable of simultaneous salt rejection and heat localization for continuous operation.