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DNC Simulation Results and Risk Assessment

The performance of Dynamic Natural Circulation (DNC) systems during a station blackout in a pressurizer water reactor was evaluated. Thermal-hydraulic calculations of a PWR with passive DNC systems were performed using RELAP5-3D. The effects of the DNC systems on the cumulative core damage frequency during a station blackout was evaluated using probabilistic and risk assessment methods.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

ALMA observations of the IRDC clump G34.43+00.24 MM3: DNC/HNC ratio

We have observed the clump G34.43+00.24 MM3 associated with an infrared dark cloud in DNC J = 3–2, HN{sup 13}C J = 3–2, and N{sub 2}H{sup +} J = 3–2 with the Atacama Large Millimeter/submillimeter Array (ALMA). The N{sub 2}H{sup +} emission is found to be relatively weak near the hot core and the outflows, and its distribution is clearly anti-correlated with the CS emission. This result indicates that a young outflow is interacting with cold ambient gas. The HN{sup 13}C emission is compact and mostly emanates from the hot core, whereas the DNC emission is extended around the hot core. Thus, the DNC and HN{sup 13}C emission traces warm regions near the protostar differently. The DNC emission is stronger than the HN{sup 13}C emission toward most parts of this clump. The DNC/HNC abundance ratio averaged within a 15{sup ′′} × 15{sup ′′} area around the phase center is higher than 0.06. This ratio is much higher than the value obtained by the previous single-dish observations of DNC and HN{sup 13}C J = 1–0 (∼0.003). It seems likely that the DNC and HNC emission observed with the single-dish telescope traces lower density envelopes, while that observed with ALMA traces higher density and highly deuterated regions. We have compared the observational results with chemical-model results in order to investigate the behavior of DNC and HNC in the dense cores. Taking these results into account, we suggest that the low DNC/HNC ratio in the high-mass sources obtained by the single-dish observations are at least partly due to the low filling factor of the high density regions.

79 ASTRONOMY AND ASTROPHYSICS↗

Risk-Informed Analysis for an Enhanced Resilient PWR with ATF, FLEX, and Passive Cooling

This report documents the activities performed by Idaho National Laboratory (INL) during the fiscal year (FY) 2019 for the DOE Light Water Reactor Sustainability (LWRS) Program, Risk-Informed System Analysis (RISA) Pathway, Enhanced Resilient Plant (ERP) Systems research. The purpose of the RISA Pathway research and development is to support plant owner-operator decisions with the aim to improve the economics, reliability, and maintain the high levels of safety of current nuclear power plants over periods of extended plant operations. The concept of ERP refers to the combinations of Accident Tolerant Fuel (ATF), optimal use of Diverse and Flexible Coping Strategy (FLEX), enhancements to plant components and systems, and the incorporation of augmented or new passive cooling systems, as well as improved fuel cycle efficiency. The objective of the ERP research effort is to use the RISA methods and toolkit in industry applications, including methods development and early demonstration of technologies, in order to enhance existing reactors safety features (both active and passive) and to substantially reduce operating costs through risk-informed approaches to plant design modifications to the plant and their characterization. The FY 2019 efforts documented in this report is an extension of those conducted in FY 2018. The same analysis process, risk analysis approaches, and analysis tools as in FY 2018 are used for near-term ATF cladding [i.e., Iron-Chromium-Aluminum (FeCrAl) cladding and Chromium (Cr) coated cladding] designs under the postulated loss of feedwater (LOFW) and steam generator tube rupture (SGTR) accident scenarios. In addition, FLEX analysis was presented for an overview of FLEX equipment and strategies implemented in nuclear industry after Fukushima accident. A FLEX model was developed and incorporated into the generic SAPHIRE model to assess the risk impact from FLEX. FLEX HRA analysis was performed which suggested an approach to HRA with FLEX strategies. Passive cooling system analysis includes an overview of the DNC system, the RELAP5-3D simulations of the DNC system in selected SBO scenarios, and the evaluation of the DNC system risk impact using the generic PRA model.

99 GENERAL AND MISCELLANEOUS↗

Crystal structure of nicarbazin, (C 13 H 10 N 4 O 5 )(C 6 H 8 N 2 O)

The crystal structure of nicarbazin has been solved and refined using synchrotron X-ray powder diffraction data and optimized using density functional theory techniques. Nicarbazin is a co-crystal of 4,4′-dinitrocarbanilide (DNC) and 2-hydroxy-4,6-dimethylpyrimidine (HDP) molecules. Nicarbazin crystallizes in space groupP-1(#2) witha= 6.90659(8),b= 12.0794(4),c= 13.5040(7) Å,α= 115.5709(11),β= 102.3658(6),γ= 91.9270(4)°,V= 982.466(5) Å 3 , andZ= 2. The DNC and HDP molecules are linked by two strong N–H⋯O and N–H⋯N hydrogen bonds, and the HDP molecules are linked into centrosymmetric dimers by another N–H⋯O hydrogen bond. These strong hydrogen bonds link the molecules into layers parallel to theab-plane and parallel stacking of both DNC and HDP molecules is prominent in the structure. The powder pattern has been submitted to ICDD for inclusion in the Powder Diffraction File™ (PDF®).

Materials Science↗

Evaluation of Digital Nautical Chart data for confirmation and expansion of GeoNames data

Here, this work examines how Digital Nautical Chart (DNC) data may contribute to the evolution and refinement of GeoNames data for near-shore features. GeoNames features are point data with one or more possible place names. DNC Earth Cover Text (ECRText) objects are map labels positioned nearby their real word counterpart. ECRText feature map position strikes a compromise between association with real features and cartographic readability. This work explores whether ECRText features can confirm (or expand names for) existing locations or contribute new locations through data conflation. Due to name variations and spatial position, conflating these data are nontrivial. Previous work engaged in a brief examination using the trigram string matching algorithm under coarse proximity constraints, indicating that ECRText could provide additional value to GeoNames. This work builds on that study, by engaging in a deeper examination of spatial proximity and exploring conflation agreement across an ensemble of string matching approaches. The result finds strong ensemble agreement about ECRText features which already exist in GeoNames but mixed results about which features contribute new information, as well as exploring why some of these matching techniques fail. With an eye toward automation, computational efficiency was found not to be a constraint in sustaining updates.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Astrochemical Properties of Planck Cold Clumps

We observed 13 Planck cold clumps with the James Clerk Maxwell Telescope/SCUBA-2 and with the Nobeyama 45 m radio telescope. The N{sub 2}H{sup +} distribution obtained with the Nobeyama telescope is quite similar to SCUBA-2 dust distribution. The 82 GHz HC{sub 3}N, 82 GHz CCS, and 94 GHz CCS emission are often distributed differently with respect to the N{sub 2}H{sup +} emission. The CCS emission, which is known to be abundant in starless molecular cloud cores, is often very clumpy in the observed targets. We made deep single-pointing observations in DNC, HN{sup 13}C, N{sub 2}D{sup +}, and cyclic-C{sub 3}H{sub 2} toward nine clumps. The detection rate of N{sub 2}D{sup +} is 50%. Furthermore, we observed the NH{sub 3} emission toward 15 Planck cold clumps to estimate the kinetic temperature, and confirmed that most targets are cold (≲20 K). In two of the starless clumps we observed, the CCS emission is distributed as it surrounds the N{sub 2}H{sup +} core (chemically evolved gas), which resembles the case of L1544, a prestellar core showing collapse. In addition, we detected both DNC and N{sub 2}D{sup +}. These two clumps are most likely on the verge of star formation. We introduce the chemical evolution factor (CEF) for starless cores to describe the chemical evolutionary stage, and analyze the observed Planck cold clumps.

79 ASTRONOMY AND ASTROPHYSICS↗

A system for the measurement of delayed neutrons and gammas from special nuclear materials

The delayed neutron counting (DNC) system at the Royal Military College of Canada has been upgraded to accommodate concurrent delayed neutron and gamma measurements. This delayed neutron and gamma counting (DNGC) system uses a SLOWPOKE-2 reactor to irradiate fissile materials before their transfer to a counting arrangement consisting of six ³He and one HPGe detector. The application of this system is demonstrated in an example where delayed neutron and gamma emissions are used in complement to examine ²³³U content and determine fissile mass with an average relative error and accuracy of -2.2 and 1.5 %, respectively.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Nonthermal Plasma-Synthesized Phosphorus–Boron co-Doped Si Nanocrystals: A New Approach to Nontoxic NIR-Emitters

We report on the successful creation of nonthermal plasma-synthesized phorphorus and boron co-doped Si nanocrystals (PB:Si NCs) with diameters ( D NC ) ranging from 2.9 to 7.3 nm. Peak photoluminescence (PL) emission energies for all PB:Si NC diameters are ca. 400-500 meV lower than the excitonic emission values in intrinsic Si NCs, which can be attributed to prevalent donor-acceptor (D-A) transitions within the co-doped system. This D-A transition model is further evidenced by PL lifetimes within the range of 40-80 us, faster than what is observed for intrinsic Si NCs. By reducing the level of confinement within PB:Si NCs (i.e., D NC > 4 nm), we are able to red-shift the near-infrared (NIR)-emitting D-A transitions to below the band gap of bulk Si (1.12 eV). We quantify the PL quantum yield (PLQY) for a range of DNC and show that the plasma method can achieve reasonably high PLQY values (12% for D NC = 2.9 nm), even without any optimization of the synthesis or surface chemistry. We posit that perfect charge compensation cannot explain these results and propose a model in which dominant n-type doping accounts for the observations. Furthermore, these results demonstrate that nonthermal plasma synthesis is a viable pathway for preparing PB:Si NCs featuring NIR sub-band gap D-A transitions with relatively high quantum yields. More generally, this study provides insight into how doping affects energy and charge transfer within quantum-confined systems.

36 MATERIALS SCIENCE↗

Very large array observations of ammonia in high-mass star formation regions

We report systematic mapping observations of the NH{sub 3} (1, 1) and (2, 2) inversion lines toward 62 high-mass star-forming regions using the Very Large Array (VLA) in its D and DnC array configurations. The VLA images cover a spatial dynamic range from 40'' to 3'', allowing us to trace gas kinematics from ∼1 pc scales to ≲0.1 pc scales. Based on the NH{sub 3} morphology and the infrared nebulosity on 1 pc scales, we categorize three subclasses in the sample: filaments, hot cores, and NH{sub 3}-dispersed sources. The ubiquitous gas filaments found on 1 pc scales have a typical width of ∼0.1 pc and often contain regularly spaced fragments along the major axis. The spacing of the fragments and the column densities is consistent with the turbulent supported fragmentation of cylinders. Several sources show multiple filaments that converge toward a center where the velocity field in the filaments is consistent with gas flows. We derive rotational temperature maps for the entire sample. For the three hot core sources, we find a projected radial temperature distribution that is best fit by power-law indices from –0.18 to –0.35. We identify 174 velocity-coherent ∼0.1 pc scale dense cores from the entire sample. The mean physical properties for these cores are 1.1 km s{sup –1} in intrinsic linewidth, 18 K in NH{sub 3} rotational temperature, 2.3 × 10{sup 15} cm{sup –2} in NH{sub 3} gas column density, and 67 M{sub ☉} in molecular mass. The dense cores identified from the filamentary sources are closer to being virialized. Dense cores in the other two categories of sources appear to be dynamically unstable.

79 ASTRONOMY AND ASTROPHYSICS↗

FLICKERING OF 1.3 cm SOURCES IN SGR B2: TOWARD A SOLUTION TO THE ULTRACOMPACT H II REGION LIFETIME PROBLEM

Accretion flows onto massive stars must transfer mass so quickly that they are themselves gravitationally unstable, forming dense clumps and filaments. These density perturbations interact with young massive stars, emitting ionizing radiation, alternately exposing and confining their H II regions. As a result, the H II regions are predicted to flicker in flux density over periods of decades to centuries rather than increase monotonically in size as predicted by simple Spitzer solutions. We have recently observed the Sgr B2 region at 1.3 cm with the Very Large Array in its three hybrid configurations (DnC, CnB, and BnA) at a resolution of ∼0.''25. These observations were made to compare in detail with matched continuum observations from 1989. At 0.''25 resolution, Sgr B2 contains 41 ultracompact (UC) H II regions, 6 of which are hypercompact. The new observations of Sgr B2 allow comparison of relative peak flux densities for the H II regions in Sgr B2 over a 23 year time baseline (1989-2012) in one of the most source-rich massive star forming regions in the Milky Way. The new 1.3 cm continuum images indicate that four of the 41 UC H II regions exhibit significant changes in their peak flux density, with one source (K3) dropping in peak flux density, and the other three sources (F10.303, F1, and F3) increasing in peak flux density. The results are consistent with statistical predictions from simulations of high mass star formation, suggesting that they offer a solution to the lifetime problem for UC H II regions.

79 ASTRONOMY AND ASTROPHYSICS↗

Evaluation of the Benefits of ATF, FLEX, and Passive Cooling System for an Enhanced Resilient PWR Model

This report, along with report INL/EXT-19-53556, documents the activities performed by Idaho National Laboratory (INL) during the fiscal year (FY) 2019 for the DOE Light Water Reactor Sustainability (LWRS) Program, Risk-Informed System Analysis (RISA) Pathway, Enhanced Resilient Plant (ERP) Systems research. This report includes additional accident scenarios for risk-informed ATF analysis, and examines the risk impacts of FLEX and passive cooling system on nuclear power plants (NPPs) from additional perspectives. The same analysis process, risk analysis approaches, and analysis tools as in FY 2018 were used for near-term ATF cladding (i.e., Iron-Chromium-Aluminum [FeCrAl] cladding and Chromium [Cr]-coated cladding) designs under the small break loss-of-coolant accident (SBLOCA) scenarios, two types of general transient scenarios (locked rotor and turbine trip), and main steam line break (MSLB) scenarios. Benchmark calculations for ATF analysis using RELAP5-3D and MELCOR are also presented. In addition, based on the generic probabilistic risk assessment (PRA) model, the risk impacts of FLEX and the dynamic natural convection (DNC) system on NPPs are evaluated through a risk-informed decision-making process, i.e., significance determination process (SDP).

99 GENERAL AND MISCELLANEOUS↗