Search NASA⌕ Search

SEARCH · Search NASA

Results for “Dark I–V”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records

Tetracene Functionalized Si(111) Achieves Enhanced Solar-to-Chemical Energy Conversion via Molecular Acceptor States

The properties of semiconductor|liquid interfaces play a critical role in determining the efficiency of solar-to-hydrogen (STH) conversion. Here, we investigate how molecular functionalization of Si(111) and Si(111)|TiO 2 surfaces impacts photoelectrochemical (PEC) hydrogen production efficiency. We find that functionalization of ∼3% of the atop sites of Si(111) with either 9-anthracene (Anth) or 5-tetracene (Tet), with the remaining sites passivated by methyl groups, provides substrates with high electronic quality and low surface oxide densities, as determined by X-ray photoelectron spectroscopy (XPS) measurements. Surface photovoltage (SPV) spectroscopy shows that surfaces modified with Anth or Tet exhibit an increased photovoltage, with Tet-functionalized surfaces yielding an additional 192 meV relative to methyl-terminated Si(111), indicating improved charge separation for Si-Tet. Further improvement in onset potential was achieved by replacing a nitrogen-containing TiO 2 atomic layer deposition (ALD) precursor (TDMAT) with a precursor lacking nitrogen (TTIP), which eliminates the parasitic defect band in the TiO 2 overlayer (p-Si(111)-Tet|TTIP-TiO 2 |Pt: V OC = +0.283 ± 0.041 V vs RHE). Density functional theory (DFT) analysis demonstrates that compared with Anth-modified Si(111), the Tet-modified surface exhibits more hybridized Si(111)-Tet states closer to the silicon band edges. Mercury contact current–voltage (I–V, dark) measurements quantified the relative interfacial density of states of Si-Tet, Si-Anth and Si-Me surfaces─revealing that the interfacial state density was highest for Si-Tet. This suggests that such hybridized interfaces serve to capture better photoexcited charge, which enables facile electron transfer to molecular acceptors in solution. Altogether, the data indicate that beneficial hybrid molecular LUMO surface states interacting with the Si conduction band edge results in improved hydrogen evolution (HER) performance for p-Si devices.

Group theory↗

High-resolution rovibrational spectroscopy of trans -formic acid in the v 1 OH stretching fundamental: Dark state coupling and evidence for charge delocalization dynamics

High-resolution infrared (IR) reduced-Doppler absorption spectra of jet-cooled gas phase trans-formic acid in the v 1 OH stretching fundamental region are reported for the first time, obtained by supersonically expanding trans- formic acid/Ar mixtures through a slit jet nozzle source and rotationally cooling to T rot ≈ 10.9(5) K, with ab- sorption signals recorded by high-resolution difference-frequency IR absorption spectroscopy. Two a/b-type rovibrational bands of comparable intensity, one ~10-fold weaker b-type band, and one ~6-fold weaker a-type band are observed, with vibrational band origins at 3570.493(5), 3566.793(5), 3560.032(9), and 3534.6869(2) cm –1 , respectively. Based on previous Raman jet spectroscopic work by Nejad and Sibert [A. Nejad, E.L. Sibert III, The Raman jet spectrum of trans-formic acid and its deuterated isotopologs: Combining theory and experi- ment to extend the vibrational database, J. Chem. Phys. 154(6) (2021) 064301.], these four rovibrational bands have been assigned to v 1 , (v 2 + v 7 ), (v 6 + 2v 7 + 2v 9 ), and 2v 3 , respectively. Specifically, two of the three upper dark states (2 1 7 1 (a') and 6 1 7 2 9 2 (a')) are close enough to the “bright” 1 1 (a') state to facilitate strong anharmonic resonance interactions, which results in intensity mixing into the two zero-order bands that would otherwise be “dark”. Furthermore, our high-resolution spectral analysis reveals that there are local rotational crossings be- tween these zero-order 1 1 and 2 1 7 1 states resulting in extra lines (i.e., some upper levels in the nominally v 1 band have majority zero-order 2 1 7 1 state character). This motivates development of a 3 coupled state (1 1 , 2 1 7 1 , and 6 1 7 2 9 2 ) picture to aid in the spectral analysis, which is able to match all 3 observed band origins and relative band intensities, as well as indicate the necessity of multistate (> 2) coupling. Though limited by range of J and Ka levels (J’ ≤ 9 and K a ’ ≤ 3) populated at supersonic jet temperatures, this work offers first precision spec- troscopic analysis of trans-formic acid in the v 1 OH stretch region, which should aid in assignment of the more complete yet highly congested room temperature FTIR spectra. Lastly, and in sharp contrast to the spectral complexity in the three predominantly b-type bands, the lone a-type 2v 3 rovibrational band at 3534.6869(2) cm –1 is well described by a simple, rigid asymmetric top Hamiltonian.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Long-lived vectors from electromagnetic cascades at SHiP

We simulate dark-vector, V, production from electromagnetic cascades at the recently approved SHiP experiment. The cascades (initiated by photons from π$^{0}$ → γγ) can lead to 3–4 orders of magnitude increase of the event rate relative to using primary production alone. We provide new SHiP sensitivity projections for dark photons and electrophilic gauge bosons, which are significantly improved compared to previous literature. The main gain in sensitivity occurs for long-lived dark vectors with masses below ~ 50 − 300 MeV. The dominant production mode in this parameter space is low-energy annihilation e$^{+}$e$^{−}$ → V (γ). This motivates a detailed study of backgrounds and efficiencies in the SHiP experiment for sub-GeV signals.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Limits on an exotic Higgs decay from a recast ATLAS four-lepton analysis

The ATLAS collaboration, using 139 fb −1 of 13 TeV collisions from the Large Hadron Collider, has placed limits on the decay of a Z boson to three dark photons. We reproduce the results of the ATLAS analysis, and then recast it as a limit on a exotic Higgs decay mode, in which the Higgs boson decays via a pair of intermediate (pseudo)scalars a to four dark photons V (or some other spin-one meson). Across the mass range for m a and m V , we find limits on the exotic Higgs branching fraction BR(H → aa → V V V V ) in the range of 4 × 10 −5 to 1 × 10 −4 .

Higgs properties↗

Cell dark current–voltage from non-calibrated module electroluminescence image analysis

Here, we present a fast, accurate, and reliable method of obtaining cell dark current–voltage (I–V) curves from module electroluminescence (EL) images without requiring calibration or correction. For a pristine module, EL-derived dark I–V are compared to directly probed data for a variety of changing imaging parameters: camera sensor, lens, filter, aperture width, exposure time (level of sensor saturation), number of images used, and various combinations of these. Pristine modules and those experiencing different modes and degrees of degradation are examined. A recent study of modules using five different cell technologies demonstrates the practicality of our “EL sweep” technique for performance and degradation studies.

14 SOLAR ENERGY↗

Field‐representative evaluation of PID‐polarization in TOPCon PV modules by accelerated stress testing

Abstract Potential‐induced degradation‐polarization (PID‐p) can reduce module power, but how to project the extent to which PID‐p may occur in field conditions considering the factors of system voltage, condensed moisture, temperature, and illumination has not been clarified. Using tunnel oxide passivated contact (TOPCon) modules, this work demonstrates a method to test full‐size crystalline silicon PV modules for PID‐p to provide field‐representative results. In initial screening tests with positive or negative 1000 V electrical bias applied at 60°C for 96 h using Al foil electrodes on the glass surfaces, the module type exhibited reversible PID‐p only on the front face when the cell circuit was in negative voltage potential. No PID was detected on the rear after testing in either polarity. We then evaluated the PID‐p sensitivity on the front side under different UV irradiances while maintaining the glass surface wet to estimate real‐world susceptibility to PID‐p. The magnitude of the observed behavior was fit using a previously developed charge transfer and depletion by light model. Whereas power loss with −1000 V applied to the cell circuit at 60°C for 96 h in the dark was about 30%, testing the module front under 0.051 W·m −2 nm −1 at 340 nm UVA irradiation using fluorescent tubes, the mean degradation was only 3%. When the modules were tested in the dark for PID‐p with in situ dark current–voltage (I‐V) characterization, the thermal activation energy for degradation was 0.71 eV; for recovery in the dark, it was 0.58 eV. Whereas recovery from the degraded state at 60°C in the dark without voltage bias was 5% absolute in 38 h, rapid recovery of about 5% absolute was observed with 1000 W·s/m 2 exposure at 25°C using a flash tester.

14 SOLAR ENERGY↗

Enhancing the performance of the perovskite solar cells by modifying the SnO 2 electron transport layer

The tin oxide (SnO 2 ) electron transport layer (ETL) plays a vital role in the photo-conversion efficiency (PCE) and stability of organic-inorganic perovskite solar cells (PSCs). However, SnO 2 ETL-induced defects such as hydroxyl groups, oxygen vacancies, exposed Sn atoms, and dangling bonds hinder device performance. In this study, rubidium chloride (RbCl) has been used to modify the SnO 2 ETL. Perovskite film formed on the RbCl-modified SnO 2 ETL exhibits improved crystallinity with enlarged grain size and reduced grain boundaries and enhanced optical absorption. Further, the Hall-effect measurements indicate the improved carrier mobility, and the dark J-V curve shows the increment of electrical conductivity for the RbCl-modified SnO 2 ETL. X-ray photoelectron spectroscopy (XPS) results demonstrate the surface defects passivation of the perovskite layer by modifying the SnO 2 ETL. A champion PCE of 19.35% has been achieved for the RbCl-modified SnO 2 ETL-based devices with improved stability, while the control devices with unmodified SnO 2 ETL show a PCE of 17.18%.

14 SOLAR ENERGY↗

Role of p-GaN layer thickness in the degradation of InGaN-GaN MQW solar cells under 405 nm laser excitation

GaN-based solar cells with InGaN multiple quantum wells (MQWs) are promising devices for application in space environment, concentrator solar systems, wireless power transmission and multi-junction solar cells. It is therefore important to understand their degradation kinetics when submitted to high-temperature and high-intensity stress. We submitted three samples of GaN-InGaN MQW solar cells with p-AlGaN electron-blocking-layer with different thickness of the p-GaN layer to constant power stress at 310 W/cm 2 , 175 °C for several hundred hours. The main degradation modes are a reduction of open-circuit voltage, short-circuit current, external quantum efficiency, power conversion efficiency and electroluminescence. In particular, we observed that a thinner p-GaN layer results in a stronger degradation observed on the cell operating parameters. The analysis of the dark I-V characteristics showed an increase in low-forward bias current and the analysis of electroluminescence showed a decrease in the electroluminescene emitted by the (forward biased) cell, as a consequence of stress. This work highlights that the cause of degradation is possibly related to a diffusion mechanism, which results in an increase of defect density in the active region. Finally, the impurities involved in the diffusion processes possibly originate from the p-side of the devices, therefore a thicker p-GaN layer reduces the amount of defects reaching the active region.

14 SOLAR ENERGY↗

In-situ Microscopy Characterization of Cu(In,Ga)Se2 Potential-Induced Degradation

We report on the role of sodium in potentialinduced degradation (PID) of Cu(In, Ga)Se 2 (CIGS) solar cells. In-situ microscopy characterizations on AFM platform were performed on two stressed CIGS device under room temperature (RT) and high temperature (HT) at 85 degrees C. During PID stressing we observed depletion region gets wider as Na migrates, p-n junction becomes leaky at RT for over a month; and similar junction evolution was observed for HT-stressed sample, eventually the junction collapsed after 18 hours. The diode behaviors were confirmed by dark I-V measurement. Time-of Flight secondary-ion mass spectrometry reveals that the Na accumulates on ZnO and CdS side, as well as the upper layer of CIGS layer. The results indicate that Na drifted by the voltage applied on the soda-lime glass, then diffuse through the whole device. And the sodium profiles have different points of evolution due to the temperature differences between the two stressed samples. The consistent results unambiguously show how Na from substrate glass causes PID in CIGS solar cells.

14 SOLAR ENERGY↗

In-Situ Measurement of Power Loss for Crystalline Silicon Modules Undergoing Thermal Cycling and Mechanical Loading Stress Testing

An in-situ method is proposed for monitoring and estimating the power degradation of mc-Si photovoltaic (PV) modules undergoing thermo-mechanical degradation tests that primarily manifest through cell cracking, such as mechanical load tests, thermal cycling and humidity freeze tests. The method is based on in-situ measurement of the module’s dark current-voltage (I-V) characteristic curve during the stress test, as well as initial and final module flash testing on a Sun simulator. The method uses superposition of the dark I-V curve with final flash test module short-circuit current to account for shunt and junction recombination losses, as well as series resistance estimation from the in-situ measured dark I-Vs and final flash test measurements. The method is developed based on mc-Si standard modules undergoing several stages of thermo-mechanical stress testing and degradation, for which we investigate the impact of the degradation on the modules light I-V curve parameters, and equivalent solar cell model parameters. Experimental validation of the method on the modules tested shows good agreement between the in-situ estimated power degradation and the flash test measured power loss of the modules, of up to 4.31 % error (RMSE), as the modules experience primarily junction defect recombination and increased series resistance losses. However, the application of the method will be limited for modules experiencing extensive photo-current degradation or delamination, which are not well reflected in the dark I-V characteristic of the PV module.

14 SOLAR ENERGY↗

The Dark Energy Camera All Data Everywhere cosmic shear project V: Constraints on cosmology and astrophysics from 270 million galaxies across 13,000 deg$^2$ of the sky

We present constraints on models of cosmology and astrophysics using cosmic shear data vectors from three datasets: the northern and southern Galactic cap of the Dark Energy Camera All Data Everywhere (DECADE) project, and the Dark Energy Survey (DES) Year 3. These data vectors combined consist of 270 million galaxies spread across 13,000 ${\rm deg}^2$ of the sky. We first extract constraints for $Λ$CDM cosmology and find $S_8= 0.805^{+0.019}_{-0.019}$ and $Ω_{\rm m} = 0.262^{+0.023}_{-0.036}$, which is consistent within $1.9 σ$ of constraints from the Planck satellite. Extending our analysis to dynamical dark energy models shows that lensing provides some (but still minor) improvements to existing constraints from supernovae and baryon acoustic oscillations. Finally, we study six different models for the impact of baryons on the matter power spectrum. We show the different models provide consistent constraints on baryon suppression, and associated cosmology, once the astrophysical priors are sufficiently wide. Current scale-cut approaches for mitigating baryon contamination result in a residual bias of $\approx 0.3σ$ in the $S_8, Ω_{\rm m}$ posterior. Using all scales with dedicated baryon modeling leads to negligible improvement as the new information is used solely to self-calibrate the baryon model on small scales. Additional non-lensing datasets, and/or calibrations of the baryon model, will be required to access the full statistical power of the lensing measurements. The combined dataset in this work represents the largest lensing dataset to date (most galaxies, largest area) and provides an apt testing ground for analyses of upcoming datasets from Stage IV surveys. The DECADE shear catalogs, data vectors, and likelihoods are made publicly available.

Anbajagane, D. [Chicago U., Astron. Astrophys. Ctr↗

CP26 is not involved in qE- or qZ-type non-photochemical quenching in Arabidopsis

CP26 is a monomeric minor light-harvesting complex of Photosystem II (LHCII) protein located at the interface between LHCII trimers and the PSII core in thylakoid membranes. Previous studies have proposed that CP26 plays a role in non-photochemical quenching (NPQ) in addition to light harvesting. Here, we utilized biophysical and pharmacological approaches to investigate this role using single- and higher-order Arabidopsis (Arabidopsis thaliana) cp26 mutants, examining its relationship to known NPQ regulators (Photosystem II subunit S, PsbS, violaxanthin de-epoxidase, and the pH gradient across the thylakoid membrane). cp26 mutants showed significantly reduced maximum PSII quantum efficiencies (F v /F m ) in darkness, indicating a constitutively quenched state, further confirmed by fluorescence lifetime measurements. Destabilized PSII-LHCII supercomplexes observed in native gel electrophoresis and tighter PSII supercomplex packing were potential causes, with no other antenna proteins capable of rescuing this phenotype. In addition, the cp26 mutants exhibited altered NPQ capacity—modest in single mutants but substantial in double mutants—independent of PsbS and violaxanthin de-epoxidase. Together, these results show that CP26 is not involved in qE or qZ but may primarily play an indirect role in apparent NPQ responses via PSII-LHCII supercomplex organization.

Walter, Julia [University of Cambridge (United Kin↗

Dark dimension and decaying dark matter gravitons

We explore the cosmology of the dark-dimension scenario taking into account perturbations in the linear regime. In the context of the dark-dimension scenario, a natural candidate for dark matter in our Universe is the excitations of a tower of massive spin-2 Kaluza-Klein (KK) gravitons. These dark gravitons are produced in the early Universe and decay to lighter KK gravitons during the course of cosmological evolution. The decay causes the average dark matter mass to decrease as the Universe evolves. In addition, the kinetic energy liberated in each decay leads to a kick velocity for the dark matter particles, leading to a suppression of structure formation. Using current cosmic microwave background (), baryon acoustic oscillation, and cosmic shear (KiDS-1000) data, we put a bound on the dark matter kick velocity today v today ≤ 2.2 × 10 − 4 c at 95% CL. This leads to rather specific regions of parameter space for the dark-dimension scenario. The combination of the experimental bounds from cosmology, astrophysics, and table-top experiments leads to the range l 5 ∼ 1 – 10 μ m for the size of the dark dimension. The dark-dimension scenario is found to be remarkably consistent with current observations and provides signatures that are within reach of near-future experiments. Published by the American Physical Society 2024

Astronomy & Astrophysics↗

Limited thermal acclimation of photosynthesis in tropical montane tree species

Abstract The temperature sensitivity of physiological processes and growth of tropical trees remains a key uncertainty in predicting how tropical forests will adjust to future climates. In particular, our knowledge regarding warming responses of photosynthesis, and its underlying biochemical mechanisms, is very limited. We grew seedlings of two tropical montane rainforest tree species, the early‐successional species Harungana montana and the late‐successional species Syzygium guineense , at three different sites along an elevation gradient, differing by 6.8℃ in daytime ambient air temperature. Their physiological and growth performance was investigated at each site. The optimum temperature of net photosynthesis ( T optA ) did not significantly increase in warm‐grown trees in either species. Similarly, the thermal optima ( T optV and T optJ ) and activation energies ( E aV and E aJ ) of maximum Rubisco carboxylation capacity ( V cmax ) and maximum electron transport rate ( J max ) were largely unaffected by warming. However, V cmax , J max and foliar dark respiration ( R d ) at 25℃ were significantly reduced by warming in both species, and this decline was partly associated with concomitant reduction in total leaf nitrogen content. The ratio of J max / V cmax decreased with increasing leaf temperature for both species, but the ratio at 25℃ was constant across sites. Furthermore, in H . montana , stomatal conductance at 25℃ remained constant across the different temperature treatments, while in S . guineense it increased with warming. Total dry biomass increased with warming in H . montana but remained constant in S . guineense . The biomass allocated to roots, stem and leaves was not affected by warming in H . montana , whereas the biomass allocated to roots significantly increased in S . guineense . Overall, our findings show that in these two tropical montane rainforest tree species, the capacity to acclimate the thermal optimum of photosynthesis is limited while warming‐induced reductions in respiration and photosynthetic capacity rates are tightly coupled and linked to responses of leaf nitrogen.

54 ENVIRONMENTAL SCIENCES↗

In Situ ATR–SEIRAS of Carbon Dioxide Reduction at a Plasmonic Silver Cathode

Illumination of a voltage-biased plasmonic Ag cathode during CO 2 reduction results in a suppression of the H 2 evolution reaction while enhancing CO 2 reduction. This effect has been shown to be photonic rather than thermal, but the exact plasmonic mechanism is unknown. Here in this paper, we conduct an in situ ATR–SEIRAS (attenuated total reflectance–surface-enhanced infrared absorption spectroscopy) study of a sputtered thin film Ag cathode on a Ge ATR crystal in CO 2 -saturated 0.1 M KHCO 3 over a range of potentials under both dark and illuminated (365 nm, 125 mW cm –2 ) conditions to elucidate the nature of this plasmonic enhancement. We find that the onset potential of CO 2 reduction to adsorbed CO on the Ag surface is -0.25 V RHE and is identical in the light and the dark. As the production of gaseous CO is detected in the light near this onset potential but is not observed in the dark until -0.5 V RHE , we conclude that the light must be assisting the desorption of CO from the surface. Furthermore, the HCO 3 – wavenumber and peak area increase immediately upon illumination, precluding a thermal effect. We propose that the enhanced local electric field that results from the localized surface plasmon resonance (LSPR) is strengthening the HCO 3 – bond, further increasing the local pH. This would account for the decrease in H 2 formation and increase the CO 2 reduction products in the light.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The discriminant power of bubble wall velocities: gravitational waves and electroweak baryogenesis

A precise determination of the bubble wall velocity v$_{w}$ is crucial for making accurate predictions of the baryon asymmetry and gravitational wave (GW) signals in models of electroweak baryogenesis (EWBG). Working in the local thermal equilibrium approximation, we exploit entropy conservation to present efficient algorithms for computing v$_{w}$, significantly streamlining the calculation. We then explore the parameter dependencies of v$_{w}$, focusing on two sample models capable of enabling a strong first-order electroweak phase transition: a ℤ$_{2}$-symmetric singlet extension of the SM, and a model for baryogenesis with CP violation in the dark sector. We study correlations among v$_{w}$ and the two common measures of phase transition strength, α$_{n}$ and v$_{n}$/T$_{n}$. Interestingly, we find a relatively model-insensitive relationship between v$_{n}$/T$_{n}$ and α$_{n}$. We also observe an upper bound on α$_{n}$ for the deflagration/hybrid wall profiles naturally compatible with EWBG, the exact value for which varies between models, significantly impacting the strength of the GW signals. In summary, our work provides a framework for exploring the feasibility of EWBG models in light of future GW signals.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Evidence of Polarization‐Type Potential‐Induced Degradation (PID‐p) in the Field and Investigation of the Recovery Mechanism on Bifacial p ‐PERC Modules

This study investigates the polarization-type potential-induced degradation (PID-p) of bifacial glass/glass p-type passivated emitter rear contact (p-PERC) modules in the field and their recovery behavior. Modules were installed with three mounting configurations providing different albedo conditions. System voltage (–600, –1500, and +1500 V) was applied to the cell circuits, with respect to the grounded module frames. No degradation was observed for positively biased modules, but PID-p was identified on the rear side when cells are negatively biased, with maximum power dropping during the first days and stabilizing at values up to 8% loss. Electroluminescence images revealed a variation of the cells' PID-p susceptibility within a module. Three parameters were shown to impact the degradation rate: rear albedo light, voltage, and wetness conditions. Degraded modules were recovered either by (1) a positive bias (+1500 V), (2) outdoor illumination with the front side facing sun, (3) outdoor illumination with the rear side facing sun, or (4) dark storage. A recovery pattern was identified with I–V parameters decreasing to a local minimum before increasing to full recovery. The proposed mechanism is based on the band bending at the rear p-type Si/AlO x/SiN x interface, going from inversion to depletion and accumulation states. Full recovery was achieved in 2–7 h for the modules recovered with the rear side facing sun, four to eight nights for the modules positively biased at night, and 10–20 days for the modules with the front side facing sun. Dark storage showed slower recovery rates as I–V parameters were not improving even after 1 month. Here, the recovery rates were correlated with the net Coulombs transferred during the preceding PID stress: When more Coulombs are transferred during the degradation, the extent of degradation is greater, leading to slower recovery rates.

14 SOLAR ENERGY↗

Dark Population Transfer Mechanism for Sterile Neutrino Dark Matter

We present a mechanism for producing a cosmologically significant relic density of one or more sterile neutrinos. This scheme invokes two steps: First, a population of “heavy” sterile neutrinos is created by scattering-induced decoherence of active neutrinos. Second, this population is transferred, via sterile neutrino self-interaction-mediated scatterings and decays, to one or more lighter mass (∼10 keV to ∼1 GeV) sterile neutrinos that are far more weakly (or not at all) mixed with active species and could constitute dark matter. Dark matter produced this way can evade current electromagnetic and structure-based bounds, but may nevertheless be probed by future observations.

Dark matter↗