Structure, properties, and disorder in the new distorted-Hollandite PbIr4Se8
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Two large construction machinery structures were welded separately with and without jig constraints. The welding distortion of the entire structure was measured by a 3D coordinate measuring system and simulated by elastic FEM using the inherent deformation method. To obtain an accurate inherent deformation, a thermal elastoplastic FE analysis of simple one-side fillet joints with and without jig constraints was performed. Efficient simulation of welding distortion in large structures was accomplished by applying inherent deformation in a localized region, and the effect of jig constraint on the reduction of welding distortion was clarified. The computation of inherent deformation, the weld zone definition and the conversion of inherent deformation into inherent strain were automated. Measured and computed welding distortions in large structures had a good correspondence with respect to both tendency and magnitude. Further investigation of jig configuration was performed for enhanced reduction of welding distortion. Alternative controlling techniques for common welded structures were also addressed.
Recently, the Lyman-α absorption observed in the spectra of high-redshift quasars has been used as a tracer of large-scale structure by means of the three-dimensional Lyman-α forest auto-correlation function at redshift z≃ 2.3, but the need to fit the quasar continuum in every absorption spectrum introduces a broadband distortion that is difficult to correct and causes a systematic error for measuring any broadband properties. Here, we describe a k-space model for this broadband distortion based on a multiplicative correction to the power spectrum of the transmitted flux fraction that suppresses power on scales corresponding to the typical length of a Lyman-α forest spectrum. In implementing the distortion model in fits for the baryon acoustic oscillation (BAO) peak position in the Lyman-α forest auto-correlation, we find that the fitting method recovers the input values of the linear bias parameter b F and the redshift-space distortion parameter β F for mock data sets with a systematic error of less than 0.5%. Applied to the auto-correlation measured for BOSS Data Release 11, our method improves on the previous treatment of broadband distortions in BAO fitting by providing a better fit to the data using fewer parameters and reducing the statistical errors on βF and the combination b F (1+β F ) by more than a factor of seven. The measured values at redshift z=2.3 are βF=1.39 +0.11 +0.24 +0.38 -0.10 -0.19 -0.28 and bF(1+βF)=-0.374 +0.007 +0.013 +0.020 -0.007 -0.014 -0.022 (1σ, 2σ and 3σ statistical errors). Our fitting software and the input files needed to reproduce our main results are publicly available.
The strength of high-duty gears can be improved by carburizing and quenching processes. Quenching distortion is inevitable during the process, and it has direct effects on the precision of the gear. For spiral bevel gear with big diameter and small thickness, die quenching process is applied in the manufacturing to control the distortion in axial direction. Die quenching parameters must be optimized to minimize the distortion while considering non-uniformity of chemical compositions and loads. In this paper, material models of gear material (22CrMoH) built based on the phase transformation kinetics, static mechanical properties and phase transformation plasticity equations. Finite element analysis (FEA) models are conducted to study the whole die quenching process based on the production process. Die quenching experiments and testing of microstructures and distortions are conducted to verify the accuracy of the FEA models. The effects of loads and bottom die obliquity on the final distortion are studied to set the appropriate range and control distortion. The distortion was very sensitive to the bottom die obliquity and some part of load ranges. The distortion changes little when the load of inner die was in the range of 1.38-2.07 MPa and the load of outer die was in the range of 2.07-2.76 MPa. The distortion range is fitted the production requirements by setting the inclination angle of bottom die between 0.12° and 0.29°.
A wind tunnel investigation was conducted to determine the amplitude and spatial distribution of steady-state and dynamic distortion produced in an inlet with 45 percent of the overall supersonic area contraction occurring internally. It was found that the inlet support strut location and/or the overboard bypass flow rate has a significant effect on the spatial distribution of distortion. Because of this effect the majority of the stall points exhibited four-per-revolution patterns of distortion. Data from this test were used to formulate a simple index that combines steady-state and dynamic distortions. Distortion results obtained with this index correlated well with exhaust nozzle area. It is shown that the exhaust nozzle area of a TF30-P-3, as modified for use in this test, can be controlled in a scheme to avoid engine stall. A considerable increase in engine distortion tolerance can be achieved by opening the 7th-stage bleed. The engine exhibited higher tolerance to distortion for multiple patterns of distortion per-revolution than for a one-per-revolution pattern of distortion.
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With first-principles calculations, we show that CsBX 3 halides withB=Sn or Pb undergo octahedral rotation distortions, while for B=Ge and Si, they undergo a ferroelectric rhombohedral distortion accompanied by a rhombohedral stretching of the lattice. We demonstrate that these are mutually exclusive at their equilibrium volume although different distortions may occur as functions of lattice expansion. The choice between the two distortion modes is in part governed by the Goldschmidt tolerance factor. However, another factor explaining the difference between Sn and Pb compared with Ge and Si is the stronger lone-pair character of Ge and Si when forced to be divalent as is the case in these structures. The lone-pair chemistry is related to the off centering. While the Si-based compounds have not yet been synthesized, the Ge compounds have been established experimentally. As a final test of the importance of the tolerance factor we consider RbGeX 3 , which has smaller tolerance factor than the corresponding CsGeX 3 because Rb is smaller than Cs. We find that it can lower its energy by both rotations or rhombohedral off-centering distortions but the latter lower the energy slightly more efficiently.
Flow angle, static pressure, total temperature and total pressure were measured in the inlet duct upstream of a turbofan engine operating with temperature distortion or combined pressure-temperature distortion. Such measurements are useful in the evaluation of analytical models of inlet distortion. A rotating gaseous-hydrogen burner and a circumferential 180 degrees-extent screen configuration mounted on a rotatable assembly generated the distortions. Reynolds number index was maintained at 0.5 and engine corrected low-rotor speeds were held at 6000 and 8600 rpm. The measurements showed that at the entrance to the engine, flow angle was largest in the hub region. As flow approached the engine, yaw angle (circumferential variation) increased and pitch angle (radial variation) decreased. The magnitude of static-pressure distortion measured along the inlet-duct and extended bullet nose walls increased exponentially as flow approached the engine.
A procedure has been developed for predicting peak dynamic inlet distortion. This procedure combines Computational Fluid Dynamics (CFD) and distortion synthesis analysis to obtain a prediction of peak dynamic distortion intensity and the associated instantaneous total pressure pattern. A prediction of the steady state total pressure pattern at the Aerodynamic Interface Plane is first obtained using an appropriate CFD flow solver. A corresponding inlet turbulence pattern is obtained from the CFD solution via a correlation linking root mean square (RMS) inlet turbulence to a formulation of several CFD parameters representative of flow turbulence intensity. This correlation was derived using flight data obtained from the NASA High Alpha Research Vehicle flight test program and several CFD solutions at conditions matching the flight test data. A distortion synthesis analysis is then performed on the predicted steady state total pressure and RMS turbulence patterns to yield a predicted value of dynamic distortion intensity and the associated instantaneous total pressure pattern.
In this study, a spin-orbital quantum liquid state is theoretically proposed in the honeycomb lattice of Ba 3 CuSb 2 O 9 , enabled by dynamic short-range correlations between the spin and orbital degrees of freedom. Using neutron diffraction, the local atomic structure of Ba 3 Cu 1+x Sb 2-x O 9 at x = 0 and 0.1 is obtained via the pair density function analysis. The results indicate that both compositions exhibit local Jahn-Teller (JT) distortions with the elongated CuO 3 octahedral configuration. In Ba 3 Cu 1.1 Sb 1.9 O 9 , JT ordering of the distorted CuO 3 octahedra gives rise to the orthorhombic symmetry with ferro-orbital order. On the other hand, in Ba 3 CuSb 2 O 9 , even though the CuO 3 octahedra are JT distorted, there is no long-range ordering hence the symmetry is hexagonal. Furthermore, the local singlet excitation at 5.8 meV observed in Ba 3 CuSb 2 O 9 below 50 K is absent in Ba 3 Cu 1.1 Sb 1.9 O 9 . Instead, an excitation at 2.5 meV is observed in the latter, which is likely associated with short-range spin order.
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Distortion analysis plots were used to determine if peak distortion data taken from a subscale inlet model can be used to predict peak distortion levels for a full scale flight test vehicle.