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The Study of Dopant Segregation Behavior During the Growth of GaAs in Microgravity

An investigation into the segregation behavior of selenium doped gallium arsenide during directional solidification in the microgravity environment was conducted using the Crystal Growth Furnace (CGF) aboard the first United States Microgravity Laboratory (USML-1). The two crystals grown were 1.5 cm in diameter and 16.5 cm in length with an initial melt length of 14 cm. Two translation periods were executed, the first at 2.5 microns/s and after a specified time, which was different between the two experiments, the translation rate was doubled to 5.0 microns/s. The translation was then stopped and the remaining sample melt was solidified using a gradient freeze technique in the first sample and a rapid solidification in the second experiment. Measurement of the selenium dopant distribution, using quantitative infrared transmission imaging, indicates that the first sample initially achieved diffusion controlled growth as desired. However, after about 1 cm of growth, the segregation behavior was driven from a diffusion controlled growth regime to a complete mixing regime. Measurements in the second flight sample indicated that the growth was always in a complete mixing regime. In both experiments, voids in the center line of the crystal, indicative of bubble entrapment, were found to correlate with the position in the crystal when the translation rates were doubled.

D H Matthiesen

Improvement in the Thermal-to-Structural Model Mapping Process for Integrated Modeling for the Roman Space Telescope

Integrated Modeling has been a key component of verifying optical requirements for the Nancy Grace Roman Space Telescope (RST) that are either impossible or impractical to verify exclusively through ground testing. Two major areas for integrated Modeling are Jitter and Thermal Distortion that require the exchanges of model performance predictions across disciplines. In both cases, distortions are impressed on optical models to evaluate the impact on boresight alignment and wave front error. In the case of Jitter, the disturbances are driven by reactions to motions most often from actuators; however, in the case of thermal distortion, the motions are driven by thermal expansion or contraction as a result of changing temperatures. This then requires a link further upstream to the thermal model, which is used to predict the thermal performance and temperature gradients and stability. The process for mapping temperatures from a thermal model to a corresponding structural model has been performed numerous times through the RST project lifecycle, with improvements in the accuracy, verification, and effort sought throughout. This paper describes some of the recent improvements to the process, including: capture of the visualization parameters, automatic generation of the mapped images for both the thermal and structural model groupings, and reduction in the effort to assemble the full set of mapped temperatures. These upgrades have greatly reduced the manual effort associated with thermal mapping and allowed for faster turn-around of Integrated Modeling predictions.

Thermal Mapping

Advancing Wildfire Monitoring with TEMPO and ML tools: Hourly Smoke and Fire‑Front Mapping and Near‑Surface NO₂ Predictions

Wildfires impose substantial impacts on communities and regions downwind of wildfire smoke. We present a TEMPO‑enabled workflow that generates value‑added Level‑3 smoke‑plume masks and fire‑front maps for large wildfires, such as 2024 Park Fire, using the self‑supervised deep learning system SIT‑FUSE, along with near‑surface NO₂ predictions produced by a foundation model (Microsoft Aurora). We conclude by outlining a roadmap for expanding these capabilities to additional Western U.S. wildfire events and for delivering actionable tools to stakeholders. This open-source, reproducible workflow provides a scalable framework for cross-agency wildfire monitoring to overcome traditional limitations in smoke-cloud discrimination and air-quality forecasting by incorporating TEMPO data and beyond.

Xiaohua Pan

The Thermal and Kinematic Sunyaev–Zeldovich Effect in Galaxy Clusters and Filaments Using Multifrequency Temperature Maps of the Cosmic Microwave Background A399–A401 Cluster Pair Case Study

We present a multifrequency and multi-instrument methodology to study the physical properties of galaxy clusters and cosmic filaments using cosmic microwave background observations. Our approach enables simultaneous measurement of both the thermal (tSZ) and kinematic Sunyaev–Zeldovich (kSZ) effects, incorporates relativistic corrections, and models astrophysical foregrounds such as thermal dust emission. We do this by jointly fitting a single physical model across multiple maps from multiple instruments at different frequencies, rather than fitting a model to a single Compton-y map. We demonstrate the success of this method by fitting the A399–A401 galaxy cluster pair and filament system using archival data from the Planck satellite and new, targeted deep data from the Atacama Cosmology Telescope, covering 11 different frequencies over 14 maps from 30 GHz to 545 GHz. Our tSZ results are consistent with previous work using Compton-y maps. We measure the line-of-sight peculiar velocities of the cluster–filament system using the kSZ effect and find statistical uncertainties on individual cluster peculiar velocities of ≲600 km s −1 , which are competitive with current state-of-the-art measurements. Additionally, we measure the optical depth of the filament component with a signal-to-noise of 8.5σ and reveal hints of its morphology. This modular approach is well-suited for application to future instruments across a wide range of millimeter and submillimeter wavebands.

Ajay S Gill

The Canadian Galactic Emission Mapper: A New 8-10 GHz Telescope To Map the Polarization of the Northern Sky

The Canadian Galactic Emission Mapper (CGEM) radio telescope is mapping polarized Galactic foregrounds from 8-10 GHz to aid in the search for B-modes in the Cosmic Microwave Background (CMB). Here we describe the design and early on-sky characterization of the CGEM optics. CGEM employs an on-axis, hat feed optical design that is a body of revolution (BOR) and exhibits excellent intrinsic polarization purity. We describe how we have optimized the optics with a novel framework that can directly minimize simulated intensity to polarized intensity (T → P) leakage in angular power spectrum space. The optimized optics exhibit simulated T → P leakage that is orders of magnitude below anticipated CℓBB for r = 10 −3 when scaled from 8-10 GHz to the CMB observing window near 95 GHz. We go on to describe the mechanical design of the optics, including a novel secondary mirror support made from Astroquartz composite that has low loss, low dielectric constant, and preserves the BOR symmetry of the optics. We then showcase the early on-sky performance of the optics with observations of the Sun and satellites, which probe the beam to 40dB down from the peak. A beam model for the deployed CGEM optics based on electromagnetic simulations is in excellent agreement with the on-sky data.

cosmic microwave background

Coma Physics of an Interstellar Object: JWST Spatial-Spectral Mapping of 3I/ATLAS

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward interstellar object 3I/ATLAS carried out on UT 2025 December 22 and 23 at a heliocentric distance (\rh{}) of $2.37-2.41$ au. These measurements of CO, \ce{CO2}, \ce{H2O}, \ce{CH3OH}, and \ce{CH4} sampled molecular chemistry in 3I/ATLAS as it receded from its encounter with our Sun and entered the vicinity of the \ce{H2O} ice line --- the region between \rh{} = $2-3$ au where the temperature becomes too low for H$_2$O to vigorously sublime and CO and \ce{CO2} begin to control the overall activity. CO was the most abundant molecule, followed by \ce{H2O} and \ce{CO2}, whose molecular abundances with respect to CO were $(40.5\pm3.1)\%$ and ($41.6\pm0.3)\%$, respectively. This work presents spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all detected species. The spatial distributions of both quantities were highly anisotropic for the apolar species in the coma of 3I/ATLAS, yet were more nearly symmetric for the polar molecules. These results demonstrate how volatiles were segregated in the nucleus ices of 3I/ATLAS and reveal heating and cooling mechanisms in its coma. Derived maps of the ortho-to-para ratio (OPR) for \ce{H2O} were flat with increasing distance from the nucleus and consistent with a coma-averaged value $\mathrm{OPR}=2.7\pm0.2$, slightly less than the expected equilibrium value of three.

Nathan X Roth

CH3OH and HCN in Interstellar Comet 3I/ATLAS Mapped with the ALMA Atacama Compact Array: Distinct Outgassing Behaviors and a Remarkably High CH3OH/HCN Production Rate Ratio

We report the detection of methanol (CH3OH) toward interstellar comet 3I/ATLAS using the At-acama Compact Array of the Atacama Large Millimeter/Submillimeter Array (ALMA) on UT 2025 August 28, September 18 and 22, and October 1, and of hydrogen cyanide (HCN) on September 12 and 15. These observations spanned pre-perihelion heliocentric distances (r H ) of 2.6 – 1.7 au. The molecules showed outgassing patterns distinct from one another, with HCN production being depleted in the sunward hemisphere of the coma, whereas CH3OH was enhanced in that direction. Statistical analysis of molecular scale lengths in 3I/ATLAS indicated that CH3OH included production from coma sources at Lp > 258 km at 99% confidence. However low signal-to-noise on long baselines, which sample emission on small spatial scales closest to the nucleus, prevented definitively ruling out CH3OH as purely a parent species. In contrast, HCN production was indistinguishable from direct nucleus sublimation. The CH3OH production rate increased sharply from August through October, including an uptick near the inner edge of the H2O sublimation zone at rH = 2 au. Compared to comets measured to date at radio wavelengths, the derived CH3OH/HCN ratios in 3I/ATLAS of 124+30−34 and 79+11−14on September 12 and 15, respectively, are among the most enriched values measured in any comet, surpassed only by anomalous solar system comet C/2016 R2 (PanSTARRS)

Comae

High Mach Number, Low-Cowl-Drag, External-Compression Inlet With Subsonic Dump Diffuser

A zero-cowl-drag, all-external-compression inlet with an abrupt area discontinuity or subsonic dump diffuser has been proposed and demonstrated for high Mach number application. Isentropic compression was focused at the lip of a cylindrical cowl and limited by the requirements for shock attachment. Theoretical calculations of the performance of such an inlet showed that it may be suited for application at Mach numbers of 4 and above. In an experimental investigation at Mach 3.85, a 4.75-inch-diameter inlet attained a total-pressure recovery of 0.41 at a corresponding mass-flow ratio of 0.92. Subsonic diffusion over an area ratio of about 3.5 to 1.0 was accomplished in 1.25 inlet diameters. Essentially no difference in performance was obtained in a comparison of the dump and a conventional subsonic diffuser. On a range basis, the over-all performance of this inlet was at least comparable with that of the best on-design isentropic external-compression inlet previously reported. A variable Mach number configuration utilizing a telescoping spike with a subsonic dump diffuser is also included.

James F Connors

Fullerenes, PAH, Carbon Nanostructures, and Soot in Low Pressure Diffusion Flames

The formation of fullerenes C 60 and C 7O is known to occur in premixed laminar benzene/oxygen/argon flames operated at reduced pressures. High resolution transmission electron microscopy (HRTEM) images of material collected from these flames has identified a variety of multishelled nanotubes and fullerene 'onions' as well as some trigonous structures. These fullerenes and nanostructures resemble the material that results from commercial fullerene production systems using graphite vaporization. As a result, combustion is an interesting method for fullerenes synthesis. If commercial scale operation is to be considered, the use of diffusion flames might be safer and less cumbersome than premixed flames. However, it is not known whether diffusion flames produce the types and yields of fullerenes obtained from premixed benzene/oxygen flames. Therefore, the formation of fullerenes and carbon nanostructures, as well as polycyclic aromatic hydrocarbons (PAH) and soot, in acetylene and benzene diffusion flames is being studied using high performance liquid chromatography (HPLC) and high resolution transmission electron microscopy (HRTEM).

William J Grieco

Radiation Temperature and Extinction of Transient Gaseous Diffusion Flames in Microgravity

The absence of buoyancy-induced flows in micro-g and the resulting increase in the reactant residence time significantly alters the fundamentals of many combustion processes. Substantial differences between 1-g and micro-g flames have been reported in experiments on candle flames, flame spread over solids, droplet combustion and others. These differences are more basic than just in the visible flame shape. Longer residence times and higher concentration of combustion products in the flame zone create a thermochemical environment which changes the flame chemistry and the heat and mass transfer processes. Processes such as flame radiation (and its interaction with flame chemistry), that are often ignored under normal gravity, become very important and sometimes even controlling. This is particularly true for conditions at extinction of a micro-g diffusion flame.

Arvind Atreya

Interpretation of Various Radiation Backgrounds Observed in the Gamma-Ray Spectrometer Experiments Carried on the Apollo Missions and Implications for Diffuse Gamma-Ray Measurements

Since the report of a preliminary analysis of cosmic gamma-ray measurements made during the Apollo 15 mission, an improved calculation of the spallation activation contribution has been made including the effects of short-lived spallation fragments, which can extend the correction to 15 MeV. In addition, a difference between Apollo 15 and 16 data enables an electron bremsstrahlung contribution to be calculated. A high level of activation observed in a crystal returned on Apollo 17 indicates a background contribution from secondary neutrons. These calculations and observations enable an improved extraction of spurious components and suggest important improvements for future detectors.

C S Dyer

A Case Study of View-Factor Rectification Procedures for Diffuse-Gray Radiation Enclosure Computations

The view factors which are used in diffuse-gray radiation enclosure calculations are often computed by approximate numerical integrations. These approximately calculated view factors will usually not satisfy the important physical constraints of reciprocity and closure. In this paper several view-factor rectification algorithms are reviewed and a rectification algorithm based on a least-squares numerical filtering scheme is proposed with both weighted and unweighted classes. A Monte-Carlo investigation is undertaken to study the propagation of view-factor and surface-area uncertainties into the heat transfer results of the diffuse-gray enclosure calculations. It is found that the weighted least-squares algorithm is vastly superior to the other rectification schemes for the reduction of the heat-flux sensitivities to view-factor uncertainties. In a sample problem, which has proven to be very sensitive to uncertainties in view factor, the heat transfer calculations with weighted least-squares rectified view factors are very good with an original view-factor matrix computed to only one-digit accuracy. All of the algorithms had roughly equivalent effects on the reduction in sensitivity to area uncertainty in this case study.

Robert P Taylor

Diffusion Quantum Monte Carlo Calculation of the Austenite and Martensite Phases of NiTi

NiTi is a promising material for smart and active technologies due to its exhibition of the shape memory effect, superelasticity, and biocompatibility. The shape memory effect is tied to the reversible transition between the austenite and martensite phases. A major research direction is to alloy NiTi with Zr, Hf, Pd, Pt, etc., in order to tune the martensitic transition temperature (MTT). Modeling the MTT from first principles is challenging because the lattice dynamics is complicated by anharmonicity and various low-energy structures. Using density functional theory, the energy difference between the austenite and martensite phases of NiTi varies by up to 100 meV/atom depending on the choice of density functional, which is of the same order of the energy difference itself. Consequently, free energy calculations with different functionals can result in estimates of the MTT that vary by several hundred K. Using diffusion quantum Monte Carlo, we calculated the energy difference between the B2 and B19' structures of NiTi to be 70.9 +- 2.5 meV/atom.

Kevin K Ly

Single-Drop Reactive Extraction/Extractive Reaction with Forced Convective Diffusion and Interphase Mass Transfer

An algorithm has been developed for the forced convective diffusion-reaction problem for convection inside and outside a droplet by a recirculating flow field hydrodynamically coupled at the droplet interface with an external flow field that at infinity becomes a uniform streaming flow. The concentration field inside the droplet is likewise coupled with that outside by boundary conditions at the interface. A chemical reaction can take place either inside or outside the droplet or reactions can take place in both phases. The algorithm has been implemented and results are shown here for the case of no reaction and for the case of an external first order reaction, both for unsteady behavior. For pure interphase mass transfer, concentration isocontours, local and average Sherwood numbers, and average droplet concentrations have been obtained as a function of the physical properties and external flow field. For mass transfer enhanced by an external reaction, in addition to the above forms of results, we present the enhancement factor, with the results now also depending upon the (dimensionless) rate of reaction.

Leonid S Kleinman