Materials Data on Dy2CdS4 by Materials Project
Dy2CdS4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Dy3+ is bonded to six equivalent S2- atoms to form DyS6 octahedra that share corners with six equivalent CdS4 tetrahedra and edges with six equivalent DyS6 octahedra. All Dy–S bond lengths are 2.74 Å. Cd2+ is bonded to four equivalent S2- atoms to form CdS4 tetrahedra that share corners with twelve equivalent DyS6 octahedra. The corner-sharing octahedral tilt angles are 57°. All Cd–S bond lengths are 2.59 Å. S2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Dy3+ and one Cd2+ atom.
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