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At least 19 records

Multicolored microwave absorbers with dynamic frequency modulation

Microwave-absorbing materials are extensively used in intelligent electronic devices and stealth technologies where the ability to dynamically adjust microwave-absorbing capacity in response to specific requirements is vitally important. Herein, we report a new approach for constructing dynamically tunable microwave absorbers with ultrawide tunable frequency ranges that are simultaneously endowed with vibrant structural colors. Here, the methodology produces structural colors and adjusts absorption properties by constructing ZnO coatings with precisely adjustable thicknesses on a polypyrrole/melamine foam (PPy/MF) surface by atomic layer deposition (ALD) in conjunction with a pressure-driven strategy that regulates the compression ratio. The electrical conductivity, electromagnetic parameters, thickness, and pore size of the ZnO-coated PPy/MF (ZnO/PPy/MF) are effectively adjusted, and simply applying external pressure widens the tunable frequency range and the effective absorption bandwidth. As a result, the effective absorption frequency of ZnO/PPy/MF is dynamically adjustable from the S band to the Ku band, thereby covering 94.3% of the entire microwave spectrum. Moreover, the brilliant and uniform structural colors of ZnO/PPy/MF, which span various color categories, are precisely regulated by tuning the thickness of the ZnO coating by adjusting the number of ALD cycles. ZnO/PPy/MF is strongly hydrophobic, which endows it with remarkable self-cleaning properties. Therefore, ZnO/PPy/MF provides a conceptually novel platform for the development of next-generation smart microwave-absorbing materials due to its integrated dynamic frequency-regulating ability, brilliant structural coloration, and self-cleaning features.

36 MATERIALS SCIENCE↗

Microwave-Absorbing Foams with Adjustable Absorption Frequency and Structural Coloration

Microwave-absorbing materials with regulatable absorption frequency and optical camouflage hold great significance in intelligent electronic devices and advanced stealth technology. Herein, we present an innovative microwave-absorbing foam that can dynamically tune microwave absorption frequencies via a simple mechanical compression while in parallel enabling optical camouflage over broad spectral ranges by adjusting the structural colors. In this study, the vivid colors spanning different color categories generated from thin-film interference can be precisely regulated by adjusting the thickness of the conformal TiO 2 coatings on Ni/melamine foam. Enhanced interfacial and defect-induced polarizations resulting from the introduction of TiO 2 coating synergistically contribute to the dielectric attenuation performance. Consequently, such a foam exhibits exceptional microwave absorption capabilities, and the absorption frequency can be dynamically tuned from the S band to the Ku band by manipulating its compression ratio. Additionally, simulation calculations validate the adjustable electromagnetic wave loss behavior, offering valuable insights for the development of next-generation intelligent electromagnetic devices across diverse fields.

36 MATERIALS SCIENCE↗

Adiabatic cooling of planar motion in a Penning-trap ion crystal to sub-millikelvin temperatures

Two-dimensional planar ion crystals in a Penning trap are a platform for quantum information science experiments. However, the low-frequency planar modes of these crystals are not efficiently cooled by laser cooling, which can limit the utility of the drumhead modes for quantum information processing. Recently, it has been shown that nonlinear mode coupling can enhance the cooling of the low-frequency planar modes. Here, in this study, we demonstrate in numerical simulations that this coupling can be dynamically tuned by adiabatically changing the rotation frequency of the ion crystal during experiments. Furthermore, we show that this technique can, in addition, produce lower temperatures for the low-frequency planar modes via an adiabatic cooling process. This result allows cooling of the planar modes to sub-millikelvin temperatures, resulting in improved spectral resolution of the drumhead modes at experimentally relevant rotation frequencies, which is crucial for quantum information processing applications.

Johnson, Wes [Univ. of Colorado, Boulder, CO (Unit↗

Dispersive nonreciprocity between a qubit and a cavity

The dispersive interaction between a qubit and a cavity is ubiquitous in circuit and cavity quantum electrodynamics. It describes the frequency shift of one quantum mode in response to excitations in the other and, in closed systems, is necessarily bidirectional, i.e., reciprocal. Here, we present an experimental study of a nonreciprocal dispersive-type interaction between a transmon qubit and a superconducting cavity, arising from a common coupling to dissipative intermediary modes with broken time reversal symmetry. We characterize the qubit-cavity dynamics, including asymmetric frequency pulls and photon shot noise dephasing, under varying degrees of nonreciprocity by tuning the magnetic field bias of a ferrite component in situ. We introduce a general master equation model for nonreciprocal interactions in the dispersive regime, providing a compact description of the observed qubit-cavity dynamics agnostic to the intermediary system. Our result provides an example of quantum nonreciprocal phenomena beyond the typical paradigms of non-Hermitian Hamiltonians and cascaded systems.

74 ATOMIC AND MOLECULAR PHYSICS↗

Quantum kinetic modeling of KEEN waves in a warm-dense regime

We report the first fully kinetic, quantum study of kinetic electrostatic electron nonlinear (KEEN) waves, showing that quantum diffraction systematically erodes the classical trapping mechanism, narrows harmonic locking to the fundamental, and hastens post-drive decay. Electrons are evolved with a second-order Strang-split 1D1V Wigner–Poisson solver that couples conservative semi-Lagrangian WENO advection to an analytic Fourier space update for the non-local Wigner term, while ions remain classical. We focus on collisionless dynamics in a weakly coupled regime, providing a controlled baseline before collisional extensions. Short, frequency-tuned ponderomotive pulses drive KEEN formation in a uniform Maxwellian plasma; as the dimensionless quantum parameter H rises from the classical limit to values relevant to warm-dense matter, doped semiconductors, and 2D electron systems, the drive threshold increases, higher harmonics are damped, trapped electron vortices diffuse, and the subplasma electrostatic energy relaxes to a lower stationary level, as confirmed by continuous wavelet analysis. These microscopic changes carry macroscopic weight. Ignition-scale capsules now compress matter to regimes where the electron de Broglie wavelength rivals the Debye length, making classical kinetic descriptions insufficient. By extending KEEN physics into this quantum domain, our results offer a potential diagnostic of non-equilibrium electron dynamics for next-generation inertial-confinement designs and high-energy-density platforms, indicating that predictive fusion modeling may benefit from the integration of kinetic fidelity with quantum effects.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Transient Terahertz Oscillations During Photoinduced Polarization Topology Reconfiguration in Ferroelectric Superlattices

Terahertz resonances embedded in crystalline heterostructures could close a spectral gap between conventional electronics and photonics while opening new windows on non-equilibrium lattice dynamics. We show that femtosecond optical screening of the depolarization field in epitaxial PbTiO3/SrTiO3 superlattices launches a collective polar mode that oscillates near 1 THz and coherently spans the entire mini-Brillouin zone. Wave-vector-resolved pump–probe X-ray diffraction resolves a nearly dispersion-less oscillation at 0.87 THz and 0.94 THz at the zone boundary and zone center, respectively, persisting for ~2.5 ps, corresponding to a weakly damped resonance. Dynamical phase-field simulations reveal the origin of the mode to mesoscopic rotation of closure-domain textures during the photo-excited transition from an unscreened to a screened electrostatic state. Varying the PbTiO3 and SrTiO3 ratio tunes the mode frequency continuously from 0.9 to 1.4 THz, providing a quantitative design rule for frequency-selectable THz oscillators in ferroelectric heterostructures. By coupling nanoscale polarization reconfiguration to long-wavelength coherent dynamics, this work establishes depolarization-field engineering to topology-driven THz functionality and expanding the landscape of collective lattice dynamics.

Sri Gyan, Deepankar [Univ. of Wisconsin, Madison, ↗

Validation of a Tapered Impact Damper for Traffic Signal Structure Vibrations Using the Method of Harmonic Balance

Significant vibration amplitudes and cycles can be produced when traffic signal structures with low inherent damping are excited near one of their natural frequencies. For the mitigation of wind-induced vibrations, dynamic vibration absorbers coupled to the structure are often used. Here, this research investigates the performance of a tapered impact damper, consisting of a hanging spring-mass oscillator inside a housing capable of reducing vibration amplitude over a broader frequency range than the conventional tuned mass damper. A nonlinear, two degree-of-freedom model is developed with coordinates representing the traffic structure and the tapered impact damper. This research focuses on the application of the harmonic balance method to approximate the periodic solutions of the nonlinear equations to compute the nonlinear dynamics of the damped traffic signal structure. After designing and manufacturing a tapered impact damper, the traffic signal structure is tested with and without the damper using free vibration snapback tests. The experimental frequency and damping backbone curves are used to validate the analytical model, and the effectiveness of the damper is discussed.

42 ENGINEERING↗

The effect of blue and infrared laser melting frequency on oxide morphology in 304L

Continuous Wave Laser Beam (LB) melting offers control over the localised heating and cooling of melt pools for welding, brazing, additive manufacturing and solidification. Research into laserliquid metal interactions has primarily focused on the heat and mass transport under large thermal gradients imposed by the localised melting conditions. Recent commercial availability of blue (450 nm) wavelength lasers has enabled the printing of material with poor IR (1064) nm attenuation like Cu. However, little research has been conducted into varying input laser frequency and scan rate at fixed absorption to understand the effects of laser light on surface oxide formation and the underlying liquid metal thermodynamic response. Here, this article conducts laser melting of 304L under Blue (450 nm) and Infrared (IR, 1064 nm) laser frequencies and examines their impact on laser oxide thickness, chemistry and coloration. We find that laser frequencies induce changes in the oxide layer thickness and chemistry that cannot be explained using conventional thermal absorption shifts and fluid dynamics. We suggest that light coupling may have thermodynamic implications for the chemical potential of the liquid metal, which may drive the observed phase behaviour. Identifying mechanisms for the tuning of the chemical potential via laser frequency control could enable the ability to control solidification microstructure and atomic ordering in laser welding and additive manufacturing processes.

304L↗

On Final Results From the Muon $g\mathrm{-}2$ Experiment at Fermilab

The Muon g-2 Experiment at Fermilab has measured the muon anomalous magnetic moment, a_mu, with unprecedented precision, leveraging a dataset from Runs 1 6 that is 21 times larger than its Brookhaven predecessor. This talk will present the experiment s final result, which serves as a benchmark for testing the Standard Model with high precision. The measurement was performed in a storage ring with a highly uniform magnetic field, where precise beam dynamics understanding is vital to determine the muon anomalous precession frequency. Key to this effort were advanced simulation tools including COSY INFINITY, precise fringe field modeling, and calculations of beam dynamics characteristics like tunes and chromaticity. We will conclude by exploring how the experiment's findings reshape our understanding of particle physics.

Valetov, Eremey [Michigan State U.]↗

Tailored ultrasound propagation in microscale metamaterials via inertia design

The quasi-static properties of micro-architected (meta)materials have been extensively studied over the past decade, but their dynamic responses, especially in acoustic metamaterials with engineered wave propagation behavior, represent a new frontier. However, challenges in miniaturizing and characterizing acoustic metamaterials in high-frequency (megahertz) regimes have hindered progress toward experimentally implementing ultrasonic-wave control. Here, we present an inertia design framework based on positioning microspheres to tune responses of 3D microscale metamaterials. We demonstrate tunable quasi-static stiffness by up to 75% and dynamic longitudinal-wave velocities by up to 25% while maintaining identical material density. Using noncontact laser-based dynamic experiments of tunable elastodynamic properties and numerical demonstrations of spatio-temporal ultrasound wave propagation, we explore the tunable static and elastodynamic property relation. This design framework expands the quasi-static and dynamic metamaterial property space through simple geometric changes, enabling facile design and fabrication of metamaterials for applications in medical ultrasound and analog computing.

42 ENGINEERING↗

Phonon-enhanced nonlinearities in hexagonal boron nitride

Abstract Polar crystals can be driven into collective oscillations by optical fields tuned to precise resonance frequencies. As the amplitude of the excited phonon modes increases, novel processes scaling non-linearly with the applied fields begin to contribute to the dynamics of the atomic system. Here we show two such optical nonlinearities that are induced and enhanced by the strong phonon resonance in the van der Waals crystal hexagonal boron nitride (hBN). We predict and observe large sub-picosecond duration signals due to four-wave mixing (FWM) during resonant excitation. The resulting FWM signal allows for time-resolved observation of the crystal motion. In addition, we observe enhancements of third-harmonic generation with resonant pumping at the hBN transverse optical phonon. Phonon-induced nonlinear enhancements are also predicted to yield large increases in high-harmonic efficiencies beyond the third.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Pressure-tuned quantum criticality in the large-D antiferromagnet DTN

Strongly correlated spin systems can be driven to quantum critical points via various routes. In particular, gapped quantum antiferromagnets can undergo phase transitions into a magnetically ordered state with applied pressure or magnetic field, acting as tuning parameters. These transitions are characterized by z = 1 or z = 2 dynamical critical exponents, determined by the linear and quadratic low-energy dispersion of spin excitations, respectively. Employing high-frequency susceptibility and ultrasound techniques, we demonstrate that the tetragonal easy-plane quantum antiferromagnet NiCl 2 · 4SC(NH 2 ) 2 (aka DTN) undergoes a spin-gap closure transition at about 4.2 kbar, resulting in a pressure-induced magnetic ordering. The studies are complemented by high-pressure-electron spin-resonance measurements confirming the proposed scenario. Powder neutron diffraction measurements revealed that no lattice distortion occurs at this pressure and the high spin symmetry is preserved, establishing DTN as a perfect platform to investigate z = 1 quantum critical phenomena. The experimental observations are supported by DMRG calculations, allowing us to quantitatively describe the pressure-driven evolution of critical fields and spin-Hamiltonian parameters in DTN.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

FOCAL Campaign II/III: Applying Active Hull Controls Using Tuned-mass Dampers/Hull Flexibility and Internal Loads

Campaign II and III of the Floating Offshore-wind Controls Advanced Laboratory Experimental Program (FOCAL) aimed to generate a dataset enabling the validation of the performance and loads of a scaled hull, with and without structural hull control. The floating platform was subjected to a variety of wave environments and controlled using tuned-mass dampers (TMDs) tuned to two of the systems natural frequencies (Platform Pitch and Tower-bending). The floating platform is fully instrumented to record a variety of parameters in real time such as platform dynamics, accelerations, and loads at different points in the structure. The test data considered was generated at the University of Maine's Harold Alfond Wind and Wave (W2) testing facility. This testing was focused only on validation of wave loading, and wind conditions were not considered. As such the platform does not support a working turbine, and instead supports a structure designed to have the same mass properties as the 1:70 IEA 15MW Reference turbine. The Load Cases (LC) considered in this testing campaign are as follows: LC 1.X - Platform Static Offset (TMD off); LC 2.X - Platform Free-decays (TMD off); LC 3.X - Wave Cases (Regular Wave, Irregular Wave, Pink Noise Wave) with and without TMDs active. Detailed properties on the model system are found in the following reference: Lenfest E., Floating Offshore-wind Controls Advanced Laboratory (FOCAL) Experimental Program - Campaigns 2 and 3: 1:70 Model-scale Testing of the IEA-Wind 15MW Reference Turbine and the VolturnUS-S Hull. UMaine ASCC Report Number 23-56-1183.

17 WIND ENERGY↗

Dynamic aperture studies at the Fermilab recycler ring

As part of the Proton Improvement Plan II (PIP-II), Fermilab aims to increase beam intensity delivered to neutrino experiments. In this context, higher intensity injection into the Recycler Ring enhances space charge effects, pushing operations closer to third-order resonances. These resonances reduce the Dynamic Aperture (DA), leading to increased beam loss. This study presents simulations of DA as a function of tune in the Recycler Ring, incorporating chaos indicators such as the Reversibility Error Method (REM) and Frequency Map Analysis (FMA). The effectiveness of existing resonance mitigation strategies is evaluated by quantifying their ability to delay DA degradation. Additionally, the study examines how space charge detuning and DA limitations dictate viable operational tune points for the Recycler Ring.

Gonzalez-Ortiz, Cristhian [Fermilab]↗

Hierarchical Ion Interactions in the Direct Air Capture of CO 2 at Air/Aqueous Interfaces

The direct air capture (DAC) of CO 2 using aqueous solvents is plagued by slow kinetics and interfacial barriers that limit effectiveness in combating climate change. Functionalizing air/aqueous surfaces with charged amphiphiles shows promise in accelerating DAC; however, insight into these interfaces and how they evolve in time remains poorly understood. Specifically, competitive ion interactions between DAC reagents and reaction products feedback onto the interfacial structure, thereby modulating interfacial chemical composition and overall function. In this work, we probe the role of glycine amino acid anions (Gly - ), an effective CO 2 capture reagent, that promotes the organization of cationic oligomers at air/aqueous interfaces. These surfaces are probed with vibrational sum frequency generation spectroscopy and molecular dynamics simulations. Our findings demonstrate that the competition for surface sites between Gly - and captured carbonaceous anions (HCO 3 - , CO 3 2 -, carbamates) drives changes in surface hydration, which in turn tunes oligomer ordering. This phenomenon is related to a hierarchical ordering of anions at the surface that are electrostatically attracted to the surface and their ability to compete for interfacial water. These results point to new ways to tune interfaces for DAC via stratification of ions based on relative surface propensities and specific ion effects.

54 ENVIRONMENTAL SCIENCES↗

Impact of the Exciter and Governor Parameters on Forced Oscillations

In recent years, the frequency of forced oscillation events due to control system malfunctions or improper parameter settings has increased. Tuning the parameters of exciters and governor models is crucial for maintaining power system stability. Traditional simulation studies typically involve small transient disturbances or step changes to find optimal parameter sets, but existing optimization algorithms often fall short in fine-tuning for forced oscillations. Identifying the sensitive parameters within these control models is essential for ensuring stability during large, sustained disturbances. This study focuses on identifying these critical exciter and governor model parameters by analyzing their influence on sustained forced oscillations. Using Kundur’s two-area system, we analyze common exciter models such as SCRX, ESST1A, and AC7B, along with governor models like GAST, HYGOV, and GGOV1, utilizing PSS®E software version 34. Sustained forced oscillations are injected at generator-1 of area-1, with individual parameter changes dynamically simulated. By considering a local oscillation frequency of 1.4 Hz and an inter-area oscillation mode of 0.25 Hz, we analyze the impact of each parameter change on the magnitude and frequency of forced oscillations as well as on active and reactive power outputs. This novel approach highlights the most influential parameters of each tested model—such as exciter, governor, and turbine gains, as well as time constant parameters—on the impact of forced oscillations. Based on our findings, the sensitive parameters of each tested model are ranked. These would provide valuable insights for industry operators to fine-tune control settings during oscillation events, ultimately enhancing system stability.

42 ENGINEERING↗

Impacts of A‐Site Composition on the Cation Dissolution‐Mediated Surface Restructuring of Layered Nickelate Oxide Electrocatalysts During Alkaline Oxygen Evolution Reaction

The oxygen evolution reaction (OER) is a key anodic counter‐reaction for electrochemical production of fuels and chemicals. It is hindered by sluggish four‐electron transfer kinetics requiring highly oxidative operating potentials to achieve commercially relevant rates. NiFeO x H y electrocatalysts are among the most promising for OER in alkaline electrolytes. The Ni(OH) 2 /NiOOH redox couple has been reported as the active phase in Ni‐based electrocatalysts; however, its activity is often hindered by deactivation arising from the formation of OER‐inactive insulating species. Limited strategies exist for mitigating this deactivation. This study aims to address this by interrogating the evolution of OER active sites as a function of precatalyst composition and structural properties using a series of layered, crystalline Ni‐based Ruddlesden–Popper (RP) oxides (A 2 NiO 4+δ ). In situ evolution of the active NiO x H y surface is probed through Ni‐site OER turnover frequency analysis, and electrochemical impedance spectroscopy coupled with scanning transmission electron microscopy. We show that the stability of layered nickelate oxide electrocatalysts is governed by the dynamic competition between cation dissolution and Ni‐site reversibility, which can be tuned through the A‐site composition of RP oxides. These findings yield insights toward engineering OER oxide precatalysts that optimize the stability of in situ‐generated OER active phases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Design and Analysis of an Integral MPPT Control Law for Wave Energy Conversion Systems

In this paper, we propose an integral-based maximum power point tracking (MPPT) algorithm for point absorber wave energy conversion (WEC) systems. A permanent magnet synchronous generator (PMSG) is coupled to the point absorber and its drive implements the proposed MPPT control. While the rotating frame of reference of the PMSG implements power control, the slower mechanical frequency of the incident waves are processed with an additional transformation that yields another set of dc dynamics. The computed dc power in the new reference frame, which is focused on slow wave dynamics, is input to the MPPT control law that tunes the emulated resistance of the machine drive to extract peak power from the wave absorber device. We derive a stability condition for the proposed controller and validate our control design on a simulated 10kW system.

wave energy, maximum power point tracking (MPPT), ↗