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Experimental Methods for the Performance Test of Environment-Assisted Cracking (EAC) in Nuclear Industry and Examples through NSUF

Environmentally assisted cracking (EAC) is a critical failure mode in nuclear reactor environments, where materials are exposed to high temperatures, radiation, and corrosive media. Specific EAC studies in nuclear environments include stress corrosion cracking in primary water chemistry, irradiation-assisted stress corrosion cracking (IASCC) under neutron exposure, and hydrogen induced cracking (HIC) in reactor pressure vessels. The experimental methodologies of EAC include slow strain rate testing (SSRT), constant load, and cyclic loading techniques, conducted in autoclaves designed to simulate the reactor’s operational environments. This paper highlights several experimental case studies, especially on IASCC, conducted within the Nuclear Science User Facilities (NSUF).

36 - MATERIALS SCIENCE

CFD Modeling of Concentration Polarization in High-Performance Flat-Sheet Modules

Membrane-based gas separation is a promising, regeneration-free route for industrial CO₂ capture, but its performance is often limited by concentration polarization (CP). Classical 1-D models neglect CP and thus overpredict fluxes, especially for today’s high-permeance, high-selectivity membranes. Therefore, we built a 3-D CFD model that resolves local species transport, boundary-layer resistance, permeate-side effects, and pressure drop in flat-sheet modules. Using the Concentration Polarization Coefficient (CPC) and the overall Effective Membrane CP Index (EAC), the model quantifies how geometry and operating conditions shape CP intensity. Simulations show CP becomes pronounced for advanced membranes, with feed-channel height emerging as the dominant geometric lever: shrinking the gap mitigates CP but raises pressure drop, forcing a trade-off between mass-transfer enhancement and energy cost. These insights emphasize the need for CFD-level analysis in next-generation module design, where 1-D treatments can severely underestimate required membrane area and misguide scale-up.

carbon capture

Materials Degradation in Extreme Environments: Novel In-situ Measurements of Cracking in Molten Salt

The safety and reliability of next-gen reactors, i.e. molten salt reactors (MSR), depends on materials performance and longevity in extreme environments, yet no in-situ, validated measurement techniques for environmentally assisted cracking (EAC), one potential degradation mechanism, exist for these conditions. This project combined the use of in-situ direct current potential drop (DCPD) crack growth rate determination applied to a horizontal load frame with high temperature fittings and novel sample geometries to enable evaluation in MSR environments and develop a full in-situ SCC measurement capability for extreme environments (high conductivity and elevated T), necessary to predict materials reliability. A successful demonstration of DCPD measurement in molten NaNO 3 /KNO 3 salts at 340 o C was accomplished and validated through post-test fractography imaging. This is the first ever public example, to the authors knowledge, of an in-situ crack growth rate measurement in a molten salt environment.

22 GENERAL STUDIES OF NUCLEAR REACTORS