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Results for “EARTH CORE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Alkaline Earth Core Level Photoemission Spectroscopy of High-Temperature Superconductors

This paper examines photoemission measurements of the alkaline Earth core levels of high-temperature superconductors and related materials, models that seek to explain the large negative shifts observed relative to the corresponding alkaline Earth metals, and the effect of lattice site disorder on the core level spectra and the presence or absence of intrinsic surface peaks.

superconductors Earth core photoemission↗

Crystal structure and equation of state of Fe-Si alloys at super-Earth core conditions

The high-pressure behavior of Fe alloys governs the interior structure and dynamics of super-Earths, rocky extrasolar planets that could be as much as ten times more massive than Earth. In experiments reaching up to 1300 GPa, we combine laser-driven dynamic ramp compression with in situ X-ray diffraction to study the effect of composition on the crystal structure and density of Fe-Si alloys, a potential constituent of super-Earth cores. We find that Fe-7wt.%Si adopts the hexagonal close packed (hcp) structure over the measured pressure range, whereas Fe-15wt.%Si is observed in a body-centered cubic (bcc) structure. This study represents the first experimental determination of the density and crystal structure of Fe-Si alloys at pressures corresponding to the center of a ~3 Earth-mass terrestrial planet. Our results allow for direct determination of the effects of light elements on core radius, density, and pressures for such planets.

36 MATERIALS SCIENCE↗

Thermal, dynamic and compositional aspects of the core-forming Earth

Core formation is the most important and singular differentiation event in the history of a terrestrial planet. It almost certainly involved the downward migration of a partially or wholly molten iron alloy through a silicate and oxide mantle, and was contemporaneous with accretion. Several important, unresolved issues which have implications for mantle and core geochemistry, the thermal history of the Earth, and the origin of geomagnetism are addressed: whether the early Earth was molten; whether core formation involved low or high pressure geochemistry, or both; early Earth mantle homogenization; whether equilibration established between core forming material and the mantle through which it migrated; and how much iron is stranded and unable to reach the core.

Stevenson, D. J.↗

Probing iron at Super-Earth core conditions

In this paper, we report on the quasi-isentropic compression of an iron sample using ramp shaped laser irradiation. This technique allows us to quasi-isentropically compress iron up to 700 GPa and 8500 K. To our knowledge, these data are the highest pressures reached on iron in off-Hugoniot conditions and the closest to the thermodynamic states thought to exist in Earth-like planetary cores. The experiment was performed on the Ligne d'Intégration laser facility at CESTA, Bordeaux, France.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Measuring the melting curve of iron at super-Earth core conditions

The discovery of more than 4500 extrasolar planets has created a need for modeling their interior structure and dynamics. Given the prominence of iron in planetary interiors, we require accurate and precise physical properties at extreme pressure and temperature. A first-order property of iron is its melting point, which is still debated for the conditions of Earth’s interior. Here, we used high-energy lasers at the National Ignition Facility and in situ x-ray diffraction to determine the melting point of iron up to 1000 gigapascals, three times the pressure of Earth’s inner core. We used this melting curve to determine the length of dynamo action during core solidification to the hexagonal close-packed (hcp) structure. We find that terrestrial exoplanets with four to six times Earth’s mass have the longest dynamos, which provide important shielding against cosmic radiation.

58 GEOSCIENCES↗

Solid Iron Compressed Up to 560 GPa [Fe at Earth core conditions probed by EXAFS]

Dynamic compression by multiple shocks is used to compress iron up to 560 GPa (5.6 Mbar), the highest solid-state pressure yet attained for iron in the laboratory. Extended x-ray absorption fine structure (EXAFS) spectroscopy offers simultaneous density, temperature, and local-structure measurements for the compressed iron. The data show that the close-packed structure of iron is stable up to 560 GPa, the temperature at peak compression is significantly higher than expected from pure compressive work, and the dynamic strength of iron is many times greater than the static strength based on lower pressure data. The results provide the first constraint on the melting line of iron above 400 GPa.

36 MATERIALS SCIENCE↗

The carbon content of Earth and its core

Earth’s core is likely the largest reservoir of carbon (C) in the planet, but its C abundance has been poorly constrained because measurements of carbon’s preference for core versus mantle materials at the pressures and temperatures of core formation are lacking. Using metal–silicate partitioning experiments in a laser-heated diamond anvil cell, we show that carbon becomes significantly less siderophile as pressures and temperatures increase to those expected in a deep magma ocean during formation of Earth’s core. Based on a multistage model of core formation, the core likely contains a maximum of 0.09(4) to 0.20(10) wt% C, making carbon a negligible contributor to the core’s composition and density. However, this accounts for ~80 to 90% of Earth’s overall carbon inventory, which totals 370(150) to 740(370) ppm. The bulk Earth’s carbon/sulfur ratio is best explained by the delivery of most of Earth’s volatiles from carbonaceous chondrite-like precursors.

Geosciences↗

High–Pressure Deformation of Iron–Nickel–Silicon Alloys and Implications for Earth’s Inner Core

Earth’s inner core exhibits strong seismic anisotropy, often attributed to the alignment of hexagonal close-packed iron (hcp-Fe) alloy crystallites with the Earth’s poles. How this alignment developed depends on material properties of the alloy and is important to our understanding of the core’s crystallization history and active geodynamical forcing. Previous studies suggested that hcp-Fe is weak under deep Earth conditions but did not investigate the effects of the lighter elements known to be part of the inner core alloy. Here, we present results from radial X-ray diffraction experiments in a diamond anvil cell that constrain the strength and deformation properties of iron-nickel-silicon (Fe–Ni–Si) alloys up to 60 GPa. We also show the results of laser heating to 1650 K to evaluate the effect of temperature. Observed alloy textures suggest different relative activities of the various hcp deformation mechanisms compared to pure Fe, but these textures could still account for the theorized polar alignment. Fe–Ni–Si alloys are mechanically stronger than Fe and Fe–Ni; extrapolated to inner core conditions, Si-bearing alloys may be more than an order of magnitude stronger. Furthermore, this enhanced strength proportionally reduces the effectivity of dislocation creep as a deformation mechanism, which may suggest that texture developed during crystallization rather than as the result of postsolidification plastic flow.

36 MATERIALS SCIENCE↗

Elastic and magnetic properties of Fe 3 P up to core pressures: Phosphorus in the Earth's core

Phosphorus (P) is considered a possible light element alloying with iron (Fe) in the Earth's core due to its siderophile nature and the ubiquity of P-bearing iron alloys in iron meteorites. The sequestration of P by liquid metals during the core formation possibly results in the relatively low concentration of P in the bulk silicate Earth. Here, we performed single-crystal and powder X-ray diffraction, synchrotron Mossbauer spectroscopy and nuclear resonant inelastic X-ray scattering measurements in diamond anvil cells to investigate the elastic and magnetic properties of Fe 3 P under high pressures. Our X-ray diffraction results suggest that there is no structural phase transition up to 111 GPa. However, a volume collapse was observed at 21.5 GPa in Fe 3 P, ascribed to a magnetic transition as evidenced by synchrotron Mhssbauer spectroscopy results. Fitting the volume-pressure data by the Birch-Murnaghan equation of state gives bulk modulus $K_{T0}$ = 162.4(7) GPa, its first pressure derivative $K'_{T0}$ = 4.0 (fixed) and zeropressure volume $V_0$ = 370.38(6) Å 3 for the magnetic phase and $K_{T0}$ = 220(7) GPa, $K'_{T0}$ = 4.0 (fixed) and $V_0$ = 357(1) Å 3 for the non-magnetic phase. Sound velocities of Fe 3 P were determined up to 152 GPa by nuclear resonant inelastic X-ray scattering, demonstrating that Fe 3 P bears a low shear velocity and high Poisson's ratio at core pressures compared to Fe and Fe 3 S. When forming a solid solution Fe 3 (S,P) with Fe 3 S at core pressures, Fe 3 P may favorably influence the elastic properties of Fe 3 (S,P) to match the seismic observations of the inner core.

58 GEOSCIENCES↗