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At least 19 records

Electric discharges in air - Near infrared emission spectrum.

The emission from glow discharges in flowing air has been investigated in the 1- to 5-micron wavelength region with a vacuum spectrometer. Most of the spectral features observed in the pressure range of .5 to 10 torr are identified, including atomic lines of OI, NI, and HI and molecular bands of N2, NO, N2O, CO2, and CO. The spectra are presented as a function of pressure and a table compiled of the atomic lines. Of particular interest are the contrasts between the emission of the air discharge and that of the pure gases, nitrogen and oxygen. In addition, the results of studies of several discharge modes, employing steady voltages and pulsed, provide data on details of the energy flow within the plasma.

Benesch, W. M.

Physical Retrieval of Surface Emissivity Spectrum from Hyperspectral Infrared Radiances

Retrieval of temperature, moisture profiles and surface skin temperature from hyperspectral infrared (IR) radiances requires spectral information about the surface emissivity. Using constant or inaccurate surface emissivities typically results in large retrieval errors, particularly over semi-arid or arid areas where the variation in emissivity spectrum is large both spectrally and spatially. In this study, a physically based algorithm has been developed to retrieve a hyperspectral IR emissivity spectrum simultaneously with the temperature and moisture profiles, as well as the surface skin temperature. To make the solution stable and efficient, the hyperspectral emissivity spectrum is represented by eigenvectors, derived from the laboratory measured hyperspectral emissivity database, in the retrieval process. Experience with AIRS (Atmospheric InfraRed Sounder) radiances shows that a simultaneous retrieval of the emissivity spectrum and the sounding improves the surface skin temperature as well as temperature and moisture profiles, particularly in the near surface layer.

Li, Jun

High-Resolution Electron-Impact Study of the Far-Ultraviolet Emission Spectrum of Molecular Hydrogen

The emission spectrum of molecular hydrogen produced by electron-impact excitation at 100 eV has been measured in the wavelength range 1140-1690 A. High-resolution, optically thin spectra (delta(lambda) = 0.136 A) of the far-ultraviolet (FUV) Lyman and Werner band systems have been obtained with a newly constructed 3 m spectrometer. Synthetic spectral intensities based on the transition probabilities calculated by Abgrall et al. are in very good agreement with experimentally observed intensities. Previous modeling that utilized Allison & Daigarno band transition probabilities with Hoenl-London factors breaks down when the transition moment has significant J dependence or when ro-vibrational coupling is significant. Ro-vibrational perturbation between upsilon = 14 of the B(sup 1)Sigma(sup +, sub u) state and upsilon = 3 of the C(sup 1)Pi(sub u) state and the rotational dependence of the transition moment in the bands of the Lyman system are examined. Complete high-resolution experimental reference FUV spectra, together with the model synthetic spectra based on the Abgrall transition probabilities, are presented. An improved calibration standard is obtained, and an accurate calibration of the 3 m spectrometer has been achieved.

Liu, Xian-Ming

Influence of the chemical bond on the K emission spectrum of oxygen and fluorine.

The K emission spectrum of oxygen and fluorine from a number of simple oxides and fluorides is divided into three to six sub-peaks. The spectra of many of these oxides and fluorides resemble one another owing to their basically ionic bonding. Certain sub-peaks, however, are ascribed to cross-over transitions and partially covalent energy levels. The different fluorine spectrum of Teflon is due to the hybrid nature of its covalent bonds.

Koster, A. S.

Airborne observations of the Orion molecular hydrogen emission spectrum

The Orion near-infrared H2 emission spectrum was observed from an altitude of 12.5 km in order to measure line intensities free from interference by terrestrial H2O. For the peak source, the observations indicate that the differential extinction between 4126 and 4712 per cm is 0.59 + or -0.06 mag, and the relative line intensities are consistent with those expected from a homogeneous source in approximate LTE at 1540 + or -100 K. An anomalous ortho/para H2 abundance ratio of 3.5(+ or - 0.2):1 is found, and the estimated total luminosity in vibrationally excited H2 lines is 300 + or - 100 solar luminosities. Rough molecular abundance limits, based on the missing H2 Q(6) line and the good agreement between other line intensities and the LTE model, place the H2 region no deeper within OMC-1 than the IR cluster and no shallower than 50 percent of the depth to the cluster.

Davis, D. S.

Extreme Ultraviolet Emission Spectrum of CO_2 Induced by Electron Impact at 200 eV

We present the extreme ultraviolet (EUV) emission spectrum of CO_2 induced by electronimpact at 200 eV. There are 36 spectral features which are identified with a resolution of 0.5 nmover the wavelength range of 40 to 125 nm. Absolute emission cross sections were obtained for eachof these features. The EUV emission spectrum induced by electron impact consist of atomicmultiplets of CI,II and OI,II,III as well as CO and CO^+ molecular band systems produced bydissociative excitation. The CI (119.4 nm) multiplet is the strongest feature of CI with a peak crosssection of 3.61 x 10^(-19) cm^2 at 200 eV. The strongest feature of OI in the EUV spectrum is theOI (99.0 nm) multiplet with a peak cross section of 3.59 x 10^(-19) cm^2 at 200 eV.

Kanik, I.

The far-ultraviolet /1180-1950 A/ emission spectrum of Arcturus

The far-ultraviolet (1180-1950 A) emission spectrum of the K2 IIIp star, Arcturus, has been obtained with a rocket-borne multichannel spectrometer. The use of multiple detectors gave an increase in effective observing time and permitted an improvement in spectral resolution over two previous rocket measurements. H I at 1216-A and O I at 1304 A are the only identified emissions, and the observed H I 1216-A flux is low compared with previous observations. A third unidentified feature was observed at 1511 A. The absence of many lines found in emission from the sun is striking. The absence of certain features implies that the coronal temperature must be either below 50,000 K or above 350,000 K.

Mckinney, W. R.

Io - A volcanic flow model for the hot spot emission spectrum and a thermostatic mechanism

The hot spots of Io are modeled as a steady state of active areas at 600 K, continuing creation of new lava flows and calderas, cooling off of recent flows and calderas, and the cessation of radiation of old flows and calderas from the accumulation of insulation added by resurfacing. There are three adjustable parameters in this model: the area of active sources at 600 K, the rate of production of new area that is cooling, and the temperature of cessation of emission as the result of resurfacing. The resurfacing rate sets constrains on this last parameter. The emission spectrum computed with reasonable values for these parameters is an excellent match to the spectrum from recent observations. A thermostatic mechanism is described whereby the volcanic activity is turned on for a long period of time and is then turned off for a nearly equal period. As a result the presently observed internal heat flow of approximately 1.5 W/sq m may be as much as twice the rate of production of internal heat. Thus the restrictions placed on theories of tidal dissipation by the observed heat flow may be partially relieved.

Sinton, V. M.

The thermal emission spectrum of Io and a determination of the heat flux from its hot spots

Observations of thermal emission from Io in the near infrared made during an eclipse were combined with unpublished 8- to 13-micron intermediate band photometry and a 16- to 22-micron spectrum to specify Io's emission spectrum from 2.2 to 22 microns. Models were calculated having 'hot spots' at several different temperatures superposed on a surface, the major part of which is assumed to be at the solar equilibrium temperature. It was possible to fit the entire composite spectrum with this model. It is argued that the total emission from the hot spots can be equated to the nonsolar energy input into Io. The disk-averaged heat radiated by the hot spots is found to be 180 + or 60 microwatts/sq cm = 43 + or - 14 microcalories/sq cm-sec. A possible bimodal temperature distribution of the hot spots is discussed.

Sinton, W. M.

Anharmonicity and the interstellar polycyclic aromatic hydrocarbon infrared emission spectrum

The hypothesis that interstellar infrared emission originates from vibrationally excited polycyclic aromatic hydrocarbons (PAHs) requires that emission can arise from all vibrational levels that are energetically accessible. Due to anharmonicity, the emission from the upper vibrational levels is shifted to longer wavelengths from that of the v = 1-0 transition. It is shown that structure in the 3-micron region is readily and quantitatively explained by emission from upper vibrational levels of excited PAHs that contain a maximum of 20-30 carbon atoms. The asymmetrical broadening of the 11.3-micron emission band may also be due to anharmonicity.

Barker, John R.