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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Accretion rate of extraterrestrial matter: Iridium deposited over the last 70 million years

In order to quantify the accretion rate of extraterrestrial matter during the Cenozoic, Ir concentrations were measured in a continuous series of 450 samples across most of the length of piston core LL44-GPC3. LL44-GPC3 is a 25-meter-long, large-diameter piston core of abyssal clay from the central North Pacific. This core contains a nearly continuous record of sedimentation over the last 70 Ma, as this site migrated from a region near the Equator in the late Cretaceous to its present position north of Hawaii. The first-cut survey across the core is nearing completion, and all of the conclusions of the earlier study, in which was reported the concentrations of Ir, Co, and Sb across 9 meters of this core, remain unchanged. The only strongly enhanced Ir concentrations occur at the Cretaceous-Tertiary (K-T) boundary and outside the K-T boundary Ir correlates well with Co, a terrestrial element which is largely present in hydrogenous ferromanganese oxide precipitates from seawater. Concentrations of both elements appear to be inversely correlated with the sedimentation rate. Although the K-T Ir anomaly is unique in magnitude in this core, there are several small bumps in the Ir profile which may reflect smaller accretionary events. The most promising Ir enhancement was observed in a 30 cm section approximately 1 m below the K-T boundary. Preliminary data suggest deposition of an excess across this interval at a time estimate to be approximate 1 Ma before the K-T impact event, but there is insufficient evidence at present to prove that this reflects enhanced accretion of extraterrestrial matter. A detailed model is being prepared of the chemical record of sedimentation in this core using a combined database of 39 elements in approximately 450 samples across the Cenozoic. Preliminary working model indicates that the only sedimentary sources which contribute significantly to the Ir budget in this core are the hydrogenous precipitates and extraterrestrial particulates.

Kyte, Frank T.↗
NASA NTRS1999

Solar-Cosmic-Ray-Produced Nuclides in Extraterrestrial Matter

There are two main types of cosmic rays that have sufficient energy to induce nuclear reactions -- the galactic cosmic rays (GCR) and solar cosmic rays (also called solar energetic particles). Both types of particles can have production rates and production ratios in the small objects often found in cold and hot deserts that are different from those seen for most meteorites, which typically have radii of approx. 10-100 centimeters. GCR production rates are often lower than those for most meteorites. GCR production ratios, such as Ne-22/Ne-21, are also often different in small objects. Smaller meteoroids also are more likely to have nuclides made by solar-cosmic-ray (SCR) particles than typically-sized meteorites. The very small meteorite Salem had large amounts of SCR-produced radionuclides. Meteorites recovered in Antarctica are more likely to contain SCR-produced nuclides than other meteorites. Martian and lunar meteorites are also likely to have SCR-produced nuclides. Production rates and profiles for SCR-produced nuclides in meteoroids have been calculated previously. However, the cross sections for the nuclear reactions making many SCR-produced nuclides, such as Be-10 were not well measured then. New rates and profiles are calculated here using good cross sections for the reactions making these nuclides.

Reedy, Robert C.↗
NASA NTRS2000

Solar-Cosmic-Ray-Produced Nuclides in Extraterrestrial Matter

There are two main types of cosmic rays that have sufficient energy to induce nuclear reactions -- the galactic cosmic rays (GCR) and solar cosmic rays (also called solar energetic particles). Both types of particles can have production rates and production ratios in the small objects often found in cold and hot deserts that are different from those seen for most meteorites, which typically have radii of approx.10-100 centimeters. GCR production rates are often lower than those for most meteorites. GCR production ratios, such as Ne-22/Ne-21, are also often different in small objects. Smaller meteoroids also are more likely to have nuclides made by solar-cosmic-ray (SCR) particles than typically-sized meteorites. The very small meteorite Salem had large amounts of SCR-produced radionuclides. Meteorites recovered in Antarctica are more likely to contain SCR-produced nuclides than other meteorites. Martian and lunar meteorites are also likely to have SCR-produced nuclides. Production rates and profiles for SCR-produced nuclides in meteoroids have been calculated previously. However, the cross sections for the nuclear reactions making many SCR-produced nuclides, such as Be-10, were not well measured then. New rates and profiles are calculated here using good cross sections for the reactions making these nuclides.

Reedy, Robert C.↗
NASA NTRS2001

Continued Investigations of the Accretion History of Extraterrestrial Matter over Geologic Time

This grant supported our ongoing project to characterize the accretion rate of interplanetary dust particles (IDPs) to Earth over geologic time using He-3 as a tracer. IDPs are derived from collisions in the asteroid belt and from disaggregation of active comets. Owing to their small size (few to few hundred micrometers diameter) these particles spiral into the sun under Poynting-Robertson drag typically in less than a few tens of kyrs. Thus IDPs must be continually resupplied to the zodiacal cloud, and because the processes of IDP production are likely to be sporadic, time variation in the IDP accretion rate to Earth is likely to be time-varying. For example, major asteroidal collisions and comet showers should greatly enhance the IDP accretion rate. Our ultimate objective (still ongoing) is to document this time variance so as to better understand the history of the solar system, the source of IDPs accreting to Earth, and the details of the mechanism by which particles are captured by Earth. To document variations in IDP accretion rate through time we use He-3 as a tracer. This isotope is in extremely low abundance in terrestrial matter, but IDPs have very high concentrations of He-3 from implantation of solar wind ions. By measuring He-3 in seafloor sediments, we can estimate the IDP accretion rate for at least the last few hundred Myrs. Under an earlier NASA grant we identified the existence of a large increase in He-3 flux in the Late Eocene (35 Myr ago), coincident with the two largest impact craters of the Cenozoic Era. The simplest interpretation of this observation is the occurrence of a shower of long period comets at that time, simultaneously increasing the impact cratering probability and accretion rate of IDPs to Earth (Farley et al., 1998). Comet showers produced by stellar perturbation of the Oort cloud should be fairly common in the geologic record, so this is not an unreasonable interpretation of our observations.

Farley, Kenneth↗
NASA NTRS2003

Tracers of the Extraterrestrial Component in Sediments and Inferences for Earth's Accretion History

The study of extraterrestrial matter in sediments began with the discovery of cosmic spherules during the HMS Challenger Expedition (1873-1876), but has evolved into a multidisciplinary study of the chemical, physical, and isotopic study of sediments. Extraterrestrial matter in sediments comes mainly from dust and large impactors from the asteroid belt and comets. What we know of the nature of these source materials comes from the study of stratospheric dust particles, cosmic spherules, micrometeorites, meteorites, and astronomical observations. The most common chemical tracers of extraterrestrial matter in sediments are the siderophile elements, most commonly iridium and other platinum group elements. Physical tracers include cosmic and impact spherules, Ni-rich spinels, meteorites, fossil meteorites, and ocean-impact melt debris. Three types of isotopic systems have been used to trace extraterrestrial matter. Osmium isotopes cannot distinguish chondritic from mantle sources, but provide a useful tool in modeling long-term accretion rates. Helium isotopes can be used to trace the long-term flux of the fine fraction of the interplanetary dust complex. Chromium isotopes can provide unequivocal evidence of an extraterrestrial source for sediments with high concentrations of meteoritic Cr. The terrestrial history of impacts, as recorded in sediments, is still poorly understood. Helium isotopes, multiple Ir anomalies, spherule beds, and craters all indicate a comet shower in the late Eocene. The Cretaceous-Tertiary boundary impact event appears to have been caused by a single carbonaceous chondrite projectile, most likely of asteroid origin. Little is known of the impact record in sediments from the rest of the Phanerozoic. Several impact deposits are known in the Precambrian, including several possible mega-impacts in the Early Archean.

Kyte, Frank T.↗
NASA NTRS2003

The Meteoritic Component in Impact Deposits

This proposal requested support for a broad-based research program designed to understand the chemical and mineralogical record of accretion of extraterrestrial matter to the Earth. The primary goal of this research is to study the accretion history of the Earth, to understand how this accretion history reflects the long-term flux of comets, asteroids, and dust in the inner solar system and how this flux is related to the geological and biological history of the Earth. This goal is approached by seeking out the most significant projects that can be attacked utilizing the expertise of the PI and potential collaborators. The greatest expertise of the PI is the analysis of meteoritic components in terrestrial sediments. This proposal identifies three primary areas of research, involving impact events in the early Archean (3.2 Ga), the late Eocene (35 Ma) and the late Pliocene (2 Ma). In the early Archean we investigate sediments that contain the oldest recorded impacts on Earth. These are thick spherule beds, three of which were deposited within 20 m.y. If these are impact deposits the flux of objects to Earth at this time was much greater than predicted by current models. Earlier work used Cr isotopes to prove that one of these contain extraterrestrial matter, from a projectile with Cr isotopes similar to CV chondrites. We planned to expand this work to other spherule beds and to search for additional evidence of other impact events. With samples from D. Lowe (Stanford Univ.) the PI proposed to screen samples for high Ir and Cr so that appropriate samples can be provided to A. Shukolyukov for Cr-isotopic analyses. This work was expected to provide evidence that at least one interval in the early Archean was a period of intense bombardment and to characterize the composition of objects accreted. The late Eocene is also a period of intense bombardment with multiple spherule deposits and two large craters. Farley et al. (1998) demonstrated an increased (3)He flux to marine sediments that was attributed to an increase in interplanetary dust due to a shower of comets invading the inner solar system. We planned to detect a change in the Cr-isotopic composition in the flux of fine-grained extraterrestrial matter to ocean sediments. This would provide evidence for the comet shower hypothesis. We planned attempt to locate late Eocene impact deposits in a new high resolution, hi-latitude site that had the potential for excellent preservation and new information of the sources and effects of these impacts. Although most impacts on Earth occur in deep-ocean basins, only one such event is known - the late Pliocene impact of the Eltanin asteroid. The ejecta from this impact includes Ir- rich impact melt, spherules, and actual meteorites from the km-sized mesosiderite asteroid. Through a study of the ejecta, we can learn about the formation, distribution, alteration and preservation of Ir-rich deposits. We can also learn about meteorite survival during hypervelocity impacts and we can study pieces of a km-sized object to learn more about the mesosiderite parent body. Analyses of sediment cores and geophysical exploration of the impact site can further our understanding of the processes involved in deep-ocean impacts and potential effects on the terrestrial climate and biosphere. We planned analyses of this ejecta, a search for ejecta 5000 km distant from the impact area, and a new oceanographic expedition to study and sample the impact site. In addition to these three specific areas of research, the PI planned to remain flexible and available to exploit new opportunities presented by new discoveries, and to engage in new collaborations if other researchers require his expertise to develop new projects that fit within the objectives of the overall research program.

Kyte, Frank T.↗
NASA NTRS2017

Organic Matter in Extraterrestrial Water-Bearing Salt Crystals

Introduction: Direct samples of early Solar System fluids are present in two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans (1998) [H5] and Zag [H3-6]), which were found to contain brine-bearing halite (NaCl) crystals that have been added to the regolith of an S-type asteroid following asteroidal metamorphism [1, 2]. The brine-bearing halite grains were proposed to be formed on an icy C-type asteroids (possibly Ceres), and transferred to an S-type asteroid via cryovolcanic event(s) [3]. A unique aspect of these halites is that they contain abundant organic rich solid inclusions hosted within the halites alongside the water inclusions. Methods: We analyzed in detail the compositions of the organic solids and the amino acid content of the halite crystals with two-step laser desorption/laser ionization mass spectrometry (L(sup 2) MS), Raman spectroscopy, X-ray absorption near edge structure (XANES), nanoscale secondary ion mass spectrometry (NanoSIMS), and ultra-performance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry (UPLC-FD/QToF-MS). Results and Discussion: The L(sup 2) MS results show signatures of low-mass polyaromatic hydro-carbons (PAHs) indicated by sequences of peaks separated by 14 atomic mass units (amu) due to successive addition of methylene (CH2) groups to the PAH skeletons [4]. Raman spectra of the micron-sized solid inclusions of the halites indicate the presence of abundant and highly variable organic matter that include a mixture of short-chain aliphatic compounds and macromolecular carbon. C-XANES analysis identified C-rich areas with peaks at 285.0 eV (aromatic C=C) and 286.6 eV (vinyl-keto C=O). However, there is no 1s-sigma* exciton peak (291.7 eV) that is indicative of the development of graphene structure [5], which suggests the organics were synthesized cold. Na-noSIMS analyses show C-rich and N-rich areas that exhibit similar isotopic values with that of the IOM in the unweathered CR chondrites and less metamorphosed meteorites [6], and are moderately enriched in N-15 (delta N-15 = 106.1-164.5 per mille). The total amino acid distribution and abundance of the Zag matrix (approximately 1,940 parts per billion [ppb]) is comparable to other ordinary chondrites (60-3,330 ppb) [7, 8]. While the Zag matrix is gamma-ABA and EACA-deficient, the halite is shown to exhibit an opposite trend and is almost depleted in amino acids. The striking difference in the amino acid contents between the halite and matrix indicates their separate synthetic origins. Conclusion: Abundant, primitive, and highly-diverse N-15-rich organic compounds were detected in brine-water bearing halite crystals that were synthesized on a cryovolcanically-active asteroid. Our study suggests that the asteroidal parent body where the halite precipitated, potentially Ceres, is a host to abundance large variety organic precursors. Insoluble organic matter and amino acids can be synthesized from similar organic precusors under hydrous conditions [9].We envision that similar organic synthetic processes could have occurred on Ceres that synthesized organic solids as well as biologically relevant molecules.

Chan, Q. H. S.↗
NASA NTRS1998

Extraterrestrial organic matter: a review

We review the nature of the widespread organic material present in the Milky Way Galaxy and in the Solar System. Attention is given to the links between these environments and between primitive Solar System objects and the early Earth, indicating the preservation of organic material as an interstellar cloud collapsed to form the Solar System and as the Earth accreted such material from asteroids, comets and interplanetary dust particles. In the interstellar medium of the Milky Way Galaxy more than 100 molecular species, the bulk of them organic, have been securely identified, primarily through spectroscopy at the highest radio frequencies. There is considerable evidence for significantly heavier organic molecules, particularly polycyclic aromatics, although precise identification of individual species has not yet been obtained. The so-called diffuse interstellar bands are probably important in this context. The low temperature kinetics in interstellar clouds leads to very large isotopic fractionation, particularly for hydrogen, and this signature is present in organic components preserved in carbonaceous chondritic meteorites. Outer belt asteroids are the probable parent bodies of the carbonaceous chondrites, which may contain as much as 5% organic material, including a rich variety of amino acids, purines, pyrimidines, and other species of potential prebiotic interest. Richer in volatiles and hence less thermally processed are the comets, whose organic matter is abundant and poorly characterized. Cometary volatiles, observed after sublimation into the coma, include many species also present in the interstellar medium. There is evidence that most of the Earth's volatiles may have been supplied by a 'late' bombardment of comets and carbonaceous meteorites, scattered into the inner Solar System following the formation of the giant planets. How much in the way of intact organic molecules of potential prebiotic interest survived delivery to the Earth has become an increasingly debated topic over the last several years. The principal source for such intact organics was probably accretion of interplanetary dust particles of cometary origin.

NASA Discipline Exobiology↗
NASA NTRS1994

Cross section parameterizations for cosmic-ray nuclei. 2: Double nucleon removal

Parameterizations of double nucleon removal from the electromagnetic and strong interactions of cosmic rays with nuclei are presented. These parameterizations are an extension of previous single nucleon removal parameterizations and combined they represent the dominant part of the electromagnetic dissociation encountered by a cosmic ray on its traversal through matter. Such parameterizations should be very useful in studying cosmic-ray transport through the interstellar medium, the Earth's atmosphere, spacecraft walls, and extraterrestrial matter.

Norbury, John W.↗
NASA NTRS1994

Cross section parameterizations for cosmic-ray nuclei. II. Double nucleon removal

Parameterizations of double nucleon removal from the electromagnetic and strong interactions of cosmic rays with nuclei are presented. These parameterizations are an extension of previous single nucleon removal parameterizations and combined they represent the dominant part of the electromagnetic dissociation encountered by a cosmic ray on its traversal through matter. Such parameterizations should be very useful in studying cosmic-ray transport through the interstellar medium, the Earth's atmosphere, spacecraft walls, and extraterrestrial matter.

NASA Discipline Radiation Health↗
NASA NTRS1990

Extraterrestrial halogen and sulfur contents of the stratosphere

Interplanetary dust represents a potential source of environmentally important chemical species in the earth's atmosphere. Previous studies have used computational models of atmospheric evolution of meteor debris to conclude that the steady-state stratospheric component of extraterrestrial matter is a small fraction of the total aerosol load. Observational data suggest such calculations may underestimate stratospheric residence times and, thus, concentrations. Two computational methods were employed here to obtain reasonable limits for the stratospheric contents of halogens and sulfur from extraterrestrial sources. The lower limit was based on the total stratospheric aerosol load and the relative influxes from interplanetary dust and tropospheric sources. The upper limit was obtained using a viscous settling method. These results suggest that the steady-state extraterrestrial influxes of halogens are minor compared to tropospheric sources but the sulfur input may be comparable to the present observed stratospheric content. Temporal enhancements in the meteoroid flux, such as passage through comet debris lanes or impact by large bodies, may produce significant chemical perturbations in the atmosphere.

Sutton, S. R.↗
NASA NTRS1982

AEM of extraterrestrial materials

Modifications to and maintenance of the JEOL 100 CX electron microscope are discussed. Research activity involving extraterrestrial matter, cosmic dust, stratosphere dust, and meteorites is summarized.

Mackinnon, I. D. R.↗