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Galileo post-Gaspra cruise and Earth-2 encounter

This article documents DSN support for the Galileo cruise after the Oct. 1991 encounter with the asteroid Gaspra. This article also details the Earth-2 encounter and the special non-DSN support provided during the Earth-2 closest approach.

Beyer, P. E.↗

Kinetically Controlled Linker Binding in Rare Earth-2,5-Dihydroxyterepthalic Acid Metal–Organic Frameworks and Its Predicted Effects on Acid Gas Adsorption

In the pursuit of highly stable and selective metal–organic frameworks (MOFs) for the adsorption of caustic acid gas species, an entire series of rare earth MOFs have been explored. Each of the MOFs in this series (RE-DOBDC; RE = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu; DOBDC = 2,5-dihydroxyterepthalic acid) was synthesized in the tetragonal space group I4/m. Crystallized MOF samples, specifically Eu-DOBDC, were seen to have a combination of monodentate and bidentate binding when synthesized under typical reaction conditions, resulting in a contortion of the structure. However, extended crystallization times determined that this binding is kinetically controlled and that the monodentate binding option was crystallographically eliminated by extended reaction times at higher temperatures. Furthermore, this series allows for the direct study of the effect of the metal center on the structure of the of the MOF; herein, the lanthanide metal ionic radii contraction across the periodic table results in a reduction of the MOF pore size and lattice parameters. Scanning electron microscopy–energy-dispersive spectroscopy was used to investigate the stages of crystal growth for these RE-DOBDC MOFs. All MOFs, except Er-DOBDC had a minimum of two stages of growth. These analogues were demonstrated by analysis of neutron diffraction (PND) to exhibit a cooperative rotational distortion of the secondary building unit, resulting in two crystallographically distinct linker sublattices. Computational modeling efforts were used to show distinct differences on acid gas (NO 2 and SO 2 ) binding energies for RE-DOBDC MOFs when comparing the monodentate/bidentate combined linker with the bidentate-only linker crystal structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Galileo Earth/Moon News Conference

This NASA Kennedy Space Center (KSC) video release (Part 1 of 2) begins with a presentation given by William J. O'Neil (Galileo Project Manager) describing the status and position of the Galileo spacecraft 7 days prior to the Galileo Earth-2 flyby. Slides are presented including diagrams of the Galileo spacecraft trajectory, trajectory correction maneuvers, and the Venus and asteroid flybys. Torrence Johnson (Galileo Project Scientist) follows Mr. O'Neil with an explanation of the Earth/Moon science activities that will be undertaken during the second Galileo/Earth encounter. These activities include remote sensing, magnetospheric and plasma measurements, and images taken directly from Galileo of the Earth and Moon. Dr. Joseph Veverka (Galileo Imaging Team, Cornell University) then gives a brief presentation of the data collected by the first Galileo/Gaspra asteroid flyby. Images sampled from the 57 photographs taken of Gaspra are presented along with discussions of Gaspra's morphology, shape and size, and surface features. These presentations are followed by a question and answer period given for the benefit of scientific journalists whose subjects include overall Galileo spacecraft health, verification of the Gaspra images timeframe, and the condition of certain scientific spacecraft instruments. Part 2 of this video can be retrieved by using Report No. NONP-NASA-VT-2000001078.

Source record↗