A report on emergent uranyl binding phenomena by an amidoxime phosphonic acid co-polymer
Abstract not provided
Abney, C. W.↗
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Differences in Outcomes between Patellar Dislocations Managed in Emergent versus Non-Emergent Care Settings
Abstract Patellar dislocations occur at a much higher rate in military than civilian populations. Past population-level studies have shown that surgical management is as good as or superior to conservative care and may reduce future reoccurrences. Although in acute cases and in civilian clinics, patellar dislocations are usually managed first in an emergent care setting, previous work suggests this can lead to increased costs. This study compared differences in downstream care type and intensity of services based on whether initial care occurred in emergent or non-emergent care settings. In our sample of 1,523 Military Health System (MHS) beneficiaries with patellar dislocation and 2-year follow-up, we found non-significant differences in costs, intensity of services, and rates of surgical repair regardless of whether the patient was initially seen in an emergent versus non-emergent care setting. Although we found significant increases in the use of imaging, patellar dislocation-related medical visits, and frequency of closed treatment approaches in emergent care settings, these values were very small and likely not clinically significant. These findings, which included all the patellar dislocations reported across the entire MHS in a 24-month period, suggest that neither emergent nor non-emergent care settings are likely to influence the long-term care received by the individual.
Orthopedics↗
Emergent Low-Symmetry Phases and Large Property Enhancements in Ferroelectric KNbO 3 Bulk Crystals [Emergent Low-Symmetry Phases with Large Property Enhancement in Ferroelectric KNbO 3 Bulk Crystals]
The design of new or enhanced functionality in materials is traditionally viewed as requiring the discovery of new chemical compositions through synthesis. Large property enhancements may however also be hidden within already well-known materials, when their structural symmetry is deviated from equilibrium through a small local strain or field. Here, the discovery of enhanced material properties associated with a new metastable phase of monoclinic symmetry within bulk KNbO 3 is reported. This phase is found to coexist with the nominal orthorhombic phase at room temperature, and is both induced by and stabilized with local strains generated by a network of ferroelectric domain walls. While the local microstructural shear strain involved is only ≈0.017%, the concurrent symmetry reduction results in an optical second harmonic generation response that is over 550% higher at room temperature. Moreover, the meandering walls of the low-symmetry domains also exhibit enhanced electrical conductivity on the order of 1 S m -1 . In conclusion, this discovery reveals a potential new route to local engineering of significant property enhancements and conductivity through symmetry lowering in ferroelectric crystals.
36 MATERIALS SCIENCE↗
Emergence and Progression of Abnormal Grain Growth in Minimally Strained Nickel-200.
Abstract not provided.
Underwood, Olivia De'Haven↗
Energy storage emerging: A perspective from the Joint Center for Energy Storage Research
Energy storage is an integral part of modern society. A contemporary example is the lithium (Li)-ion battery, which enabled the launch of the personal electronics revolution in 1991 and the first commercial electric vehicles in 2010. Most recently, Li-ion batteries have expanded into the electricity grid to firm variable renewable generation, increasing the efficiency and effectiveness of transmission and distribution. Important applications continue to emerge including decarbonization of heavy-duty vehicles, rail, maritime shipping, and aviation and the growth of renewable electricity and storage on the grid. This perspective compares energy storage needs and priorities in 2010 with those now and those emerging over the next few decades. The diversity of demands for energy storage requires a diversity of purpose-built batteries designed to meet disparate applications. Advances in the frontier of battery research to achieve transformative performance spanning energy and power density, capacity, charge/discharge times, cost, lifetime, and safety are highlighted, along with strategic research refinements made by the Joint Center for Energy Storage Research (JCESR) and the broader community to accommodate the changing storage needs and priorities. Innovative experimental tools with higher spatial and temporal resolution, in situ and operando characterization, first-principles simulation, high throughput computation, machine learning, and artificial intelligence work collectively to reveal the origins of the electrochemical phenomena that enable new means of energy storage. This knowledge allows a constructionist approach to materials, chemistries, and architectures, where each atom or molecule plays a prescribed role in realizing batteries with unique performance profiles suitable for emergent demands.
Trahey, Lynn↗
Emergency department overcrowding and its associated factors at HARME medical emergency center in Eastern Ethiopia
Introduction: Emergency department (ED) overcrowding has become a significant concern as it can lead to compromised patient care in emergency settings. Various tools have been used to evaluate overcrowding in ED. However, there is a lack of data regarding this issue in resource-limited countries, including Ethiopia. This study aimed to validate NEDOCS, assess level of ED overcrowding and identify associated factors at HARME Medical Emergency Center, located in Hiwot Fana Comprehensive Specialized Hospital, Harar, Ethiopia. Methods: A cross-sectional study was conducted at the HARME Medical Emergency Center, Hiwot Fana Comprehensive Specialized Hospital, involving a total of 899 patients during 120 sampling intervals. The area under the receiver operating characteristic curves (AUC) was calculated to evaluate the agreement between objective and subjective assessments of ED overcrowding. A multivariable logistic regression analysis was employed to identify factors associated with ED overcrowding and statistically significant association was declared using 95% confidence level and a p-value < 0.05. Results: The interrater agreement showed a strong correlation with a Cohen's kappa (κ) of 0.80. The National Emergency Department Overcrowding Study Score demonstrated a strong association with subjective assessments from residents and case team nurses, with an AUC of 0.81 and 0.79, respectively. According to residents' perceptions, ED were considered overcrowded 65.8% of the time. Factors significantly associated with ED overcrowding included waiting time for triage (AOR: 2.24; 95% CI: 1.54–3.27), working time (AOR: 2.23; 95% CI: 1.52–3.26), length of stay (AOR: 2.40; 95% CI: 1.27–4.54), saturation level (AOR: 2.35; 95% CI: 1.31–4.20), chronic illness (AOR: 2.19; 95% CI: 1.37–3.53), and abnormal pulse rate (AOR: 1.52; 95% CI: 1.06–2.16). Conclusion: The study revealed that ED were overcrowded approximately two-thirds of the time.
60 APPLIED LIFE SCIENCES↗
Accurate Efficiency Measurements for Emerging PV: A Comparison of NREL's Steady-State Performance Calibration Protocol Between Conventional and Emerging PV Technologies
Emerging PV technologies (e.g. Perovskite, and Quantum Dot) are commonly known to possess challenges for accurate performance measurement under the existing IEC 60904 series of standards, which were developed for conventional Si solar cells. Potential performance artifacts depending on scan rates and directions and light bias exposure history are often seen in those emerging solar cells. To avoid these artifacts and provide an unbiased and reliable efficiency measurement, NREL's Cell and Module Performance (CMP) Group has developed a steady-state performance calibration protocol - the asymptotic P MAX method. In this paper, we applied this procedure to four PV cell technologies, Si, CIGS, perovskite, and Quantum Dot (QD), and compared their performance variations between the transient and the steady-state conditions. By comparison, we found that the performance parameters ( i.e. V OC , I SC , FF, ..eta..) measured between fast I-V scans (and the asymptotic method (steady-state) change significantly for perovskite and QD cells. These changes do not happen for Si and CIGS cells. Furthermore, the statistical performance analysis on nearly 100 emerging cells received globally (including OPV, Perovskite, and QD) shows that over 70 % of the fast I-V scans have a relative performance deviation larger than 1% compared to those determined using the asymptotic P MAX scan. Given the complex dynamic behavior observed in emerging PV devices, the CMP group at NREL thus only certifies their steady steady-state performance using the Asymptotic P MAX method. We highly recommend similar steady-state performance calibration protocol for all researchers in emerging PV because accuracy in reported efficiencies is critical to the long-term success of those promising new PV technologies.
41 EE - Solar Energy Technologies Office (EE-4S)↗
Probing ab initio emergence of nuclear rotation
Structural phenomena in nuclei, from shell structure and clustering to superfluidity and collective rotations and vibrations, reflect emergent degrees of freedom. Ab initio theory describes nuclei directly from a fully microscopic formulation. We can therefore look to ab initio theory as a means of exploring the emergence of effective degrees of freedom in nuclei. For the illustrative case of emergent rotational bands in the $Be$ isotopes, we establish an understanding of the underlying oscillator space and angular momentum (orbital and spin) structure. We consider no-core configuration interaction (NCCI) calculations for 7, 9, 11 Be with the Daejeon16 internucleon interaction. Although shell model or rotational degrees of freedom are not assumed in the ab initio theory, the NCCI results are suggestive of the emergence of effective shell model degrees of freedom (0$\hbar$ω and 2$\hbar$ω excitations) and LS-scheme rotational degrees of freedom, consistent with an Elliott–Wilsdon SU(3) description. Finally, these results provide some basic insight into the connection between emergent effective collective rotational and shell model degrees of freedom in these light nuclei and the underlying ab initio microscopic description.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Outdoor urban nanomaterials: The emergence of a new, integrated, and critical field of study
Engineered nanomaterials (ENMs) are currently widely incorporated in the outdoor urban environmental fabric and numerous new applications and products containing ENMs are expected in the future. As has been shown repeatedly, products containing ENMs have the potential, at some point in their lifetime, to release ENMs into their surrounding environment. However, the expanding body in environmental nanomaterial research has not yet shifted toward ENMs in the context of the complex outdoor urban environment. This is especially surprising because the world's human populations are on a steady march toward more and more urbanization and technological development, accompanied with increased applications for ENMs in the outdoor urban environment. Our objective for this paper is therefore to review, assess, and provide new information in this emerging field. We provide an overview of nanomaterials (NMs, encompassing both ENMs and incidental nanomaterials, INMs) that are likely to be released in the urban environment from outdoor sources by discussing 1) the applications of ENMs that may lead to release of ENMs in urban areas, 2) the recently published data on the release of ENMs from novel nano-enabled applications in the outdoor urban environment, 3) the available literature on the occurrence of INMs in the atmosphere and within/on dust particles, and 4) the potential pathways and fate of NMs in the outdoor urban environment. This review is then followed by three case studies demonstrating the importance of NMs in the outdoor urban environment. The first and second case studies illustrate the occurrence of NMs in urban dust and stormwater ponds, respectively, whereas the third case study discusses the lessons learned from the release of NMs (e.g. Pt, ph and Rh) from automotive vehicle catalytic convertors. This article ends with a discussion of the research priorities needed to advance this emerging field of “outdoor urban nanomaterials” and to assess the potential risks of NMs in the context of urban environments.
77 NANOSCIENCE AND NANOTECHNOLOGY↗
Emergency Management of Tomorrow Research: Emergency Operations Center of the Future Tabletop Exercise Nashua, NH Tabletop Exercise
As part of the Emergency Management (EM) of Tomorrow Research (EMOTR) program, sponsored by the Department of Homeland Security (DHS) Science and Technology (S&T) Directorate, Pacific Northwest National Laboratory (PNNL) developed concepts for the Emergency Operations Center (EOC) of the Future to provide recommendations to assist DHS S&T in future decision-making with regards to research and development (R&D) and investments toward establishing a framework for a national, coordinated approach to EM. PNNL is conducting tabletop exercises (TTXs) designed to assess the impacts and benefits of emerging technologies on EM organizations.
99 GENERAL AND MISCELLANEOUS↗
Emergency Management of Tomorrow Research: Emergency Operations Center of the Future Seattle, WA Tabletop Exercise
As part of the Emergency Management (EM) of Tomorrow Research (EMOTR) program, sponsored by the Department of Homeland Security (DHS) Science and Technology (S&T) Directorate, Pacific Northwest National Laboratory (PNNL) developed concepts for the Emergency Operations Center (EOC) of the Future to provide recommendations to assist DHS S&T in future decision-making with regards to research and development (R&D) and investments toward establishing a framework for a national, coordinated approach to EM. PNNL is conducting tabletop exercises (TTXs) designed to assess the impacts and benefits of emerging technologies on EM organizations.
99 GENERAL AND MISCELLANEOUS↗
Emergency Management of Tomorrow Research: Emergency Operations Center of the Future Madison, WI Tabletop Exercise
As part of the Emergency Management (EM) of Tomorrow Research (EMOTR) program, sponsored by the Department of Homeland Security (DHS) Science and Technology (S&T) Directorate, Pacific Northwest National Laboratory (PNNL) developed concepts for the Emergency Operations Center (EOC) of the Future to provide recommendations to assist DHS S&T in future decision-making with regards to research and development (R&D) and investments toward establishing a framework for a national, coordinated approach to EM. PNNL is conducting tabletop exercises (TTXs) designed to assess the impacts and benefits of emerging technologies on EM organizations.
99 GENERAL AND MISCELLANEOUS↗
Emergency Management of Tomorrow: Emerging Technologies and Concepts
This article for the Domestic Preparedness Journal introduces the Emergency Management of Tomorrow Research Program and its role exploring artificial intelligence for emergency management and emergency operation centers in the future.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
Emerging Trends in Emergent Stroke Neuroimaging
Purpose of Review: Various imaging techniques used in stroke evaluation have complementary, evolving roles. This article reviews recent updates in emergent stroke neuroimaging. Recent Findings: Multiple recent randomized trials showing benefit of endovascular therapy in strokes with confirmed large-vessel occlusion emphasize need for vessel imaging, typically CTA, in addition to unenhanced head CT. In addition, because recent trials published in 2018 showed efficacy of mechanical thrombectomy at up to 24 h from symptom onset in stroke patients with favorable ischemic core and/or penumbra assessments, imaging techniques to define viable and infarcted tissue, such as DWI or CT/MR perfusion imaging, have an increasing role in emergent stroke assessment. Other studies contributing to new AHA/ASA stroke guidelines are also discussed. Summary: Neuroimaging remains crucial to emergent stroke evaluation, with CTA, MRI, and perfusion studies playing an increasing role in identifying patients likely to benefit from treatment.
62 RADIOLOGY AND NUCLEAR MEDICINE↗
Learning emergent partial differential equations in a learned emergent space
We propose an approach to learn effective evolution equations for large systems of interacting agents. This is demonstrated on two examples, a well-studied system of coupled normal form oscillators and a biologically motivated example of coupled Hodgkin-Huxley-like neurons. For such types of systems there is no obvious space coordinate in which to learn effective evolution laws in the form of partial differential equations. In our approach, we accomplish this by learning embedding coordinates from the time series data of the system using manifold learning as a first step. In these emergent coordinates, we then show how one can learn effective partial differential equations, using neural networks, that do not only reproduce the dynamics of the oscillator ensemble, but also capture the collective bifurcations when system parameters vary. The proposed approach thus integrates the automatic, data-driven extraction of emergent space coordinates parametrizing the agent dynamics, with machine-learning assisted identification of an emergent PDE description of the dynamics in this parametrization.
97 MATHEMATICS AND COMPUTING↗
Fast Evaluation of Viral Emerging Risks (FEVER): A computational tool for biosurveillance, diagnostics, and mutation typing of emerging viral pathogens
Viral pathogens can rapidly evolve, adapt to novel hosts, and evade human immunity. The early detection of emerging viral pathogens through biosurveillance coupled with rapid and accurate diagnostics are required to mitigate global pandemics. However, RNA viruses can mutate rapidly, hampering biosurveillance and diagnostic efforts. Here, we present a novel computational approach called FEVER (Fast Evaluation of Viral Emerging Risks) to design assays that simultaneously accomplish: 1) broad-coverage biosurveillance of an entire group of viruses, 2) accurate diagnosis of an outbreak strain, and 3) mutation typing to detect variants of public health importance. We demonstrate the application of FEVER to generate assays to simultaneously 1) detect sarbecoviruses for biosurveillance; 2) diagnose infections specifically caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2); and 3) perform rapid mutation typing of the D614G SARS-CoV-2 spike variant associated with increased pathogen transmissibility. These FEVER assays had a high in silico recall (predicted positive) up to 99.7% of 525,708 SARS-CoV-2 sequences analyzed and displayed sensitivities and specificities as high as 92.4% and 100% respectively when validated in 100 clinical samples. The D614G SARS-CoV-2 spike mutation PCR test was able to identify the single nucleotide identity at position 23,403 in the viral genome of 96.6% SARS-CoV-2 positive samples without the need for sequencing. This study demonstrates the utility of FEVER to design assays for biosurveillance, diagnostics, and mutation typing to rapidly detect, track, and mitigate future outbreaks and pandemics caused by emerging viruses.
59 BASIC BIOLOGICAL SCIENCES↗
A Tale of Two Emergences: Sunrise II Observations of Emergence Sites in a Solar Active Region
In 2013 June, the two scientific instruments on board the second Sunrise mission witnessed, in detail, a small-scale magnetic flux emergence event as part of the birth of an active region. The Imaging Magnetograph Experiment (IMaX) recorded two small (∼5{sup ′′}) emerging flux patches in the polarized filtergrams of a photospheric Fe i spectral line. Meanwhile, the Sunrise Filter Imager (SuFI) captured the highly dynamic chromospheric response to the magnetic fields pushing their way through the lower solar atmosphere. The serendipitous capture of this event offers a closer look at the inner workings of active region emergence sites. In particular, it reveals in meticulous detail how the rising magnetic fields interact with the granulation as they push through the Sun’s surface, dragging photospheric plasma in their upward travel. The plasma that is burdening the rising field slides along the field lines, creating fast downflowing channels at the footpoints. The weight of this material anchors this field to the surface at semi-regular spatial intervals, shaping it in an undulatory fashion. Finally, magnetic reconnection enables the field to release itself from its photospheric anchors, allowing it to continue its voyage up to higher layers. This process releases energy that lights up the arch-filament systems and heats the surrounding chromosphere.
79 ASTRONOMY AND ASTROPHYSICS↗