Surface Reactivity of Carbon in High-Enthalpy, Atmospheric-Pressure Nitrogen and Air Plasmas
Explore the source record for details and available documents.
Murray, John Stuart [Sandia National Laboratories ↗
SEARCH · Search NASA
Results for “Enthalpy”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Evaluation of a self-aspirating local total enthalpy probe in a low-density arc-heated hypersonic wind tunnel
A shock-swallowing, self-aspirating, local total enthalpy probe has been evaluated in a low density nonequilibrium, hypervelocity airstream. The probe, which incorporated an air gap to separate the internal and external cooling passages, was tested in an electric archeated wind tunnel at an average Mach number of 11.7 and an average Reynolds number per meter of 57,000. The free stream enthalpy probe data are compared with bulk calorimeter measurements of total enthalpy at the beginning of the gas expansion and with local total enthalpy inferred from a theoretical nonequilibrium gas expansion model by using free stream velocity measurements obtained from a mass flow probe. The three techniques are in relative agreement at the lower enthalpies. However, at the higher enthalpies, the enthalpy probe data lie considerably below the other data. This low data may be caused by the chemical and vibrational energy frozen in the flow not being sensed by the probe. Other problems associated with the shock-swallowing total enthalpy probe are discussed, and recommendations for improving the probe performance are presented.
Guy, R. W.↗
Increase of stagnation pressure and enthalpy in shock tunnels
High stagnation pressures and enthalpies are required for the testing of aerospace vehicles such as aerospace planes, aeroassist vehicles, and reentry vehicles. Among the most useful ground test facilities for performing such tests are shock tunnels. With a given driver gas condition, the enthalpy and pressure in the driven tube nozzle reservoir condition can be varied by changing the driven tube geometry and initial gas fill pressure. Reducing the driven tube diameter yields only very modest increases in reservoir pressure and enthalpy. Reducing the driven tube initial gas fill pressure can increase the reservoir enthalpy significantly, but at the cost of reduced reservoir pressure and useful test time. A new technique, the insertion of a converging section in the driven tube is found to produce substantial increases in both reservoir pressure and enthalpy. Using a one-dimensional inviscid full kinetics code, a number of different locations and shapes for the converging driven tube section were studied and the best cases found. For these best cases, for driven tube diameter reductions of factors of 2 and 3, the reservoir pressure can be increased by factors of 2.1 and 3.2, respectively and the enthalpy can be increased by factors of 1.5 and 2.1, respectively.
Bogdanoff, David W.↗
Thermochemically-Closed Sonic-Flow Inversion for Enthalpy and Temperature in Multispecies Arc-Jet Flows
A thermochemically-closed sonic-flow inversion framework (TSIF) is developed to infer bulk enthalpy and total temperature upstream of a choked nozzle in arc-jet flows. The formulation recasts a pressure-rise total enthalpy quantification technique as an inverse problem in characteristic-velocity c * space using measured mass flow rate, upstream total pressure, gas composition, and nozzle throat geometry as inputs. Unlike calorimetric energy-balance approaches or optical diagnostics, the method relies primarily on routinely measured facility quantities combined with explicit thermochemical closure. Thermochemical states are obtained using NASA’s open-source Chemical Equilibrium with Applications (CEA) code, enabling construction of a chemistry-consistent relation between characteristic velocity, total enthalpy, and total temperature under equilibrium or frozen assumptions. A discharge coefficient is self-calibrated using cold-flow (arc-off) operation data and applied to hot-flow (arc-on) measurements, enabling upstream losses to be accounted for without empirical correlations. The framework is applied to air, N 2 , and CO 2 –N 2 arc-jet flows and demonstrates expected trends for the inferred thermochemical states as function of arc power, specific energy input, mass-flow, heater configuration, and test gas. In the air limit, under equilibrium assumptions, the method recovers the classical high-enthalpy asymptotic correlation of Winovich with a mean residual of 4.4%, demonstrating compatibility with established sonic-flow scaling, while extending applicability to arbitrary multi-species mixtures and non-equilibrium chemistry. The framework provides a mixture-flexible methodology for determining bulk thermochemical states in modern arc-jet environments using routine facility pressure, mass-flow, gas-composition, and nozzle-geometry information together with a cold-flow calibration.
stagnation heat flux↗
Thermochemically-Closed Sonic-Flow Inversion for Enthalpy and Temperature in Multispecies Arc-Jet Flows
A thermochemically-closed sonic-flow inversion framework (TSIF) is developed to infer bulk enthalpy and total temperature upstream of a choked nozzle in arc-jet flows. The formulation recasts a pressure-rise total enthalpy quantification technique as an inverse problem in characteristic-velocity c * space using measured mass flow rate, upstream total pressure, gas composition, and nozzle throat geometry as inputs. Unlike calorimetric energy-balance approaches or optical diagnostics, the method relies primarily on routinely measured facility quantities combined with explicit thermochemical closure. Thermochemical states are obtained using NASA’s open-source Chemical Equilibrium with Applications (CEA) code, enabling construction of a chemistry-consistent relation between characteristic velocity, total enthalpy, and total temperature under equilibrium or frozen assumptions. A discharge coefficient is self-calibrated using cold-flow (arc-off) operation data and applied to hot-flow (arc-on) measurements, enabling upstream losses to be accounted for without empirical correlations. The framework is applied to air, N 2 , and CO 2 –N 2 arc-jet flows and demonstrates expected trends for the inferred thermochemical states as function of arc power, specific energy input, mass-flow, heater configuration, and test gas. In the air limit, under equilibrium assumptions, the method recovers the classical high-enthalpy asymptotic correlation of Winovich with a mean residual of 4.4%, demonstrating compatibility with established sonic-flow scaling, while extending applicability to arbitrary multi-species mixtures and non-equilibrium chemistry. The framework provides a mixture-flexible methodology for determining bulk thermochemical states in modern arc-jet environments using routine facility pressure, mass-flow, gas-composition, and nozzle-geometry information together with a cold-flow calibration.
inviscid theory↗
Theoretical and experimental quantification of Suzuki segregation enthalpy and strengthening mechanisms in a binary alloy
Solute segregation to planar defects in metallic alloys has been shown to drastically alter mechanical properties. While various works using first-principles and thermodynamic calculations have studied the fundamental driving forces for solute segregation via the Suzuki criterion, planar defect energy, or a comparison of energies of the HCP-like phase and FCC matrix, a quantitative experimental and computational comparison of equilibrium composition and segregation enthalpies has not yet been reported. In this work, we predict the equilibrium composition and segregation enthalpy to intrinsic stacking faults in a Ni-60Co (at.%) alloy and compare the results to two independent experimental methods. We observed that Co segregates to the innermost two planes of the intrinsic stacking fault, and we found that the experimental segregation enrichment, measured from transmission electron microscopy energy dispersive X-ray spectroscopy, of the faults is 6.8 at.% Co, which is 2.2 at.% less than the predicted value at the same temperature. We also find that the segregation enthalpy measured from the composition profile is −21.1 ± 6.4 meV/atom and separately from differential scanning calorimetry segregation enthalpy is −33.2 meV/atom, whereas the predicted enthalpy is −31 ± 1 meV/atom. Based on these results, we determine that segregation occurs very rapidly, within 8 min at temperatures as low as 36% of the homologous solidus temperature. Furthermore, this analysis provides an overview of the possible dislocation mechanisms responsible for strengthening effects due to solute segregation, and concludes that changes in room temperature hardness from local phase transformation is likely tied to post-segregation room temperature equilibrium partial separation distance.
Ab initio calculation↗
Upward band gap bowing and negative mixing enthalpy in multi-component cubic halide perovskite alloys
Physical properties intermediate between constituents of alloys can be achieved as downward convex positive bowing, upward concave negative bowing, or zero bowing. Such bowing effects are essential for band gap engineering in semiconductor alloys. Upward band gap bowing effects are rather rare, hindering the exploration on half of the available physical property space of alloys. Part of this being a rare event is related to the need to stabilize an alloy with low mixing enthalpy, so it does not phase separate. Here, in this paper, we find via density functional theory that one can satisfy the simultaneous conditions of negative mixing enthalpy and upward band gap bowing in four-component ABX 3 halide perovskite alloys in the cubic perovskite structure. Such perovskite alloys have the B-site occupied by a mixture of group IVB and IIB elements that have the IVB-𝑠 and IIB-s states in the valence bands and conduction bands, respectively, leaving the delocalized 𝑠 states to strongly repel each other. This 𝑠−𝑠 repulsion leads to the upward band gap bowing and negative mixing enthalpies simultaneously. Remarkably, we identify a perovskite alloy that has a band gap much larger than all its components. Analogous trends of upward band gap bowing and negative mixing enthalpy also appear in the corresponding three-component and two-component ABX 3 halide perovskite alloys. These observations of upward band gap bowing and negative mixing enthalpy will significantly accelerate the design of stable upward band gap bowing alloys in a broad range of material families.
14 SOLAR ENERGY↗
Enthalpy damping for the steady Euler equations
For inviscid steady flow problems where the enthalpy is constant at steady state, it was previously proposed to use the difference between the local enthalpy and the steady state enthalpy as a driving term to accelerate convergence of iterative schemes. This idea is analyzed, both on the level of the partial differential equation and on the level of a particular finite difference scheme. It is shown that for the two-dimensional unsteady Euler equations, a hyperbolic system with eigenvalues on the imaginary axis, there is no enthalpy damping strategy which moves all the eigenvalues into the open left half plane. For the numerical scheme, however, the analysis shows and examples verify that enthalpy damping is potentially effective in accelerating convergence to steady state.
Jespersen, D. C.↗
Enthalpy damping for the steady Euler equations
For inviscid steady flow problems where the enthalpy is constant at steady state, it was previously proposed to use the difference between the local enthalpy and the steady state enthalpy as a driving term to accelerate convergence of iterative schemes. This idea is analyzed, both on the level of the partial differential equation and on the level of a particular finite difference scheme. It is shown that for the two-dimensional unsteady Euler equations, a hyperbolic system with eigenvalues on the imaginary axis, there is no enthalpy damping strategy which moves all the eigenvalues into the open left half plane. For the numerical scheme, however, the analysis shows and examples verify that enthalpy damping is potentially effective in accelerating convergence to steady state.
Jespersen, D. C.↗
Bulk Enthalpy Calculations in the Arc Jet Facility at NASA ARC
The Arc Jet Facilities at NASA Ames Research Center generate test streams with enthalpies ranging from 5 MJ/kg to 25 MJ/kg. The present work describes a rigorous method, based on equilibrium thermodynamics, for calculating the bulk enthalpy of the flow produced in two of these facilities. The motivation for this work is to determine a dimensionally-correct formula for calculating the bulk enthalpy that is at least as accurate as the conventional formulas that are currently used. Unlike previous methods, the new method accounts for the amount of argon that is present in the flow. Comparisons are made with bulk enthalpies computed from an energy balance method. An analysis of primary facility operating parameters and their associated uncertainties is presented in order to further validate the enthalpy calculations reported herein.
Thompson, Corinna S.↗
Impact of Flight Enthalpy, Fuel Simulant, and Chemical Reactions on the Mixing Characteristics of Several Injectors at Hypervelocity Flow Conditions
The high total temperatures or total enthalpies required to duplicate the high-speed flight conditions in ground experiments often place stringent requirements on the material selection and cooling needs for the test articles and intrusive flow diagnostic equipment. Furthermore, for internal flows, these conditions often complicate the use of nonintrusive diagnostics that need optical access to the test section and interior portions of the flowpath. Because of the technical challenges and increased costs associated with experimentation at high values of total enthalpy, an attempt is often made to reduce it. This is the case for the Enhanced Injection and Mixing Project (EIMP) currently underway in the Arc-Heated Scramjet Test Facility at the NASA Langley Research Center. The EIMP aims to investigate supersonic combustion ramjet (scramjet) fuel injection and mixing physics, improve the understanding of underlying physical processes, and develop enhancement strategies and functional relationships between mixing performance and losses relevant to flight Mach numbers greater than 8. The experiments will consider a "direct-connect" approach and utilize a Mach 6 nozzle to simulate the combustor entrance flow of a scramjet engine. However, while the value of the Mach number is matched to that expected at the combustor entrance in flight, the maximum value of the total enthalpy for these experiments is limited by the thermal-structural limits of the uncooled experimental hardware. Furthermore, the fuel simulant is helium, not hydrogen. The use of "cold" flows and non-reacting mixtures of fuel simulants for mixing experiments is not new and has been extensively utilized as a screening technique for scramjet fuel injectors. In this study, Reynolds-averaged simulations are utilized (RAS) to systematically verify the implicit assumptions used by the EIMP. This is accomplished by first performing RAS of mixing for two injector configurations at planned nominal experimental conditions. The mixing parameters of interest, such as mixing efficiency and total pressure recovery, are then computed and compared to the values obtained from RAS under the true enthalpy conditions and using helium and hydrogen. Finally, the impact of combustion on mixing, often deemed small enough to neglect at hypervelocity conditions, is assessed by comparing the results obtained from the hydrogen-fueled reacting and non-reacting RAS. For reacting flows, in addition to mixing efficiency and total pressure recovery, the combustion efficiency and thrust potential are also considered. In all of the simulations, the incoming air Mach number and the fuel-to-air ratio are the same, while the total pressure, total enthalpy, and the fuel simulant vary depending on the case considered. It is found that under some conditions the "cold" flow experiments are a good approximation of the flight.
Drozda, Tomasz G.↗
Expanding the Measurement Capabilities of the mARC II Arc-Jet to Map the Operating Envelope for High-Enthalpy Air Flows
The mARC II is a 30 kW arc-jet facility at NASA Ames Research Center developed to produce high-enthalpy flows for low-cost technology development purposes. In this work, we introduce new measurement capabilities following the latest facility upgrades and begin characterizing the operating envelope for the two-disk arc-heater configuration with air as the working gas. The lower bound of the envelope corresponds to the lowest set current and the farthest sensor distance from the nozzle (𝐼set = 40 A, 𝑧 = 69 mm), while the upper bound corresponds to the highest current and closest sensor distance (𝐼set = 200 A, 𝑧 = 2 mm). Stagnation point heat flux was measured using a water-cooled Gardon gauge (⌀4.76 mm, 3/16" hemispherical), with values ranging from 15 ≤ q̇₀ ≤ 900 W/cm2. Stagnation pressure was measured using a water-cooled Pitot probe (⌀4.76 mm, 3/16" hemispherical), with values ranging from 18 ≤ p₀ ≤ 1100 Pa. The upgraded vacuum system is demonstrated to significantly extend the lower end of the operating envelope of the mARC II. Additionally, measurements of bulk enthalpy (3 ≤ h ≤ 13 MJ/kg) and stagnation enthalpy (4 ≤ h₀ ≤ 34 MJ/kg) demonstrate the mARC II facility's high-enthalpy capabilities. Completion of the operating envelope characterization is ongoing in tandem with the development of complementary diagnostic capabilities and numerical simulations.
TPS↗
Expanding the Measurement Capabilities of the mARC II Arc-Jet to Map the Operating Envelope for High-Enthalpy Air Flows
The mARC II is a 30 kW arc-jet facility at NASA Ames Research Center developed to produce high-enthalpy flows for low-cost technology development purposes. In this work, we introduce new measurement capabilities following the latest facility upgrades and begin characterizing the operating envelope for the two-disk arc-heater configuration with air as the working gas. The lower bound of the envelope corresponds to the lowest set current and the farthest sensor distance from the nozzle (𝐼set = 40 A, 𝑧 = 69 mm), while the upper bound corresponds to the highest current and closest sensor distance (𝐼set = 200 A, 𝑧 = 2 mm). Stagnation point heat flux was measured using a water-cooled Gardon gauge (⌀4.76 mm, 3/16" hemispherical), with values ranging from 15 ≤ q̇₀ ≤ 900 W/cm 2 . Stagnation pressure was measured using a water-cooled Pitot probe (⌀4.76 mm, 3/16" hemispherical), with values ranging from 18 ≤ p₀ ≤ 1100 Pa. The upgraded vacuum system is demonstrated to significantly extend the lower end of the operating envelope of the mARC II. Additionally, measurements of bulk enthalpy (3 ≤ h ≤ 13 MJ/kg) and stagnation enthalpy (4 ≤ h₀ ≤ 34 MJ/kg) demonstrate the mARC II facility's high-enthalpy capabilities. Completion of the operating envelope characterization is ongoing in tandem with the development of complementary diagnostic capabilities and numerical simulations.
instrumentation↗
Mass, enthalpy, and chemical‐derived emission flows in mineral processing
Abstract The production of materials from mineral resources is a significant contributor to anthropogenic CO 2 emissions. This contribution is driven primarily by chemical CO 2 emissions from the conversion of mineral resources and emissions tied to energy demands for material processing. In this work, we synthesize the thermodynamically required enthalpy and chemically derived emissions of mineral processing and consumption in the United States. We quantify mass, enthalpy, and emissions flows for minerals described by the US Geological Survey, with 882 mass flows and 155 chemical reactions analyzed. In total, 503 PJ of enthalpy is thermodynamically required for 398 Mt of chemically converted material consumption in the United States, resulting in 129 Mt of chemically derived CO 2 emissions. Additionally, 249 PJ of fuel resources such as coke are stoichiometrically required for the chemical conversion of minerals. These enthalpy requirements and CO 2 emissions are primarily from high‐mass consumption materials such as cement, carbon steel, fertilizer, and aluminum. Cumulatively, the dataset synthesized in this work provides a complete view of the chemical requirements of mineral processing and can aid in guiding decarbonization or sustainable growth in critical minerals sectors, including construction materials and materials for energy storage or generation.
Kane, Seth↗
Enthalpies of a binary alloy during solidification
The purpose of the paper is to present a method of calculating the enthalpy of a dendritic alloy during solidification. The enthalpies of the dendritic solid and interdendritic liquid of alloys of the Pb-Sn system are evaluated, but the method could be applied to other binaries, as well. The enthalpies are consistent with a recent evaluation of the thermodynamics of Pb-Sn alloys and with the redistribution of solute in the same during dendritic solidification. Because of the heat of mixing in Pb-Sn alloys, the interdendritic liquid of hypoeutectic alloys (Pb-rich) of less than 50 wt pct Sn has enthalpies that increase as temperature decreases during solidification.
Poirier, D. R.↗
ARCFLO analysis for high-enthalpy arc heaters
Feasibility, physical constraints, and preliminary design and operating envelope are calculated for a next-generation segmented arc heater with enthalpies of 70-90 MJ/kg, for simulation of fast lunar or Martian return trajectories. The ARCFLO computer program is modified for improved accuracy in high-enthalpy radiation-dominated flows. The ARCFLO band-radiation model is compared with the state-of-the-art spectral-radiation code NEQAIR. The band-radiation model is corrected, and band-absorption coefficients are reduced by up to 40 percent at high temperatures. Parametric studies show that, with conventional wall-heating limitations, high mass flow and high enthalpy are contradictory design goals owing to the increase of radiation losses with pressure, current density, and constrictor diameter. With existing hardware limitations, an enthalpy of 70 MJ/kg with a flow rate of 0.1 kg/s can be achieved in a constrictor with 5-6 cm diameter operating near 3-atm stagnation pressure. The total power is under 100 MW, but the current is very high: 14,000-18,000 amperes.
Milos, Frank S.↗
Transition on a sharp cone at high enthalpy - New measurements in the shock tunnel T5 at GALCIT
An exploratory study of the laminar, transitional and turbulent boundary layer on a slender cone in hypervelocity flow was conducted in the high-enthalpy shock tunnel T5. A novel flow visualization technique using sodium seeding to increase the sensitivity of conventional interferometric techniques by resonant enhancement of the refractivity of the medium was developed to study its structure. The experiments were designed to cover a large range of specific reservoir enthalpy, ranging from the perfect-gas region to the range where significant oxygen and some nitrogen dissociation and recombination effects may be expected in the boundary layer. Surface heat flux measurements indicate that the transition Reynolds number is approximately the same as that observed in cold hypersonic flow in conventional continuous flow facilities, but significantly lower than that observed in 'quiet' tunnels. No significant effect of reservoir specific enthalpy on transition was observed. The heat flux distribution showed differences between the air and the nitrogen experiments in the laminar regime. These are consistent with the presence of recombination of oxygen at the wall. This view is supported by the fact that this effect is absent in the low-enthalpy region, where the heat flux distribution agrees with the similarity theory.
Germain, P.↗
A flow calorimeter for determining combustion efficiency from residual enthalpy of exhaust gases
A flow calorimeter for determining the combustion efficiency of turbojet and ram-jet combustors from measurement of the residual enthalpy of combustion of the exhaust gas is described. Briefly, the calorimeter catalytically oxidizes the combustible constituents of exhaust-gas samples, and the resultant temperature rise is measured. This temperature rise is related to the residual enthalpy of combustion of the sample by previous calibration of the calorimeter. Combustion efficiency can be calculated from a knowledge of the residual enthalpy of the exhaust gas and the combustor input enthalpy. An accuracy of +-0.2 Btu per cubic foot was obtained with prepared fuel-air mixtures, and the combustion efficiencies of single turbojet combustors measured by both the flow-calorimeter and heat-balance methods compared within 3 percentage units. Flow calorimetry appears to be a suitable method for determining combustion efficiencies at high combustor temperatures where ordinary thermocouples cannot be used. The method is fundamentally more accurate than heat-balance methods at high combustion efficiencies and can be used to verify near-100-percent efficiency data.
Evans, Albert↗