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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Sb2I2F11 by Materials Project

Sb2I2F11 crystallizes in the monoclinic C2 space group. The structure is one-dimensional and consists of two Sb2I2F11 ribbons oriented in the (-1, 0, 1) direction. Sb+0.50+ is bonded to six F1- atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 7°. There are a spread of Sb–F bond distances ranging from 1.90–2.07 Å. I5+ is bonded in a distorted linear geometry to one I5+ and one F1- atom. The I–I bond length is 2.62 Å. The I–F bond length is 2.78 Å. There are six inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb+0.50+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb+0.50+ atom. In the third F1- site, F1- is bonded in a linear geometry to two equivalent Sb+0.50+ atoms. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to one Sb+0.50+ and one I5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb+0.50+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Sb+0.50+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on SbIF10 by Materials Project

SbF6IF4 is gamma CuTi structured and crystallizes in the orthorhombic Ibca space group. The structure is zero-dimensional and consists of eight IF4 clusters and eight SbF6 clusters. In each IF4 cluster, I5+ is bonded in a 4-coordinate geometry to four F1- atoms. There is two shorter (1.85 Å) and two longer (1.90 Å) I–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one I5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one I5+ atom. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is two shorter (1.90 Å) and four longer (1.94 Å) Sb–F bond length. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.

36 MATERIALS SCIENCE↗