Search NASA⌕ Search

SEARCH · Search NASA

Results for “F-I-Sn”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

3 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Sn2IF3 by Materials Project

Sn2IF3 crystallizes in the orthorhombic C222_1 space group. The structure is two-dimensional and consists of two Sn2IF3 sheets oriented in the (0, 1, 0) direction. Sn2+ is bonded in a 4-coordinate geometry to one I1- and four F1- atoms. The Sn–I bond length is 3.54 Å. There are a spread of Sn–F bond distances ranging from 2.17–2.45 Å. I1- is bonded in a 4-coordinate geometry to two equivalent Sn2+ and two equivalent F1- atoms. Both I–F bond lengths are 3.62 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Sn2+ atoms. In the second F1- site, F1- is bonded in a distorted trigonal planar geometry to three equivalent Sn2+ and one I1- atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Sn2IF3 by Materials Project

Sn2IF3 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Sn2+ is bonded in a 4-coordinate geometry to two equivalent I1- and four F1- atoms. Both Sn–I bond lengths are 3.57 Å. There are a spread of Sn–F bond distances ranging from 2.17–2.39 Å. I1- is bonded in a 11-coordinate geometry to four equivalent Sn2+ and seven F1- atoms. There are a spread of I–F bond distances ranging from 3.62–3.91 Å. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a distorted trigonal planar geometry to three equivalent Sn2+ and two equivalent I1- atoms. In the second F1- site, F1- is bonded in a bent 120 degrees geometry to two equivalent Sn2+ and three equivalent I1- atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Sn3IF5 by Materials Project

Sn3IF5 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are three inequivalent Sn2+ sites. In the first Sn2+ site, Sn2+ is bonded in a 3-coordinate geometry to one I1- and three F1- atoms. The Sn–I bond length is 3.47 Å. There are one shorter (2.21 Å) and two longer (2.22 Å) Sn–F bond lengths. In the second Sn2+ site, Sn2+ is bonded in a 3-coordinate geometry to one I1- and three F1- atoms. The Sn–I bond length is 3.48 Å. There are a spread of Sn–F bond distances ranging from 2.20–2.22 Å. In the third Sn2+ site, Sn2+ is bonded in a 4-coordinate geometry to two equivalent I1- and four F1- atoms. There are one shorter (3.56 Å) and one longer (3.58 Å) Sn–I bond lengths. There are a spread of Sn–F bond distances ranging from 2.22–2.55 Å. I1- is bonded in a 2-coordinate geometry to four Sn2+ and six F1- atoms. There are a spread of I–F bond distances ranging from 3.72–3.89 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a bent 150 degrees geometry to two Sn2+ and one I1- atom. In the second F1- site, F1- is bonded in a bent 120 degrees geometry to two Sn2+ and one I1- atom. In the third F1- site, F1- is bonded in a distorted bent 120 degrees geometry to two Sn2+ and one I1- atom. In the fourth F1- site, F1- is bonded in a bent 120 degrees geometry to two Sn2+ and one I1- atom. In the fifth F1- site, F1- is bonded in a 2-coordinate geometry to two equivalent Sn2+ and two equivalent I1- atoms.

36 MATERIALS SCIENCE↗