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TiF3 is alpha Rhenium trioxide structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Ti3+ is bonded to six equivalent F1- atoms to form corner-sharing TiF6 octahedra. The corner-sharing octahedral tilt angles are 1°. All Ti–F bond lengths are 1.98 Å. F1- is bonded in a linear geometry to two equivalent Ti3+ atoms.
TiF2 is Fluorite structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ti2+ is bonded in a body-centered cubic geometry to eight equivalent F1- atoms. All Ti–F bond lengths are 2.25 Å. F1- is bonded to four equivalent Ti2+ atoms to form a mixture of edge and corner-sharing FTi4 tetrahedra.
TiF3 is alpha Rhenium trioxide structured and crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Ti3+ is bonded to six equivalent F1- atoms to form corner-sharing TiF6 octahedra. The corner-sharing octahedral tilt angles are 7°. All Ti–F bond lengths are 1.97 Å. F1- is bonded in a linear geometry to two equivalent Ti3+ atoms.
TiF3 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Ti3+ is bonded in a distorted hexagonal planar geometry to six F1- atoms. There are two shorter (1.96 Å) and four longer (2.17 Å) Ti–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a linear geometry to two equivalent Ti3+ atoms. In the second F1- site, F1- is bonded in a linear geometry to two equivalent Ti3+ atoms.
TiF3 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Ti3+ is bonded in a distorted hexagonal planar geometry to six F1- atoms. There are two shorter (1.99 Å) and four longer (2.02 Å) Ti–F bond lengths. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a linear geometry to two equivalent Ti3+ atoms. In the second F1- site, F1- is bonded in a linear geometry to two equivalent Ti3+ atoms.