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Magnetic Damping in Polycrystalline Thin-Film Fe-V Alloys

Here, we report on the magnetic damping properties of polycrystalline Fe-V alloy thin films that are deposited at room temperature. By varying the concentration of V in the alloy, the saturation magnetization can be adjusted from that of Fe to near zero.We show that exceptionally low values of the damping parameter can be maintained over the majority of this range, with a minimum damping at approximately 15%–20% V concentration. Such a minimum is qualitatively reproduced with ab initio calculations of the damping parameter, although at a concentration closer to 10% V. The measured intrinsic damping has a minimum value of (1.53±0.08)×10 –3 , which is approximately a factor of 3 higher than our calculated value of 0.48×10 –3 . From first-principles theory, we outline the factors that are mainly responsible for the trend of the damping parameter in these alloys. In particular, the band structure and resulting damping mechanism is shown to change at V concentrations greater than approximately 35% V content.

36 MATERIALS SCIENCE↗

Materials Data on VFe by Materials Project

FeV is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. V is bonded in a body-centered cubic geometry to eight equivalent Fe atoms. All V–Fe bond lengths are 2.50 Å. Fe is bonded in a body-centered cubic geometry to eight equivalent V atoms.

36 MATERIALS SCIENCE↗

Materials Data on VFe3 by Materials Project

VFe3 is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. V is bonded in a distorted body-centered cubic geometry to fourteen Fe atoms. There are eight shorter (2.48 Å) and six longer (2.86 Å) V–Fe bond lengths. There are two inequivalent Fe sites. In the first Fe site, Fe is bonded in a distorted body-centered cubic geometry to four equivalent V and four equivalent Fe atoms. All Fe–Fe bond lengths are 2.48 Å. In the second Fe site, Fe is bonded in a 8-coordinate geometry to six equivalent V and eight equivalent Fe atoms.

36 MATERIALS SCIENCE↗

Materials Data on VFe3 by Materials Project

VFe3 crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. V is bonded in a 8-coordinate geometry to four equivalent Fe atoms. All V–Fe bond lengths are 2.50 Å. There are two inequivalent Fe sites. In the first Fe site, Fe is bonded in a 8-coordinate geometry to two equivalent V and two equivalent Fe atoms. Both Fe–Fe bond lengths are 2.46 Å. In the second Fe site, Fe is bonded in a distorted body-centered cubic geometry to eight Fe atoms. All Fe–Fe bond lengths are 2.49 Å.

36 MATERIALS SCIENCE↗