Synthesis and processing effects on magnetic properties in the Fe5SiB2 system
Not Available
Lejeune, B. T.↗
SEARCH · Search NASA
Results for “Fe5SiB2”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Materials Data on Fe5SiB2 by Materials Project
Fe5SiB2 crystallizes in the tetragonal I4/mcm space group. The structure is three-dimensional. there are two inequivalent Fe2+ sites. In the first Fe2+ site, Fe2+ is bonded in a 5-coordinate geometry to three equivalent B3- and two equivalent Si4- atoms. There are two shorter (2.14 Å) and one longer (2.16 Å) Fe–B bond lengths. Both Fe–Si bond lengths are 2.36 Å. In the second Fe2+ site, Fe2+ is bonded in a distorted square co-planar geometry to four equivalent B3- and two equivalent Si4- atoms. All Fe–B bond lengths are 2.20 Å. Both Fe–Si bond lengths are 2.57 Å. B3- is bonded in a 9-coordinate geometry to eight Fe2+ and one B3- atom. The B–B bond length is 1.86 Å. Si4- is bonded in a 10-coordinate geometry to ten Fe2+ atoms.
36 MATERIALS SCIENCE↗