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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Theory Guided Fine‐Tune of Strain Effects in Pt Ternary Alloy via Rare Earth Templating: Achieving High Performance PEMFCs Catalysts

The sluggish kinetics and insufficient durability of platinum-based catalysts remain crucial barriers limiting proton-exchange-membrane fuel cells (PEMFCs) deployment. Here, we report a theory-guided synthesis combined with rare-earth templating to realize a previously inaccessible Pt 5 Co-like phase with tailored atomic-scale strain. Guided by density functional theory (DFT) calculations, we identified that a Pt 5 Co-like sublayer can induce a unique mild compressive strain (−1.24%) to the Pt(111) shell and an optimal *OH binding energy shift (ΔE ≈ 0.11 eV). This shift positions the alloy catalyst near the apex of the oxygen reduction reaction activity volcano. This prediction guided the synthesis of ternary alloy Pt 5 (Ce)Co@Pt multilayer nanoparticles, featuring a Ce-stabilized core, a Pt 5 Co-like sublayer, and a Pt-rich shell. This catalyst demonstrates both exceptionally high activity and durability, achieving a mass activity of 2.6 A∙mg Pt −1 in rotating disk electrode testing. In fuel cell membrane electrode assembly tests, Pt 5 (Ce)Co@Pt achieves a current density of 1.9 A∙cm −2 at 0.7 V under heavy-duty vehicle conditions. Remarkably, it maintains 1.2 A∙cm −2 after 1 80 000 AST cycles, doubling the U.S. DOE 2025 target. This work demonstrates a rational design strategy that DFT-guided strain engineering integrates with rare-earth templating to advance Pt-based catalysts for fuel cell applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Enhancing generative molecular design via uncertainty-guided fine-tuning of variational autoencoders

In recent years, deep generative models have been successfully applied to various molecular design tasks, particularly in the life and materials sciences. One critical challenge for pre-trained generative molecular design (GMD) models is to fine-tune them to be better suited for downstream design tasks that aim at optimizing specific molecular properties. However, redesigning and training an existing effective generative model from scratch for each new design task are impractical. Furthermore, the black-box nature of typical downstream tasks that involve property prediction makes it nontrivial to optimize the generative model in a task-specific manner. In this work, we propose an uncertainty-guided fine-tuning strategy that can effectively enhance a pre-trained variational autoencoder (VAE) for GMD through performance feedback in an active learning setting. The strategy begins by quantifying the model uncertainty of the generative model using an efficient active subspace-based UQ (uncertainty quantification) scheme. Next, the decoder diversity within the characterized model uncertainty class is explored to expand the viable space of molecular generation. The low-dimensionality of the active subspace makes this exploration tractable using a black-box optimization scheme, which in turn enables us to identify and leverage a diverse set of high-performing models to generate enhanced molecules. Empirical results across six target molecular properties using multiple VAE-based generative models demonstrate that our uncertainty-guided fine-tuning strategy consistently leads to improved models that outperform the original pre-trained models.

97 MATHEMATICS AND COMPUTING↗

Astrometric telescope of ten microarcsecond accuracy on the Space Station

The Astrometric Telescope Facility (ATF) will be operated in the NASA Space Station in the 1990s, furnishing long term, highly accurate relative astrometry of nearby stars in order to detect gravitational perturbations by companion stars with masses as small as that of Neptune. An accuracy of 10 microarcsec is required; this is 100 times better than ground observatory performance. In the Gatewood et al. (1980) astrometric technique used, the relative positions of star images in the telescope focal plane are indicated by the relative phases of the modulations of star brightnesses introduced by translating a Ronchi ruling across the focal plane at uniform speed. Space Station vibration damping, fine guiding accuracy, optical configuration, Ronchi ruling metric accuracy, and the choice of detectors, are discussed.

Levy, E. H.↗

Determination and characterization of the Hubble Space Telescope pointing stability

The Hubble Space Telescope (HST) was designed to maintian a pointing stability (jitter) of 0.007 arc seconds rms throughout every observing period, which can last from a few seconds to several orbits. On-orbit measurements indicate that the hardware excitation induced by the reaction wheels. gyros, high gain antennae, science instrument mechanisms and tape recorders are well within specifications. Unexpectedly, the solar arrays because the dominant source of jitter. Every passage through an orbital terminator produces vibrations which emanate from the solar arrays due to thermal effects, which affect the relative positional stability. Broadband frequencies centered about 0.11 and 0.65 Hz were detected in the frequency content of the vehicle jitter. On-board modifications to the control law have attenuated the disturbance torques and reduced the vehicle jitter close to specification. Replacement of the solar arrays in December, 1993, should eliminate the torque distubances. Astrometric science observations are extremely susceptible to corruption from vehicle jitter. The removal of vehicle jitter from astrometric Transfer function scans of binary stars is explained in detail. A binary star separation of 16 milli-seconds of arc has been achieved, a separation resolution of 10 to 12 milli-seconds of arc appears feasible, with a binary star magnitude of 9 m(sub V). The achievement of this resolution is in part due to vehicle jitter removal. Comparison of vehicle jitter measurements from the position path of the vehicle control law, or from the guiding Fine Guidance Sensors (FGS), are shown to be equivalent to approximately 0.001 arc second.

Bradley, A. J.↗

Optical Modeling Activities for NASA's James Webb Space Telescope (JWST): Wavefront Aberrations due to Alignment and Figure Compensation - 3

This is part three of a series describing the ongoing optical modeling activities for James Webb Space Telescope (JWST). The first two discussed modeling JWST on-orbit performance using wavefront sensitivities to predict line of sight motion induced blur, and stability during thermal transients. The work here investigates the aberrations resulting from alignment and figure compensation of the controllable degrees of freedom (primary and secondary mirrors), which may be encountered during ground alignment and on-orbit commissioning of the observatory. The optical design of the telescope is a three-mirror anastigmat, with an active fold mirror at the exit pupil for fine guiding. The primary mirror is over 6.5 meters in diameter, and is composed of 18 hexagonal segments that can individually positioned on hexapods, as well as compensated for radius of curvature. This effectively gives both alignment and figure control of the primary mirror. The secondary mirror can be moved in rigid body only, giving alignment control of the telescope. The tertiary mirror is fixed, however, as well as the location of the science instrumentation. Simulations are performed of various combinations of active alignment corrections of component figure errors, and of primary mirror figure corrections of alignment errors. Single field point and moderate field knowledge is assumed in the corrections. Aberrations over the field are reported for the varying cases, and examples presented.

Howard, Joseph↗

JWST Cryo Fine Guidance Closed Loop Test Results

The James Webb Space Telescope uses the Fine Guidance Controller to achieve pointing accuracy to a millionth of a degree needed for its scientific observations. This closed loop controller includes the Fine Guidance Sensor instrument, the Attitude Control System, and the Fine Steering Mirror, all working together to generate precise attitude updates every 64 ms to stabilize and point the Observatory. It was exercised for the first time with the flight hardware during the cryogenic test at Johnson Space Center. We provide a top level summary of the test, the results, and its performance in preparation for on-orbit operations.

Line of Sight↗

An analysis of the Hubble Space Telescope fine guidance sensor Fine Lock mode

There are two guiding modes of the Hubble Space Telescope used for the acquisition of astronomical data by one of its six scientific instruments. The more precise one is called Fine Lock. Command and control problems in the on-board electronics, compounded by the aberrations in the main optics, has limited routinely successful Fine Lock to brighter stars, V less than 13.0 mag, instead of fulfilling its prelaunch goal of V = 14.5 mag. Consequently, the less precise guiding mode of Coarse Track (about 25 milliarcsecond in practice) has to be used fairly frequently. Indeed, almost half of the celestial hemisphere has stars too faint to support guidance in the Fine Lock mode. Hence, some of the scientific observations to have been made with the Hubble Space Telescope will be compromised. In this paper a report on the only realistic or extensive simulations of the Fine Lock guidance mode is presented. The theoretical analysis underlying the Monte Carlo experiments and the numerical computations show that the control electronics have significant limitations and how to adjust the various control parameters in an attempt to extend Fine Lock guiding performance back to V - 14.0 mag.

Taff, L. G.↗

An analysis of the Hubble Space Telescope fine guidance sensor fine lock mode

There are two guiding modes of the Hubble Space Telescope (HST) used for the acquisition of astronomical data by one of its six scientific instruments. The more precise one is called Fine Lock. Command and control problems in the onboard electronics has limited Fine Lock to brighter stars, V less than 13.0 mag, instead of fulfilling its goal of V = 14.5 mag. Consequently, the less precise guiding mode of Coarse Track (approximately 40 milli-arc seconds) has to be used fairly frequently. Indeed, almost half of the scientific observations to have been made with the HST will be compromised. The only realistic or extensive simulations of the Fine Lock guidance mode are reported. The theoretical analysis underlying the Monte Carlo experiments and the numerical computations clearly show both that the control electronics are severely under-engineered and how to adjust the various control parameters to successfully extend Fine Lock guiding performance back to V = 14.0 mag and sometimes beyond.

Taff, L. G.↗

Identifying management opportunities to combat climate, land, and marine threats across less climate exposed coral reefs

Conserving coral reefs is critical for maintaining marine biodiversity, protecting coastlines, and supporting livelihoods in many coastal communities. Climate change threatens coral reefs globally, but researchers have identified a portfolio of coral reefs (bioclimatic units [BCUs]) that are relatively less exposed to climate impacts and strongly connected to other coral reef systems. These reefs provide a proactive opportunity to secure a long-term future for coral reefs under climate change. To help guide local management efforts, we quantified marine cumulative human impact (CHI) from climate, marine, and land pressures (2013 and from 2008 to 2013) in BCUs and across countries tasked with BCU management. Additionally, we created a management index based on common management measures and policies for each pressure source (climate, marine, and land) to identify a country's intent and commitment to effectively manage these pressures. Twenty-two countries (79%) had increases in CHI from 2008 to 2013. Climate change pressures had the highest proportional contribution to CHI across all reefs and in all but one country (Singapore), but 18 BCUs (35%) and nine countries containing BCUs (32%) had relatively high land and marine impacts. There was a significant positive relationship between climate impact and the climate management index across countries (R 2 = 0.43, p = 0.02), potentially signifying that countries with greater climate impacts are more committed to managing them. However, this trend was driven by climate management intent in Fiji and Bangladesh. Our results can be used to guide future fine-scale analyses, national policies, and local management decisions, and our management indices reveal areas where management components can be improved. Cost-effectively managing local pressures (e.g., fishing and nutrients) in BCUs is essential for building a climate-ready future that benefits coral reefs and people.

59 BASIC BIOLOGICAL SCIENCES↗

Space telescope - The next generation

The command handling approach as applied to fine guidance sensor guide star acquisition is described in order to illustrate the flexibility it provides to users of the Space Telescope. User control of pointing operations is detailed, and the pointing control system/fine guidance system interface is depicted along with the guide star acquisition sequence. Reaction wheel interaction with vehicle structural modes and the rate gyro assembly noise level are discussed and some test data are shown.

Dougherty, H.↗

Hybrid Architecture Active Wavefront Sensing and Control

A method was developed for performing relatively high-speed wavefront sensing and control to overcome thermal instabilities in a segmented primary mirror telescope [e.g., James Webb Space Telescope (JWST) at L2], by using the onboard fine guidance sensor (FGS) to minimize expense and complexity. This FGS performs centroiding on a bright star to feed the information to the pointing and control system. The proposed concept is to beam split the image of the guide star (or use a single defocused guide star image) to perform wavefront sensing using phase retrieval techniques. Using the fine guidance sensor star image for guiding and fine phasing eliminates the need for other, more complex ways of achieving very accurate sensing and control that is needed for UV-optical applications. The phase retrieval occurs nearly constantly, so passive thermal stability over fourteen days is not required. Using the FGS as the sensor, one can feed segment update information to actuators on the primary mirror that can update the primary mirror segment fine phasing with this frequency. Because the thermal time constants of the primary mirror are very slow compared to this duration, the mirror will appear extremely stable during observations (to the level of accuracy of the sensing and control). The sensing can use the same phase retrieval techniques as the JWST by employing an additional beam splitter, and having each channel go through a weak lens (one positive and one negative). The channels can use common or separate detectors. Phase retrieval can be performed onboard. The actuation scheme would include a coarse stage able to achieve initial alignment of several millimeters of range (similar to JWST and can use a JWST heritage sensing approach in the science camera) and a fine stage capable of continual updates.

Feinberg, Lee↗

Planetary Science with Balloon-Borne Telescopes

The National Aeronautics and Space Administration (NASA) and the planetary science community have recently been exploring the potential contributions of stratospheric balloons to the planetary science field. A study that was recently concluded explored the roughly 200 or so science questions raised in the Planetary Decadal Survey report and found that about 45 of those questions are suited to stratospheric balloon based observations. In September of 2014, a stratospheric balloon mission called BOPPS (which stands for Balloon Observation Platform for Planetary Science) was flown out of Fort Sumner, New Mexico. The mission had two main objectives, first, to observe a number of planetary targets including one or more Oort cloud comets and second, to demonstrate the applicability and performance of the platform, instruments, and subsystems for making scientific measurements in support planetary science objectives. BOPPS carried two science instruments, BIRC and UVVis. BIRC is a cryogenic infrared multispectral imager which can image in the.6-5 m range using an HgCdTe detector. Narrow band filters were used to allow detection of water and CO2 emission features of the observed targets. The UVVis is an imager with the science range of 300 to 600 nm. A main feature of the UVVis instrument is the incorporation of a guide camera and a Fine Steering Mirror (FSM) system to reduce image jitter to less than 100 milliarcseconds. The BIRC instrument was used to image targets including Oort cloud comets Siding Spring and Jacques, and the dwarf planet 1 Ceres. BOPPS achieved the first ever earth based CO2 observation of a comet and the first images of water and CO2 of an Oort cloud comet (Jacques). It also made the first ever measurement of 1Ceres at 2.73 m to refine the shape of the infrared water absorption feature on that body. The UVVis instrument, mounted on its own optics bench, demonstrated the capability for image correction both from atmospheric disturbances as well as some of the residual motion from the gondola that was not addressed by the gondolas coarse pointing systems. The mission met its primary science and engineering objectives. The results of the BOPPS mission will feed into the body of science knowledge but also feed into future planning for more science from balloon-borne platforms. A notional platform called Gondola for High-Altitude Planetary Science (GHAPS) has been explored and this concept platform can address a number of important decadal questions. This paper provides a summary of the assessment of potential balloon borne observations for planetary science purposes including where potential science contributions can be expected, the necessary performance characteristics of the platform, and other features required or desired. The BOPPS mission is summarized including descriptions of the main elements and key science and engineering results. The paper then briefly describes GHAPS, and the salient features that can make it a valuable tool for future planetary observations.

Telescope↗

Uprated fine guidance sensor study

Future orbital observatories will require star trackers of extremely high precision. These sensors must maintain high pointing accuracy and pointing stability simultaneously with a low light level signal from a guide star. To establish the fine guidance sensing requirements and to evaluate candidate fine guidance sensing concepts, the Space Telescope Optical Telescope Assembly was used as the reference optical system. The requirements review was separated into three areas: Optical Telescope Assembly (OTA), Fine Guidance Sensing and astrometry. The results show that the detectors should be installed directly onto the focal surface presented by the optics. This would maximize throughput and minimize point stability error by not incoporating any additional optical elements.

Source record↗

Guide star probabilities

Probabilities are calculated for acquiring suitable guide stars (GS) with the fine guidance system (FGS) of the space telescope. A number of the considerations and techniques described are also relevant for other space astronomy missions. The constraints of the FGS are reviewed. The available data on bright star densities are summarized and a previous error in the literature is corrected. Separate analytic and Monte Carlo calculations of the probabilities are described. A simulation of space telescope pointing is carried out using the Weistrop north galactic pole catalog of bright stars. Sufficient information is presented so that the probabilities of acquisition can be estimated as a function of position in the sky. The probability of acquiring suitable guide stars is greatly increased if the FGS can allow an appreciable difference between the (bright) primary GS limiting magnitude and the (fainter) secondary GS limiting magnitude.

Soneira, R. M.↗

Hubble Space Telescope Reduced-Gyro Control Law Design, Implementation, and On-Orbit Performance

Following gyro failures in April 2001 and April 2003, HST Pointing Control System engineers designed reduced-gyro control laws to extend the spacecraft science mission. The Two-Gyro Science (TGS) and One-Gyro Science (OGS) control laws were designed and implemented using magnetometers, star trackers, and Fine Guidance Sensors in succession to control vehicle rate about the missing gyro axes. Both TGS and OGS have demonstrated on-orbit pointing stability of 7 milli-arcseconds or less, which depends upon the guide star magnitude used by the Fine Guidance Sensor. This paper describes the design, implementation, and on-orbit performance of the TGS and OGS control law fine-pointing modes using Fixed Head Star Trackers and Fine Guidance Sensors, after successfully achieving coarse-pointing control using magnetometers.

Clapp, Brian R.↗

Loads Produced During the Ingression and Egression of the Portable Foot Restraint on the Hubble Space Telescope

The Hubble Space Telescope (HST) was deployed from the Space Shuttle Discovery on April 25, 1990. It is capable of performing observations in the visible, near-ultraviolet, and near-infrared (1150 A to 1 mm). The HST weighs 12 tons, and collects light with an 8-ft-diameter mirror. The attitude control and maneuvering is performed by four of six gyroscopes, or reaction wheels. The HST contains fine guidance sensors that lock onto guide stars to reduce the spacecraft drift and increase the pointing accuracy. The HST was designed to last 15 years, with crewed service missions approximately every three years. The first service mission, STS-61, took place in 1993. The second service mission took place in 1997. In 1999, the STS-103 crew performed the third service mission to the HST. This mission's purpose was to replace the right sensor units and make improvements on the fine guidance sensors. To perform these tasks on the HST, the STS-103 crewmembers used a portable foot restraint to anchor themselves to the HST in the zero-gravity environment. The solar arrays currently used on the telescope are second-generation, and therefore susceptible to loads placed on the telescope. The crew and Mission Operations Directorate worried about the damage that the crew could possibly cause during ingress and egress of the PFR and by transferring loads to the solar arrays. The purpose of this study is to inform the crewmembers of the loads they are imparting on the HST, and train them to decrease these loads to a safer level. Minimizing these loads will significantly decrease the chance of crewmembers causing damage to the solar arrays while repairing the HST.

Ramsey, Susan↗

Global ion heating/transport during merging spherical tokamak formation

Here we report global ion heating/transport characteristics of magnetic reconnection during merging spherical tokamak formation experiment on TS-6 (TS-3U). Using the 96CH/320CH ultra high resolution ion Doppler tomography diagnostics, the full- 2 D imaging measurement clearly revealed that magnetic reconnection initially forms localized hot spots in the downstream region of outflow jet with inboard/outboard asymmetry (more deposition in the high field side) but the continuous accumulation of the heating coupled with transport process expands the high temperature region globally and forms characteristic poloidally ring-like structure aligned with field lines. The dynamic ion heating/transport process is also affected by the polarity of toroidal field and poloidally tilted/rotating global structure has experimentally been found both during and after merging. The characteristic poloidal asymmetry gets flipped when toroidal field direction is reversed and it was found that higher temperature appears in the positive potential side, which is opposite to the conventional understanding/prediction of guide field reconnection. Through the parallel acceleration process coupled with global heat transport, poloidally asymmetric non-classical feature has experimentally been found for the first time.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Hubble Space Telescope fine guidance system operating in the coarse track pointing control mode

The Hubble Space Telescope (HST) Fine Guidance System has set new standards in pointing control capability for earth orbiting spacecraft. Two precision pointing control modes are implemented in the Fine Guidance System; one being a Coarse Track Mode which employs a pseudo-quadrature detector approach and the second being a Fine Mode which uses a two axis interferometer implementation. The Coarse Track Mode was designed to maintain FGS pointing error to within 20 milli-arc seconds (rms) when guiding on a 14.5 Mv star. The Fine Mode was designed to maintain FGS pointing error to less than 3 milli-arc seconds (rms). This paper addresses the HST FGS operating in the Coarse Track Mode. An overview of the implementation, the operation, and both the predicted and observed on orbit performance is presented. The discussion includes a review of the Fine Guidance System hardware which uses two beam steering Star Selector servos, four photon counting photomultiplier tube detectors, as well as a 24 bit microprocessor, which executes the control system firmware. Unanticipated spacecraft operational characteristics are discussed as they impact pointing performance. These include the influence of spherically aberrated star images as well as the mechanical shocks induced in the spacecraft during and following orbital day/night terminator crossings. Computer modeling of the Coarse Track Mode verifies the observed on orbit performance trends in the presence of these optical and mechanical disturbances. It is concluded that the coarse track pointing control function is performing as designed and is providing a robust pointing control capability for the Hubble Space Telescope.

Whittlesey, Richard↗