SEARCH · Search NASA

Results for “Fluorescent mechanisms”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records

All sources NASA NTRS DOE OSTI

NASA NTRS2003

Carbon-Nitrogen-Oxygen Line Radiation and the X-ray Bowen Fluorescence Mechanism in Optically Thick, Highly Ionized Media

Radiative transfer effects due to overlapping X-ray lines in a high-temperature, optically thick, highly ionized medium are investigated. One particular example, in which the O VIII Lyalpha doublet (2(sup 2) P(sub 1/2,3/2)-1(sup 2) S(sub 1/2) coincides in frequency with the N VII Lyzeta lines (7(sup 2) P(sub 1/2,3/2)-1(sup 2) S(sub 1/2) is studied in detail to illustrate the effects on the properties of the emergent line spectrum. We solve the radiative transfer equation to study the energy transport of resonance-line radiation in a static, infinite, plane-parallel geometry, which is used to compute the destruction/escape probabilities for each of the lines for various total optical thicknesses of the medium, as well as destruction probabilities by sources of underlying photoelectric opacity. It is found that a large fraction of the O vIII Lyalpha line radiation can be destroyed by N VII, which can result in a reversal of the O VIII Lyalpha/N VII Lyalpha line intensity ratio similar to what may be seen under nonsolar abundances. Photoelectric absorption by ionized carbon and nitrogen can also subsequently increase the emission-line intensities of these ions. We show that line ratios, which are directly proportional to the abundance ratios in optically thin plasmas, are not good indicators of the true CNO abundances. Conversely, global spectral modeling that assumes optically thin conditions may yield incorrect abundance estimates when compared with observations, especially if the optical depth is large. Other potentially important overlapping lines and continua in the X-ray band are also identified, and their possible relevance to recent high-resolution spectroscopic observations with Chandra and XMM-Newton are briefly discussed.

Sako, Masao↗

NASA NTRS1970

Kinetics and mechanism of NO2 fluorescence

Kinetics and mechanism of nitrogen dioxide fluorescence

Kaufman, F.↗

NASA NTRS1981

Bowen fluorescence on the sun

An identification is made of a weak line in the high-resolution EUV solar spectrum, and the contribution of the Bowen fluorescence mechanism to line emission is considered. The line at 303.625 A is noted to coincide with the 2p 3d(3P2 0) - 2p2(3P1) transition of O III at 303.621 A, which could be excited by He II line excitation of the O III 2p2(3P2) - 2p 3d(3P2 0) transition at 303.799 A. Computations of the collisionally induced intensities of the 2p2(3P) - 2p3d(3P 0) multiplet are shown to result in values not observed in the solar spectrum, indicating that Bowen fluorescence, rather than collisional excitation, is the source of the line. The Bowen fluorescence mechanism is noted to have implications for the identification of other spectral lines, and for models of the solar corona.

Kastner, S. O.↗

NASA NTRS1985

Lateral-angular and temporal characteristics of EAS optical radiation

Characteristics of the direct and scattered components of electron-photon shower optical radiation for distances R 500 m from the shower core to a detector, allowing for the Cerenkov and fluorescent mechanism of photon generation are presented. The results of calculations are employed to clarify the techniques for determination of the shower parameters detected by both installations registering fluorescent light and those recording Cerenkov light.

Chuykova, T. A.↗

NASA NTRS2011

Interpreting Methanol v(sub 2)-Band Emission in Comets Using Empirical Fluorescence g-Factors

For many years we have been developing the ability, through high-resolution spectroscopy targeting ro-vibrational emission in the approximately 3 - 5 micrometer region, to quantify a suite of (approximately 10) parent volatiles in comets using quantum mechanical fluorescence models. Our efforts are ongoing and our latest includes methanol (CH3OH). This is unique among traditionally targeted species in having lacked sufficiently robust models for its symmetric (v(sub 3) band) and asymmetric (v(sub 2) and v(sub 9) bands) C-H3 stretching modes, required to provide accurate predicted intensities for individual spectral lines and hence rotational temperatures and production rates. This has provided the driver for undertaking a detailed empirical study of line intensities, and has led to substantial progress regarding our ability to interpret CH3OH in comets. The present study concentrates on the spectral region from approximately 2970 - 3010 per centimeter (3.367 - 3.322 micrometer), which is dominated by emission in the (v(sub 7) band of C2H6 and the v(sub 2) band of CH3OH, with minor contributions from CH3OH (v(sub 9) band), CH4 (v(sub 3)), and OH prompt emissions (v(sub 1) and v(sub 2)- v(sub 1)). Based on laboratory jet-cooled spectra (at a rotational temperature near 20 K)[1], we incorporated approximately 100 lines of the CH3OH v(sub 2) band, having known frequencies and lower state rotational energies, into our model. Line intensities were determined through comparison with several comets we observed with NIRSPEC at Keck 2, after removal of continuum and additional molecular emissions and correcting for atmospheric extinction. In addition to the above spectral region, NIRSPEC allows simultaneous sampling of the CH3OH v(sub 3) band (centered at 2844 per centimeter, or 3.516 micrometers and several hot bands of H2O in the approximately 2.85 - 2.9 micrometer region, at a nominal spectral resolving power of approximately 25,000 [2]. Empirical g-factors for v(sub 2) lines were based on the production rate as determined from the v(sub 3) Q-branch intensity; application to comets spanning a range of rotational temperatures (approximately 50 - 90 K) will be reported. This work represents an extension of that presented for comet 21P/Giacobini-Zinner at the 2010 Division for Planetary Sciences meeting [3]. Our empirical study also allows for quantifying CH3OH in comets using IR spectrometers for which the v(sub 3) and v(sub 2) bands are not sampled simultaneously, for example CSHELL/NASA IRTF or CRIRES/VLT.

DiSanti, Michael↗

NASA NTRS1989

Red fluorescence and 3-12 micron emission in NGC 2023, HD 44179, M 82, and Lynds 1780

A red excess observed in the Red Rectangle (HD 44179), was attributed to a possible molecular fluorescence mechanism was discovered in NGC 2023 and analyzed in subsequent work in this and other nebulae. An unexpected red light excess was also noticed in a high latitude dark cloud L 1780. The fluorescence was attributed to hydrogenated amorphous carbon by Duley (1985), on the basis of laboratory work. Alternatively, transitions between electronic states of free polycyclic aromatic hydrocarbon molecules, by-passing the cascade along the vibrational states was considered. In L 1780, the red excess was related to the 12 micron emission detected by IRAS. A quantitative comparison of the intensity of the red fluorescence and that of the 3 to 12 micron features is thus warranted in helping assess the physical properties of large interstellar molecules. The red fluorescence radiation, F(R), appears as a bump on the spectra between 0.6 and 0.9 micron. Values were deduced from the spectra for HD 44179, and for the high latitude cloud L 1780. Corrections for the extinction, both interstellar and internal to the nebulae, were included. The 3 to 12 micron brightness, F(IR), was obtained through integration of the spectra for NGC 2023, and for HD 44179 after removal of a smooth continuum due to hot large grains. The values of the ratio of fluorescence flux to the infrared flux, F(R)/F(IR), are summarized. Red fluorescence and infrared radiation are two separate ways to access to the size of the molecules through observation, and it is rewarding that both approaches give similar results. These findings bring a striking coherence into the physical description of the particles, and add further support to the initial attribution of the infrared features to polycyclic aromatic hydrocarbons (PAHs).

Ryter, Charles↗

NASA NTRS1971

The difficulty of ultraviolet emssion from supernovae

There are certain conceptual difficulties in the theory of the generation of ultraviolet radiation which is presumed for the creation of the optical fluorescence mechanism of supernova light emission and ionization of a nebula as large as the Gum nebula. Requirements concerning the energy distribution of the ultraviolet photons are: 1) The energy of the greater part of the photons must be sufficient to cause both helium fluorescence and hydrogen ionization. 2) If the photons are emitted in an approximate black body spectrum, the fraction of energy emitted in the optical must be no more than what is already observed. Ultraviolet black body emission depends primarily on the energy source. The probability that the wide mixture of elements present in the interstellar medium and supernova ejecta results in an emission localized in a limited region with less than 0.001 emission in the visible, for either ionization or fluorescence ultraviolet, is remote. Therefore transparent emission must be excluded as unlikely, and black body or at least quasi-black-body emission is more probable.

Colgate, S. A.↗

NASA NTRS1982

OH fluorescence in comets - Fluorescence efficiency of the ultraviolet bands

The present investigation is concerned with the calculation of the fluorescence efficiency of OH over a wide range of heliocentric radial velocities. Three vibrational states in each of the two lowest electronic states are included in these calculations, producing a total of nine vibrational bands in the ultraviolet. The attempt is made to reproduce observed, ultraviolet, cometary spectra of OH by utilizing the Swings fluorescence mechanism. The inclusion of four rotational states within each of the three vibrational states and a detailed solar atlas make it possible to match observations very well, although there remain some discrepancies. This ability to reproduce observations provides confidence that the more general results obtained for the fluorescence efficiency as a function of heliocentric radial velocity can be used in interpreting both previous and future observations of OH in comets.

Schleicher, D. G.↗

NASA NTRS2021

Seventeen Tidal Disruption Events from the First Half of ZTF Survey Observations: Entering a New Era of Population Studies

While tidal disruption events(TDEs) have long been heralded as laboratories for the study of quiescent blackholes, the small number of known TDEs and uncertainties in their emission mechanism have hindered progress toward this promise. Here we present 17 new TDEs that have been detected recently by the Zwicky Transient Facility along with Swift UV and X-ray follow-up observations. Our homogeneous analysis of the optical/UV light curves, including 22 previously known TDEs from the literature, reveals a clean separation of light-curve properties with spectroscopic class. The TDEs with Bowen fluorescence features in their optical spectra have smaller blackbody radii, lower optical luminosities, and higher disruption rates compared to the rest of the sample. The small subset of TDEs that show only helium emission lines in their spectra have the longest rise times, the highest luminosities, and the lowest rates. A high detection rate of Bowen lines in TDEs with small photometric radii could be explained by the high density that is required for this fluorescence mechanism. The stellar debris can provide a source for this dense material. Diffusion of photons through this debris may explain why the rise and fade timescale of the TDEs in our sample are not correlated. We also report, for the first time, the detection of soft X-ray flares from a TDE on∼day timescales. Based on the fact that the X-ray flares peak at a luminosity similar to the optical/UV blackbody luminosity, we attribute them to brief glimpses through a reprocessing layer that otherwise obscures the inner accretion flow.

Sjoert van Velzen↗

NASA NTRS1965

C2 Swan bands in comets

Relative population calculation of vibration levels of electronic levels assuming fluorescence mechanism for carbon-carbon bond Swan bands in comets

SWAN BAND↗

NASA NTRS1974

The surface brightness of reflection nebulae

Hubble's equation relating the maximum apparent angular extent of a reflection nebula to the apparent magnitude of the illuminating star has been reconsidered under a set of less restrictive assumptions. A computational technique is developed which permits the use of fits to observed m, log a values to determine the albedo of the particles composing reflection nebulae, providing only that one assumes a particular phase function. Despite the fact that all orders of scattering, anisotropic phase functions, and illumination by the general stellar field are considered, the albedo which is determined for reflection nebulae by this method appears larger than that for interstellar particles in general. The possibility that the higher surface brightness might be due to a continuous fluorescence mechanism is considered both theoretically and observationally.

Rush, W. F.↗

NASA NTRS1977

Analysis of the chromospheric spectrum of O I in Arcturus

The ultraviolet and near-infrared spectra of O I in Arcturus are analyzed by a 15-level 14-transition model for O I and the Ayres-Linsky (1975) model chromosphere. It is found that the anomalously bright O I resonance lines at 1302, 1305, and 1306 A can be readily explained by a Ly-beta-pumped fluorescence mechanism as originally proposed by Bowen (1974). Observed equivalent widths of the near-infrared triplet and singlet lines are also consistent with the model predictions, but the intercombination lines at 1355 and 1359 A and near-infrared quintet lines may pose a problem.

Haisch, B. M.↗

NASA NTRS1978

Emission lines of H2 in the extreme-ultraviolet solar spectrum

A sunspot EUV spectrum covering the wavelength range from 1175 to 1714 A with high spatial and spectral resolution is examined which contains about 200 lines not previously reported in solar spectra. Many of the lines are identified as transitions in the Lyman bands of H2. It is shown that the H2 lines are photoexcited not only by H L-alpha, as reported previously, but also by the strong transition-region lines of C II, Si IV, and O IV. The line intensities are analyzed as far as is possible at present, and differences between the quiet chromosphere and the sunspot chromosphere are deduced. The polarization of the observed lines is briefly discussed, the importance of the H L-alpha fluorescence mechanism for the excitation of the H2 Lyman bands is demonstrated, and it is concluded that the H2 lines could also be observable in stars of spectral type later than the sun.

Jordan, C.↗

NASA NTRS1990

Modeling the ultraviolet photospheric spectrum of cool giant stars. I - Arcturus. II - Gamma Crucis

The UV photospheric spectra of cool giants are modeled analytically to facilitate the identification of UV spectral features and aid in the measurement of actual chromospheric flux at different wavelengths. Atomic line data derived experimentally and semiempirically are used with LTE model atmospheres by means of the SYNTHE FORTRAN code to generate the synthetic spectra. Surface flux spectra are determined and fitted to the absorption features of observed IUE high resolution spectra, and the modeled results are compared to the observed spectra of the cool giants Arcturus and the cooler Gamma Crucis. It is shown that the synthetic spectra can be produced for the stars, and chromospheric emission lines are thought to account for significant discrepancies between observed and calculated values. Two new fluorescence mechanisms are identified by modeling the ultraviolet photospheric spectrum of Gamma Crucis.

Carpenter, Kenneth G.↗

NASA NTRS2000

Distorted Wave Calculation and Applications

Physical properties such as temperature and electron density of solar plasma and other astrophysical objects can be inferred from EUV and X-ray emission lines observed from space. These lines are emitted when the higher states of an ion are excited by electron impact and then decay by photon emission. Excitation cross sections are required for the spectroscopic analyses of the observations and various approximations have been used to calculate the scattering functions. One of them which has been widely used is a distorted wave approximation. This approximation, along with its applications to solar observations, is discussed. The Bowen fluorescence mechanism and optical depth effects are also discussed. It is concluded that such calculations are reliable for highly charged ions and for high electron temperatures.

Bhatia, A. K.↗

NASA NTRS2000

Distorted Wave Calculations and Applications

Bhatia, A. K.↗

NASA NTRS2010

Infrared Spectroscopy of Parent Volatiles in Comets: Implications for Astrobiology

Current cometary orbits provide information on their recent dynamical history. However, determining a given comet's formation region from its current dynamical state alone is complicated by radial migration in the proto-planetary disk and by dynamical interactions with the growing giant planets. Because comets reside for long periods of time in the outer Solar System, the ices contained in their nuclei (native ices) retain a relatively well-preserved footprint of when and where they formed, and this in turn can provide clues to conditions in the formation epoch. As a comet approaches the Sun, sublimation of its native ices releases parent volatiles into the coma where they can be measured spectroscopically. The past to - 15 years have seen the advent of infrared spectrometers with high sensitivity between about 2.8 and 5.0 micron, enabling a taxonomy among comets based on abundances of parent volatiles (e.g., H2O, CO, CH4, C2H6, HCN, CH30H, H2CO, NH3). Such molecules are of keen interest to Astrobiology, as they include important pre-biotic species that likely were required for the emergence of life on Earth and perhaps elsewhere. Approximately 20 comets have thus far been characterized, beginning with C/1996 82 (Hyakutake) in 1996. Molecular production rates are established through comparison of observed emission line intensities with those predicted by quantum mechanical fluorescence models. Abundances of parent volatiles (relative to H2O) vary among even the relatively small number of comets sampled, with the most volatile species (CO and CH4) displaying the largest variations. Techniques developed for measuring parent volatile abundances in comets will be discussed, as will possible implications for their formation.

DiSanti, Michael A.↗

NASA NTRS1978

Airglow from the inner comas of comets

The intensities of radiation from the inner comas of comets which are composed primarily of water and carbon monoxide have been calculated. Only 'airglow' emissions initiated by the absorption of EUV radiation have been considered. The photoionizations of H2O, CO, CO2, and N2 are the most important emission sources, although photoelectron excitation is also considered. Among the emission features for which intensities were calculated are H2O(+), CO(+) (first negative), CO (fourth positive), CO (Cameron), CO2(+), N2 (Vegard-Kaplan), N2(+) (first negative), and O I (1304 A). In the inner coma (collision region) these airglow mechanisms are shown to be possible competitors with the usually assumed resonance-scattering and fluorescence-excitation mechanisms appropriate for the outer coma and tail.

Cravens, T. E.↗