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Results for “Fused Silica”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

HVI Ballistic Limit Characterization of Fused Silica Thermal Panes

Fused silica window systems are used heavily on crewed reentry vehicles, and they are currently being used on the next generation of US crewed spacecraft, Orion. These systems improve crew situational awareness and comfort, as well as, insulating the reentry critical components of a spacecraft against the intense thermal environments of atmospheric reentry. Additionally, these materials are highly exposed to space environment hazards like solid particle impacts. This paper discusses impact studies up to 10 km/s on a fused silica window system proposed for the Orion spacecraft. A ballistic limit equation that describes the threshold of perforation of a fuse silica pane over a broad range of impact velocities, obliquities and projectile materials is discussed here.

Miller, J. E.↗
NASA NTRS2022

Fracture Mechanics Properties of Fused Silicas Used for International Space Station Windowpanes

The fracture toughness and slow crack growth (SCG) parameters of a quartz-based silica and a high-purity fused silica were measured as part of a program to review the reliability of the International Space Station windows. The materials exhibit the same fracture toughness (.75 MPa m^(1/2) in N2) and very similar SCG parameters. The literature on fused silica indicates excellent agreement of fracture toughness, but a very wide range of SCG parameters, even from the same institution, with strength-based methods usually yielding a lower power law exponent than direct crack velocity measurements. Use of the exponential function is shown to provide better agreement between test methods, with velocity curves derived from strength tests of bare fiber and polished or ground test specimens paralleling those from wide-range, direct crack velocity observations, implying that constant stress rate tests can predict long lifetime via the exponential function. However, much variation still exists. SCG parameters for soda–lime silicate are much less sensitive to the test method than fused silica. Static load tests and stress intensity measurements resulted in a fatigue threshold of .3 MPa m^(1/2) for fused silica.

Silica, toughness, impact, crack growth, windows, ↗
DOE OSTI2023

$\gamma$-to-neutron branching ratio for deuterium-tritium fusion determined using high-energy-density plasmas and a fused silica Cherenkov detector

A fused silica Cherenkov detector was used to measure deuterium-tritium (DT) gammas during a set of 52 direct-drive cryogenic experiments performed at OMEGA. The detector was calibrated using the 4.4 MeV$\gamma$ from the first-excited state of carbon, which is produced when 14-MeV DT neutrons impinge upon a carbon puck. An approximate DT $\gamma$ spectrum as well as neutron yields from a standard neutron time-of-flight detector at OMEGA were used to calculate a DT $\gamma$-to-neutron branching ratio of (8.42 ± 2.84 ) x 10 -5 . Assuming an excited-state to ground-state ratio of 2.1:1, the measurement detailed in this work results in an approximate ground state only$\gamma$-to-neutron branching ratio of 2.72 x 10 -5 . So, this value is somewhat lower than accelerator-based measurements of the ground-state DT $\gamma$ only.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1973

Fused Silica Surface Coating for a Flexible Silica Mat Insulation System

Fused silica insulation coatings have been developed for application to a flexible mat insulation system. Based on crystalline phase nucleation and growth kinetics, a 99+% SiO2 glass was selected as the base composition. A coating was developed that incorporated the high emissivity phase NiCr2O4 as a two phase coating with goals of high emittance and minimum change in thermal expansion. A second major coating classification has a plasma sprayed emittance coating over a sealed pure amorphous SiO2 layer. A third area of development centered on extremely thin amorphous SiO2 coatings deposited by chemical vapor deposition. The coating characterization studies presented are mechanical testing of thin specimens extracted from the coatings, cyclic arc exposures, and emittance measurements before and after arc exposures.

Rhodes, W. H.↗
NASA NTRS2013

Quantification of Residual Stress from Photonic Signatures of Fused Silica

A commercially available grey-field polariscope (GFP) instrument for photoelastic examination is used to assess impact damage inflicted upon the outer-most pane of Space Shuttle windows made from fused silica. A method and apparatus for calibration of the stress-optic coefficient using four-point bending is discussed. The results are validated on known material (acrylic) and are found to agree with literature values to within 6%. The calibration procedure is then applied to fused-silica specimens and the stress-optic coefficient is determined to be 2.43 +/- 0.54 x 10(exp -12)/Pa. Fused silica specimens containing impacts artificially made at NASA's Hypervelocity Impact Technology Facility (HIT-F), to simulate damage typical during space flight, are examined. The damage sites are cored from fused silica window carcasses and examined with the GFP. The calibrated GFP measurements of residual stress patterns surrounding the damage sites are presented. Keywords: Glass, fused silica, photoelasticity, residual stress

Cramer, K. Elliott↗
NASA NTRS1972

Optical absorption in fused silica at elevated temperatures during 1.5-MeV electron irradiation

An experimental determination of the optical transmission of Corning 7940 UV and Suprasil 1 and 2 fused silica has been made during 1.5-MeV electron bombardment. The fused silica reached temperatures ranging from 150 to 1000 C. The Lewis Research Center dynamitron provided electron current densities which corresponded to a dose rate of 2.6 to 20 Mrad/sec. The irradiation induced absorption was measured at 215.0, 270.0, and 450.0 nm (2150, 2700, 4500 A). The length of each irradiation was sufficient so that an equilibrium between radiation induced coloration and high temperature annealing was reached. The experimental results indicate a significant optical absorption, with values of the induced absorption coefficient at 215.0 nm (2150 A) of 14.5 to 2.2/cm, at 270.0 nm (2700 A) of 9.7 to 3.0/cm and at 450.0 nm (4500 A) of 3.7 to 0.5/cm. This would make the use of fused silica as the separating wall material in the nuclear light bulb propulsion concept questionable.

Smith, A. B.↗
NASA NTRS2016

Fused Silica and Other Transparent Window Materials

Several transparent ceramics, such as spinel and AlONs are now being produced in sufficient large areas to be used in space craft window applications. The work horse transparent material for space missions from Apollo to the International Space Station has been fused silica due in part to its low coefficient of expansion and optical quality. Despite its successful use, fused silica exhibits anomalies in its crack growth behavior, depending on environmental preconditioning and surface damage. This presentation will compare recent optical ceramics to fused silica and discuss sources of variation in slow crack growth behavior.

Optical Ceramics↗
NASA NTRS1969

Impact characteristics in fused silica.

Impact crater cross section in fused silica, describing photomicrographic technique for distinguishing hypervelocity from low energy impacts

Flaherty, R. E.↗
DOE OSTI2022

Laser-induced damage characteristics of fused silica surfaces polished to different depths using fluid jet polishing

Deterministic finishing methods of optical components for high-peak-power laser applications that can meet the requirements for high laser damage resistance are not sufficiently developed to meet all needs. This is especially the case for ultraviolet (UV) laser applications. Fused silica is the material of choice for optics operating at UV wavelengths owing to its intrinsically large bandgap, high transparency, and excellent uniformity. Here we report on the laser damage behavior of fused silica surfaces finished by fluid jet polishing (FJP) as a function of removal depth. Fused silica test substrates were processed by FJP to depths ranging from 0.7 μm to 18 μm. Laser damage testing was conducted on these surfaces at 351 nm and 1-ns pulse lengths for both, 1-on-1 and R-on-1 testing protocols. The results for 1-on-1 testing showed no degradation in the laser-induced damage threshold (LIDT) of the substrates. Instead, a gradual improvement starting at a depth of 2.1 μm was observed and continued to the 18-μm surface. At 18-μm of removal, the LIDT was 16% higher than a surface that was not finished by FJP. For R-on-1 testing, all surfaces treated by FJP demonstrated an improvement in laser damage resistance. At depths greater than 5 μm, the improvements were significantly more pronounced and a 30% increase in the LIDT was realized.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Radiation-induced negative optical nonlinearities in fused silica, sapphire, and borosilicate glass

Here, negative nonlinear absorption is reported in neutron- and gamma-irradiated high-OH content fused silica, low-OH content fused silica, sapphire, borosilicate glass, and radiation-resistant borosilicate glass irradiated to total neutron fluences of 3.4 × 10 16 n ∙ cm –2 (42 Mrad γ), 1.7 × 10 17 n ∙ cm –2 (211 Mrad γ), and 3.6 × 10 17 n ∙ cm –2 (433 Mrad γ). Nonlinear absorption coefficients were measured via Z-scan and are on the order of – (10 –14 –10 –10 ) m∙W –1 . The Z-scan also reveals a negative nonlinear index of refraction in neutron- and gamma-irradiated radiation-resistant borosilicate glass on the order of –10 –19 m 2 ∙ W –1 . Thermal annealing at temperatures up to 800 °C is shown to restore these nonlinearities to their positive unirradiated values in all four materials. All Z-scan measurements were performed at 532 nm with a nanosecond pulsed laser. The occurrence of negative nonlinearities may be attributed to the presence of metallic impurities and the resulting saturable absorption. A limited effect of photobleaching is observed in measurements and is quantified in multiple Z-scans.

36 MATERIALS SCIENCE↗
DOE OSTI2021

A semi-analytical model for laser induced densification in fused silica at elevated temperatures

A semi-analytical model for deterministic surface smoothing of fused silica below the evaporation temperature threshold is presented. Using this model, a method for calculating deterministic track depths for laser polishing fused silica is derived and validated with experiments. In this work, model predictions were in good agreement with experiment across varying laser preheating temperature and power. With the semi-analytical method presented here, deterministic laser smoothing can be achieved in the densification regime to close the process loop of laser polishing.

36 MATERIALS SCIENCE↗
NASA NTRS2007

Fluorine-Based DRIE of Fused Silica

A process of deep reactive-ion etching (DRIE) using a fluorine-based gas mixture enhanced by induction-coupled plasma (ICP) has been demonstrated to be effective in forming high-aspect-ratio three-dimensional patterns in fused silica. The patterns are defined in part by an etch mask in the form of a thick, high-quality aluminum film. The process was developed to satisfy a need to fabricate high-aspect-ratio fused-silica resonators for vibratory microgyroscopes, and could be used to satisfy similar requirements for fabricating other fused-silica components.

Yee, Karl↗
DOE OSTI2022

Na 22 activation level measurements of fused silica rods in the LHC target absorber for neutrals compared to simulations

The Target Absorbers for Neutrals (TANs) are located in a high intensity radiation environment inside the tunnel of the Large Hadron Collider (LHC). TANs are positioned about 140 m downstream from the beam interaction points. Seven 40-cm long fused silica rods with different dopant specifications were irradiated in the TAN by the Beam RAte of Neutrals (BRAN) detector group during p + p data taking from 2016 to 2018 at the LHC. The peak dose delivered to the fused silica rods was 18 MGy. We report measurements of the 22 Na activation of the fused silica rods carried out at the University of Illinois at Urbana-Champaign and Argonne National Laboratory. At the end of the irradiation campaign, the maximum 22 Na activity observed was A = 21 kBq/cm 3 corresponding to a density, ρ = 2.5 x 10 12 /cm 3 , of 22 Na nuclei. FLUKA Monte Carlo simulations have been performed by the CERN FLUKA team to estimate 22 Na activities for the irradiated BRAN rod samples. The simulations reproduce the 22 Na activity profile measured along the rods, with a 35% underestimation of the experimental measurement results.

43 PARTICLE ACCELERATORS↗
NASA NTRS1975

Fused silica reflecting heat shields for outer planet entry probes

The development of slip-cast fused silica is discussed as a heat shield designed to meet the needs of outer-planet entry probes. The distinguishing feature of silica is its ability to reflect the radiation imposed by planetary-entry environments. This reflectivity is particularly sensitive to degradation by the presence of trace amounts of contaminants introduced by the starting materials or by processing. The microstructure of a silica configuration also significantly influences the reflectivity and other thermomechanical properties. The processing techniques attendant on controlling microstructure while maintaining purity are discussed. The selection of a starting material of essential purity precludes the use of purified natural quartz and requires the use of synthetic fused silica. The silica is characterized in a limited combined heating test environment. The surface mass loss is controlled by liquid runoff from a relatively low-temperature melt layer; the reflectance is basically maintained and the material achieves a surprisingly high heat of ablation.

Congdon, W. M.↗
NASA NTRS2017

Applying Fused Silica and Other Transparent Window Materials in Aerospace Applications

A variety of transparent ceramics, such as AlONs and spinels, that were developed for military applications hold promise as spacecraft windows. Window materials in spacecraft such as the Space Shuttle must meet many requirements such as maintaining cabin pressure, sustaining thermal shock, and tolerating damage from hyper-velocity impact while providing superior optical characteristics. The workhorse transparent material for space missions from Apollo to the International Space Station has been fused silica due in part to its low density, low coefficient of expansion and optical quality. Despite its successful use, fused silica exhibits lower fracture toughness and impact resistance as compared to newer materials. Can these newer transparent ceramics lighten spacecraft window systems and might they be useful for applications such as phone screens? This presentation will compare recent optical ceramics to fused silica and demonstrate how weight can be saved.

Standards↗