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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Temporally and spatially resolved X-ray densitometry in a shock tube

Gas densities were measured by x-ray absorption spectroscopy to examine spatial inhomogeneity in density behind incident and reflected shock waves in a miniature (12.7 mm bore) high repetition rate shock tube. Shock waves were generated in argon. The pressure and temperature behind the incident shock were P 2 ~ 1.72 bar and T 2 ~ 800 K, while those behind the reflected shock were P 5 ~ 6.5 bar and T 5 ~ 1480 K. Time-resolved line-of-sight transmission measurements using x-rays at 9 keV photon energy were made along various axial and transverse locations covering the entire shock tube cross section. The x-ray transmission at each location was converted to pathlength-integrated densities, which in some conditions could be further converted to pathlength-averaged densities. The measured gas densities were compared with those calculated by the normal shock wave relations, and good agreement was found in the preshock and immediately behind the incident shock regions. Similar agreement was found for reflected shock conditions very near the endwall. However, increasingly large differences between the measured and calculated gas densities were found as distance from the endwall increased. Furthermore, reconstruction by Abel inversion allowed time and radially resolved densities to be obtained from the transverse measurements. While the profiles measured in this experiment are of insufficient signal-to noise level and resolution to definitively assign boundary layer thicknesses, future improvements may be able to do this. The radially resolved densities reveal growing sidewall thermal boundary layers in gases behind the reflected shock. These reconstructions were compared with a model of the thermal boundary layer and are consistent with values of the thermal boundary layer thickness being between 0.25 mm and 1 mm at 0.7 ms after shock reflection.

42 ENGINEERING↗

Mu2e straw tube tracker gas flow quality control

Here, we present a tracker gas flow quality control method developed for the Mu2e straw tube tracker. Using time-dependent current measurements, we quantify the onset time of ionization gain induced by an 55 F source during gas exchange, which is correlated to the gas conductance in the straw. This allows for the identification of channels with inadequate flow. This approach is broadly applicable to other gaseous detectors that require high-channel-count screening.

Flow↗

SPC-70791 Rev 0 MARVEL Inert Gas Subsystem, Secondary Coolant Management Subsystem, and Secondary Coolant Cover Gas Subsystem Tubing and Valve Specification

This specification covers the requirements and details for the selection, testing, cleaning, marking, shipping, inspection and installation (including welding) of the Inert Gas Subsystem, Secondary Coolant Management Subsystem, and Secondary Cover Gas Management Subsystem from the Valve Panel up to the classification division, the patch panel of the upper confinement. Including NaK, argon, eutectic gallium indium tin (eGaInSn), and helium fill tubing, valves, and hangers. These systems consist of the necessary straight lengths, elbows, reducers, fittings, tube connections, instrument taps, and valves called for by applicable drawings. All components shall be procured as ASME Section III Class 2 unless otherwise modified hereinafter. Pressure relief valves have been sized to prevent overpressure in the event there is full regulator flow. This is documented in ECAR-7365.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

Advanced Test Reactor Safety Basis Update for Gas-Cooled Experiments

The Advanced Test Reactor (ATR) supports neutron irradiation of several types of experiments. One such experiment type is referred to as a gas leadout. Gas leadout experiments actively flow gas through the experiment which allows for active temperature control. It also allows for in-situ data of the experiment. For example, fission gas migration through a fuel sample can be monitored via activity of the sweep gas. Historically, ex-pile equipment and fission product monitors were housed in shielded ATR cubicles. Due to other facility updates, cubicle space is no longer available for gas leadout experiment equipment. To support continued operation of gas leadout experiments, ATR completed a safety basis update that supports a new housing for leadout equipment that may process potentially contaminated gas. In addition to the structure and associated equipment, technical safety requirements regarding handling and storage of experiments needed to be revised to support fueled gas leadout experiments and associated outage configurations. The safety basis update addressed the full lifecycle of these experiments, including experiment movement and interim storage, and credible abnormal events such as failures or leaks in contaminated gas tubing in occupied areas. This paper discusses the completed analyses performed to support the safety basis update associated with gas leadout experiments, including thermal-hydraulic evaluation, probabilistic analysis, and dose consequence analyses.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Prethermalization in coupled one-dimensional quantum gases

We consider the problem of the development of steady states in one-dimensional Bose gas tubes that are weakly coupled to one another through a density-density interaction. We analyze this development through a Boltzmann collision integral approach. We argue that when the leading order of the collision integral, where single particle-hole excitations are created in individual gases, is dominant, the state of the gas evolves first to a non-thermal fixed point, i.e. a prethermalization plateau. This order is dominant when a pair of tubes are inequivalent with, say, different temperatures or different effective interaction parameters, \gamma γ . When both tubes are in the strongly interacting regime we additionally characterize this non-thermal prethermalization plateau by constructing the quasi-conserved quantities that control the existence of this plateau as well as the associated generalized Gibbs ensemble.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Evaluation of steam supply performance: Steamer vs. bubbler

Water/steam electrolysis is a key enabling technology for clean, low-carbon and sustainable production of hydrogen and will play a crucial role in future hydrogen economy. For high temperature solid oxide electrolytic cells, steam is the chemical feedstock. A stable and accurate supply of steam to solid oxide electrolytic cells is of vital importance to smooth production of hydrogen. In this study, we compare steam supply performance of two commonly used steam generators: steamer and bubbler. Our results show that bubbler with proper volume and fritted inlet gas tubing can provide more stable and accurate steam supply than steamer for laboratory use. We also provide the explanation for the unstable steam supply observed in steamer. Overall, we conclude that bubbler is generally a better choice for small-scale laboratory use (e.g., ≤50%H 2 O, ≤100 sccm carrier gas flow) to produce stable and accurate steam and steamer might be a better choice for higher steam contents and flow rates (e.g., >60% H 2 O and >200) encountered in large-scale testing and/or aggressive high steam conditions.

08 HYDROGEN↗

Modeling and Simulation of Air-Source CO2 Heat Pump Water Heater

Carbon dioxide (CO2) has been widely used as working fluid for the vapor-compression refrigeration systems in large marine device. Due to the potential energy efficiency and the favorable environmental properties of CO2 as a working fluid, CO2 heat pump water heater (HPWH) systems are regarded a promising technology for centralized domestic hot water (DHW) heating in residential and commercial buildings. However, there is still at the early stage of appropriately optimizing and improving the energy performance of CO2 HPWH. This requires CO2 HPWH simulation tools capable of capturing the accurate impact of the emerging compressor, throttle device, and heat exchanger technology on CO2 heat transfer and energy efficiency. In this study, high efficiency components (compressors, pumps, fans, heat exchangers) were identified and applied to the state-of-art CO2 HPWH designs and analyzed their performance by using numerical simulation. This was done by simulating the performance of CO2 HPWH using ACMODEL design model combined with the component models developed at Oak Ridge National Laboratory (ORNL) for orifice tube, map-based compressor, and tube-in-tube gas cooler. ACMODEL is an equipment design model for CO2-based air conditioners and heat pumps developed by Purdue University to account for the details of each component. The simulated CO2 HPWH performance was then compared with the heat pump water heater using conventional refrigerants.

Gao, Zhiming↗

ECAR-7813 Rev 0 Secondary Coolant Cover Gas System Stirling Engine Tube Rupture Analysis, Insulation Block Analysis, and Labyrinth Seal Design

The purpose of this ECAR is to document compliance with best engineering practices for the Secondary Coolant Cover Gas System of the MARVEL microreactor which includes a Stirling Engine helium tube rupture analysis, an analysis to verify the strength of the insulation blocks, and the design of the Labyrinth Seal.

21 - SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLAN↗

Spouted bed with venturi draft tube and method for improved gas-solid contacting

A Venturi draft tube spouted bed and method are disclosed that enables scale-up with small particles and improves heat and mass transfer by increasing material turnover rate. A Venturi-style eductor has been incorporated into the spouted bed draft tube to provide suction at the bottom of the bed to better entrain material and reduce the propensity for dead zones at the bottom of the narrow conical section.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Upgrade of Gamma Spectrometry Systems for ORNL TRISO Fuel PIE

Gamma spectrometry is a key element in much of the post-irradiation examination (PIE) work performed under the Advanced Gas Reactor Fuel Development and Qualification (AGR) Program (Demkowicz et al. 2015; Stempien et al. 2021). Gamma spectrometers are integrated into three major capabilities used at the Oak Ridge National Laboratory (ORNL) Irradiated Fuels Examination Laboratory (IFEL) for PIE of tristructural-isotropic (TRISO) coated particles and fuel compacts: the Core Conduction Cooldown Test Facility (CCCTF), the Vertical Counting System (VCS), and the Irradiated Microsphere Gamma Analyzer (IMGA). The CCCTF includes liquid-nitrogen-cooled traps to extract 85 Kr out of the He sweep gas that passes through the furnace in which the fuel compacts are heated during safety testing. Analysis of the 85 Kr activity in the traps is the primary indicator for TRISO failure during safety testing. The VCS is a system used to accurately measure gamma emission from components placed in a lead-shielded chamber. It is used to count the CCCTF deposition cups after removal from furnace. Each cup resides in the CCCTF furnace for typically 12–24 h and is periodically replaced with a fresh cup throughout the safety test. Metallic fission products collect on the water-cooled cups and several gamma-emitting isotopes ( 110 mAg, 134 Cs, 137 Cs, 154 Eu, and 155 Eu) are often measured and provide indication of the retention performance of the TRISO coatings. The VCS is also used to measure the presence of these isotopes on the CCCTF tantalum liner and sweep gas inlet tube for the determination of cup collection efficiency, as well as support other gamma spectrometry needs related to calibration of the 85 Kr fission gas traps and various other special PIE tasks. The IMGA uses gamma spectrometry to measure the inventory of gamma-emitting isotopes in individual TRISO particles. An automated particle handling system within the IMGA hot cell removes each particle from a source vial and positions it in front of a gamma detector, and output from the gamma spectrometer is used by the IMGA software to determine a destination vial such that particles are sorted according to their inventory and retention characteristics. At the conclusion of the AGR-1 and AGR-2 PIE campaigns, the gamma spectrometer systems used at ORNL to support that PIE had reached the end of its life cycle due to gradual obsolescence of the hardware and software. Upgrade of the Canberra Genie 2000 software used by these systems to a Windows 10 version was not a viable option, because the newest Windows 10 version offered by Mirion (the new owner of the Canberra technology) did not include the dynamic-link libraries (DLLs) needed for integration with the custom PIE software used with the CCCTF and IMGA, and Mirion had no current plans for development and release of Windows 10 versions of these DLLs with the Model S560 Genie 2000 Programming Library. Ultimately a switch was made to ORTEC gamma spectrometry systems, which appeared to be a more sustainable solution due to more proactive vendor support. The ORTEC conversion involved replacing the aging detector preamplifier and multichannel analyzer (MCA) hardware, upgrading the obsolete Windows 7 computers to Windows 10 compatible models, adopting ORTEC GammaVision software, and extensive modification of the ORNL-developed Visual Basic .NET (VB.NET) programs that provide the CCCTF and IMGA user interfaces.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Modeling Study of Reduced Tubing Size Effects on Flow in Depleted Reservoir Natural Gas Storage Wells

This report explores the effects of tubing size reductions on natural gas flow from representative depleted reservoir underground storage wells and fields using basic models for coupled reservoir and pipe flow. This work was motivated by interest at the U.S. Department of Transportation, Pipeline and Hazardous Materials Safety Administration, in evaluating the effects of tubing and packer as a potential safety upgrade to implement double-barrier systems to existing underground natural gas storage wells. Reservoir and well flow models were developed from widely accepted industry equations, verified against a commercial process simulator model, and validated against field data. The study utilized U.S. operator survey data to provide context and assure that modeling parameters including aver age deliverability rates for wells and fields, operating pressures, well depths, and storage capacities were all carefully considered to keep the modeling relevant to the known range of U.S. operations. The models generally found that wells and fields with inherently low deliverability were relatively insensitive to reductions in tubing diameter, primarily because the hydraulics in those cases were controlled by reservoir properties. For the high-producing wells and fields, the models found that reducing tubing diameter could produce significant reductions in deliverability, both at the field- and well-level. When put into context with occurrence data regarding average deliverability of fields and wells, it appears that most wells and most fields across the U.S. would experience deliverability reductions on the low end of what was simulated here, generally below 20%. For fields with moderate to high deliverability, reductions were generally larger, and could reach as high as 60% for the highest-producing wells and fields.

03 NATURAL GAS↗

Plasma generation by household microwave oven for surface modification and other emerging applications

A simple and inexpensive method to generate plasma using a kitchen microwave oven is described in this paper. The microwave-generated plasma is characterized by spectroscopic analysis and compared with the absorption spectra of a gas discharge tube. A Paschen-like curve is observed as the microwave plasma initiation time is plotted as a function of the pressure of the plasma chamber. We have also demonstrated that this microwave-generated air plasma can be used in a multitude of applications such as: (a) surface modification of a substrate to change its wettability; (b) surface modification to change electrical/optical properties of a substrate; and (c) enhancement of adhesive forces for improved bonding of polymeric microfluidic molds, such as bonding polydimethylsiloxane (PDMS) chips to glass covers. These simple techniques of plasma generation and subsequent surface treatment and modification applications may bring new opportunities leading to new innovations not only in advanced labs, but also in undergraduate and even high school research labs.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

ICONS: Solid-State Composite Neutron Detector

Neutron detection is essential for identifying and monitoring nuclear materials and nuclear reactions. Most deployed neutron-detection systems rely on helium-3 ( 3 He) gas-filled tubes, which have been the standard technology for decades.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Atomic layer etching with pulsed plasmas

A system and method for rapid atomic layer etching (ALET) including a pulsed plasma source, with a spiral coil electrode, a cooled Faraday shield, a counter electrode disposed at the top of the tube, a gas inlet and a reaction chamber including a substrate support and a boundary electrode. The method includes positioning an etchable substrate in a plasma etching chamber, forming a product layer on the surface of the substrate, removing a portion of the product layer by pulsing a plasma source, then repeating the steps of forming a product layer and removing a portion of the product layer to form an etched substrate.

Donnelly, Jr., Vincent M.↗

Gas sensor system

A gas sensing tube includes an outer surface, and an inner surface defining a passage. A sensor node is arranged along the sensing tube. The sensor node includes an inlet fluidically connected to the passage, an outlet fluidically connected to the passage, and an interior chamber arranged between the inlet and the outlet. A sensor cable extends along the sensing tube. The sensor cable includes a first conduit having a first connector coupled to the sensor node at the inlet and a second conduit having a second connector connected to the sensor node at the outlet. The sensor cable has a first conductor extending through the first conduit and being coupled to the first connector and a second conductor extending through the second conduit and being coupled to the second connector.

Challener, William Albert↗

Characterizing Hazardous Gases from NMC811 Materials and Coin Cells with TGA and Tube-Furnace FTIR-MS Evolved-Gas-Analysis

Abuse testing is useful for informing the risks of different battery chemistries but has been limited to larger formats. This paper conducted thermal abuse tests at the smaller coin cell level to determine its relevance in specifying vent gas flammability and toxicity. A nitrogen purge carried the evolved gases into a parallel Fourier-transform infrared spectrometer (FTIR) and a mass spectrometer (MS) downstream of the tube furnace. The experimental system was validated by comparing evolved gas data for single components between the tube furnace system and a thermogravimetric analysis (TGA) instrument. Multiple samples were tested during validation, including CaCO3, electrolyte, delithiated NMC 811 cathode, and lithiated graphite anode. Temperature-resolved gas evolution of HF, CO2, CO, H2, and hydrocarbons from isolated components helped to characterize the emission sources. A previously unreported H2 generation mechanism was found. It was shown that the reduced NMC cathode acts as a catalyst to crack polypropylene-decomposed hydrocarbons into H2 at around 450 degrees C. It was also shown, while studying LiPF6 thermal decomposition, that using the tube furnace with a coin cell casing as the sample holder has some advantages for evolved-gas analysis of environmentally sensitive samples relative to testing in TGA instruments. After validation with single components, a fully charged NMC 811 coin cell was failed in the tube furnace. The measured evolved gases were found to be a combination of the species measured from the single component tests. H2 formation related to the reduced cathode was found to have greater abundance than H2 formed from the anode. Hydrogen fluoride emission factors and diethyl carbonate conversion emission factors assist in understanding the gaseous hazards for larger format cells.

25 ENERGY STORAGE↗

Effect of mass flow rate on gas propagation after vacuum break in a liquid helium cooled tube

Vacuum break in particle accelerators is a major concern due to risks associated with personnel and extensive equipment damage. Continuing research in our lab focuses on the sudden loss of vacuum in the liquid helium cooled beam-line tubes of superconducting particle accelerators. In our previous research, we studied nitrogen gas propagation in a uniform tube system immersed in both normal helium (He I) and superfluid helium (He II). It was observed that He II has a stronger effect in slowing down the gas propagation compared to He I, but this effect was largely due to the variation of the point where condensation and deposition of the nitrogen gas on the tube inner wall. Here, we discuss our modifications to the tube system that now allow us to accurately control the starting location of gas condensation in both the He I and He II experiments. Systematic studies of gas propagation were conducted using this new tube system by varying the nitrogen mass flow rate at the tube inlet.

43 PARTICLE ACCELERATORS↗

Systems Engineering Approach for Design and Implementation of a Gas Breech for Actinide Experiments at the JASPER Facility

The Joint Actinide Shock Physics Experimental Research (JASPER) Facility is located approximately 65 miles north of Las Vegas, Nevada at the Nevada National Security Site (NNSS). The primary mission is to conduct shock physics research on actinide materials in support of NNSA’s Stockpile Stewardship Program. JASPER experiment uses a two-stage light gas gun to accelerate projectiles into targets at velocities up to 8 km/s (17,000 mph). The first stage uses an ignited propellent to drive a piston to compress gas in the pump tube. At the second stage, the gas compression exceeds a specified pressure and a rupture valve at the end of the pump tube opens. This launches a projectile to impact the target. The target is housed inside the target assembly and the debris field is contained inside the primary target chamber (PTC). The PTC is placed inside the secondary confinement chamber (SCC) as an added protection against possible contamination. These major components are illustrated in Figure 1.JASPER is capable of generating and measuring data on the properties of radioactive chemical elements at high shock pressures, temperatures, and strain rates approximating the conditions in nuclear weapons by using a two-stage gas gun. The data is used to determine material equations-of-state and validate computer models of material response. The work advances predictive capability, thus ensuring confidence in the nuclear stockpile.

42 ENGINEERING↗