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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Arsenic Removal of Contaminated Soils by Phytoremediation of Vetiver Grass, Chara Algae and Water Hyacinth

This research has been carried out for assessing phytoremediation of contaminated soils with 4 concentrations of arsenic by three plants, namely Vetiver grass (Vetiveria zizanioides), Chara algae (Chara vulgaris) and Water hyacinth (Hyacintus orientalis). The experimental results showed that at least two sampling times were significantly different. In addition, at least two plants were also significantly different in terms of percentages of total arsenic that were removed from the soil of the pots, as well as significant interactions between plant and arsenic concentrations. The results obtained from the thermodynamic studies show that, obtained by zero Gibbs free-energy, the process reached an equilibrium on the 60th day of the experiment, and, in fact, the adsorption of arsenic after the 60th day would be negligible.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Modelling the response of vegetation restoration to changes in groundwater level, based on ecologically suitable groundwater depth

Groundwater-level fluctuations at a large scale have a significant effect on the preservation and restoration of vegetation. This study determined suitable groundwater depth within which natural vegetation grows well, and analysed the effect of groundwater regulation on vegetation restoration in Tianjin City, northern China. Normal and lognormal distributions were used to fit the curve of the relation between vegetation and groundwater depth. The groundwater depth range corresponding to the higher frequency of vegetation distribution was regarded as the ‘suitable water depth’ range for vegetation growth. The suitable groundwater depth for shrub growth was 3–5 m and for grass growth 1–3 m. A groundwater flow model predicted the future changes of groundwater depths in the vegetation distribution area under the condition that the current levels of groundwater extraction are maintained. The results showed that there is potential for the extraction of groundwater in shrubland areas, but for grassland areas the water-table elevation showed a downward trend, meaning that water shortages in some areas may be more severe in the future. Finally, based on the current groundwater extraction regime, two regulation schemes were developed: (1) for shrubland, groundwater extraction was reduced by 10% in the ecological water deficit areas, and extraction was increased by 10% in the ecological water surplus and suitable areas, and (2) for grassland, groundwater recharge was increased by the restoration of the wetland areas. In conclusion, the groundwater depths in most of the area would be more suitable for vegetation growth under the regulation schemes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

An open source GIS tool to quantify the visual impact of wind turbines and photovoltaic panels

Although there are clear economic and environmental incentives for producing energy from solar and wind power, there can be local opposition to their installation due to their impact upon the landscape. To date, no international guidelines exist to guide quantitative visual impact assessment of these facilities, making the planning process somewhat subjective. In this paper we demonstrate the development of a method and an Open Source GIS tool to quantitatively assess the visual impact of these facilities using line-of-site techniques. The methods here build upon previous studies by (i) more accurately representing the shape of energy producing facilities, (ii) taking into account the distortion of the perceived shape and size of facilities caused by the location of the observer, (iii) calculating the possible obscuring of facilities caused by terrain morphology and (iv) allowing the combination of various facilities to more accurately represent the landscape. The tool has been applied to real and synthetic case studies and compared to recently published results from other models, and demonstrates an improvement in accuracy of the calculated visual impact of facilities. The tool is named r.wind.sun and is freely available from GRASS GIS AddOns. - Highlights: • We develop a tool to quantify wind turbine and photovoltaic panel visual impact. • The tool is freely available to download and edit as a module of GRASS GIS. • The tool takes into account visual distortion of the shape and size of objects. • The accuracy of calculation of visual impact is improved over previous methods.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2013

Study on the reduction of atmospheric mercury emissions from mine waste enriched soils through native grass cover in the Mt. Amiata region of Italy

Atmospheric mercury emissions from mine-waste enriched soils were measured in order to compare the mercury fluxes of bare soils with those from other soils covered by native grasses. Our research was conducted near Mt. Amiata in central Italy, an area that was one of the largest and most productive mining centers in Europe up into the 1980s. To determine in situ mercury emissions, we used a Plexiglas flux chamber connected to a portable mercury analyzer (Lumex RA-915+). This allowed us to detect, in real time, the mercury vapor in the air, and to correlate this with the meteorological parameters that we examined (solar radiation, soil temperature, and humidity). The highest mercury flux values (8000 ng m{sup −2} h{sup −1}) were observed on bare soils during the hours of maximum insulation, while lower values (250 ng m{sup −2} h{sup −1}) were observed on soils covered by native grasses. Our results indicate that two main environmental variables affect mercury emission: solar radiation intensity and soil temperature. The presence of native vegetation, which can shield soil surfaces from incident light, reduced mercury emissions, a result that we attribute to a drop in the efficiency of mercury photoreduction processes rather than to decreases in soil temperature. This finding is consistent with decreases in mercury flux values down to 3500 ng m{sup −2} h{sup −1}, which occurred under cloudy conditions despite high soil temperatures. Moreover, when the soil temperature was 28 °C and the vegetation was removed from the experimental site, mercury emissions increased almost four-fold. This increase occurred almost immediately after the grasses were cut, and was approximately eight-fold after 20 h. Thus, this study demonstrates that enhancing wild vegetation cover could be an inexpensive and effective approach in fostering a natural, self-renewing reduction of mercury emissions from mercury-contaminated soils. -- Highlights: ► Mercury air/surface exchange from grass covered soil is different from bare soil. ► Light enhances mercury emissions and is the main parameter driving the process. ► The presence of wild vegetation covering the soil reduces mercury emission. ► Vegetative covers could be a solution to reduce atmospheric mercury pollution.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Analyzing urban ecosystem variation in the City of Dongguan: A stepwise cluster modeling approach

Highlights: • A stepwise cluster modeling approach is proposed for urban ecosystem simulation. • Nonlinear relationship is established among NDVI and multiple drivers. • Vegetation conditions get better gradually from the north to the south of Dongguan. • Ecosystem in the east of Dongguan is sensitive to growth of economy and population. In this study, a stepwise cluster modeling approach (SCMA) is developed for analyzing urban ecosystem variation via Normalized Difference Vegetation Index (NDVI). NDVI is an indicator of vegetation growth and coverage and useful in reflecting urban ecosystem. SCMA is established on a cluster tree that can characterize the complex relationship between independent and dependent variables. SCMA is applied to the City of Dongguan for simulating the urban NDVI and identifying associated drivers of human activity, topography and meteorology without specific functions. Results show that SCMA performances better than conventional statistical methods, illustrating the ability of SCMA in capturing the complex and nonlinear features of urban ecosystem. Results disclose that human activities play negative effects on NDVI due to the destruction of green space for pursuing more space for buildings. NDVI reduces gradually from the south part to the north part of Dongguan due to increased gross domestic product and population density, indicating that the ecosystem in Dongguan is better in the south part. NDVI in the northeast part (dominated by agriculture) is sensitive to the growth of economy and population. More attention should be paid to this part for sustainable development, such as increasing afforestation, planting grass and constructing parks. Precipitation has a positive effect on NDVI due to the promotion of soil moisture that is beneficial to plants’ growth. Awareness of these complexities is helpful for sustainable development of urban ecosystem.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Contribution of climate and land cover changes to reduction in soil erosion rates within small cultivated catchments in the eastern part of the Russian Plain during the last 60 years

Highlights: • The soil erosion has decreased at least 2–3 times over the last 30 years at the RP. • The increase in winter air temperature is the key reason for the soil loss reduction. • The crop rotation changes is the factor of erosion rate reduction at the forest zone. The eastern part of the Russian Plain is an important agricultural region of European Russia with high proportion of cultivated lands in the steppe, forest-steppe and forest (southern part) landscape zones. Soil erosion is the main process of land degradation and surface water contamination there. Climate and land cover changes have been observed in this region during the last 30 years. However, field quantitative assessments of soil erosion rates are not available for the eastern part of European Russia due to the lack of monitoring data as well as the evaluation of erosion/deposition processes in cultivated catchments using other field methods. Three representative small cultivated catchments with high (> 80%) proportion of cultivated lands were selected in the forest (southern part), forest-steppe and steppe zones of the study region to evaluate sedimentation rates in dry valley bottoms of the catchments for two-time intervals (1963–1986 and 1987–2016) based on the application of the bomb-derived and Chernobyl-derived {sup 137}Cs isotope for sediment dating. The 3–4 depth {sup 137}Cs profiles were used to assess the sedimentation rates within the each investigated catchment. It was established that the sedimentation rates have considerably decreased (at least 2–3 times) over the last 30 years compared to 1963–1986 in all the investigated catchments. This is in agreement with results of erosion rate calculations using erosion models for the forest zone, however not consistent with erosion rates assessments for the forest-steppe and steppe zones. According to the model calculations, erosion rates show a slight decrease in the forest-steppe zone and increase in the steppe zone. The reduction in surface runoff during snowmelt period is one of the reasons for decrease in erosion rates within cultivated slopes for all the investigated catchments. The increase in proportion of perennial grasses in the regional crop rotation is another important reason for the decrease in erosion rates for the catchment located in the south of the forest zone. The importance of land cover changes in a major decrease of soil losses from the cultivated fields of the investigated catchments located in the forest-steppe and steppe zones cannot be identified due to the lack detailed information about crop rotation for those particular sites. However, available regional information about crop rotation changes for the two-time intervals (1960–1980 and 1996–2012) do not explain very high reduction in sedimentation rates in the dry valley bottoms after 1986.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Effects of rows arrangement, soil management, and rainfall characteristics on water and soil losses in Italian sloping vineyards

Highlights: • GC effectiveness varies according to the type of rainfall event and row orientation. • Rows orientation along contour lines prevents runoff also when CT is adopted. • Highest runoff and soil losses depend on “long-lasting” or “intense” events. • Rainfall depth and rainfall maximum intensity count in predicting erosion rate. Erosional processes are highly affected by seasonal climatic fluctuations and soil management practices. Controlled grass cover is one of the most used soil conservation practices adopted in temperate climates, even if the protective effect of grass cover may decrease according to seasonal pattern. This technique is effective and, thus, widely adopted in the inter-rows of orchards such as olives, citrus or vineyards. This study reports the erosive events recorded in two different rain-fed hillslope vineyards with different rows orientation located in the Monferrato region, NW Italy. The study is addressed at compare the effects of different inter-row managements and rainfall characteristics on runoff and soil loss in hillslope vineyards (average slope from 15% to 35%). Rainfall, runoff and erosion variables were monitored in hydraulically bounded vineyard plots, where the inter-rows were managed with tillage and grass cover. Seventy-two erosive events were recorded in the period 1992–1996 in two vineyard plots with rows along the contour lines while 86 erosive events were recorded in two plots with rows up-and-down the slope from 2000 to 2014 (158 erosive events and four plots in total). Events were classified according to rainfall characteristics as “long-lasting”, “intense” and “normal”. In plots with rows along the contour lines, “intense” events were responsible for the highest mean soil loss in tilled plots (0.7 Mg ha{sup −1}) with very high erosion rates (12.3 Mg ha{sup −1}) observed during a single storm. In plots with rows up-and-down the slope the highest erosion rates, 21.2 and 3.4 Mg ha{sup −1}, were recorded during fall “long-lasting” events in the tilled and grass cover plots respectively. The grass cover proved to be effective in decreasing runoff and soil losses during most of the events (at least 68% and 61% of the occurrences, respectively) reducing soil losses especially during summer storms when most of the “intense” events occured. Furthermore, the results show the fundamental role of contour-slope row orientation in reducing runoff and soil losses, disregarding the inter-rows soil management that is adopted.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2012

Developing custom fire behavior fuel models from ecologically complex fuel structures for upper Atlantic Coastal Plain forests.

Currently geospatial fire behavior analyses are performed with an array of fire behavior modeling systems such as FARSITE, FlamMap, and the Large Fire Simulation System. These systems currently require standard or customized surface fire behavior fuel models as inputs that are often assigned through remote sensing information. The ability to handle hundreds or thousands of measured surface fuelbeds representing the fine scale variation in fire behavior on the landscape is constrained in terms of creating compatible custom fire behavior fuel models. In this study, we demonstrate an objective method for taking ecologically complex fuelbeds from inventory observations and converting those into a set of custom fuel models that can be mapped to the original landscape. We use an original set of 629 fuel inventory plots measured on an 80,000 ha contiguous landscape in the upper Atlantic Coastal Plain of the southeastern United States. From models linking stand conditions to component fuel loads, we impute fuelbeds for over 6000 stands. These imputed fuelbeds were then converted to fire behavior parameters under extreme fuel moisture and wind conditions (97th percentile) using the fuel characteristic classification system (FCCS) to estimate surface fire rate of spread, surface fire flame length, shrub layer reaction intensity (heat load), non-woody layer reaction intensity, woody layer reaction intensity, and litter-lichen-moss layer reaction intensity. We performed hierarchical cluster analysis of the stands based on the values of the fire behavior parameters. The resulting 7 clusters were the basis for the development of 7 custom fire behavior fuel models from the cluster centroids that were calibrated against the FCCS point data for wind and fuel moisture. The latter process resulted in calibration against flame length as it was difficult to obtain a simultaneous calibration against both rate of spread and flame length. The clusters based on FCCS fire behavior parameters represent reasonably identifiable stand conditions, being: (1) pine dominated stands with more litter and down woody debriscomponents than other stands, (2) hardwood and pine stands with no shrubs, (3) hardwood dominated stands with low shrub and high non-woody biomass and high down woody debris, (4) stands with high grass and forb (i.e., non-woody) biomass as well as substantial shrub biomass, (5) stands with both high shrub and litter biomass, (6) pine-mixed hardwood stands with moderate litter biomass and low shrub biomass, and (7) baldcypress-tupelo stands. Models representing these stand clusters generated flame lengths from 0.6 to 2.3 musing a 30 km h{sub 1} wind speed and fireline intensities of 100-1500 kW m{sub 1} that are typical within the range of experience on this landscape. The fuel models ranked 1 < 2 < 7 < 5 < 4 < 3 < 6 in terms of both flame length and fireline intensity. The method allows for ecologically complex data to be utilized in order to create a landscape representative of measured fuel conditions and to create models that interface with geospatial fire models.

09 BIOMASS FUELS↗
DOE OSTI2016

Morphology-controlled synthesis of grass-like GO-CdSe nanocomposites with excellent optical properties and field emission properties

Four different morphologies of the CdSe semiconductor nanograss have been successfully grown on graphene oxide (GO) sheets via hydrothermal method at 220 °C for 12 h. The morphologies, structures, chemical compositions and optical properties of the as-obtained GO-CdSe nanocomposites were characterized by XRD, SEM, TEM, EDS, XPS and Raman spectra. It was found that the EDTA/Cd{sup 2+} molar ratio is important for the formation of morphology of GO-CdSe nanocomposites. The results of XRD revealed that all the as-obtained GO-CdSe nanocomposites have zinc blend structure. Room temperature photoluminescence (PL) showed that the sample emits red light under different excitation wavelengths. The results of Raman spectra, EDS and XPS showed that the CdSe nanograss is grown on GO sheets. The results showed that GO-CdSe nanocomposites composed of nanorods have best field emission (FE) properties with a low turn-on electric field of 4.14 V μm{sup −1} and a high field enhancement factor of 3315 among all the samples. - Graphical abstract: SEM images of as-synthesized CdSe nanograss grown on GO sheets. Room temperature PL emission spectra of the as-synthesized CdSe nanograss grown on GO sheets. Field emission J–E curve of the as-synthesized CdSe nanograss grown on GO sheets. - Highlights: • Novel CdSe nanograsses are grown on graphene oxide sheets by hydrothermal method. • The morphology of CdSe nanograsses is controlled by adjusting EDTA/Cd{sup 2+} molar ratio. • The FE performance of sample is investigated. • Optimum morphology for FE performance is CdSe nanograsses composed of nanorods on GO.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Solvent-controlled preparation and photocatalytic properties of nanostructured TiO{sub 2} thin films with different morphologies

Graphical abstract: Low-temperature growth of nanostructured TiO{sub 2} thin films was presented by a solvent-controlled method. Nanoparticle structured films in anatase phase have been successfully fabricated with some adjustment. The effects of the solvent were investigated and the formation mechanism was proposed. - Highlights: • Nanostructured TiO{sub 2} thin films with different morphologies were obtained at low temperature. • The effects of the solvent on the morphologies of the products were investigated. • The effects of the solvent on the phtocatalytic activity were investigated. - Abstract: A low-temperature growth method of nanostructured TiO{sub 2} thin films with different morphologies was reported. Rod-like, grass-like and nanosheet structured films have been successfully fabricated just by adjusting the ratio of different solvents. The effects of the solvent on the morphologies of the TiO{sub 2} nanostructures were investigated. The formation mechanism of different morphologies was proposed based on the experiment results. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM). The photocatalytic activity of as-prepared samples for the degradation of methylene blue (MB) in water was evaluated under UV illumination. Results showed that the solvents exhibited important effect on the morphologies and photocatalytic activity of as-prepared nanostructured titania films.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Hexavalent chromium is cytotoxic and genotoxic to hawksbill sea turtle cells

Sea turtles are a charismatic and ancient ocean species and can serve as key indicators for ocean ecosystems, including coral reefs and sea grass beds as well as coastal beaches. Genotoxicity studies in the species are absent, limiting our understanding of the impact of environmental toxicants on sea turtles. Hexavalent chromium (Cr(VI)) is a ubiquitous environmental problem worldwide, and recent studies show it is a global marine pollutant of concern. Thus, we evaluated the cytotoxicity and genotoxicity of soluble and particulate Cr(VI) in hawksbill sea turtle cells. Particulate Cr(VI) was both cytotoxic and genotoxic to sea turtle cells. Concentrations of 0.1, 0.5, 1, and 5 μg/cm{sup 2} lead chromate induced 108, 79, 54, and 7% relative survival, respectively. Additionally, concentrations of 0, 0.1, 0.5, 1, and 5 μg/cm{sup 2} lead chromate induced damage in 4, 10, 15, 26, and 36% of cells and caused 4, 11, 17, 30, and 56 chromosome aberrations in 100 metaphases, respectively. For soluble Cr, concentrations of 0.25, 0.5, 1, 2.5, and 5 μM sodium chromate induced 84, 69, 46, 25, and 3% relative survival, respectively. Sodium chromate induced 3, 9, 9, 14, 21, and 29% of metaphases with damage, and caused 3, 10, 10, 16, 26, and 39 damaged chromosomes in 100 metaphases at concentrations of 0, 0.25, 0.5, 1, 2.5, and 5 μM sodium chromate, respectively. These data suggest that Cr(VI) may be a concern for hawksbill sea turtles and sea turtles in general. - Highlights: • Particulate Cr(VI) is cytotoxic and clastogenic to hawksbill sea turtle cells. • Soluble Cr(VI) is cytotoxic and clastogenic to hawksbill sea turtle cells. • Cr(VI) may be a risk factor for hawksbill sea turtle health.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2012

Treatment of sludge containing nitro-aromatic compounds in reed-bed mesocosms - Water, BOD, carbon and nutrient removal

Highlights: Black-Right-Pointing-Pointer It is necessary to improve existing and develop new sludge management techniques. Black-Right-Pointing-Pointer One method is dewatering and biodegradation of compounds in constructed wetlands. Black-Right-Pointing-Pointer The result showed high reduction of all tested parameters after treatment. Black-Right-Pointing-Pointer Plants improve degradation and Phragmites australis is tolerant to xenobiotics. Black-Right-Pointing-Pointer The amount of sludge could be reduced by 50-70%. - Abstract: Since the mid-1970s, Sweden has been depositing 1 million ton d.w sludge/year, produced at waste water treatment plants. Due to recent legislation this practice is no longer a viable method of waste management. It is necessary to improve existing and develop new sludge management techniques and one promising alternative is the dewatering and treatment of sludge in constructed wetlands. The aim of this study was to follow reduction of organic carbon, BOD and nutrients in an industrial sludge containing nitro-aromatic compounds passing through constructed small-scale wetlands, and to investigate any toxic effect such as growth inhibition of the common reed Phragmites australis. The result showed high reduction of all tested parameters in all the outgoing water samples, which shows that constructed wetlands are suitable for carbon and nutrient removal. The results also showed that P. australis is tolerant to xenobiotics and did not appear to be affected by the toxic compounds in the sludge. The sludge residual on the top of the beds contained low levels of organic carbon and is considered non-organic and could therefore be landfilled. Using this type of secondary treatment method, the amount of sludge could be reduced by 50-70%, mainly by dewatering and biodegradation of organic compounds.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Benefits of supplementing an industrial waste anaerobic digester with energy crops for increased biogas production

Highlights: Black-Right-Pointing-Pointer This study demonstrates the feasibility of co-digestion food industrial waste with energy crops. Black-Right-Pointing-Pointer Laboratory batch co-digestion led to improved methane yield and carbon to nitrogen ratio as compared to mono-digestion of industrial waste. Black-Right-Pointing-Pointer Co-digestion was also seen as a means of degrading energy crops with nutrients addition as crops are poor in nutrients. Black-Right-Pointing-Pointer Batch co-digestion methane yields were used to predict co-digestion methane yield in full scale operation. Black-Right-Pointing-Pointer It was concluded that co-digestion led an over all economically viable process and ensured a constant supply of feedstock. - Abstract: Currently, there is increasing competition for waste as feedstock for the growing number of biogas plants. This has led to fluctuation in feedstock supply and biogas plants being operated below maximum capacity. The feasibility of supplementing a protein/lipid-rich industrial waste (pig manure, slaughterhouse waste, food processing and poultry waste) mesophilic anaerobic digester with carbohydrate-rich energy crops (hemp, maize and triticale) was therefore studied in laboratory scale batch and continuous stirred tank reactors (CSTR) with a view to scale-up to a commercial biogas process. Co-digesting industrial waste and crops led to significant improvement in methane yield per ton of feedstock and carbon-to-nitrogen ratio as compared to digestion of the industrial waste alone. Biogas production from crops in combination with industrial waste also avoids the need for micronutrients normally required in crop digestion. The batch co-digestion methane yields were used to predict co-digestion methane yield in full scale operation. This was done based on the ratio of methane yields observed for laboratory batch and CSTR experiments compared to full scale CSTR digestion of industrial waste. The economy of crop-based biogas production is limited under Swedish conditions; therefore, adding crops to existing industrial waste digestion could be a viable alternative to ensure a constant/reliable supply of feedstock to the anaerobic digester.

09 BIOMASS FUELS↗
DOE OSTI2012

Two-year performance by evapotranspiration covers for municipal solid waste landfills in northwest Ohio

Highlights: Black-Right-Pointing-Pointer All ET covers produced rates of percolation less than 32 cm yr{sup -1}, the maximum allowable rate by the Ohio EPA. Black-Right-Pointing-Pointer Dredged sediment provided sufficient water storage and promoted growth by native plant species. Black-Right-Pointing-Pointer Native plant mixtures attained acceptable rates of evapotranspiration throughout the growing season. - Abstract: Evapotranspiration (ET) covers have gained interest as an alternative to conventional covers for the closure of municipal solid waste (MSW) landfills because they are less costly to construct and are expected to have a longer service life. Whereas ET covers have gained acceptance in arid and semi-arid regions (defined by a precipitation (P) to potential evapotranspiration (PET) ratio less than 0.75) by meeting performance standards (e.g. rate of percolation), it remains unclear whether they are suitable for humid regions (P:PET greater than 0.75). The goal of this project is to extend their application to northwest Ohio (P:PET equals 1.29) by designing covers that produce a rate of percolation less than 32 cm yr{sup -1}, the maximum acceptable rate by the Ohio Environmental Protection Agency (OEPA). Test ET covers were constructed in drainage lysimeters (1.52 m diameter, 1.52 m depth) using dredged sediment amended with organic material and consisted of immature (I, plants seeded onto soil) or mature (M, plants transferred from a restored tall-grass prairie) plant mixtures. The water balance for the ET covers was monitored from June 2009 to June 2011, which included measured precipitation and percolation, and estimated soil water storage and evapotranspiration. Precipitation was applied at a rate of 94 cm yr{sup -1} in the first year and at rate of 69 cm yr{sup -1} in the second year. During the first year, covers with the M plant mixture produced noticeably less percolation (4 cm) than covers with the I plant mixture (17 cm). However, during the second year, covers with the M plant mixture produced considerably more percolation (10 cm) than covers with the I plant mixture (3 cm). This is likely due to a decrease in the aboveground biomass for the M plant mixture from year 1 (1008 g m{sup -2}) to year 2 (794 g m{sup -2}) and an increase for the I plant mixture from year 1 (644 g m{sup -2}) to year 2 (1314 g m{sup -2}). Over the 2-year period, the mean annual rates of percolation for the covers with the M and I plant mixtures were 7 and 8 cm yr{sup -1}, which are below the OEPA standard. The results suggest the application of ET covers be extended to northwest Ohio and other humid regions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Climate response of the South Asian monsoon system to anthropogenic aerosols

The equilibrium climate response to the total effects (direct, indirect and semi-direct effects) of aerosols arising from anthropogenic and biomass burning emissions on the South Asian summer monsoon system is studied using a coupled atmosphere-slab ocean model. Our results suggest that anthropogenic and biomass burning aerosols generally induce a reduction in mean summer monsoon precipitation over most parts of the Indian subcontinent, strongest along the western coastline of the Indian peninsula and eastern Nepal region, but modest increases also occur over the north western part of the subcontinent. While most of the noted reduction in precipitation is triggered by increased emissions of aerosols from anthropogenic activities, modest increases in the north west are mostly associated with decreases in local emissions of aerosols from forest fire and grass fire sources. Anthropogenic aerosols from outside Asia also contribute to the overall reduction in precipitation but the dominant contribution comes from aerosol sources within Asia. Local emissions play a more important role in the total rainfall response to anthropogenic aerosol sources during the early monsoon period, whereas both local as well as remote emissions of aerosols play almost equally important roles during the later part of the monsoon period. While precipitation responses are primarily driven by local aerosol forcing, regional surface temperature changes over the region are strongly influenced by anthropogenic aerosols from sources further away (non-local changes). Changes in local anthropogenic organic and black carbon emissions by as much as a factor of two (preserving their ratio) produce the same basic signatures in the model's summer monsoon temperature and precipitation responses.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2012

Reference genome sequence of the model plant Setaria

We generated a high-quality reference genome sequence for foxtail millet (Setaria italica). The ~400-Mb assembly covers ~80% of the genome and >95% of the gene space. The assembly was anchored to a 992-locus genetic map and was annotated by comparison with >1.3 million expressed sequence tag reads. We produced more than 580 million RNA-Seq reads to facilitate expression analyses. We also sequenced Setaria viridis, the ancestral wild relative of S. italica, and identified regions of differential single-nucleotide polymorphism density, distribution of transposable elements, small RNA content, chromosomal rearrangement and segregation distortion. The genus Setaria includes natural and cultivated species that demonstrate a wide capacity for adaptation. The genetic basis of this adaptation was investigated by comparing five sequenced grass genomes. We also used the diploid Setaria genome to evaluate the ongoing genome assembly of a related polyploid, switchgrass (Panicum virgatum).

Bennetzen, Jeffrey L↗
DOE OSTI2011

Fractal structures in two-metal electrodeposition systems I: Pb and Zn

Pattern formation in two-metal electrochemical deposition has been scarcely explored in the chemical literature. In this paper, we report new experiments on zinc-lead fractal co-deposition. Electrodeposits are grown in special cells at a fixed large value of the zinc ion concentration, while that of the lead ion is increased gradually. A very wide diversity of morphologies are obtained and classified. Most of the deposited domains are almost exclusively Pb or Zn. But certain regions originating at the base cathode, ranging from a short grass alley to dense, grown-up bushes or shrubs, manifest a combined Pb-Zn composition. Composition is determined using scanning electron microscopy/energy dispersive x ray measurements as well atomic absorption spectroscopy. Pb domains are characterized by shiny leaf-like and dense deposits as well as flowers with round, balloon-like corollas. The Zn zones display a greater variety of morphologies such as thick trunks and thin and fine branching, in addition to minute ''cigar flower'' structures. The various morphologies are analyzed and classified from the viewpoint of fractal nature, characterized by the box-count fractal dimension. Finally, macroscopic spatial alternation between two different characteristic morphologies is observed under certain conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Tracking Dynamics of Plant Biomass Composting by Changes in Substrate Structure, Microbial Community, and Enzyme Activity

Understanding the dynamics of the microbial communities that, along with their secreted enzymes, are involved in the natural process of biomass composting may hold the key to breaking the major bottleneck in biomass-to-biofuels conversion technology, which is the still-costly deconstruction of polymeric biomass carbohydrates to fermentable sugars. However, the complexity of both the structure of plant biomass and its counterpart microbial degradation communities makes it difficult to investigate the composting process. In this study, a composter was set up with a mix of yellow poplar (Liriodendron tulipifera) wood-chips and mown lawn grass clippings (85:15 in dry-weight) and used as a model system. The microbial rDNA abundance data obtained from analyzing weekly-withdrawn composted samples suggested population-shifts from bacteria-dominated to fungus-dominated communities. Further analyses by an array of optical microscopic, transcriptional and enzyme-activity techniques yielded correlated results, suggesting that such population shifts occurred along with early removal of hemicellulose followed by attack on the consequently uncovered cellulose as the composting progressed. The observed shifts in dominance by representative microbial groups, along with the observed different patterns in the gene expression and enzymatic activities between cellulases, hemicellulases, and ligninases during the composting process, provide new perspectives for biomass-derived biotechnology such as consolidated bioprocessing (CBP) and solid-state fermentation for the production of cellulolytic enzymes and biofuels.

09 BIOMASS FUELS↗