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Materials Data on GdAs by Materials Project

GdAs is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Gd3+ is bonded to six equivalent As3- atoms to form a mixture of edge and corner-sharing GdAs6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Gd–As bond lengths are 2.95 Å. As3- is bonded to six equivalent Gd3+ atoms to form a mixture of edge and corner-sharing AsGd6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗

Growth, structural, and magnetic properties of single-crystal full-Heusler Co 2 TiGe thin films

This paper presents the growth, structural characterization, and measurement of magnetic properties of Co 2 TiGe thin films grown by molecular beam epitaxy on insulating MgO (001) substrates and conductive lattice matched InAlAs/InGaAs/InAlAs epitaxial layers grown on n-InP (001) substrates. A GdAs diffusion barrier was used to minimize interfacial reactions during Co 2 TiGe growth on InAlAs. The surface morphology, structural quality, and magnetic behavior were examined by reflection high-energy electron diffraction, scanning tunneling microscopy, X-ray diffraction, and superconducting quantum interference device magnetometry. The results reveal high quality Co 2 TiGe thin films with a saturation magnetization of ~1.8 μ B /formula unit and a Curie temperature of ~375 K. Finally, the magnetic easy axis was found to lie in the [110] direction but magnetometry also reveals that there is only a small difference in energy between the [110] and [010] magnetization directions.

36 MATERIALS SCIENCE↗

Back Trajectories during SAIL

This data set contains air mass back trajectories generated during the Surface Atmosphere Integrated Field Laboratory (SAIL) campaign using the Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT, Stein et al. 2015, Rolph et al. 2017). For each hour from January 1, 2021 to June 30, 2023, a 96-hour back trajectory was initiated at the SAIL sampling site, starting 100 m above ground level. The calculations used the GDAS meteorological data set with model vertical velocity. The files within this dataset show location and meteorological parameters of the back trajectory analysis. There are 21 columns within each data file. The first 2 columns pertain to back trajectory parameters: the trajectory number (which is always 1) and the meteorological grid number. The next 9 columns pertain to spatiotemporal information: the year, month, day, hour (0-23), and minute of the trajectory, the previous time of the trajectory (in negative hours), and the airmass location (latitude, longitude, and height in m AGL). The rest of the parameters within each file pertains to surface and meteorological characteristics of the airmass: pressure (in hPa), potential temperature (in K), temperature (in K), precipitation rate (in mm/hr), mixing depth (in m), relative humidity (in % relative to liquid water), specific humidity (in g/kg), H2O mixing ratio (in g/kg), underlying terrain height (in meters above sea level), and incoming radiation (in W/m^2).

back trajectory↗

The Impact of QuikScat on Weather Analysis and Forecasting

Scatterometer observations of the ocean surface wind speed and direction improve the depiction and prediction of storms at sea. These data are especially valuable where observations are otherwise sparse, mostly in the Southern Hemisphere and tropics, but also on occasion in the North Atlantic and North Pacific The SeaWinds scatterometer on the QuikScat satellite was launched in June 1999 and it represents a dramatic departure in design from the other scatterometer instruments launched during the past decade (ERS-1,2 and NSCAT). More details on the SeaWinds instrument can be found in Atlas et al. (2001) and Bloom et al. (1999). This presentation shows the influence of QuikScat data in data assimilation systems both from the NASA Data Assimilation Office (GEOS-3) and from NCEP (GDAS).

Atlas, Robert↗

Impact of Quikscat Data on Numerical Weather Prediction

Scatterometer observations of the ocean surface wind speed and direction improve the depiction and prediction of storms at sea. These data are especially valuable where observations are otherwise sparse ---mostly in the Southern Hemisphere and tropics, but also on occasion in the North Atlantic and North Pacific. The SeaWinds scatterometer on the QuikScat satellite was launched in July 1999 and it represents a dramatic departure in design from the other scatterometer instruments launched during the past decade (ERS-1,2 and NSCAT). The NASA Data Assimilation Office (DAO) was the first data assimilation center to assimilate QuikScat SeaWinds data and evaluate their impact on numerical weather prediction. Several data impact experiments have been performed, using systems from both the DAO (GEOS-3) and from NCEP (GDAS). In general, these experiments have shown a modest impact of SeaWinds data on numerical weather prediction, the magnitude of which appears to be comparable to the magnitude of the impact of AMI scatterometer data from the ERS satellites. Some of the main results from these experiments will be presented at the meeting.

Atlas, Robert↗

Impact of SeaWinds Scatterometer Data on Numerical Weather Prediction

Scatterometer observations of the ocean surface wind speed and direction improve the depiction and prediction of storms at sea. These data are especially valuable where observations are otherwise sparse - mostly in the Southern Hemisphere and tropics, but also on occasion in the North Atlantic and North Pacific. The SeaWinds scatterometer on the QuikScat satellite was launched in June 1999 and it represents a dramatic departure in design from the other scatterometer instruments launched during the past decade (ERS-1,2 and NSCAT). More details on the SeaWinds instrument can be found in Atlas et a1 (2001) and Bloom et al. (1999). At the time of this writing, SeaWinds scatterometer data from the ADEOS 2 satellite are not yet available . Therefore this paper will be limited to results from the SeaWinds scatterometer on Quikscat. This presentation shows the influence of QuikScat data in data assimilation systems both from the NASA Data Assimilation Office (GEOS-3) and from NCEP (GDAS).

Atlas, Robert↗

Polarimetric Microwave Remote Sensing of Hurricane Ocean Winds

We presented the analysis of Windsat data for hurricanes Isabel and Fabian in 2003. The polarimetric third and fourth Stokes parameter observations from the Windsat 10, 18 and 37 GHz channels were collocated with the ocean surface winds from the Holland wind model, the QuikSCAT wind vectors and the Global Data Assimilation System (GDAS) operated by the National Center for Environmental Prediction (NCEP). The collocated data were binned as a function of wind speed and wind direction, and were expanded by sinusoidal series of the relative azimuth angles between wind and observation directions. The coefficients of the sinusoidal series, corrected for atmospheric attenuation, have been used to develop an empirical geophysical model function (GMF). The Windsat GMF for extreme high wind compares very well with the aircraft radiometer and radar measurements.

widebands↗

Combined Active and Passive Remote Sensing of Hurricane Ocean Winds

The synergism of active and passive microwave techniques for hurricane ocean wind remote sensing is explored. We performed the analysis of Windsat data for Atlantic hurricanes in 2003-2005. The polarimetric third Stokes parameter observations from the Windsat 10, 18 and 37 GHz channels were collocated with the ocean surface winds from the Holland wind model, the QuikSCAT wind vectors and the Global Data Assimilation System (GDAS) operated by the National Center for Environmental Prediction (NCEP). The collocated data were binned as a function of wind speed and wind direction, and were expanded by sinusoidal series of the relative azimuth angles between wind and observation directions. The coefficients of the sinusoidal series, corrected for atmospheric attenuation, have been used to develop an empirical geophysical model function (GMF). The Windsat GMF for extreme high wind compares very well with the aircraft radiometer and radar measurements.

sea surface winds↗

Improving Incremental Balance in the GSI 3DVAR Analysis System

The Gridpoint Statistical Interpolation (GSI) analysis system is a unified global/regional 3DVAR analysis code that has been under development for several years at the National Centers for Environmental Prediction (NCEP)/Environmental Modeling Center. It has recently been implemented into operations at NCEP in both the global and North American data assimilation systems (GDAS and NDAS). An important aspect of this development has been improving the balance of the analysis produced by GSI. The improved balance between variables has been achieved through the inclusion of a Tangent Linear Normal Mode Constraint (TLNMC). The TLNMC method has proven to be very robust and effective. The TLNMC as part of the global GSI system has resulted in substantial improvement in data assimilation both at NCEP and at the NASA Global Modeling and Assimilation Office (GMAO).

Errico, Ronald M.↗

Dynamic Responses of the Earth's Outer Core to Assimilation of Observed Geomagnetic Secular Variation

Assimilation of surface geomagnetic observations and geodynamo models has advanced very quickly in recent years. However, compared to advanced data assimilation systems in meteorology, geomagnetic data assimilation (GDAS) is still in an early stage. Among many challenges ranging from data to models is the disparity between the short observation records and the long time scales of the core dynamics. To better utilize available observational information, we have made an effort in this study to directly assimilate the Gauss coefficients of both the core field and its secular variation (SV) obtained via global geomagnetic field modeling, aiming at understanding the dynamical responses of the core fluid to these additional observational constraints. Our studies show that the SV assimilation helps significantly to shorten the dynamo model spin-up process. The flow beneath the core-mantle boundary (CMB) responds significantly to the observed field and its SV. The strongest responses occur in the relatively small scale flow (of the degrees L is approx. 30 in spherical harmonic expansions). This part of the flow includes the axisymmetric toroidal flow (of order m = 0) and non-axisymmetric poloidal flow with m (is) greater than 5. These responses can be used to better understand the core flow and, in particular, to improve accuracies of predicting geomagnetic variability in future.

secular variation↗

Influence of Precipitation Forcing Uncertainty on Hydrological Simulations with the NASA South Asia Land Data Assimilation System

Accurate meteorological estimates are critical for process-based hydrological simulationand prediction. This presents a significant challenge in mountainous Asia where in situmeteorological stations are limited and major river basins cross international borders. In thiscontext, remotely sensed and model-derived meteorological estimates are often necessary inputsfor distributed hydrological analysis. However, these datasets are difficult to evaluate on accountof limited access to ground data. In this case, the implications of uncertainty associated withprecipitation forcing for hydrological simulations is explored by driving the South Asia Land DataAssimilation System (South Asia LDAS) using a range of meteorological forcing products.MERRA2, GDAS, and CHIRPS produce a wide range of estimates for rainfall, which causes awidespread simulated streamflow and evapotranspiration. A combination of satellite-derived andlimited in situ data are applied to evaluate model simulations and, by extension, to constrain theestimates of precipitation. The results show that available gridded precipitation estimates based onin situ data may systematically underestimate precipitation in mountainous regions and thatperformance of gridded satellite-derived or modeled precipitation estimates varies systematicallyacross the region. Since no station-based data or product including station data is satisfactoryeverywhere, our results suggest that the evaluation of the hydrological simulation of streamflowand ET can be used as an indirect evaluation of precipitation forcing based on ground-basedproducts or in-situ data. South Asia LDAS produces reasonable evapotranspiration and streamflowwhen forced with appropriate meteorological forcing and the choice of meteorological forcingshould be made based on the geographical location as well as on the purpose of the simulations.

South Asia land data assimilation system (South As↗

Developing a Hydrological Monitoring and Sub-Seasonal to Seasonal Forecasting System for South and Southeast Asian River Basins

South and Southeast Asia is subject to significant hydrometeorological extremes, including drought. Under rising temperatures, growing populations, and an apparent weakening of the South Asian monsoon in recent decades, concerns regarding drought and its potential impacts on water and food security are on the rise. Reliable sub-seasonal to seasonal (S2S) hydrological forecasts could, in principle, help governments and international organizations to better assess risk and act in the face of an oncoming drought. Here, we leverage recent improvements in S2S meteorological forecasts and the growing power of Earth Observations to provide more accurate monitoring of hydrological states for forecast initialization. Information from both sources is merged in a South and Southeast Asia sub-seasonal to seasonal hydrological forecasting system (SAHFS-S2S), developed collaboratively with the NASA SERVIR program and end-users across the region. This system applies the Noah-MultiParameterization (NoahMP) Land Surface Model (LSM) in the NASA Land Information System (LIS), driven by downscaled meteorological fields from the Global Data Assimilation System (GDAS) and Climate Hazards InfraRed Precipitation products (CHIRP and CHIRPS) to optimize initial conditions. The NASA Goddard Earth Observing System Model - sub-seasonal to seasonal (GEOS-S2S) forecasts, downscaled using the National Center for Atmospheric Research (NCAR) General Analog Regression Downscaling (GARD) tool and quantile mapping, are then applied to drive 5-km resolution hydrological forecasts to a 9-month forecast time horizon. Results show that the skillful predictions of root zone soil moisture can be made one to two months in advance for forecasts initialized in rainy seasons and up to 8 months when initialized in dry seasons. The memory of accurate initial conditions can positively contribute to forecast skills throughout the entire 9-month prediction period in areas with limited precipitation. This SAHFS-S2S has been operationalized at the International Centre for Integrated Mountain Development (ICIMOD) to support drought monitoring and warning needs in the region.

Yifan Zhou↗

Evidence of Warm Core Structure Maintenance Over Land: A Case Study Analysis of Cyclone Kelvin

Cyclone Kelvin made landfall in northwest Australia as a category 1 storm on 18 February 2018. After landfall, tropical cyclones typically weaken due to the exhaustion of a moisture supply. Cyclone Kelvin continued to intensify with winds gusting to 100 knots and significant flooding well inland. A distinct eye feature also formed well after landfall. An analysis of meteorological satellite, MERRA2reanalysis, and Global Data Assimilation System (GDAS) data was employedin a case study of Cyclone Kelvin. Using a cyclone phase diagram, it is confirmed that a warm core structure was maintained as Cyclone Kelvin continued to move inland, even through a period of brief inland intensification.

Cyclone Kelvin↗

Assimilation of CrIS Shortwave Infrared Channels into the GEOS Atmospheric Data Assimilation System

In recent years, there has been a renewed interest in using the 4.3 μmshortwave infrared (SWIR) band for temperature sounding. This is in part brought on by proposed cubesat missions sensing the 4.3 μmband such as MiSTIC and CIRAS. Jones et al. has shown that shortwave infrared channels on CrIScan be used effectively in NOAA's Global Forecast and Data Assimilation System (GDAS). In this work a similar study is presented using the Goddard Earth Observing System - Atmospheric Data Assimilation System (GEOS-ADAS). Results from Observing System Experiments (OSEs) utilizing SWIR CrISare presented using standard community accepted forecast metrics including Forecast Sensitivity to Observation Impact (FSOI), and an assessment of vertical sensitivity using Jacobians from the Community Radiative Transfer Model (CRTM). The implications and utility within the GEOS-ADAS for future NASA GMAO products are discussed.

Bryan M Karpowicz↗

Seasonal Soil Freeze/Thaw Variability Across North America via Ensemble Land Surface Modeling

Land surface modeling provides the opportunity to investigate winter soil processes such as soil freezing and thawing over large domains. However, the variability in simulated winter soil characteristics among land surface models and forcing datasets is not well understood. In this study, a nine-member ensemble was employed to characterize the spatial and inter-annual variability of three winter soil characteristics, annual number of frozen days, annual minimum temperature and annual number of freeze-thaw cycles over North America during the water years 2010–2016. The ensemble, including three land surface model (JULES, Noah2.7.1 and Noah-MP) and three forcing datasets (ECMWF, GDAS and MERRA2), was developed through the Snow Ensemble Uncertainty Project (SEUP). In many regions, there was remarkably good agreement across the ensemble for the winter soil temperatures. However, the variability among the ensemble's annual number of frozen days, as quantified with standard deviation, exceeded 150 days at the northern Pacific coastline. While the differences among the ensemble members' annual minimum temperature were typically <3 °C, the differences exceeded 6 °C north of 50°N. The ensemble members generally agreed within one to three freeze-thaw cycles in mid latitude regions, Alaska, and the south and west coasts of the USA. High variability among the ensemble, more than six freeze-thaw cycles, occurred in the Great Plains, northern Pacific coastline, and along the Appalachian Mountains. Differences in winter soil temperature characteristics were more apparent among the LSMs rather than the meteorological forcing datasets. Except for maritime regions, the Noah2.7.1 members had the fewest annual number of frozen days and the least number of freeze-thaw cycles. Noah2.7.1 also had the coldest annual minimum temperatures except for ephemeral regions. Comparisons between in-situ observations and the SEUP estimates of winter soil characteristics revealed that the modeled frozen period was much longer than observed, that the modeled annual minimum temperatures were much colder than observed, and the modeled freeze-thaw cycles occurred more frequently than observed. Excluding the high latitude sites, the observed frozen period is less than two months with the minimum temperature above − 5 °C at most of the studied sites, while the ensemble members simulated, on average, a four month frozen period with − 10 °C minimum temperature. Errors in capturing snow during the accumulation period appear to impact differences in modeled versus observed soil temperature throughout the entire winter.

Soil freeze/thaw↗

Enabling the Assimilation of CrIS Shortwave Infrared Observations in Global NWP at NOAA. Part I: Background and Methods

Radiance observations from Earth-observing satellites have a significant positive impact on numerical weather prediction (NWP) forecasts, but some spectral regions are not fully exploited. Observations from hyperspectral infrared (IR) sounders in the longwave region (650-1100 cm -1 ), for instance, are routinely assimilated in many NWP models, but observations in the shortwave region (2155-2550 cm -1 ) are not. Each of these regions provides information on the temperature structure of the atmosphere, but the shortwave IR (SWIR) region is considered challenging to assimilate due to noise equivalent delta temperature (NEDT) that is highly variable depending on scene brightness temperature and to phenomena that are difficult to model, like non-Local Thermodynamic Equilibrium (NLTE) and solar reflectance. With recent advances in small-satellite technology, SWIR temperature sounders may provide an agile and cost-effective complement to the current constellation of IR sounders. Therefore, a better understanding of the use and impact of SWIR observations in data assimilation for NWP is warranted. In part one of this study, as presented here, the amount of unique information (as determined by Empirical Orthogonal Decomposition (EOD)) made available to a data assimilation system by Cross-track Infrared Sounder (CrIS) SWIR observations is reviewed, recent advancements to the Community Radiative Transfer Model (CRTM) for the simulation of CrIS shortwave radiances are tested, and enhancements to NOAA’s Global Data Assimilation System (GDAS) for the assimilation of CrIS SWIR observations are implemented and evaluated. Part two of this study, which seeks to assess the value of assimilating shortwave IR observations in global NWP, is also introduced.

Erin Jones↗

Enabling the Assimilation of CrIS Shortwave Infrared Observations in Global NWP at NOAA. Part II: OSEs and Results

The assimilation of data from hyperspectral infrared sounders in global data assimilation systems has historically been focused on observations in the longwave infrared (LWIR) region of the spectrum (650-1100 cm−1), despite the often concurrent availability of measurements from the shortwave infrared (SWIR) region of the spectrum (2150-2550 cm−1), because issues (like solar effects) have generally prevented the assimilation of SWIR observations. Recent advances in radiative transfer models have worked to address some of the previous challenges in simulating SWIR observations, and the assimilation of SWIR data (e.g. from potential future small-satellites) is now a feasible prospect. Still, a better understanding of how these observations perform in a data assimilation system and impact resulting analyses and NWP forecasts is necessary. In this study, the value of SWIR observations in global NWP is assessed by assimilating SWIR observations from the Cross-track Infrared Sounder (CrIS) in NOAA’s Global Data Assimilation System (GDAS). The methodologies used to enable the assimilation of these observations, including the implementation of a scene-dependent observation error and the enhancement of quality control procedures, are discussed, as are the results of Observing System Experiments (OSEs) conducted to evaluate the impact of assimilating SWIR observations on forecast skill. The overall results show that SWIR assimilation produces similar forecast impacts to LWIR assimilation. The ability to demonstrate that the assimilation or SWIR observations in NWP is a realistic prospect may help to shape future constellations of small-satellites to serve as a beneficial complement to the current constellation if hyperspectral IR sounders.

Erin Jones↗

Challenges in the UK Generic Design Assessment Process - 17062

In the UK, Generic Design Assessment (GDA) is a voluntary step-wise joint assessment process undertaken by the Office for Nuclear Regulation (ONR) and the Environment Agency (EA) of a generic reactor design. The process focuses purely on the reactor design and does not consider any site specific issues. The key objective of GDA is for the regulators to consider the adequacy of claims, arguments and evidence (CAE) put forward by a requesting party (RP) to demonstrate the safety of its design in the UK context. This includes all CAE relating to management of spent fuel and radioactive waste. The CAE are generally applied to a reference design put forward by the RP that is substantially complete in terms of the overall concepts and functions of the major systems, having already been deployed elsewhere. GDA assessment encompasses a broad range of topic areas which include fuel and core design, management of spent fuel, radioactive waste management and decommissioning. Other technical disciplines also have valid interests in particular aspects of the management of spent fuel. This paper summarises the UK GDA process and the types of issues raised; in particular aspects of the proposed operation of liquid waste management systems and Spent Fuel Interim Storage are presented and the instructive resolution of the RP's original limited design scope to allow the regulators to carry out a meaningful assessment. Some examples are presented and useful lessons learned for future GDAs are discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗