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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Effects of silicate-graphite dust in H II regions

Interstellar dust that is present in H II regions will most likely absorb H-ionizing photons more efficiently than He-ionizing photons. Assuming a silicate-graphite dust composition, the effects of such selective absorption on the ionization structure of H, He, O, and N are investigated with emphasis on a blister geometry. Scattering by the dust grains is included in the generalized on-the-spot approximation. For a relatively soft radiation field of effective temperature about 35,000 K, the radiation hardening may cause the He(+) zone to be nearly coextensive with the H(+) zone, and the O(++) volume is strongly increased relative to the N(++) volume. The smaller grains (radii about 0.005 micron) contribute most to the selective absorption. We show that because of a cancellation of effects a simple analytical formula for the fraction of ionizing photons absorbed by the dust given by Petrosian, Silk, and Field is quite accurate in the case of silicate-graphite dust, even for blister regions.

Aannestad, Per A.↗
NASA NTRS1997

Observational Evidence for Mixing and Dust Condensation in Core-Collapse Supernovae

Recent findings of isotopic anomalies of Ca-44 (the decay product of Ti-44) and the enhanced ratio of Si-28/Si-30 in SiC grains X, TiC subgrains, and graphite dust grains within primitive meteorites provides strong evidence that these presolar grains came from core-collapse supernovae. The chemical composition of the presolar grains requires macroscopic mixing of newly nucleo-synthesized elements from explosive silicon burning at the innermost zone of the ejects to higher velocities where C exists and where C/O > 1 in either the outer edge of the oxygen zone or in the He-C zone. To date, the only core-collapse supernova observed to form dust is the brightest supernova of the past four centuries, SN1987A in the Large Magellanic Cloud. Observations of SN1987A confirm large scale macroscopic mixing occurs in the explosions of massive stars. Rayleigh-Taylor instabilities macroscopically mix most of the ejects into regions which are still chemically homogeneous and which cool with different time scales. Only small clumps in the ejects are microscopically mixed. Observations show that dust condensed in the ejects of SN1987A after approx.500 days in the Fe-rich gas. Neither silicates nor SiC grains were seen in the dust emission spectrum of SN1987A. SN1987A, the Rosetta Stone of core-collapse supernovae, shows that while the mixing required to explain presolar grains occurs, the rapid cooling of the Fe zone and the sustained high temperatures of the O-Si, O-C, and He-C zones favor the formation of iron-rich rather than oxygen- or carbon-rich grains.

Wooden, Diane↗
NASA NTRS1992

The anomalous extinction curve in the direction of Rho Ophiuchi from 950 to 1180 A

We report the interstellar extinction from 950 to 1180 A in the direction of Rho Oph. These data were obtained with a moderate-resolution sounding rocket observation of Ro Oph, and two lightly reddened B stars of identical spectral type. Unlike Voyager observations in this wavelength region, our spectral resolution is sufficient to directly measure the contribution of molecular hydrogen along the line of sight and unambiguously identify the dust contribution. The derived curves compare favorably with the extrapolation of functional fits to the Rho Oph derived from longer wavelengths. In addition, we have fitted a model of dust extinction to the derived curve and find that the best fits indicate that the line of sight exhibits a larger than average grain size and a preferential concentration of graphite relative to silicates. The sharp rise seen at the shortest wavelengths (below 1000 A) cannot be explained by standard silicate-graphite dust models and may be indicative of a nonstandard grain shape or a missing component in the extinction models.

Green, James C.↗
NASA NTRS1990

The 2175-A feature from irradiated graphitic particles

In diffuse clouds, a subpopulation of the carbon grains is graphitized by UV starlight during cloud lifetimes of roughly 100 Myr. Graphitic dust created in this way will behave like monosize Rayleigh particles and produce a 2175-A absorption band showing a Lorentzian profile. A physical model is outlined in which the strength and width of the band correlate with the dust grain environment, but the central wavelength is fixed by the Froehlich frequency for surface plasmons in a homogeneous sphere. On this model, the band appears strong and narrow only in dust clouds where the flux of UV starlight is high and the H atom gas density is low. The width of the band increases from diffuse to dense clouds mainly as a result of gas-phase H atoms accreted on to the grain surface. It is shown that hydrogenation weakens the band in dense clouds, and thus explains the anticorrelation between band strength and high carbon depletion. The model as a whole uses only 30 percent of the cosmic carbon and gives good agreement with observations of the 2175-A feature and the average interstellar extinction law.

Sorrell, Wilfred H.↗
NASA NTRS2012

Transformation of Graphitic and Amorphous Carbon Dust to Complex Organic Molecules in a Massive Carbon Cycle in Protostellar Nebulae

More than 95% of silicate minerals and other oxides found in meteorites were melted, or vaporized and recondensed in the Solar Nebula prior to their incorporation into meteorite parent bodies. Gravitational accretion energy and heating via radioactive decay further transformed oxide minerals accreted into planetesimals. In such an oxygen-rich environment the carbonaceous dust that fell into the nebula as an intimate mixture with oxide grains should have been almost completely converted to CO. While some pre-collapse, molecular-cloud carbonaceous dust does survive, much in the same manner as do pre-solar oxide grains, such materials constitute only a few percent of meteoritic carbon and are clearly distinguished by elevated D/H, N-15/N-16, C-13/C-12 ratios or noble gas patterns. Carbonaceous Dust in Meteorites: We argue that nearly all of the carbon in meteorites was synthesized in the Solar Nebula from CO and that this CO was generated by the reaction of carbonaceous dust with solid oxides, water or OH. It is probable that some fraction of carbonaceous dust that is newly synthesized in the Solar Nebula is also converted back into CO by additional thermal processing. CO processing might occur on grains in the outer nebula through irradiation of CO-containing ice coatings or in the inner nebula via Fischer-Tropsch type (FTT) reactions on grain surfaces. Large-scale transport of both gaseous reaction products and dust from the inner nebula out to regions where comets formed would spread newly formed carbonaceous materials throughout the solar nebula. Formation of Organic Carbon: Carbon dust in the ISM might easily be described as inorganic graphite or amorphous carbon, with relatively low structural abundances of H, N, O and S . Products of FTT reactions or organics produced via irradiation of icy grains contain abundant aromatic and aliphatic hydrocarbons. aldehydes, keytones, acids, amines and amides.. The net result of the massive nebular carbon cycle is to convert relatively inert carbonaceous dust from the ISM into the vital organic precursors to life such as amino acids and sugars intimately mixed with dust and ice in primitive planetesimals. Since the number of carbon atoms entering the Solar Nebula as dust exceeds the number of atoms entering the nebula as oxide grains. the formation of large quantities of complex organic molecules may represent the largest single chemical cycle in the nebula.

Nuth, Joseph A., III↗
NASA NTRS1988

On graphite in primitive meteorites, chondritic interplanetary dust, and interstellar dust

Vapor phase-condensed primary and secondary graphites require prolonged solid-state thermal annealing and are less likely than amorphous graphitizable carbons to occur in the interstellar medium as dust. Some unknown fraction of this amorphous carbon may be converted to secondary graphite by radiative annealing due to UV photons. Grain size distribution may differentiate between primary and secondary graphites; secondary graphite should, moreover, be associated with poorly graphitized carbon. Small, as-yet undetected amounts of small secondary graphite particles may exist in carbon-rich astrophysical environments.

Rietmeijer, Frans J. M.↗
NASA NTRS1991

Constraints on the optical properties of interstellar dust in the far-ultraviolet - Voyager observations of the diffuse sky background

Four regions of the sky have been observed at various Galactic latitudes and H I column densities, with the ultraviolet spectrometer aboard Voyager 2 finding no evidence for the presence of a diffuse radiation field between 912 and 1100 A at a level of 100-200 photons per sq cm s sr A. As starlight scattered by dust grains may be expected to be a major contributor to the diffuse background, especially at low Galactic latitudes, it is possible to place a very stringent upper limit of less than 0.1 on the reflectivity of the dust in this spectral range. This albedo is much lower than the canonical value of about 0.5 for standard graphite-silicate dust models.

Murthy, Jayant↗
NASA NTRS1989

Far-infrared observations of thermal dust emission from supernova 1987A

Observations of SN1987A in the spectral range 18-35 microns taken on November 16 and 23, 1988, 632 and 639 days after core collapse, are reported. A strong and rather flat continuum underlies weak fine-structure lines from heavy elements and declines slowly between 24 and 30 microns. The spectral shape indicates thermal emission from an almost featureless dust component, probably graphite, with silicates contributing less than 20 percent of the emitting dust mass. Some of the emission may be an 'echo' of supernova light reflected from a preexisting dust cloud, but a better explanation which can account for the entirety of emission from infrared to gamma wavelengths, is that dust is being formed in the supernova ejecta. This also accounts more naturally for the inferred dust composition.

Moseley, S. H.↗
NASA NTRS2010

Spitzer Observations of Dust Destruction in the Puppis A Supernova Remnant

The interaction of the Puppis A supernova remnant (SNR) with a neighboring molecular cloud provides a unique opportunity to measure the amount of grain destruction in an SNR shock. Spitzer Space Telescope MIPS imaging of the entire SNR at 24, 70, and 160 micrometers shows an extremely good correlation with X-ray emission, indicating that the SNR's IR radiation is dominated by the thermal emission of swept-up interstellar dust, collisionally heated by the hot shocked gas. Spitzer IRS spectral observations targeted both the Bright Eastern Knot (BEK) of the SNR where a small cloud has been engulfed by the supernova blast wave and outlying portions of the associated molecular cloud that are yet to be hit by the shock front. Modeling the spectra from both regions reveals the composition and the grain size distribution of the interstellar dust, both in front of and behind the SNR shock front. The comparison shows that the ubiquitous polycyclic aromatic hydrocarbons of the interstellar medium are destroyed within the BEK, along with nearly 25% of the mass of graphite and silicate dust grains.

Arendt, Richard G.↗
NASA NTRS2010

Spitzer Observations of Dust Destruction in the Puppis A Supernova Remnant

Imaging and spectral observations of the Puppis A supernova remnant (SNR) with the Spitzer Space Telescope confirm that its IR emission is dominated by the thermal continuum emission of swept-up interstellar dust which is collisionally heated by the X-ray emitting gas of the SNR. Line emission is too weak to affect the fluxes measured in broadband observations, and is poorly correlated with the IR or X-ray emission. Modeling of spectra from regions both in the SNR and in the associated ISM show that the ubiquitous polycyclic aromatic hydrocarbons (PAHs) of the ISM are destroyed within the SNR, along with nearly 25% of the mass of graphite and silicate dust grains.

Arendt, Richard G.↗
NASA NTRS1993

Spectroscopic constraints on the properties of dust in active galactic nuclei

The optical properties of graphite, silicate, and SiC grains over the wavelength range 1000 microns - 1 A are calculated for grains in the 0.005-10-micron size range. Both graphite + silicate (MRN) and graphite + SiC grain mixtures are considered, with various grain size distributions. A detailed radiative transfer calculation is performed to obtain constraints on the emission properties of dust in AGN in either 'optically thin' or optically thick configurations. Warm graphite + silicate or graphite + SiC dust (T is greater than 200 K) with the MRN size distribution and a column density less than about 10 exp 23/sq cm produces a strong silicate or SiC emission feature. Such dust cannot be responsible for the observed IR emission from AGN. MRN dust with a high optical depth at 10 microns produces an emission feature with an amplitude of about 57 percent, in excess of the typical observational limit for most objects. Reddening of the broad emission lines and continuum is unlikely to be common.

Laor, Ari↗
NASA NTRS1991

Astro - Science in the fast lane

The Space Shuttle mission devoted to astronomy (Astro) is described and data obtained during the nine-day flight are briefly reviewed. The Wisconsin Ultraviolet Photo-Polarimeter Experiment reveals a trough at 2200 A in the spectrum of Alpha Camelopardalis. It is suggested that the 2200-A feature is caused by absorption by graphite-rich interstellar dust. The Broad Band X-ray Telescope made it possible to study the NGC 1399 X-ray spectrum, the spectrum of the BL Lacertae object PKS 2155-304, and a cooling flow in a cluster of galaxies. The Astro mission's search for the missing mass in the form of neutrinos is discussed. Attention is also given to the effect of delays on the Astro activity, and to equipment problems and how they were solved.

Maran, Stephen P.↗
NASA NTRS1995

The 5-8 Micron Infrared Spectrum of the Galactic Center and the Composition of Interstellar Dust

Interstellar dust is an important component of the interstellar medium which dominates the opacity and, hence, regulates radiative transfer, molecule formation, and thermal balance of the ISM. Much of our knowledge on the composition of interstellar dust results from infrared spect,oscopy. The extinction along the line of sight towards the galactic center is believed to be dominated by dust in the diffuse ISM. Because of the high extinction and high IR flux, IR spectra of galactic center sources have been a prime sampling ground for the characteristics of interstellar dust. We have obtained 5-8 micrometer spectra of the galactic center using the KAO. These spectra show absorption features at 5.5, 5.8, 6.1, and 6.8 micrometers. Together with features in the 3 micrometer region previously observed by us using the IRTF, these features are compared to laboratory spectra of candidate materials. We conclude that the 3.0 and 6.1 micrometer feature are carried by H2O, likely in the form of water of hydration in interstellar silicates. The 3.4, 5.5, 5.8, and 6.8 micrometer features are due to CH2, CH3 and C=O stretching and deformation modes in a hydrocarbon grain component. Comparing derived dust abundances, we conclude that silicates dominate the interstellar dust volume. Hydrocarbon and (small) graphite grains contribute each about 0.1. The remainder of the interstellar dust volume does not show strong IR absorption features and is likely in the form of large graphite, amorphous, carbon, or diamond grains.

Tielens, A. G. G. M.↗
NASA NTRS1986

Composition, structure and chemistry of interstellar dust

The observational constraints on the composition of the interstellar dust are analyzed. The dust in the diffuse interstellar medium consists of a mixture of stardust (amorphous silicates, amorphous carbon, polycyclic aromatic hydrocarbons, and graphite) and interstellar medium dust (organic refractory material). Stardust seems to dominate in the local diffuse interstellar medium. Inside molecular clouds, however, icy grain mantles are also important. The structural differences between crystalline and amorphous materials, which lead to differences in the optical properties, are discussed. The astrophysical consequences are briefly examined. The physical principles of grain surface chemistry are discussed and applied to the formation of molecular hydrogen and icy grain mantles inside dense molecular clouds. Transformation of these icy grain mantles into the organic refractory dust component observed in the diffuse interstellar medium requires ultraviolet sources inside molecular clouds as well as radical diffusion promoted by transient heating of the mantle. The latter process also returns a considerable fraction of the molecules in the grain mantle to the gas phase.

Tielens, Alexander G. G. M.↗
NASA NTRS1989

Infrared emission from ultracompact H II regions

Models of circumstellar dust shells around ultracompact (UC) H II regions were constructed that accurately fit the observed IR flux distributions. The models assume spherically symmetric dust shells illuminated by stars whose bolometric luminosity is inferred from the integrated FIR flux densities. Assuming ionization by a single zero age main sequence (ZAMS) star, the relations of Panagia were used to infer the stellar radius and effective temperature for a given luminosity. The grain mixture in the dust shell consists of bare graphite and silicate grains with the optical properties of Draine and Lee and the size distribution of Mathis et al. The computer code of Wolfire et al was used to solve the radiative transfer equations through a spherical dust shell. The model provides monochromatic luminosities, dust temperatures, and opacities through the shell. Aside from the stellar and dust properties, the only other input parameters to the model are the distance to the shell, the form of its density distribution, and its outer radius. Predictions of the model are compared with observations of a typical UC H II region and the run of dust temperature with radius and the optical depth with frequency are discussed.

Churchwell, ED↗
NASA NTRS1990

Constraints on astronomical silicate dust

Numerical radiative-transfer models are used to discuss the properties of circumstellar dust grains around the premain-sequence star AB Aur (HD 31293). It is assumed that the dust consists of a silicate-graphite mixture with Draine and Lee (1984) optical properties. The modeling technique is to match the observed FUV through FIR energy distribution with the spectral energy distribution predicted for a spherical dust shell around a luminous hot star. Special attention is given to matching the observed 10-micron silicate emission feature and the observed circumstellar absorption curve at UV wavelengths, making it possible to strengthen constraints on dust-grain opacity and chemical composition. It is concluded that, although silicate grains can explain the observed 10-micron emission feature, the Draine and Lee silicate-graphite mixture cannot explain the observed FUV circumstellar absorption at the same time. The dust shell around AB Aur contains an additional population of small particles, the most likely candidate being amorphous carbon grains in a nonhydrogenated form.

Sorrell, Wilfred H.↗
NASA NTRS1974

Interstellar abundances - Gas and dust

Data on abundances of interstellar atoms, ions and molecules in front of zeta Oph are assembled and analyzed. The gas-phase abundances of at least 11 heavy elements are significantly lower, relative to hydrogen, than in the solar system. The abundance deficiencies of certain elements correlate with the temperatures derived theoretically for particle condensation in stellar atmospheres or nebulae, suggesting that these elements have condensed into dust grains near stars. There is evidence that other elements have accreted onto such grains after their arrival in interstellar space. The extinction spectrum of zeta Oph can be explained qualitatively and, to a degree, quantitatively by dust grains composed of silicates, graphite, silicon carbide, and iron, with mantles composed of complex molecules of H, C, N, and O. This composition is consistent with the observed gas-phase deficiencies.

Field, G. B.↗