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At least 19 records

Data Report: Pore Water Geochemistry at Green Canyon 955, deepwater Gulf of Mexico

Two holes were drilled in Green Canyon Block 955 (GC 955) in the deepwater Gulf of Mexico: Hole GC 955 H002 (H002) and Hole GC 955 H005 (H005). Here we present the solute concentrations and oxygen and hydrogen isotope ratios of pore water extracted from sediment whole-round samples collected from these holes. The analytical methods, degree of sample contamination, and the method for contamination correction are discussed as are the general trends in the geochemical data.

03 NATURAL GAS↗

Data Report: High-Resolution Microscopy Images of Sediments from Green Canyon Block 955, Gulf of Mexico

We took Leica microscopy images of sediment samples acquired at Holes H002 (4 samples) and H005 (1 sample) during the UT-GOM2-1 Expedition in Green Canyon Block 955, in the northern Gulf of Mexico. A total of 37 images were acquired. The images document a prevalence of spherical conchoidal minerals, cleavage planes typical of feldspar or mica, and black fragmented minerals which stand out from the surrounding matrix. Drilling mud intrusion is thought to contribute to a grey metallic matrix observed across multiple samples.

03 NATURAL GAS↗

CO2 Storage Site Analysis, Screening, and Resource Estimation for Cenozoic Offshore Reservoirs in the Central Gulf of Mexico

The storage potential of hydrocarbon reservoirs in the central Gulf of Mexico (GOM) makes future development of CO2 storage projects in those areas promising for secure, large-scale, and long-term storage purposes. Focusing on the producing and depleted hydrocarbon fields in the continental slope of the central GOM, this paper analyzed, assessed, and screened the producing sands and evaluated their CO2 storage potential. A live interactive CO2 storage site screening system was built in the SAS® Viya system with a broad range of screening criteria combined from published studies. This offers the users a real-time assessment of the storage sites and enables them to adjust the filters and visualize the results to determine the most suitable filter range. The CO2 storage resources of the sands were estimated using a volumetric equation and the correlation developed by the National Energy Technology Laboratory (NETL). The results of this study indicate that 1.05 gigatons of CO2 storage resources are available in the developed reservoirs at the upper slope area of the central GOM. The Mississippi Canyon and Green Canyon protraction areas contain the fields with the largest storage resources.

Hu, Xitong↗

Salt Diapir‐Driven Recycling of Gas Hydrate

Abstract By harnessing both hypothetical, synthetic basin and gas hydrate (GH) system models and real‐world models of well‐studied salt diapir‐associated GH sites at Green Canyon (Gulf of Mexico) and Blake Ridge (U.S. Atlantic coast), we propose and demonstrate salt movement (and in particular, diapirism) to be a new mechanism for the recycling of marine GH. At Green Canyon, for example, we show that by considering this newly proposed diapir‐driven recycling mechanism in conjunction with previously proposed lithological control on sandy‐reservoir‐hosted hydrate at the base of the GH stability zone (BGHSZ; ∼bottom‐simulating reflector, BSR), modeled GH saturations match drilling data. Overall, salt diapir movement‐induced GH recycling provides a temperature‐driven mechanism by which GH saturations at the BGHSZ may reach >90 vol. % and by which GH volumes near and free gas volumes beneath the BGHSZ may be increased significantly through time. Interestingly, comparison of salt diapir‐driven recycling and sediment burial‐driven recycling scenarios suggests notably higher rates of recycling via diapir‐driven versus burial‐driven processes. Our results suggest that GH and associated free gas accumulations above salt diapir crests represent particularly attractive targets for unconventional and conventional hydrocarbon resource exploration and for scientific and academic drilling expeditions aimed at exploiting GH systems. Salt basins containing GH systems—including passive margin basins of the Gulf of Mexico, southeastern Brazil, and southwestern Africa—are therefore compelling localities for studying salt‐driven GH recycling and for salt diapir‐associated natural gas exploration.

58 GEOSCIENCES↗

Data Report: UT-GOM2-1 Sediment Grain Size Measurements at Site GC 955, Holes H002 and H005

Sediment grain size measurement in marine sediments provides a record of the stratigraphic variation in grain size and thus energy regime at the time of deposition. In addition to the grain size distribution, the degree of sediment sorting can also be calculated, and together they both influence primary sediment porosity and permeability. Here we present sediment grain size results from laser diffraction particle size analysis of samples from pressure cores collected during the 2017 UT GOM2-1 Expedition. We measured both bulk sediment and organic carbon-free sediment fractions for 46 samples and organic carbon-free sediment for 5 samples at Site GC 955, Holes H002 and H005. Differences between the bulk sediment and organic carbon-free fractions reflect the relative amount and size fraction of the organic carbon. The sample results presented here represent the grain size variation of the host lithology across the Green Canyon (GC) 955 gas hydrate reservoir.

03 NATURAL GAS↗

Data Report: UT-GOM2-1 Lithostratigraphic Core Description Logs at Site GC 955, Holes H002 and H005

Lithostratigraphic core description provides a record of the stratigraphic variation in composition, texture, and sedimentary structure preserved in marine sediment cores. Here we present graphical lithostratigraphic core description logs for pressure cores collected during the 2017 UT GOM2-1 Expedition. The cores summarized here were those that were not retrieved under pressure, but nevertheless recovered some sufficient, intact strata that represent the host lithology across the Green Canyon (GC) 955 gas hydrate reservoir. Our results here represent visual core descriptions and include split core photos and location data for samples collected during core description.

03 NATURAL GAS↗

The Viscoplastic Behavior of Natural Hydrate‐Bearing Sandy‐Silts Under Uniaxial Strain Compression ( K 0 Loading)

Abstract The in‐situ stress state and geomechanical properties of hydrate‐bearing sediments impact hydrate formation and gas production strategies. We explore the uniaxial strain compression and stress evolution of natural hydrate‐bearing sandy‐silts from Green Canyon Block 955 in the deep‐water Gulf of Mexico. We performed constant rate of strain uniaxial strain experiments, interrupted by periods where we held the axial stress constant, to explore the vertical deformation and the evolution of the ratio of lateral to axial effective stress ( K 0 ) with time. The hydrate‐bearing sandy‐silt is stiffer and has a larger K 0 than the equivalent hydrate‐free sediment upon loading. During stress holds, the void ratio decreases sigmoidally with the log of time, and K 0 converges to isotropic conditions. We interpret that during loading, the hydrate bears the load and deforms. With time, the hydrate redistributes the load and K 0 increases. We used a viscoelastic model to describe the behavior. The model accurately captures deformation and K 0 trends but does not reproduce all the complex interactions of the hydrate with the porous skeleton. We anticipate that viscous effects within hydrate sediments will impact reservoir compression and stresses during production (hours to days), result in isotropic stress state over geological timescales, and explain the creeping movement in submarine landslides.

58 GEOSCIENCES↗

Pore-scale observations of natural hydrate-bearing sediments via pressure core sub-coring and micro-CT scanning

Abstract Both intra-pore hydrate morphology and inter-pore hydrate distribution influence the physical properties of hydrate-bearing sediments, yet there has been no pore-scale observations of hydrate habit under pressure in preserved pressure core samples so far. We present for the first time a pore-scale micro-CT study of natural hydrate-bearing cores that were acquired from Green Canyon Block 955 in UT-GOM2-1 Expedition and preserved within hydrate pressure–temperature stability conditions throughout sub-sampling and imaging processes. Measured hydrate saturation in the sub-samples, taken from units expected to have in-situ saturation of 80% or more, ranges from 3 ± 1% to 56 ± 11% as interpreted from micro-CT images. Pore-scale observations of gas hydrate in the sub-samples suggest that hydrate in silty sediments at the Gulf of Mexico is pore-invasive rather than particle displacive, and hydrate particles in these natural water-saturated samples are pore-filling with no evidence of grain-coating. Hydrate can form a connected 3D network and provide mechanical support for the sediments even without cementation. The technical breakthrough to directly visualize particle-level hydrate pore habits in natural sediments reported here sheds light on future investigations of pressure- and temperature-sensitive processes including hydrate-bearing sediments, dissolved gases, and other biochemical processes in the deep-sea environment.

58 GEOSCIENCES↗

UT-GOM2-2 Drilling Fluid (Technical Note)

It is proposed that a salt-saturated, water-based mud might improve borehole stability for UT-GOM2-2 relative to a fresh-water-based mud. However, the primary objective for UT-GOM2-2 is to safely and successfully acquire uncompromised hydrate-bearing sediment cores. This can only be done if conditions stay within the hydrate stability zone, and well away from the hydrate stability boundary. The addition of salt to the drilling mud, shifts the hydrate stability boundary closer to estimated conditions. This shift, by some estimates of pressure and temperature, where conditions now fall outside of the hydrate stability zone, may result in borehole enlargement and the release of free gas into the borehole. This shift by all estimates, even when coring conditions stay inside the hydrate stability zone, shrinks the window between the estimated conditions and the hydrate stability boundary. This shift is likely to compromise the hydrate-bearing cores while they are being recovered from the bottom-hole to the rig floor. In this report we present two examples: 1) Assuming temperature and pressure from in-situ estimates: Hydrate within the target reservoirs (Orange and Blue) at Walker Ridge Block 313 (WR 313) will be outside the hydrate stability zone in the presence of a drilling mud with 9.5 wt.% salinity (the salinity of the proposed 10.5 ppg salt-based mud) at in situ pressure and temperature. Thus, the hydrate will be unstable. A 10.5 ppg salt-based mud may result in dissociation of the hydrate into its components: water and gas. 10.5 ppg salt-based mud may enlarge the borehole, release free gas into the borehole, and compromise the cores. 2) Assuming temperatures equal to the measured LWD borehole temperatures at this location: Hydrate within the target reservoirs will be stable with a salinity of 9.5 wt.% (the salinity of the proposed 10.5 ppg salt-based mud), but possibly unstable (just at the methane hydrate stability boundary) for a salinity of 17.2 wt.% (the salinity of the proposed 13.5 ppg salt-based kill mud). if the borehole has the same temperature as recorded during previous LWD drilling at this location. A 13.5 ppg salt-based kill mud may destabilize the borehole. More importantly, a 10.5 ppg salt-based mud does not provide a large enough window between the estimated conditions and the hydrate stability boundary. Core temperatures and pressures fluctuate from the bottom-hole conditions as the core is brought up from the bottom-hole to the rig floor. These fluctuations are likely to cause the hydrate in the cores to touch or cross the stability boundary. Therefore, cores captured using a 10.5 ppg salt-based mud are likely to be compromised during core recovery to the rig floor.

03 NATURAL GAS↗

The Optical Green Valley Versus Mid-infrared Canyon in Compact Groups

Compact groups of galaxies provide conditions similar to those experienced by galaxies in the earlier universe. Recent work on compact groups has led to the discovery of a dearth of mid-infrared transition galaxies (MIRTGs) in Infrared Array Camera (3.6-8.0 micrometers) color space as well as at intermediate specific star formation rates. However, we find that in compact groups these MIRTGs have already transitioned to the optical ([g−r]) red sequence. We investigate the optical color-magnitude diagram (CMD) of 99 compact groups containing 348 galaxies and compare the optical CMD with mid-infrared (mid-IR) color space for compact group galaxies. Utilizing redshifts available from Sloan Digital Sky Survey, we identified new galaxy members for four groups. By combining optical and mid-IR data, we obtain information on both the dust and the stellar populations in compact group galaxies. We also compare with more isolated galaxies and galaxies in the Coma Cluster, which reveals that, similar to clusters, compact groups are dominated by optically red galaxies. While we find that compact group transition galaxies lie on the optical red sequence, LVL (Local Volume Legacy) + (plus) SINGS (Spitzer Infrared Nearby Galaxies Survey) mid-IR (infrared) transition galaxies span the range of optical colors. The dearth of mid-IR transition galaxies in compact groups may be due to a lack of moderately star-forming low mass galaxies; the relative lack of these galaxies could be due to their relatively small gravitational potential wells. This makes them more susceptible to this dynamic environment, thus causing them to more easily lose gas or be accreted by larger members.

X-rays: binaries↗