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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Groups and the Entropy Floor: XMM-Newton Observations of Two Groups

Using XMM-Newton spatially resolved X-ray imaging spectroscopy we obtain the temperature, density, entropy, gas mass, and total mass profiles for two groups of galaxies out to approximately 0.3 R(sub vir)(R(sub vir), the virial radius). Our density profiles agree well with those derived previously, and the temperature data are broadly consistent with previous results but are considerably more precise. Both of these groups are at the mass scale of 2x10(exp 13) M(solar mass), but have rather different properties. Both have considerably lower gas mass fractions at r < 0.3 R(sub vir), than the rich clusters. NGC2563, one of the least luminous groups for its X-ray temperature, has a very low gas mass fraction of approximately 0.004 inside 0.1 R(sub vir), which increases with radius. NGC4325, one of the most luminous groups at the same average temperature, has a higher gas mass fraction of 0.02. The entropy profiles and the absolute values of the entropy as a function of virial radius also differ, with NGC4325 having a value of approximately 100 keV cm(exp -2) and NGC2563 a value of approximately 300 keV cm(exp -2) at r approximately 0.1 R(sub vir). For both groups the profiles rise monotonically with radius and there is no sign of an entropy 'floor'. These results are inconsistent with pre-heating scenarios that have been developed to explain a possible entropy floor in groups, but are broadly consistent with models of structure formation that include the effects of heating and/or the cooling of the gas. The total entropy in these systems provides a strong constraint on all models of galaxy and group formation, and on the poorly defined feedback process that controls the transformation of gas into stars and thus the formation of structure in the universe.

Mushotzky, R. F.↗

Oxygen Effects and Selective Oxidation of Group IV Alloying Additions in Group V-Based Refractory Multi-principal Element Alloys

Refractory multi-principal element alloys (RMPEAs) hold significant potential for advancing ultra-high-temperature technologies due to their remarkable strength retention under these conditions. However, the beneficial effects of alloying on microstructural evolution and mechanical properties are often obscured by the presence of interstitial alloying elements. The intricate interactions between substitutional alloying elements of Groups IV, V, and VI and interstitial content, whether intentional or incidental, remain poorly understood. In this study, we investigate the impact of dissolved oxygen on the microstructural evolution and stability of RMPEAs primarily composed of Group V elements, Nb and V, along with Group IV elements Ti, Zr, and Hf. We show that the strong affinity of oxygen for Group IV elements Zr and Hf leads to the internal precipitation of oxides during heat treatment, which competes with the homogenization of the as-cast dendritic microstructure. Here, we demonstrate that careful control and design of oxygen content and Group IV alloying additions are essential to minimize micro-segregation and prevent the detrimental precipitation of internal oxides. To address these challenges, we propose employing non-equilibrium solidification calculations to predict and optimize as-cast solidification structures, thereby reducing the reliance on homogenization processes.

Alloy design↗

Programming with process groups: Group and multicast semantics

Process groups are a natural tool for distributed programming and are increasingly important in distributed computing environments. Discussed here is a new architecture that arose from an effort to simplify Isis process group semantics. The findings include a refined notion of how the clients of a group should be treated, what the properties of a multicast primitive should be when systems contain large numbers of overlapping groups, and a new construct called the causality domain. A system based on this architecture is now being implemented in collaboration with the Chorus and Mach projects.

Birman, Kenneth P.↗

Diffuse X-ray emission from the NGC 2300 group of galaxies - Implications for dark matter and galaxy evolution in small groups

The discovery of diffuse X-ray emission from the NGC 2300 group of galaxies using the ROSAT Position Sensitive Proportional Counter is reported. The gas distributions is roughly symmetric and extends to a radius of at least 0.2/h(50) Mpc. A Raymond-Smith hot plasma model provides an excellent fit the X-ray spectrum with a best-fit value temperature of 0.9 + -/15 or - 0.14 keV and abundance 0.06 + 0/.12 or - 0.05 solar. The assumption of gravitational confinement leads to a total mass of the group of 3.0 + 0.4 or - 0.5 x 10 exp 13 solar. Baryons can reasonably account for 4 percent of this mass, and errors could push this number not higher than 10-15 percent. This is one of the strongest pieces of evidence that dark matter dominates small groups such as this one. The intragroup medium in this system has the lowest metal abundance yet found in diffuse gas in a group or cluster.

Mulchaey, John S.↗

Acoustics Technical Working Group and UAM Noise Working Group Proceedings

The NASA Acoustics Technical Working Group Meeting originally started as a program planning meeting in 1992 and has grown through the years. The purpose of these biannual meetings is to foster communication and collaboration among NASA researchers and their university, industry, and government colleagues on activities and work of current and future mutual interest. The NASA-led Urban Air Mobility (UAM) Noise Working Group (UNWG) Meeting began in 2018 as a one-day meeting immediately following the Acoustics Technical Working Group Meeting. The UNWG utilizes four subgroups that conduct regular meetings throughout the year to focus on challenges facing UAM vehicles for community noise and acceptance. The four subgroups coordinate research for development of noise prediction tools/noise reduction technologies, ground and flight test methods, human response and metrics, and regulations and policy (led by the FAA). This work is a compilation of the presentations given at ATWG/UNWG Fall 2022 held in person and via Teams at NASA Glenn Research Center. All NASA content was previously submitted through STRIVES for public presentation. This is merely a compilation. Non-NASA content has permission to distribute. Slide 208 video is included in the Available Downloads as Medial.MOV.

Advanced Air Mobility↗

Reductive Dynamic and Static Excited State Quenching of a Homoleptic Ruthenium Complex Bearing Aldehyde Groups

A new homoleptic Ru polypyridyl complex bearing two aldehyde groups on each bipyridine ligand, [Ru(dab) 3 ](PF 6 ) 2 , where dab is 4,4′-dicarbaldehyde-2,2′-bipyridine, was synthesized, characterized, and utilized for iodide photo-oxidation studies. In acetonitrile (CH 3 CN) solution, the complex displayed an intense metal-to-ligand charge transfer (MLCT) absorbance maximum at 475 nm (ε = 22,000 M –1 cm –1 ) and an infrared (IR) band at 1712 cm –1 assigned to the pendent aldehyde groups. Visible light excitation in air-saturated solution resulted in room temperature photoluminescence (PL) with a maximum at 675 nm, a quantum yield, ϕ PL = 0.048, and an excited state lifetime, τ ο = 440 ns, from which radiative and nonradiative relaxation rate constants were extracted, k r = 9.1 × 10 4 s –1 and knr = 1.8 × 10 6 s –1 . Pulsed visible light excitation yielded transient UV–vis and IR absorption spectra consistent with an MLCT excited state; relaxation occurred with the maintenance of two isosbestic points in the visible region, and a lifetime that agreed with that measured by time-resolved PL. Cyclic voltammetry studies in a CH 3 CN solution with 0.1 M TBAPF 6 electrolyte revealed a quasi-reversible oxidation, E°(Ru III/II ) = +1.25 V vs. Fc +/0 , and three sequential one-electron reductions at −1.10, −1.25, and −1.54 V vs. Fc +/0 . Here, an excited state reduction potential of E°(Ru *2+/+ ) = +0.89 V vs. Fc +/0 was estimated with the Rehm–Weller expression. Titration of tetrabutylammonium iodide, TBAI, into a CD 3 CN solution of [Ru(dab) 3 ](PF 6 ) 2 resulted in significant shifts in the aldehyde H atom and 3,3′-biypridyl resonances that were analyzed with a 1:1 equilibrium model, from which K eq = 460 M –1 was extracted, increasing to 5800 M –1 when the solvent was changed to acetone-d 6 . Iodide titrations resulted in a significant quenching of the [Ru(dab) 3 ] *2+ lifetime and quantum yield in both CH 3 CN and acetone solvents. In CH 3 CN, the quenching was mainly dynamic and well described by the Stern–Volmer model, from which a quenching rate constant, k q , of 4.5 × 10 10 M –1 s –1 and an equilibrium constant, K eq , of 8.3 × 10 3 M –1 were obtained. In acetone, the static quenching pathway by iodide was greatly enhanced, with a K eq of 1.2 × 10 4 M –1 and a higher k q of 9.2 × 10 10 M –1 s –1 .

Aldehydes↗

The utilization of abelian point group symmetry in the graphical unitary group approach to the calculation of correlated electronic wavefunctions

A procedure is described for the utilization of abelian point group symmetry in the graphical unitary group approach (GUGA) to calculations of correlated electronic wavefunctions. The procedure is based on a recursively computed set of symmetry dependent counting indices, and results in the separate numbering, without gaps, of the Gelfand states (configuration functions) belonging to each symmetry species

Shavitt, I.↗

Group structure and group process for effective space station astronaut teams

Space Station crews will encounter new problems, many derived from the social interaction of groups working in space for extended durations. Solutions to these problems must focus on the structure of groups and the interaction of individuals. A model of intervention is proposed to address problems of interpersonal relationships and emotional stress, and improve the morale, cohesiveness, and productivity of astronaut teams.

Nicholas, J. M.↗

Population studies in groups and clusters of galaxies. IV - Comparison of the luminosity functions and morphological-type distributions in seven nearby groups

Published observational data on the Leo, Dorado, NGC 1400, NGC 5044, Antlia, Fornax, and Virgo groups of galaxies are analyzed in terms of the luminosity functions and morphological types of their members. The data sets employed are characterized, and the results are presented in extensive tables and graphs and discussed in detail. While the fractions of early and late galaxies in the groups are similar, the ratio of dwarfs to giants (D/G) in the early galaxies varies monotonically with the richness of the cluster, leading to artificial flattening at the faint end of the total luminosity function in environments with low D/G. The luminosity function for dwarfs in all environments is found to have a slope of about -1.3.

Ferguson, Henry C.↗

Stellar kinematic groups. I - The Ursa Major group

The Ursa Major Group (UMaG) is studied as a test case for the authenticity of Stellar Kinematic Groups, using Coravel radial velocities, recent compilations of astrometric data, and new spectroscopic observations. Spectroscopic age indicators, particularly indices of the strength of chromospheric emission, are applied to solar-type candidate members of UMaG, and it is shown that stars that meet the spectroscopic criteria also have kinematics that agree better with the space motions of the nucleus of UMaG than does the starting sample as a whole. The primary limitation on the precision of kinematics is now parallaxes instead of radial velocities. These more restrictive kinematic criteria are then applied to other UMaG candidates and a list summarizing membership is presented. UMaG is also examined as a cluster, confirming its traditional age of 0.3 Gyr, and a mean Fe/H of -0.08 +/- 0.09 for those stars most likely to be bona fide members.

Soderblom, David R.↗

Advanced Air Mobility(AAM) Ecosystems Working Group Briefing Urban Air Mobility Noise Working Group (UNWG) Subgroup 2: Ground & Flight Testing

Overview of Urban Air Mobility Noise Working Group (UNWG) activities of Subgroup 2, responsible for developing Urban Air Mobility (UAM) vehicle ground and flight testing recommendations for those tasked with evaluating the acoustic characteristics of UAM vehicles under development. This topic is being briefed to an audience at the Advanced Air Mobility (AAM) Ecosystems Working Group Meeting (AEWG).

acoustics↗