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NIST Efforts to Quality-Assure Gunpowder Measurements

In the past few years, the National Institute for Standards and Technology (NIST) has been promoting the idea of quantitatively determining the additives in smokeless gunpowder using micellar capillary electrophoresis as a means of investigating the criminal use of hand guns and pipe bombs. As a part of this effort, we have evaluated both supercritical fluid and ultrasonic solvent extractions for the quantitative recovery of nitroglycerin (NG), diphenylamine (DPA), N-nitrosodiphenylamine (NnDPA), and ethyl centralite (EC) from gunpowder. Recoveries were evaluated by repeat extraction and matrix spiking experiments. The final extraction protocol provides greater than 95 percent recoveries. To help other researches validate their own analytical method for additive determinations, NIST is exploring the development of a standard reference material, Additives in Smokeless Gunpowder. The evaluated method is being applied to two double-base (NG-containing) powders, one stabilized with diphenylamine and the other with ethyl centralite. As part of this reference material development effort, we are conducting an interlaboratory comparison exercise among the forensic and military gunpowder measurement community.

MacCrehan, William A.↗

Development and Testing of Pulse Guns for Combustion Instability Testing

To test liquid rocket engines (LREs) for combustion instabilities, devices such as bombs are often used to create pressure wave disturbances. Bombs, while effective, are inherently dangerous, expensive, and difficult to procure. Over the years, pulse guns have been used as a safer and more cost-effective way to generate controlled pressure disturbances in engine chambers. In anticipation of the need for stability testing of prototype LREs at NASA Marshall Space Flight Center (MSFC), a set of pulse guns have been designed, fabricated, tested, and characterized. The pulse gun program is funded by the RS-25 Engine Program managed out of MSFC and funded by NASA’s Space Launch System (SLS) through the MSFC Liquid Engines Office (LEO). A pulse gun is a simple device – like a traditional gun, it has a breech and barrel section. However, unlike a traditional gun, there is no bullet, as the purpose of the pulse gun is strictly to fire a high pressure pulse. Instead of a firing pin and primer that would normally be used in a traditional gun, an initiator is used to activate the gun powder. The initiator is a highly reliable pyrotechnic initiator. For this study, clone versions of the NASA Standard Initiator (NSI) were used. The initiator is used to ignite a pre-measured amount of gun powder loaded into the breech. When the pressure of the burnt gun powder exceeds the set point of a downstream burst disk, the disk ruptures, allowing the high pressure pulse to travel downstream through the barrel section. A ballistic pressure transducer located in the breech section is used to measure the short duration, high pressure pulse. Some configurations of the pulse gun have barrel sections that include one or more additional ballistic pressure transducers. These additional pressure measurements help track the degradation and damping of the pulse as it travels out of the barrel section. The measurements may also be used to determine the velocity of pulse. The objective of this paper is to present the different variants of this newly-developed pulse gun and characterize performance over a range of parameters. The parameters include breech diameter, barrel length, amount of gun powder used, the way the gun powder is packed, and the pressure setting of the burst disk. There are a total of six pulse guns: three with the 0.25 inch breech and three different length barrels, and three with the 0.40 inch breech and three different length barrels. For both breech sizes, the associated barrels are referred to as standard, one-port, and two-port barrels. The standard barrel has no instrumentation and is likely the barrel that will be used for engine stability testing. The one- and two-port barrels were designed specifically for pulse gun component testing to allow measurements of the magnitude and timing of the high pressure pulse as it makes its way through the pulse gun. The burst disks tested were commercially-available burst disks designed to rupture at 8,000, 16,000, and 24,000 psid. Testing was accomplished by firing the pulse gun into a test chamber pressurized with nitrogen at about 2300 psig. A total of four Model 113B23 High frequency ICP® pressure sensors (10k psi) were mounted in the test chamber, in the same plane as the pulse gun. Two of the sensors had “trimmed” adapters, and two did not. Given the symmetrical configuration of the sensors within the test chamber, different amplitudes of pressure measurements are attributed to the use of trimmed versus untrimmed adapters. The untrimmed adapters, with their narrower passages, tended to amplify the pressure amplitudes by as much as 50%. In total, 41 pulse gun tests have been conducted.Data are still being analyzed, but some trends are apparent. For example, measurements taken within the pulse gun are shown in Figures 3 and 4 for Hot-fires (HFs) # 11 and 39, respectively. Both tests were identical in that the 0.40 inch ID breech, two-port barrel, 8,000 psid burst disk, and same amount of gunpowder (6.639 grains for HF# 11, and 6.576 grains for HF# 39) were used, and the back pressure in the nitrogen test chamber was ~2300 psig. Despite keeping all these variables constant, the results from these two tests look quite different. For both tests, the first pressure peak shown in the P2111 trace within the breech is the firing of the initiator. The second peak and any subsequent peaks are from the combustion of the gunpowder. It should be noted that because the sensors are dynamic, the ~2300 psig baseline static pressure is not shown in the figures. For HF# 11, the burst disk clearly ruptured in a little over 0.1 ms from the time the initiator was fired. This is evident from the abrupt rise in pressure for P2112 followed by another abrupt rise in pressure for P2113. The sensors track the movement of the high pressure pulse through the pulse gun. For HF# 39, however, there was nearly 1 ms delay between the initiator firing and the burst disk rupturing. The only difference between these two tests was the way in which the gunpowder was packed within the breech. For HF# 11, the gunpowder was poured directly into the breech, atop the initiator, and held in place with a vegetable fiber wad appropriately sized for the barrel diameter. Once in place, the wad firmly held the gunpowder in place. For HF# 39, the gunpowder was rolled within cigarette paper with the ends of the paper twisted. The rolled gunpowder was gently pushed down into the breech, toward the initiator, and no wad was used. This method of loading the gunpowder consistently produced longer delays in the rupture of the burst disk, presumably because there was a steady, fuller burning of the gunpowder. The burst disk was rated for 8,000 psid, which means that the burst disk should not have opened until the pressure in the breech reached ~10,300 since there was ~2300 psig back pressure in the test chamber. In the case of HF# 11, the breech pressure only reached roughly 4200 psi before there was leakage either through or past the burst disk, but for HF#39, the breech pressure reached 10,600 psi prior to the burst disk opening. The temperature of the burst disk is certainly a factor in determining when the burst disk will rupture. A sharp rise in the burst disk temperature could weaken it and cause it to stray from the designed set point burst pressure. The burst disks are manufactured of Inconel to try to reduce their sensitivity to temperature, but how the burst disks perform above 900°F is not documented. All burst disks were engineered and tested by the manufacturer for ambient temperature conditions. One theory for why rolling the gunpowder in cigarette paper may produce better results is related to a more controlled temperature environment. The cigarette paper may act as a sheath that protects the burst disk from excessive temperatures during the rapid buildup of pressure in the breech. The ultimate benefit of not breeching the burst disk prematurely is shown in Figures 5 and 6, which graphs the resultant pressure pulse produced in the test chamber. For HF #11, the peak pressure on the P2123 trimmed adapter is about 270 psi, while for HF# 39 it is 343 psi, which is about 1.27 times greater in magnitude. In either case, the pressure pulse is ~20 μs in width once it reaches the test chamber. Another pressure rise about 100 μs later can be seen on the sensors located across from the pulse gun port, P2124 and P2121. These pressures are lower due to attenuation of the pressure wave as it moves across the test chamber. After the wave encounters the wall, it reflects back and forth within the chamber until it completely dissipates.

Pulse Gun↗

Development and Testing of Pulse Guns for Combustion Instability Testing

Combustion stability requirements of a liquid propellant rocket engine are most commonly verified by evaluating the oscillatory pressure or vibration characteristics following an artificial disturbance of the combustion in the combustion chamber. Two types of devices are most commonly used for dynamic stability rating – nondirectional bombs and pulse guns. Bombs have historically been used most often, especially for the large engines developed around the Apollo era. However, bombs in recent years have become much more expensive and difficult to procure, and their transportation and handling requirements have become more demanding. Pulse guns, with inherently less expensive materials, and far less restrictive handling and shipping requirements, have become an attractive alternative. The NASA Marshall Space Flight Center has developed a pulse gun for use during future development programs at the center, and as a design reference for interested commercial users. The objective of this paper is to present the different variants of the pulse gun and characterize performance over a range of parameters. The parameters include the breech diameter and corresponding volume, barrel length, amount of gun powder used, the method of containing the gunpowder within the breech, and the pressure rating of the burst disk. In total, 44 tests were conducted with the pulse gun firing into a test chamber pressurized to 2300 psig with gaseous nitrogen. The best experimental results – including the highest and most consistent peak pressure amplitudes recorded by dynamic pressure sensors in the test chamber – were from a configuration consisting of a 0.40” inner-diameter breech, 15-16 grains of gunpowder wrapped in cigarette paper, and a 24,000 psid burst disk. With this configuration, the zero-to-peak overpressures recorded in the test chamber ranged from about 37% to 58% of the 2300 psig mean pressure, which is adequate for typical combustion stability rating. To complement the data analysis, the acoustics of the pressure waves as they propagated through the pulse gun and into the test chamber were modeled. A more comprehensive final report of this pulse gun development program is planned to be available in the near future.

Pulse Gun↗

New higher-order Godunov code for modelling performance of two-stage light gas guns

A new quasi-one-dimensional Godunov code for modeling two-stage light gas guns is described. The code is third-order accurate in space and second-order accurate in time. A very accurate Riemann solver is used. Friction and heat transfer to the tube wall for gases and dense media are modeled and a simple nonequilibrium turbulence model is used for gas flows. The code also models gunpowder burn in the first-stage breech. Realistic equations of state (EOS) are used for all media. The code was validated against exact solutions of Riemann's shock-tube problem, impact of dense media slabs at velocities up to 20 km/sec, flow through a supersonic convergent-divergent nozzle and burning of gunpowder in a closed bomb. Excellent validation results were obtained. The code was then used to predict the performance of two light gas guns (1.5 in. and 0.28 in.) in service at the Ames Research Center. The code predictions were compared with measured pressure histories in the powder chamber and pump tube and with measured piston and projectile velocities. Very good agreement between computational fluid dynamics (CFD) predictions and measurements was obtained. Actual powder-burn rates in the gun were found to be considerably higher (60-90 percent) than predicted by the manufacturer and the behavior of the piston upon yielding appears to differ greatly from that suggested by low-strain rate tests.

Bogdanoff, D. W.↗

Historical review of missile aerodynamic developments

The development of missiles from early history up to about 1970 is discussed. Early unpowered missiles beyond the rock include the spear, the bow and arrow, the gun and bullet, and the cannon and projectile. Combining gunpowder with projectiles resulted in the first powered missiles. In the early 1900's, the development of guided missiles was begun. Significant advances in missile technology were made by German scientists during World War II. The dispersion of these advances to other countries following the war resulted in accelerating the development of guided missiles. In the late 1940's and early 1950's there was a proliferation in the development of missile systems in many countries. These developments were based primarily on experimental work and on relatively crude analytical techniques. Discussed here are some of the missile systems that were developed up to about 1970; some of the problems encountered; the development of an experimental data base for use with missiles; and early efforts to develop analytical methods applicable to missiles.

Spearman, M. Leroy↗

Crime scene investigations using portable, non-destructive space exploration technology

The National Institute of Justice (NIJ) and the National Aeronautics and Space Administration's (NASAs) Goddard Space Flight Center (GSFC) have teamed up to explore the use of NASA developed technologies to help criminal justice agencies and professionals solve crimes. The objective of the program is to produce instruments and communication networks that have application within both NASA's space program and NIJ programs with state and local forensic laboratories. A working group of NASA scientists and law enforcement professionals has been established to develop and implement a feasibility demonstration program. Specifically, the group has focused its efforts on identifying gunpowder and primer residue, blood, and semen at crime scenes. Non-destructive elemental composition identification methods are carried out using portable X-ray fluorescence (XRF) systems. These systems are similar to those being developed for planetary exploration programs. A breadboard model of a portable XRF system has been constructed for these tests using room temperature silicon and cadmium-zinc telluride (CZT) detectors. Preliminary tests have been completed with gunshot residue (GSR), blood-spatter and semen samples. Many of the element composition lines have been identified. Studies to determine the minimum detectable limits needed for the analyses of GSR, blood and semen in the crime scene environment have been initiated and preliminary results obtained. Furthermore, a database made up of the inorganic composition of GSR is being developed. Using data obtained from the open literature of the elemental composition of barium (Ba) and antimony (Sb) in handswipes of GSR, we believe that there may be a unique GSR signature based on the Sb to Ba ratio.

Firearms↗

Upgrades and Modifications of the NASA Ames HFFAF Ballistic Range

The NASA Ames Hypervelocity Free Flight Aerodynamics Facility ballistic range is described. The various configurations of the shadowgraph stations are presented. This includes the original stations with film and configurations with two different types of digital cameras. Resolution tests for the 3 shadowgraph station configurations are described. The advantages of the digital cameras are discussed, including the immediate availability of the shadowgraphs. The final shadowgraph station configuration is a mix of 26 Nikon cameras and 6 PI-MAX2 cameras. Two types of trigger light sheet stations are described visible and IR. The two gunpowders used for the NASA Ames 6.251.50 light gas guns are presented. These are the Hercules HC-33-FS powder (no longer available) and the St. Marks Powder WC 886 powder. The results from eight proof shots for the two powders are presented. Both muzzle velocities and piston velocities are 5 9 lower for the new St. Marks WC 886 powder than for the old Hercules HC-33-FS powder (no longer available). The experimental and CFD (computational) piston and muzzle velocities are in good agreement. Shadowgraph-reading software that employs template-matching pattern recognition to locate the ballistic-range model is described. Templates are generated from a 3D solid model of the ballistic-range model. The accuracy of the approach is assessed using a set of computer-generated test images.

Ballistic Range↗

Upgrades and Modifications of the NASA Ames HFFAF Ballistic Range

The NASA Ames Hypervelocity Free Flight Aerodynamics Facility ballistic range is described. The various configurations of the shadowgraph stations are presented. This includes the original stations with film and configurations with two different types of digital cameras. Resolution tests for the 3 shadowgraph station configurations are described. The advantages of the digital cameras are discussed, including the immediate availability of the shadowgraphs. The final shadowgraph station configuration is a mix of 26 Nikon cameras and 6 PI-MAX2 cameras. Two types of trigger light sheet stations are described visible and IR. The two gunpowders used for the NASA Ames 6.251.50 light gas guns are presented. These are the Hercules HC-33-FS powder (no longer available) and the St. Marks Powder WC 886 powder. The results from eight proof shots for the two powders are presented. Both muzzle velocities and piston velocities are 5 9 lower for the new St. Marks WC 886 powder than for the old Hercules HC-33-FS powder (no longer available). The experimental and CFD (computational) piston and muzzle velocities are in good agreement. Shadowgraph-reading software that employs template-matching pattern recognition to locate the ballistic-range model is described. Templates are generated from a 3D solid model of the ballistic-range model. The accuracy of the approach is assessed using a set of computer-generated test images.

Ballistic Range↗