Materials Data on HCS(OF)3 by Materials Project
CF3SO3H crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four fluoroform molecules and four sulfurous acid molecules.
36 MATERIALS SCIENCE↗
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Ulysses Data Analysis: Magnetic Topology of Heliospheric Structures
In this final technical report on research funded by a NASA grant, a project overview is given by way of summaries on nine published papers. Research has included: 1) Using suprathermal electron data to study heliospheric magnetic structures; 2) Analysis of magnetic clouds, coronal mass ejections (CME), and the heliospheric current sheet (HCS); 3) Analysis of the corotating interaction region (CIR) which develop from interactions between solar wind streams of different velocities; 4) Use of Ulysses data in the interpretation of heliospheric events and phenomena.
Crooker, Nancy↗
The interactivity of sources and dietary levels of resistant starches – impact on growth performance, starch, and nutrient digestibility, digesta oligosaccharides profile, cecal microbial metabolites, and indicators of gut health in broiler chickens
In a 21-d study, 480 Cobb 500 (off-sex) male broiler chicks were used to investigate the effects of feeding different sources and levels of resistant starches (RS) on growth performance, nutrient and energy utilization, and intestinal health in broiler chickens. The birds were allocated to 10 dietary treatments in a 3 × 3 + 1 factorial arrangement. The factors were 3 RS-sources (RSS): banana starch (BS), raw potato starch (RPS), and high-amylose corn starch (HCS); each at 3 levels (RSL) 25, 50, or 100 g/kg plus a corn-soybean meal control diet. Birds and feed were weighed on d 0, 8, and 21. On d 21, samples of jejunal tissue and digesta were collected for chemical analysis. Data were analyzed using the mixed model procedure of JMP with factor levels nested with the control. In the 0 to 21 phase, the birds fed the RPS diets had higher (P = 0.011) FI than those fed HCS or control diets, and FCR was greater (P = 0.030) in birds that received BS diets than in other diets. RSS × RSL was significant (P < 0.05) for total tract nutrient retention, AME, and AMEn on d 21. The starch digestibility was higher (P < 0.001) in birds that received the control diet than in RS diets, and decreased as RS levels increased, except for HCS. The apparent metabolizable energy (AME) and nitrogen-corrected AME (AMEn) were higher (P < 0.001) in birds fed 100 g/kg HCS diet, with both decreasing with increasing levels of BS and RPS, except for HCS. Relative ileal oligosaccharides profile showed significant (P < 0.05) RSS × RSL with a higher relative abundance of Hex(3) (P = 0.01) and Pent(3) (P = 0.001) in HCS diets. In conclusion, RS may influence gut health and growth performance in broiler chickens through modulation of cecal SCFA and nutrient digestion, but these depend largely on the botanical origin and concentrations of individual RS.
60 APPLIED LIFE SCIENCES↗
Hydrothermally stable Pd/SiO 2 @Zr Core@Shell catalysts for diesel oxidation applications
Hydrothermally stable diesel oxidation catalysts (DOCs) with improved low-temperature activity are desired for the abatement of emissions from diesel vehicles. Herein, novel palladium(Pd)/SiO 2 (core)@Zr(shell) structured DOCs were developed. SiO 2 was completely covered by an 8.4 nm thickness Zr-based shell using a hard template method. The SiO 2 @Zr support was decorated by Pd and evaluated under a simulated diesel exhaust stream. Degreened 1 wt% Pd/SiO 2 @Zr achieved 90% CO and total hydrocarbon conversion at 178 and 372 °C, respectively (feed: 6% CO 2 , 12% O 2 , 6% H 2 O, 400 ppm H 2 , 2000 ppm CO, 100 ppm NO, 1667 ppm C 2 H 4 , 1000 ppm C 3 H 6 , 333 ppm C 3 H 8 ; HCs in C 1 basis and GHSV = 113,000 h –1 ). After hydrothermal aging, only a minor deactivation was observed, while the surface area of 1 wt% Pd/SiO 2 @Zr was as high as 104 m 2 /g. The hydrothermal stability of 1 wt% Pd/SiO 2 @Zr was attributed to the poor crystallinity of SiO 2 @Zr, possibly due to the formation of Si-O-Zr bonds. Lastly, this work highlights the promising potential of utilizing durable Pd/SiO 2 @Zr catalysts for diesel oxidation applications.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
STEREO Observations of Stream Interaction Regions in 2007-2016:Relationship with Heliospheric Current Sheets, Solar Cycle Variations, and Dual Observations
We have conducted a survey of 575 slow-to-fast stream interaction regions (SIRs) using STEREOA/B data in 2007-2016 (Jian et al., 2019). Among 518 well-defined SIRs, 54% are associated with heliospheric current sheet (HCS) crossings, and 34% are without any HCS crossing. The other 12% of the SIRs often occur in association with magnetic sectors shorter than 3 days. The SIRs with HCS crossings have slightly slower speeds but higher maximum number densities, magnetic field strengths, dynamic pressures, and total pressures than the SIRs without an HCS. The iron charge state is higher throughout the SIRs with an HCS than the SIRs without an HCS, by about 1/3 charge unit. In contrast with the comparable phases of solar cycle 23,slightly more SIRs and higher recurrence rates are observed in the years 2009-2016 of cycle 24,with a lower HCS association rate, possibly attributed to persistent equatorial coronal holes and more pseudostreamers in this recent cycle. The solar wind speed, peak magnetic field and pressures of SIRs are all lower in this cycle, but the weakening is less than for the comparable background solar wind parameters. Before STEREO B lost contact in 2014 October, 151 SIR pairs were observed by the twin spacecraft. Of the dual observations, the maximum speed is the best correlated of the plasma parameters. We have obtained a sample of plasma parameter differences analogous to those that would be observed for a mission at Lagrange point 4 or 5.By studying several cases with large discrepancies between the dual observations, we have also investigated the effects of HCS relative location, tilt of stream interface, and small transients on the SIR properties.
Lan K Jian↗
Components Refurbishment and Chemical Analysis Facility, Hot Spot 1 SWMU #041 Year 3 Annual Performance Monitoring Report Kennedy Space Center, Florida
This Year 3 Annual Performance Monitoring Report (PMR) presents the operations, maintenance, and monitoring activities for the Hydraulic Containment System (HCS) Interim Measure (IM) at the Components Refurbishment and Chemical Analysis (CRCA) facility located at John F. Kennedy Space Center (KSC), Florida. The primary objective of the HCS is to attain hydraulic control of the dissolved-phase chlorinated volatile organic compound (CVOC) plume, with the secondary objective to reduce concentrations of CVOCs in the high-concentration plume to support transition to monitored natural attenuation (MNA). CRCA has been designated Solid Waste Management Unit 041 under the KSC Resource Conservation and Recovery Act Corrective Action Program. The timeframe for activities documented in this Year 3 PMR extends from September 2021 through October 2022. Baseline sampling activities were completed in June 2019, and full-scale startup of the HCS IM was completed in July-August 2019. The operational runtime of the HCS for the Year 3 reporting period was approximately 91%, with the majority of downtime attributed to system maintenance and repair. This is generally consistent with Year 1 and Year 2 runtimes of 85% and 92%, respectively. To help reduce downtime, an anti-scaling amendment, Redux 390, has been used to reduce scaling and help maintain system design parameters. Over nine million gallons of groundwater were treated during Year 3 of HCS operations, and concentrations of the site’s contaminants of concern (trans-1,2-dichloroethene and vinyl chloride) have been reduced by over 97%. This PMR describes the activities that were performed during Year 3 to operate and monitor the HCS IM, which includes three extraction wells, seven injection wells, and conveyance piping to a modular structure containing the control panel and an air stripper. Influent and effluent sampling results from the air stripper show that the system is operating as designed and is reducing concentrations of contaminants of concern to below detection limits. In addition to HCS operation, this PMR also discusses performance monitoring that has been implemented to assess progress of the HCS IM and overall plume conditions through scheduled groundwater (quarterly and semi-annual) and sub-slab soil gas (quarterly) sampling and analysis. Two ambient air samples were also collected on a quarterly basis in the vicinity of the modular structure and the paved driveway east of the Solvent Reclamation Area during routine operation and maintenance (O&M) activities to ensure safe breathing zone air quality for on-site personnel. All sub-slab soil gas and ambient air sampling conducted during the Year 3 operational period showed results below applicable regulatory air screening limits. Predictions made during the Year 2 groundwater model updates were in close correlation to post Year 3 plume conditions. Therefore, it can be assumed that the projected path remains valid for transition to MNA in one to two years of continuous HCS operation. The contents of this Year 3 PMR were presented during the February 2023 KSC Remediation Team meeting, where Team consensus was reached on several items including continued O&M of the HCS, and continued monitoring of groundwater, ambient air, and sub-slab soil gas. Replacement of MW0019 and VMP04 was also recommended, as well as additional direct-push technology sampling to further delineate the downgradient plume and confirm overall site-wide low-concentration plume boundaries. Sampling for per- and polyfluoroalkyl substances at CRCA is ongoing and will be submitted under separate cover.
K. Alex Murphy↗
The Bastille Day Magnetic Clouds and Upstream Shocks: Near Earth Interplanetary Observations
The energetic charged particle, interplanetary magnetic field, and plasma characteristics of the 'Bastille Day' shock and ejecta/magnetic cloud events at 1 AU occurring over the days 14-16 July 2000 are described. Profiles of MeV (WIND/LEMT) energetic ions help to organize the overall sequence of events from the solar source to 1 AU. Stressed are analyses of an outstanding magnetic cloud (MC2) starting late on 15 July and its upstream shock about 4 hours earlier in WIND magnetic field and plasma data. Also analyzed is a less certain, but likely, magnetic cloud (MC1) occurring early on 15 July; this was separated from MC2 by its upstream shock and many heliospheric current sheet (HCS) crossings. Other HCS crossings occurred throughout the 3-day period. Overall this dramatic series of interplanetary events caused a large multi-phase magnetic storm with min Dst lower than -300 nT. The very fast solar wind speed (greater than or equal to 1100 km/s) in and around the front of MC2 (for near average densities) was responsible for a very high solar wind ram pressure driving in the front of the magnetosphere to geocentric distances estimated to be as low as approx. 5 R(sub E), much lower than the geosynchronous orbit radius. This was consistent with magnetic field observations from two GOES satellites which indicated they were in the magnetosheath for extended times. A static force free field model is used to fit the two magnetic cloud profiles providing estimates of the clouds' physical and geometrical properties. MC2 was much larger than MCI, but their axes were nearly antiparallel, and their magnetic fields had the same left-handed helicity. MC2's axis and its upstream shock normal were very close to being perpendicular to each other, as might be expected if the cloud were driving the shock at the time of observation. The estimated axial magnetic flux carried by MC2 was 52 x 10(exp 20) Mx, which is about 5 times the typical magnetic flux estimated for other magnetic clouds in the WIND data over its first 4 years and is 17 times the flux of MC1. This large flux is due to both the strong axially-directed field of MC2 (46.8 nT on the axis) and the large radius (R(sub 0) = 0.189 AU) of the flux tube. MC2's average speed is consistent with the expected transit time from a halo-CME to which it is apparently related.
Lepping, R. P.↗
Editors’ Choice—Review—Recent Advances in Mixed Potential Sensors
Gas sensors are widely used in environmental monitoring and provide controls especially when working with toxic gases. YSZ based λ-sensors have been utilized in the automobile industry for exhaust gas monitoring for more than 40 years. However, recent regulations on emissions reduction has forced further development of toxic gases monitoring in various applications. Mixed potential sensors with YSZ electrolyte are receiving increased attention due to their higher sensitivity and durability under harsh conditions. This review focuses on recent (past 5 years) developments made on electrode and electrolyte structure along with new sensing electrode materials towards detecting gases such as NO x , NH 3 , H 2 , CO and hydrocarbons (HCs). The theory of mixed potential sensors is discussed along with recent developments in detection of multi-gas mixtures using the output from an array of sensors in a mathematical model. Future directions for mixed potential sensor research, and methodologies to improving sensing characteristics are also outlined
47 OTHER INSTRUMENTATION↗
Global, quasi-steady dynamics of the distant solar wind 2: Deformation of the heliospheric current sheet
A three-dimensional (3-D) magnetohydrodynamic (MHD) numerical model is used to trace global deformations of the heliospheric current sheet (HCS) caused by large-scale dynamical interactions associated with corotating solar wind flows. Configurations incorporating the tilted-dipole geometry are investigated out past 30 AU for a variety of dipole tilt angles, alpha. Inclusion of the full, 3-D interplanetary dynamics allows north-south displacements and the east-west warping of the HCS by advective corotational effects to be accurately assessed for the first time. It is found that large-scale spatial correlations between velocity and density imposed at the coronal source (i.e., the geometric arrangement whereby regions of high-speed low-density material lying adjacent to areas of slow, dense flow interact obliquely under the influence of solar rotation) result in a distinctive pattern of deformation of the HCS. For an alpha = 30 deg tilted-dipole example, it is shown that typical zonal variations in radial velocity lead to significant folding of the HCS within about 5 AU of the Sun. By 10 AU, additional sharp bends appear near the latitudinal extremes of the HCS surface, where it is overtaken by shock fronts driven by 3-D corotating interaction regions (CIRs). Moreover, the model suggests that inside about 20 AU, major plasma structures are systematically organized, about the HCS, such that the greatest concentrations of material and magnetic field (the centroids of the 3-D CIR structures) are coincident with the folded crests of the HCS (near heliographic latitudes lambda = +/- alpha). Thus, in these circumstances many of the more interesting dynamical features inconveniently lie well away from the heliographic equator. At larger heliocentric distances, where neighboring CIRs begin to interact strongly, the warping of the HCS abates dramatically and the association between folds in the HCS and major field and density concentrations is weakened and ultimately breaks down. On the basis of the model calculations, quasi-steady deformations and related phenomena should figure prominently in the interplanetary medium, except during those periods when the magnetic dipole and solar spin axes are nearly aligned (alpha is approximately less than 10 deg). Even then, they may be of significance if there are any substantial local warps or kinks in the streamer belt.
Pizzo, V. J.↗
Multiple Subscale Magnetic Reconnection Embedded inside a Heliospheric Current Sheet Reconnection Exhaust: Evidence for Flux Rope Merging
We report observations of multiple subscale reconnecting current sheets embedded inside a large-scale heliospheric current sheet (HCS) reconnection exhaust. The discovery was made possible by the unusual skimming trajectory of Parker Solar Probe through a sunward-directed HCS exhaust, sampling structures convecting with the exhaust outflows for more than 3 hr during Encounter 14, at a radial distance of ∼17 solar radii. A large number of subscale current sheets (SCSs) were detected inside the HCS exhaust. Remarkably, five SCSs showed direct evidence for reconnection, displaying near-Alfvénic outflow jets and bifurcated current sheets. The reconnecting SCSs all had small magnetic shears (27°–81°), i.e., strong guide fields. The thickness of the subscale reconnecting current sheets ranged from ∼60 km to ∼5000 km (∼20–2000 ion inertial lengths). The SCS exhausts were directed predominantly in the normal or out-of-plane direction of the HCS, i.e., nearly orthogonal to the HCS exhaust direction. The presence of multiple low-magnetic-shear reconnecting current sheets inside a large-scale exhaust could be associated with coalescence of multiple large flux ropes inside the HCS exhaust. The orientation of some SCS exhausts was partly in the ecliptic plane of the HCS, which may indicate that the coalescence process is highly three-dimensional. Since the coalescence process is likely short-lived, the detection of five such events inside a single HCS crossing could imply the common occurrence of flux rope coalescence in large-scale HCS reconnection exhausts.
T D Phan↗
Opposed Jet Burner Approach for Characterizing Flameholding Potentials of Hydrocarbon Scramjet Fuels
Opposed Jet Burner (OJB) tools have been used extensively by the authors to measure Flame Strength (FS) extinction limits of laminar H2/N2 air and (recently) hydrocarbon (HC) air Counterflow Diffusion Flames (CFDFs) at one atm. This paper details normalization of FSs of N2- diluted H2 and HC systems to account for effects of fuel composition, temperature, pressure, jet diameter, inflow Reynolds number, and inflow velocity profile (plug, contoured nozzle; and parabolic, straight tube). Normalized results exemplify a sensitive accurate means of validating, globally, reduced chemical kinetic models at approx. 1 atm and the relatively low temperatures approximating the loss of non-premixed idealized flameholding, e.g., in scramjet combustors. Laminar FS is defined locally as maximum air input velocity, U(sub air), that sustains combustion of a counter-jet of g-fuel at extinction. It uniquely characterizes a fuel. And global axial strain rate at extinction (U(sub air) normalized by nozzle or tube diameter, D(sub n or (sub t)) can be compared directly with computed extinction limits, determined using either a 1-D Navier Stokes stream-function solution, using detailed transport and finite rate chemistry, or (better yet) a detailed 2-D Navier Stokes numerical simulation. The experimental results define an idealized flameholding reactivity scale that shows wide ranging (50 x) normalized FS s for various vaporized-liquid and gaseous HCs, including, in ascending order: JP-10, methane, JP-7, n-heptane, n-butane, propane, ethane, and ethylene. Results from H2 air produce a unique and exceptionally strong flame that agree within approx. 1% of a recent 2-D numerically simulated FS for a 3 mm tube-OJB. Thus we suggest that experimental FS s and/or FS ratios, for various neat and blended HCs w/ and w/o additives, offer accurate global tests of chemical kinetic models at the Ts and Ps of extinction. In conclusion, we argue the FS approach is more direct and fundamental, for assessing, e.g., idealized scramjet flameholding potentials, than measurements of laminar burning velocity or blowout in a Perfectly Stirred Reactor, because the latter characterize premixed combustion in the absence of aerodynamic strain. And FS directly measures a chemical kinetic characteristic of non-premixed combustion at typical flameholding temperatures. It mimics conditions where gfuels are typically injected into a subsonic flameholding recirculation zone that captures air, where the effects of aerodynamic strain and associated multi-component diffusion become important.
Pellett, Gerald L.↗
Preliminary Results of Observations of Comets De Vico and Hyakutake by the Ulysses Comet Watch Network
Cometary interactions with the solar wind allow us to use comets as probes of the inner regions of the heliosphere. During their close passage to the Sun, comets are exposed to different environments depending on their latitude. Until recently, characterizing these environments has been difficult because most spacecraft studying the sun have been confined to studying its mid-latitudes. A valuable source of information about the differing regimes of the solar wind is the joint ESA/NASA ULYSSES mission, which is the first spacecraft to explore the polar regions of the heliosphere. In 1995, ULYSSES' orbit covered a range of solar latitudes from -80 degrees to +80 degrees - an interval referred to as the 'fast latitude scan.' The Ulysses Comet Watch incorporates in-situ measurements during these periods by the ULYSSES spacecraft with images contributed by a world-wide network of observers (both amateur and professional). Bright comets whose paths come within 20 degrees solar latitude of the spacecraft are considered especially good targets for correlation between spacecraft data and plasma tail activity. Ulysses findings of interest to cometary plasma research are: Verification of global differences in solar wind properties (speed and density) at different solar latitudes. At polar latitudes - ranging from roughly +/-30 degrees to +/-80 degrees - the solar wind speed is about 750 kilometers/sec, and has a proton density (1 AU) around 3 cm(exp -3). Changes in properties are small and the heliospheric current sheet (HCS) is not seen. In the equatorial latitudes (roughly +30 to -30 degrees), the average solar wind speed is about 450 kilometers/sec, with an average proton density (at 1 AU) around 9 cm(exp -3). The HCS is seen and changes in properties can be large. An object, spacecraft or comet, at a given latitude, can be entirely in the polar, entirely in the equatorial, or can experience both - sort of a transition region.
Petersen, C. C.↗
Design and Optimization of Structured Multi-Functional Trapping Catalysts for Conversion of Hydrocarbons and NOx from Diesel and Advanced Combustion Engines
Oxides of nitrogen in the form of nitric oxide (NO) and nitrogen dioxide (NO 2 ) commonly referred to as NOx, is one of the two chemical precursors that lead to ground-level ozone, a ubiquitous air pollutant in urban areas. A major source of NOx is generated by equipment and vehicles powered by diesel engines, which have a combustion exhaust that contains NOx in the presence of excess O 2 . Vehicular emission control catalysts are ineffective in eliminating CO, hydrocarbons, and NOx during engine cold-start when exhaust temperatures are below 200°C. The objective of the project was to develop and demonstrate a multi-functional, catalyzed trap that enables vehicles with advanced combustion strategies to meet Tier 3 emissions standards while achieving the 150 °C challenge for sustained co-oxidation of HCs and CO and ≥90% NO trapping and release during warmup. Specifically, the multi-functional Lean HC+NOx (LHCNT) was developed for application in the exhaust aftertreatment of conventional diesel engines and engines having low temperature combustion (LTC) regimes. Activities included the design and synthesis of adsorbents and catalysts, screening and evaluation. Passive NOx absorbers (PNA), hydrocarbon (HC) traps, and oxidation catalysts (OC) were evaluated for use in series or as integrated devices. Predictive tools were developed utilizing the characterization and analysis of these materials, and an emission system was designed and optimized utilizing the catalyst systems. Microkinetic models were developed for the PNA for the simple NO-only feed and complex feed containing CO, H 2 , and model hydrocarbons (ethylene and dodecane). A first-principles, mechanistic-based model of the PNA was developed which utilized molecular-scale estimates (density functional theory) of energy barriers, mechanistic-based kinetics and realistic treatments of the flow and transport processes. Two new oxidation catalysts were developed (PdCu alloy, mixed copper-ceria-cobalt oxide), both of which significantly lessened the detrimental inhibition by CO on hydrocarbon and NO oxidation. A method for lessening the detrimental impact of CO on PNA activity was developed that involves use of an oxidation catalyst upstream of the PNA. The SwRI Ectolab TM burner system was applied to evaluate the baseline PNA material and confirmed performance comparable to the benchflow PNA studies using simulated exhaust. Spatially-resolved mass spectrometry (SpaciMS) was used to measure the transient spatial profiles of reacting species spanning the length of a three-function LHCNT containing PNA, HCT, and OC. The findings from this study provide diesel vehicle and catalyst companies valuable information to develop more cost effective emission control catalysts which helps to expand the use of more fuel efficient diesel power. The fundamental modeling and experimental tools and findings from this project can be applied to catalyst technologies used in the energy and chemical industries. The project led to 14 publications in the peer-reviewed literature with 2 additional currently under review. Finally, the project also led to training of several doctoral students who were placed in research jobs in industry and academia. Specifically, Mugdha Ambast (UH) has joined Cummins, Kevin Gu (UVa) has joined GM, and Abhay Gupta (UH) is to join Caterpillar.
02 PETROLEUM↗
Design and Optimization of Structured Multi-Functional Trapping Catalysts for Conversion of Hydrocarbons and NOx from Diesel and Advanced Combustion Engines
Oxides of nitrogen in the form of nitric oxide (NO) and nitrogen dioxide (NO 2 ) commonly referred to as NOx, is one of the two chemical precursors that lead to ground-level ozone, a ubiquitous air pollutant in urban areas. A major source of NOx is generated by equipment and vehicles powered by diesel engines, which have a combustion exhaust that contains NOx in the presence of excess O 2 . Vehicular emission control catalysts are ineffective in eliminating CO, hydrocarbons, and NO x during engine cold-start when exhaust temperatures are below 200°C. The objective of the project was to develop and demonstrate a multi-functional, catalyzed trap that enables vehicles with advanced combustion strategies to meet Tier 3 emissions standards while achieving the 150 °C challenge for sustained co-oxidation of HCs and CO and ≥90% NO trapping and release during warmup. Specifically, the multi-functional Lean HC+NOx (LHCNT) was developed for application in the exhaust aftertreatment of conventional diesel engines and engines having low temperature combustion (LTC) regimes. Activities included the design and synthesis of adsorbents and catalysts, screening and evaluation. Passive NOx absorbers (PNA), hydrocarbon (HC) traps, and oxidation catalysts (OC) were evaluated for use in series or as integrated devices. Predictive tools were developed utilizing the characterization and analysis of these materials, and an emission system was designed and optimized utilizing the catalyst systems. Microkinetic models were developed for the PNA for the simple NO-only feed and complex feed containing CO, H 2 , and model hydrocarbons (ethylene and dodecane). A first-principles, mechanistic-based model of the PNA was developed which utilized molecular-scale estimates (density functional theory) of energy barriers, mechanistic-based kinetics and realistic treatments of the flow and transport processes. Two new oxidation catalysts were developed (PdCu alloy, mixed copper-ceria-cobalt oxide), both of which significantly lessened the detrimental inhibition by CO on hydrocarbon and NO oxidation. A method for lessening the detrimental impact of CO on PNA activity was developed that involves use of an oxidation catalyst upstream of the PNA. The SwRI Ectolab TM burner system was applied to evaluate the baseline PNA material and confirmed performance comparable to the benchflow PNA studies using simulated exhaust. Spatially-resolved mass spectrometry (SpaciMS) was used to measure the transient spatial profiles of reacting species spanning the length of a three-function LHCNT containing PNA, HCT, and OC. The findings from this study provide diesel vehicle and catalyst companies valuable information to develop more cost effective emission control catalysts which helps to expand the use of more fuel efficient diesel power. The fundamental modeling and experimental tools and findings from this project can be applied to catalyst technologies used in the energy and chemical industries. The project led to 14 publications in the peer-reviewed literature with 2 additional currently under review. Finally, the project also led to training of several doctoral students who were placed in research jobs in industry and academia. Specifically, Mugdha Ambast (UH) has joined Cummins, Kevin Gu (UVa) has joined GM, and Abhay Gupta (UH) is to join Caterpillar.
42 ENGINEERING↗
Parker Solar Probe Observations of Solar Wind Energetic Proton Beams Produced by Magnetic Reconnection in the Near‐Sun Heliospheric Current Sheet
We report observations of reconnection exhausts in the Heliospheric Current Sheet (HCS) during Parker Solar Probe Encounters 08 and 07, at 16 Rs and 20 Rs, respectively. Heliospheric current sheet (HCS) reconnection accelerated protons to almost twice the solar wind speed and increased the proton core energy by a factor of ∼3, due to the Alfvén speed being comparable to the solar wind flow speed at these near-Sun distances. Furthermore, protons were energized to super-thermal energies. During E08, energized protons were found to have leaked out of the exhaust along separatrix field lines, appearing as field-aligned energetic proton beams in a broad region outside the HCS. Concurrent dropouts of strahl electrons, indicating disconnection from the Sun, provide further evidence for the HCS being the source of the beams. Around the HCS in E07, there were also proton beams but without electron strahl dropouts, indicating that their origin was not the local HCS reconnection exhaust.
T D Phan↗
Solar coronal structure: A comparison of NSO/SP ground-based coronal emission line intensities and temperatures with Yohkoh SXT and WSO magnetic data
The large-scale structure of the solar corona is investigated using synoptic maps produced from Fe XIV (530.3 nm), Fe X (637.4 nm) and Ca XV (569.4 nm) data obtained at National Solar Observatory (NSO/SP), Yohkoh/Soft X-ray Telescope (SXT) X-ray data and Wilcox Solar Observatory (WSO) 'source surface' maps. We find that the Fe XIV data are an excellent proxy for spatially-average Yohkoh/SXT data. Isolated emission features and large-scale structures are nearly identical in SXT and Fe XIV maps. In addition, coronal holes and other low-emission regions are very similar. Synoptic temperature maps, calculated from the Fe X/Fe XIV ratio, show a tendency for the highest temperatures to occur where the large-scale magnetic fields change polarity at high latitudes, while lower-latitude features, including active regions, have lower apparent tempertures. Regions of enhanced temperature generally follow the helisopheric current sheet (HCS) as defined by the WSO maps. Further, emission in Ca XV (formed at T is approximately equal to 3 MK), generally occurs only over low-latitude regions that are bright in both FE X (T approximately equal to 1 MK) and Fe XIV (T approximately equal to 2 MK). Thus, there is evidence for low (approximately equal to 1 MK), moderate (approximately equal to 2 MK) and high (approximately 3 MK) temperatures in close proximity in the low corona.
Altrock, R. C.↗
Launch Complex 34, SWMU CC054 2023 DNAPL Source Zone Operations, Maintenance, and Monitoring, Site-Wide Long-Term Monitoring, and Hot Spot 6 Air Sparge System Annual Performance Monitoring and Phase Two Expansion Construction Completion Report Cape Canaveral Space Force Station, Florida
This Annual Performance Monitoring Report (PMR) for the Dense Non-Aqueous Phase Liquid (DNAPL) Source Zone (DSZ), Site-Wide Long-Term Monitoring (LTM), and Hot Spot 6 (HS 6) Air Sparge (AS) System presents the results of Year 14 operations and performance monitoring of the hydraulic containment (HC) Interim Measure (IM), details associated with construction and implementation of the HS 6 AS system expansion (Phase Two), and the results of operations and performance sampling of the HS 6 AS IM at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. The timeframe for activities documented in this PMR extends from April 1, 2023 to March 31, 2024. LC34 has been designated Solid Waste Management Unit CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act Corrective Action Program. The objective of the HC IM at LC34 is to contain the shallow and deep DSZ and surrounding dissolved-phase trichloroethene (TCE) high concentration plume via operation of a hydraulic containment system (HCS). The pre-IM design 300 micrograms per liter (μg/L) TCE groundwater contour was used to establish the deep zone capture area for deep recovery wells, and the shallow zone capture area was defined by the DSZ. The system began operating in 2010, and in 2015, the system was expanded to provide HC for areas within the 300 μg/L TCE groundwater isocontours of HS 3 and 4. In 2018 and 2019, an investigation was conducted to recharacterize the DSZ, which included investigating TCE mass in Layer 7. This data was subsequently used to optimize the pumping rates of the HCS and install additional recovery wells in Layer 7 to more adequately capture residual contaminant mass. The operational period for Year 14 of the HCS was from April 1, 2023 to March 31, 2024. Operational runtime for the system was 94 percent during Year 14, with downtime events attributed to planned maintenance, system repairs, and power outages. As of March 31, 2024, a total of 344,849,634 cumulative gallons of groundwater containing 94,656 pounds of chlorinated volatile organic compounds (CVOCs) have been removed by the HCS. During the reporting period covered under this report, the HCS recovered 31,176,393 gallons and approximately 6,319 pounds of CVOC mass. Total combined influent concentrations of TCE have decreased since startup from approximately 280,000 µg/L (January 2010) to 25,000 µg/L (March 2024). During the reporting period, all effluent concentrations from the HCS (aqueous and vapor) were below regulatory reporting limits, indicating the system continues to operate as intended. Performance monitoring was conducted in January 2024 within the DSZ to evaluate TCE contamination. Groundwater samples were collected via DPT at nine locations, consistent with previous events between 2017 and 2022. Full vertical profile sampling was completed at each DPT from 8 to 98 feet below land surface (bls), at 5-foot intervals. The DPT performance monitoring results are summarized in this PMR. The results revealed TCE remains at concentrations greater than 11,000 µg/L in the DSZ (1-percent solubility, indicative of DNAPL) at eight of the nine DPT locations and at depths ranging from 28 to 98 feet bls. An overall decreasing trend of TCE concentrations was observed in DPT samples during this reporting period, which is a reduction from the previous event (December 2022) and the peak event in December 2021, where TCE percentages appeared to increase in all depth zones because several recovery wells were turned off during the AS pilot study in the DSZ. The maximum TCE concentration in January 2024 was 1,600,000 µg/L in the 53 feet bls depth interval at DPT594 (previous maximum result in 2022 was 1,800,000 µg/L in the 48 feet bls depth interval at DPT599). This maximum concentration in the 53 feet bls depth interval is in the deep capture zone. During the January 2024 DPT event, the largest portion of TCE mass was observed in the 48 feet bls interval above/within Layer 4. This trend remains consistent with previous years and appears to indicate continued mass discharge from Layer 4 (fine-grained unit). In addition to DPT sampling, annual groundwater samples were collected from 11 deep monitoring wells in the DSZ area (Layers 7 and 8) in December 2023 to verify vertical and horizontal delineation. Three of the wells were also sampled biweekly to evaluate operations of recovery well RW21D (screened 86 to 106 feet bls), which was installed in January 2023. Of the Layer 7/8 monitoring sampled only annually, results were non-detect or less than groundwater cleanup target levels GCTLs in December 2023, with the exception of one well, IW45D2, which had a cis-1,2-dichloroethene (cDCE), detection greater than the GCTL. Of the three wells sampled biweekly during the operational period, the well located closest to Layer 7 recovery well RW21D (IW44D2, screened 105 to 115 feet bls) had concentrations of TCE, cDCE and vinyl chloride (VC) greater than GCTLs throughout the operational period, but displayed a decreasing trend since the peak concentrations in September 2023. The maximum TCE concentration during this operational period was 190,000 µg/L at IW44D2 in September 2023, but reduced to 700 µg/L in March 2024, indicating the HCS is still effectively removing mass from the source area. Expansion of the HCS and addition of new recovery wells is ongoing and will continue to be evaluated as the groundwater recovery scheme is optimized. Details of the expansion and optimization will be provided in a future PMR. The HS 6 AS IM was initiated in 2018 with 160 AS wells and expanded in 2019 with another 140 AS wells. An additional expansion of the HS 6 AS IM was completed during the reporting period covered under this report and details of the construction implementation and startup of the expansion are detailed in Section III of this report. The new expansion, referred to as Phase Two, was implemented between August 17, 2022 and August 28, 2023, and included the installation of 190 air sparge wells to treat an additional 11.2 acres. The original configuration (referred to as Phase One) operated until Phase Two came online, then all but 52 AS wells were turned off so the components could be moved and utilized in the Phase Two area. The 52 AS wells that remain on are in a barrier configuration preventing contaminated groundwater from impacting the treated area. The HS 6 AS system (both Phase One and Two) operated normally during the reporting period covered under this report. Semi-annual performance monitoring of the Phase One configuration was conducted in April and November 2023, consistent with previous years. For the Phase Two configuration, 21 new monitoring wells were installed and sampled quarterly, with a baseline event in July 2023, and quarterly events in November 2023 and February 2024 summarized in this report. Semi-annual monitoring results collected in April and October 2023 show concentrations of contaminants of concern (cDCE, trans-1,2-dichloroethene, and VC) have decreased to less than GCTLs in nearly all wells and not impacting the surface water drainage canal, indicating the HS 6 IM continues to meet objectives. The baseline and quarterly sampling for the Phase Two configuration indicate generally decreasing concentrations in wells within and around the perimeter of the treatment area. At least two more quarters of monitoring will be conducted and once those results are evaluated a reduced the sampling frequency may be considered. Overall, the tasks associated with Year 14 operation of the HC IM and operation of the HS 6 AS IM were performed in accordance with recommendations included in the previous 2022 LC34 (Year 13) PMR. Evaluation of results from the HC IM and HS 6 IM show that these systems are operating as designed and meeting performance objectives.
groundwater remediation↗
Launch Complex 34, SWMU Cc054 2021 DNAPL Source Zone Operations, Maintenance, and Monitoring, and Hot Spot 6 Air Sparge System Annual Performance Monitoring Report Cape Canaveral Space Force Station, Florida
This Annual Performance Monitoring Report (PMR) for the Dense Non-Aqueous Phase Liquid (DNAPL) Source Zone (DSZ) and Hot Spot 6 (HS 6) Air Sparge (AS) System presents the results of Year 12 operation of the hydraulic containment (HC) Interim Measure (IM), the results of performance monitoring direct-push technology (DPT) sampling and monitoring well sampling conducted in the DSZ, and the results of operations and performance sampling of the HS 6 AS IM at Launch Complex 34 (LC34), located at Cape Canaveral Space Force Station (CCSFS), Florida. Site-wide biennial LTM sampling was not conducted during this reporting period and is scheduled to be conducted in December 2022. The timeframe for activities documented in this PMR extends from April 1, 2021 to March 31, 2022. LC34 has been designated Solid Waste Management Unit CC054 under the Kennedy Space Center (KSC) Resource Conservation and Recovery Act Corrective Action Program. The objective of the HC IM at LC34 is to contain the DSZ and deep dissolved-phase trichloroethene (TCE) high concentration plume via operation of a hydraulic containment system (HCS). The pre-IM design 300 micrograms per liter (μg/L) TCE groundwater contour was used to establish the deep zone capture area for deep recovery wells, and the shallow zone capture area was defined by the DSZ. The system began operating in 2010, and in 2015, the system was expanded to provide HC for areas within the 300 μg/L TCE groundwater isocontours of HS 3 and 4. In 2018 and 2019, an investigation was conducted to re-characterize the DSZ, which included investigating TCE mass in Layer 7. This data was subsequently used to optimize the pumping rates of the HCS to more adequately capture residual contaminant mass. The operational period for Year 12 of the HCS was from April 1, 2021 to March 31, 2022. Operational runtime for the system was 94 percent during Year 12, with downtime events attributed to planned maintenance, system repairs, and power outages. As of March 31, 2022, a total of 285,712,801 gallons of groundwater containing 84,933 pounds of VOCs have been removed by the HCS. Influent concentrations of TCE have decreased since startup from approximately 280,000 µg/L (January 2010) to 12,000 µg/L (March 2022). During the reporting period, all effluent concentrations from the HCS (aqueous and vapor) were below regulatory reporting limits, indicating the system continues to operate as intended. Performance monitoring was conducted in December 2021 within the DSZ to evaluate TCE contamination. Groundwater samples were collected via DPT at nine locations, consistent with previous events in 2017, 2018, 2019, and 2020. Full vertical profile sampling was completed at each DPT from 8 to 98 ft bls, at 5 foot intervals. The DPT performance monitoring results are summarized in this PMR. The results revealed TCE remains at concentrations greater than 11,000 µg/L in the DSZ (1-percent solubility, indicative of DNAPL) at eight of the nine DPT locations at depths ranging from 8 to 98 ft bls. An overall increasing trend of TCE concentrations was observed in DPT samples during this reporting period, which may be due to several recovery wells that were turned off during the AS Pilot Study in the DSZ that operated from July 2021 to February 2022 (documented separately from this report). The maximum TCE concentration in 2021 was 15,400,000 µg/L in the 58 ft bls depth interval at DPT597 (previous maximum result in 2020 was 1,690,000 at 48 ft bls at DPT596). During the 2021 DPT event, the overall majority of TCE contamination was identified in the 58 ft bls interval (below Layer 4), where in the previous year the majority of mass was observed in Layer 4. This trend appears to indicate continued mass discharge from Layer 4 (fine-grained unit). In addition to DPT sampling, monitoring well samples were collected from deep wells in the DSZ area (Layers 7 and 8) to verify vertical delineation. All monitoring well results were non-detect or below cleanup levels, with exception of one well (IW0162, screened 105 to 115 ft bls, which is below the existing recovery well capture zone) where TCE was identified above cleanup target levels. The HS 6 AS system remained operational during the reporting period covered under this report. The HS 6 AS IM was initiated in 2018 with 160 AS wells, and expanded in 2019 with an additional 140 AS wells. Quarterly performance monitoring was reduced to semi-annual prior to this operational period. The results of the HS 6 system operation and semi-annual performance monitoring are summarized in this report. Semi-annual monitoring results collected in April and October 2021 show concentrations of contaminants of concern (cis-1,2-dichloroethene, trans-1,2- dichloroethene, and vinyl chloride) are generally decreasing and not impacting the surface water drainage canal, indicating the HS 6 IM is meeting objectives. Overall, the tasks associated with Year 12 operation of the HC IM and operation of the HS 6 AS IM were performed in accordance with the recommendations of the 2020 LC34 (Year 11) Operations, Maintenance, and Monitoring Report for DNAPL Source Zone, Site Wide LongTerm Monitoring, and Hot Spot 6 Air Sparging System PMR (NASA, 2021c). Evaluation of results from the HC IM and HS 6 IM show that these systems are operating as designed and meeting performance objectives.
trichloroethene↗