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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Limited Role of Absolute Humidity in Intraurban Heat Variability

Abstract Monitoring and understanding the variability of heat within cities is important for urban planning and public health, and the number of studies measuring intraurban temperature variability is growing. Recognizing that the physiological effects of heat depend on humidity as well as temperature, measurement campaigns have included measurements of relative humidity alongside temperature. However, the role the spatial structure in humidity, independent from temperature, plays in intraurban heat variability is unknown. Here we use summer temperature and humidity from networks of stationary sensors in multiple cities in the United States to show spatial variations in the absolute humidity within these cities are weak. This variability in absolute humidity plays an insignificant role in the spatial variability of the heat index and humidity index (humidex), and the spatial variability of the heat metrics is dominated by temperature variability. Thus, results from previous studies that considered only intraurban variability in temperature will carry over to intraurban heat variability. Also, this suggests increases in humidity from green infrastructure interventions designed to reduce temperature will be minimal. In addition, a network of sensors that only measures temperature is sufficient to quantify the spatial variability of heat across these cities when combined with humidity measured at a single location, allowing for lower-cost heat monitoring networks. Significance Statement Monitoring the variability of heat within cities is important for urban planning and public health. While the physiological effects of heat depend on temperature and humidity, it is shown that there are only weak spatial variations in the absolute humidity within nine U.S. cities, and the spatial variability of heat metrics is dominated by temperature variability. This suggests increases in humidity will be minimal resulting from green infrastructure interventions designed to reduce temperature. It also means a network of sensors that only measure temperature is sufficient to quantify the spatial variability of heat across these cities when combined with humidity measured at a single location.

Meteorology & Atmospheric Sciences↗
DOE OSTI2017

Development of Smart Ventilation Control Algorithms for Humidity Control in High-Performance Homes in Humid U.S. Climates

Past field research and simulation studies have shown that high performance homes experience elevated indoor humidity levels for substantial portions of the year in humid climates. This is largely the result of lower sensible cooling loads, which reduces the moisture removed by the cooling system. These elevated humidity levels lead to concerns about occupant comfort, health and building durability. Use of mechanical ventilation at rates specified in ASHRAE Standard 62.2-2013 are often cited as an additional contributor to humidity problems in these homes. Past research has explored solutions, including supplemental dehumidification, cooling system operational enhancements and ventilation system design (e.g., ERV, supply, exhaust, etc.). This project’s goal is to develop and demonstrate (through simulations) smart ventilation strategies that can contribute to humidity control in high performance homes. These strategies must maintain IAQ via equivalence with ASHRAE Standard 62.2-2013. To be acceptable they must not result in excessive energy use. Smart controls will be compared with dehumidifier energy and moisture performance. This work explores the development and performance of smart algorithms for control of mechanical ventilation systems, with the objective of reducing high humidity in modern high performance residences. Simulations of DOE Zero-Energy Ready homes were performed using the REGCAP simulation tool. Control strategies were developed and tested using the Residential Integrated Ventilation (RIVEC) controller, which tracks pollutant exposure in real-time and controls ventilation to provide an equivalent exposure on an annual basis to homes meeting ASHRAE 62.2-2013. RIVEC is used to increase or decrease the real-time ventilation rate to reduce moisture transport into the home or increase moisture removal. This approach was implemented for no-, one- and two-sensor strategies, paired with a variety of control approaches in six humid climates (Miami, Orlando, Houston, Charleston, Memphis and Baltimore). The control options were compared to a baseline system that supplies outdoor air to a central forced air cooling (and heating) system (CFIS) that is often used in hot humid climates. Simulations were performed with CFIS ventilation systems operating on a 33% duty-cycle, consistent with 62.2-2013. The CFIS outside airflow rates were set to 0%, 50% and 100% of 62.2-2013 requirements to explore effects of ventilation rate on indoor high humidity. These simulations were performed with and without a dehumidifier in the model. Ten control algorithms were developed and tested. Analysis of outdoor humidity patterns facilitated smart control development. It was found that outdoor humidity varies most strongly seasonally—by month of the year—and that all locations follow the similar pattern of much higher humidity during summer. Daily and hourly variations in outdoor humidity were found to be progressively smaller than the monthly seasonal variation. Patterns in hourly humidity are driven by diurnal daily patterns, so they were predictable but small, and were unlikely to provide much control benefit. Variation in outdoor humidity between days was larger, but unpredictable, except by much more complex climate models. We determined that no-sensor strategies might be able to take advantage of seasonal patterns in humidity, but that real-time smart controls were required to capture variation between days. Sensor-based approaches are also required to respond dynamically to indoor conditions and variations not considered in our analysis. All smart controls face trade-offs between sensor accuracy, cost, complexity and robustness.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

Advanced HVAC Humidity Control for Hot-Humid Climates

During this project we develop and validate a cost-effective, integrated control solution to improve humidity control and comfort for energy-efficient homes in hot-humid climates. This study focuses on developing a strategy that is effective, field tested, and practical for builders to install with minimal disruption to standard practices. A successful solution would simplify the transition to high-performance humidity control and be the basis for design and installation guidance. By relying on the central system as a starting point, the strategy employed minimizes system complexity and cost for builders, while improving comfort and operating cost for homeowners. The solution strategy was to coordinate the cooling, dehumidification, and ventilation functions of central, ducted HVAC systems to better control indoor humidity, improve occupant thermal comfort, and capture energy savings. The primary strategic goals were to: (1) optimize dehumidification by the central air-conditioning system, particularly during part-load conditions, using conventional equipment with modified control settings and lower system airflows; (2) maximize ventilation during heating/cooling on-cycles, to “bank” and condition outdoor ventilation air, and minimize ventilation during off-cycles; (3) quantify the effectiveness and energy impact of the dehumidification and ventilation strategies, while identifying a metric that would be useful to evaluate latent effectiveness. For the test houses in our study, located in Richmond Hill, Georgia; Houston, Texas; and Monroe, Louisiana we observed: (1) the indoor humidity did not exceed 60% RH during the monitored cooling season for 99% of the time in Richmond Hill, 96% of the time in Houston, and 90% of the time in Monroe; (2) the dehumidification strategy improved the steady-state latent capacity of the HVAC system at design conditions by 16% to 49% at the Houston test house and by 28% to 71% at the Monroe test house, depending on which mode the system was operating in; and (3) the good results at the test houses were primarily due to the amount of time the air-conditioning system operated in ramping or dehumidification modes, or both, particularly during the early cooling season. This study demonstrates that air conditioners or heat pumps with a single-stage compressor can provide good humidity control without the need for a two-stage or variable-stage compressor system. The airflow and control settings for ramping and dehumidification modes are critical to control indoor humidity in hot-humid climates, particularly during part-load and shoulder season conditions. The dehumidification strategy used in this study did not jeopardize the mechanical reliability of the cooling equipment. The strategies used in this study are applicable across various equipment brands, models, and efficiency levels, and also applicable to a broad range of homes in hot-humid climates. Results will vary by specific equipment, location, and house configuration and construction.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2019

The dependence of radius on relative humidity and solute mass at high relative humidities up to and including 100%

This manuscript presents a rigorous examination of the equilibrium radius ratio of hygroscopic aerosol particles that are solution drops of ideal and actual inorganic solutes for a range of solute masses in the relative humidity range 99-100%. Analysis is presented first for ideal solutes over a range of solute masses for different hygroscopicities, providing a theoretical framework for the subsequent analysis of actual solutes. Dimensionless quantities are used to reduce the Kohler equation to one with no free parameters and an approximate solution is presented. Next analysis is presented for three common inorganic solutes of atmospheric importance: sodium chloride, ammonium sulfate, and sulfuric acid, with a range of solute masses considered for each substance. The extent to which non-ideality is important for these solutes over the ranges of relative humidities and solute masses considered is examined. A simple but accurate single-parameter expression is presented for the equilibrium radius ratio as a function of relative humidity that contains the dependenceso on solute mass and composition for these solutes. The accuracy of this expression is quantified and factors that limit this accuracy are discussed. The expression is accurate to within 5% over most of the range of mass-equivalent dry radii from 10 to 250 nm and relative humidities from below 99 up to 100%, over which the equilibrium radius ratio varies by more than a factor of five, and it remains finite at 100% relative humidity. Lastly, measurements of hygroscopic growth of aerosol particles in this relative humidity range are discussed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Humidity effects on tip-induced polarization switching in lithium niobate

In the last several decades, ferroelectrics have attracted much attention as perspective materials for nonlinear optics and data storage devices. Scanning probe microscopy (SPM) has emerged as a powerful tool both for studies of domain structures with nanoscale spatial resolution and for writing the isolated nanodomains by local application of the electric field. Quantitative analysis of the observed behavior requires understanding the role of environmental factors on imaging and switching process. Here, we study the influence of the relative humidity in the SPM chamber on tip-induced polarization switching. The observed effects are attributed to existence of a water meniscus between the tip and the sample surface in humid atmosphere. These results are important for a deeper understanding of complex investigations of ferroelectric materials and their applications and suggest the necessity for fundamental studies of electrocapillary phenomena at the tip-surface junction and their interplay with bias-induced materials responses.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Quasielastic neutron scattering with in situ humidity control: Water dynamics in uranyl fluoride

The structural phase diagram of uranyl fluoride (UO{sub 2}F{sub 2}), while incomplete, contains at least one anhydrous crystal structure and a second, zeolite-like structure with the formula [(UO{sub 2}F{sub 2})(H{sub 2}O)]{sub 7} ⋅ (H{sub 2}O){sub 4} that can be produced by adding water to the anhydrous structure. While traditional diffraction measurements can easily differentiate these crystals, additional aqueous structures (in general of the form UO{sub 2}F{sub 2} + xH{sub 2}O) have been proposed as well. We present results using a novel sample environment setup to intercalate water during a quasielastic neutron scattering measurement over the course of 86 h. Our sample environment allows low-pressure (<2 atm) humid air flow across the sample coupled with a system to control the relative humidity of this air flow between 10% and 70%. The water dynamics in UO{sub 2}F{sub 2} and [(UO{sub 2}F{sub 2})(H{sub 2}O)]{sub 7} ⋅ (H{sub 2}O){sub 4} are sufficiently different to distinguish them, with water in the latter executing a restricted diffusion (D = 2.7 × 10{sup −6} cm{sup 2}/s) within the structure's accessible pores (r = 3.17 Å) such that the dynamics can be used as a fingerprinting tool. We confirm that water vapor pressure is the driving thermodynamic force for the conversion of the anhydrous structure to [(UO{sub 2}F{sub 2})(H{sub 2}O)]{sub 7} ⋅ (H{sub 2}O){sub 4}, and we demonstrate the feasibility of extending this approach to aqueous forms of UO{sub 2}F{sub 2} + xH{sub 2}O. This method has general applicability to systems in which water content itself is a driving variable for structural or dynamical phase transitions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Thickness, humidity, and polarization dependent ferroelectric switching and conductivity in Mg doped lithium niobate

Mg doped lithium niobate (Mg:LN) exhibits several advantages over undoped LN such as resistance to photorefraction, lower coercive fields, and p-type conductivity that is particularly pronounced at domain walls and opens up a range of applications, e.g., in domain wall electronics. Engineering of precise domain patterns necessitates well founded knowledge of switching kinetics, which can differ significantly from that of undoped LN. In this work, the role of humidity and sample composition in polarization reversal has been investigated under application of the same voltage waveform. Control over domain sizes has been achieved by varying the sample thickness and initial polarization as well as atmospheric conditions. In addition, local introduction of proton exchanged phases allows for inhibition of domain nucleation or destabilization, which can be utilized to modify domain patterns. Polarization dependent current flow, attributed to charged domain walls and band bending, demonstrates the rectifying ability of Mg:LN in combination with suitable metal electrodes that allow for further tailoring of conductivity.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Energy-Efficient Management of Mechanical Ventilation and Relative Humidity in Hot-Humid Climates

In hot and humid climates, it is challenging to energy-efficiently maintain indoor RH at acceptable levels while simultaneously providing required ventilation, particularly in high performance low cooling load homes. The fundamental problem with solely relying on fixed capacity central cooling systems to manage moisture during low sensible load periods is that they are oversized for cooler periods of the year despite being 'properly sized' for a very hot design cooling day. The primary goals of this project were to determine the impact of supplementing a central space conditioning system with 1) a supplemental dehumidifier and 2) a ductless mini-split on seasonal energy use and summer peak power use as well as the impact on thermal distribution and humidity control inside a completely furnished lab home that was continuously ventilated in accordance with ASHRAE 62.2-2013.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2016

Energy-Efficient Management of Mechanical Ventilation and Relative Humidity in Hot-Humid Climates

In hot and humid climates, it is challenging to energy-efficiently maintain indoor RH at acceptable levels while simultaneously providing required ventilation, particularly in high performance low cooling load homes. The fundamental problem with solely relying on fixed capacity central cooling systems to manage moisture during low sensible load periods is that they are oversized for cooler periods of the year despite being 'properly sized' for a very hot design cooling day. The primary goals of this project were to determine the impact of supplementing a central space conditioning system with 1) a supplemental dehumidifier and 2) a ductless mini-split on seasonal energy use and summer peak power use as well as the impact on thermal distribution and humidity control inside a completely furnished lab home that was continuously ventilated in accordance with ASHRAE 62.2-2013.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2017

Building America Case Study: Energy Efficient Management of Mechanical Ventilation and Relative Humidity in Hot-Humid Climates, Cocoa, Florida

In hot and humid climates, it is challenging to energy-efficiently maintain indoor RH at acceptable levels while simultaneously providing required ventilation, particularly in high performance low cooling load homes. The fundamental problem with solely relying on fixed capacity central cooling systems to manage moisture during low sensible load periods is that they are oversized for cooler periods of the year despite being 'properly sized' for a very hot design cooling day. The primary goals of this project were to determine the impact of supplementing a central space conditioning system with 1) a supplemental dehumidifier and 2) a ductless mini-split on seasonal energy use and summer peak power use as well as the impact on thermal distribution and humidity control inside a completely furnished lab home that was continuously ventilated in accordance with ASHRAE 62.2-2013.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2017

Influence of humidity on performance and microscopic dynamics of an ionic liquid in supercapacitor

We investigated the influence of water molecules on the diffusion, dynamics, and electrosorption of a room temperature ionic liquid (RTIL), [BMIm + ][Tf 2 N - ], confined in carbide-derived carbon with a bimodal nanoporosity. Water molecules in pores improved the charge storage densities and rate handling abilities of these materials in supercapacitor electrode configurations. We measured the water-dependent microscopic dynamics of the RTIL cations using quasi-elastic neutron scatting (QENS). The ionic liquid demonstrated greater mobility with increasing water uptake, facilitated by the nanoporous carbon environment, up to a well-defined saturation point. We concluded that water molecules displaced RTIL ions attached to the pore surfaces and improved the diffusivity of the displaced cations. This effect consequently increased capacitance and rate handling of the electrolyte in water-containing pores. Our findings suggest the possible effect of immiscible co-solvents on energy and power densities of energy storage devices, as well as the operating viability of non-aqueous supercapacitor electrolytes in humid environments.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Effects of Porous Carbon Morphology, Agglomerate Structure and Relative Humidity on Local O 2 Transport Resistance

The morphology and ionomer distribution in a polymer electrolyte membrane fuel cell (PEMFC) cathode electrode are quantified with nano-scale resolution X-ray computed tomography (nano-CT). Using the nano-CT data, different shapes, sizes and compositions of agglomerates are extracted. Statistical information from multiple techniques, including transmission electron microscopy (TEM), ultra-small angle X-ray scattering (USAXS), and Brunauer-Emmett-Teller (BET) gas adsorption porosimetry are combined to reconstruct the high surface-area porous carbon (HSC) support, exterior (on the surface of carbon) and interior (inside carbon pores) catalysts, ionomer, and primary pores in the extracted agglomerates. Application of capillary condensation theory to the reconstructed agglomerate structure is shown to accurately represent the experimentally-observed relative humidity (RH) dependence of the electrochemically-active surface area (ECA). Direct numerical simulations show that the high local O 2 transport resistance ( R O 2 ) under dry conditions is mainly associated with the reduced ECA. We demonstrate that the agglomerate shape and size affect R O 2 only if the primary pores are poorly accessible (i.e., capillary-condensed water filled primary pores). We also evaluate the effect of transport to the interior catalyst particles on R O 2 .

agglomerate↗
DOE OSTI2018

Developing a landscape of urban building energy use with improved spatiotemporal representations in a cool-humid climate

Urban buildings account for up to 75% of total energy use in the United States (U.S.). Understanding urban building energy use is important for developing feasible options to mitigate energy use and greenhouse gas emissions. In this study, an improved bottom-up building energy use model, named City Building Energy Use Model (City-BEUM), was developed to estimate building energy use for all buildings in Polk County, Iowa. First, 28 commercial and 6 residential building prototypes were designed by combing Assessor's parcel data and building footprint data. Then, the EnergyPlus in the CityBEUM was calibrated for all building prototypes using the U.S. Energy Information Administration's survey data, monthly utility meter data, and actual weather data. Finally, spatial and temporal variations of building energy use in the study area were estimated using the CityBEUM. Results indicate that the spatial variation of building energy use in the study area can be captured using the CityBEUM. With the monthly-calibrated model, the temporal pattern of urban building energy use can be well represented. The comparison of building energy use using the Typical Meteorological Year and actual weather data demonstrates the importance of using actual weather data in building energy modeling for an improved temporal representation.

CityBEUM, Urban building energy use, High spatiote↗