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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Effect of Oxygen Concentration on Autogenous Ignition Temperature and Pneumatic Impact Ignitability of Nonmetallic Materials

Extensive test data exist on the ignitability of nonmetallic materials in pure oxygen, but these characteristics are not as well understood for lesser oxygen concentrations. In this study, autogenous ignition temperature testing and pneumatic impact testing were used to better understand the effects of oxygen concentration on ignition of nonmetallic materials. Tests were performed using oxygen concentrations of 21, 34, 45, and 100 %. The following materials were tested: PTFE Teflon(Registered Trademark), Buna-N, Silicone, Zytel(Registered Trademark) 42, Viton(registered Trademark) A, and Vespel(Registered Trademark) SP-21.

Smith, Sarah↗

Ignition Temperatures of Metals in Oxygen Atmospheres

The ignition temperature of ten common non-toxic metals has been determined experimentally in an oxygen environment. In this investigation a induction furnace facility that emphasized the preignition surface.oxidation effects upon the ignition temperature was used. The bulk ignition temperatures of barium, bismuth, calcium, iron, lead, magnesium, molybdenum, strontium, tin, and zinc were found and compared to the previous results of Grosse and Conway. The differences in the results are attributed to how the heating cycle is carried out and how the cycle affects the surface oxide coat.

Laurendeau, N. M.↗

Spontaneous ignition temperature limits of jet A fuel in research-combustor segment

The effects of inlet-air pressure and reference velocity on the spontaneous-ignition temperature limits of Jet A fuel were determined in a combustor segment with a primary-zone length of 0.076 m (3 in.). At a constant reference velocity of 21.4 m/sec (170 ft/sec), increasing the inlet-air pressure from 21 to 207 N/sq cm decreased the spontaneous-ignition temperature limit from approximately 700 to 555 K. At a constant inlet-air pressure of 41 N/sq cm, increasing the reference velocity from 12.2 to 30.5 m/sec increased the spontaneous-ignition temperature limit from approximately 575 to 800 K. Results are compared with other data in the literature.

Ingebo, R. D.↗

Comparative results of autogenous ignition temperature measurements by ASTM G 72 and pressurized scanning calorimetry in gaseous oxygen

The autogenous ignition temperature of four materials was determined by ASTM (G 72) and pressurized differential scanning calorimetry at 0.68-, 3.4-, and 6.8-MPa oxygen pressure. All four materials were found to ignite at lower temperatures in the ASTM method. The four materials evaluated in this program were Neoprene, Vespel SP-21, Fluorel E-2160, and nylon 6/6.

Bryan, C. J.↗

Near-infrared two-color pyrometer for determining ignition temperatures of metals and metal alloys

A two-color pyrometer has been designed, constructed, and used to measure the ignition temperatures of metals and metal alloys. Cylindrical metal and metal alloy specimens were ignited by a focused cw CO2 laser beam in a cool, static, pure oxygen environment. The pyrometer operates in the near-infrared at two narrow spectral regions, with a nominal bandwidth of 10 nm centered at 0.9051 and 1.06 micron, and has a temperature range from 1000 to 4000 K. In the present design the temperature of a spot, about 0.5 mm in diameter, can be recorded with a maximum time resolution of 25 microseconds and with an accuracy of a few percent. Results of CO2 laser ignition of cylindrical specimens of 6061 aluminum alloy and 302 SS in a pure oxygen environment were obtained from the two-color pyrometer and were compared with those obtained from a thermocouple placed inside the specimen near the laser-irradiated surface.

Nguyen, K.↗

Determination of Autogenous Ignition Temperature for Isopropyl Alcohol and Ethanol

As part of a recent liquid rocket engine shutdown investigation, a commercial partner requested that NASA provide the autogenous ignition (or autoignition) temperature (AIT) of isopropyl alcohol (IPA). NASA provided the available data, but the data were somewhat scattered, likely due to test configuration and test technique differences. NASA Engineering and Safety Center (NESC) support was requested to experimentally determine the AIT of IPA and ethanol, both of which are extensively applied to propulsion systems. This report contains the outcome of the NESC assessment.

Autoignition Temperature; Isopropyl Alcohol; Comme↗

Computational Fluid Dynamics Modeling of Low Temperature Ignition Processes From a Nanosecond Pulsed Discharge at Quiescent Conditions

Recent interest in nonequilibrium plasma discharges as sources of ignition for the automotive industry has not yet been accompanied by the availability of dedicated models to perform this task in computational fluid dynamics (CFD) engine simulations. The need for a low-temperature plasma (LTP) ignition model has motivated much work in simulating these discharges from first principles. Most ignition models assume that an equilibrium plasma comprises the bulk of discharge kernels. LTP discharges, however, exhibit highly nonequilibrium behavior. In this work, a method to determine a consistent initialization of LTP discharge kernels for use in engine CFD codes like CONVERGE is proposed. The method utilizes first principles discharge simulations. Such an LTP kernel is introduced in a flammable mixture of air and fuel, and the subsequent plasma expansion and ignition simulation is carried out using a reacting flow solver with detailed chemistry. Finally, the proposed numerical approach is shown to produce results that agree with experimental observations regarding the ignitability of methane-air and ethylene-air mixtures by LTP discharges.

33 ADVANCED PROPULSION SYSTEMS↗

A Phenomenological Thermal Spray Wall Interaction Modeling Framework Applied to a High Temperature Ignition Assistant Device

Airborne compression ignition engines must operate with reliable ignition systems to achieve proper ignition at every cycle, particularly at high altitudes. Glow-plug-based ignition-assistant (IA) devices can provide the necessary energy to preheat the fuel and ensure ignitability of the fuel-air mixture. Ignitability of liquid sprays can be facilitated via direct impingement onto the hot IA surface, however this comes with adverse effects on the IA durability. Therefore, optimizing an IA’s design requires detailed understanding of the physics of fuel spray impingement of superheated surfaces. While spray impingement on relatively low wall temperatures has been extensively studied and appropriate numerical models have been proposed through the years, fundamental understanding of high-speed liquid spray impingement on superheated walls is still elusive. This work aims to formulate a phenomenological thermal spray-wall interaction framework for modeling the film-boiling-induced heat transfer, atomization, and dispersion of fuel spray droplets impinging onto a superheated IA device. A qualitative comparison of the new phenomenological model is performed against optical experiments from the literature of an F-24 fuel spray injected onto an IA device located 12 mm away from the injector tip. The temperature of the IA was set at 1400 K. The fuel injection pressure was 400 bar, while the ambient gas pressure and temperature were 30 bar and 800 K, respectively. The performance of the phenomenological model is evaluated in comparison with two other state-of-art models from the literature. A qualitative analysis of the different spray and fuel-air mixture characteristics is performed to outline the differences in the predictions offered by the new phenomenological model and the two state-of-art spray-wall interaction models.

droplet dispersion↗

Innovative Comparison of Transient Ignition Temperature at the Booster Interface, New Stainless Steel Pyrovalve Primer Chamber Assembly "V" (PCA) Design Versus the Current Aluminum "Y" PCA Design

An assessment of four spacecraft pyrovalve anomalies that occurred during ground testing was conducted by the NASA Engineering & Safety Center (NESC) in 2008. In all four cases, a common aluminum (Al) primer chamber assembly (PCA) was used with dual NASA Standard Initiators (NSIs) and the nearly simultaneous (separated by less than 80 microseconds) firing of both initiators failed to ignite the booster charge. The results of the assessment and associated test program were reported in AIAA Paper AIAA-2008-4798, NESC Independent Assessment of Pyrovalve Ground Test Anomalies. As a result of the four Al PCA anomalies, and the test results and findings of the NESC assessment, the Mars Science Laboratory (MSL) project team decided to make changes to the PCA. The material for the PCA body was changed from aluminum (Al) to stainless steel (SS) to avoid melting, distortion, and potential leakage of the NSI flow passages when the device functioned. The flow passages, which were interconnected in a Y-shaped configuration (Y-PCA) in the original design, were changed to a V-shaped configuration (V-PCA). The V-shape was used to more efficiently transfer energy from the NSIs to the booster. Development and qualification testing of the new design clearly demonstrated faster booster ignition times compared to the legacy AL Y-PCA design. However, the final NESC assessment report recommended that the SS V-PCA be experimentally characterized and quantitatively compared to the Al Y-PCA design. This data was deemed important for properly evaluating the design options for future NASA projects. This test program has successfully quantified the improvement of the SS V-PCA over the Al Y-PCA. A phase B of the project was also conducted and evaluated the effect of firing command skew and enlargement of flame channels to further assist spacecraft applications.

Saulsberry, Regor L.↗