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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1996

The Inventory of Interstellar Materials Available for the Formation of the Solar System

Dr. Derek Sears, the editor of the journal Meteoritics and Planetary Science, has established a policy of having each issue of the journal contain an invited review of an area that he deems to be of special cur-rent importance. Typically 20 to 25 pages of the beginning of the journal are devoted to each review. He has asked me to prepare such a review summarizing what we know about the composition and structure of interstellar materials. The attached paper is the result. This is a good time for such a review since tremendous progress has been made in the field of interstellar dust in recent years through the use of telescopic observations, theoretical studies, laboratory studies of analogs, and the study of actual interstellar samples found in meteorites. It is increasing clear that the interstellar medium (ISM) contains an enormous diversity of materials created by a wide range of chemical and physical processes. This understanding is a far cry from the picture of interstellar materials held as recently as two decades ago, a picture which incorporated only a few generic types of grains and few molecules. In the paper I review our current knowledge of the more abundant materials thought to exist in the ISM. The review concentrates on matter in interstellar dense molecular clouds since it is the materials in these environments from which new stars and planetary systems are formed, although materials in circumstellar environments and in the diffuse ISM are also discussed. The paper focuses largely on solid materials since they contain a major fraction of the heavier elements in clouds and because solids are most likely to survive incorporation into new planetary systems in identifiable form. The paper concludes with discussion of some of the implications resulting from the identification of these interstellar materials. I also present some new thoughts, the most intriguing being that meteoritic 'microdiamonds' may be the same material that modelers of the interstellar extinction call graphite! If my suggestion is correct it will help resolve the dilemma associated with the current over-subscription of cosmic C and should lead to some new approaches to both extinction models and the study of meteoritic interstellar microdiamonds.

Sandford, Scott A.↗
NASA NTRS1979

The interstellar material in front of Chi Ophiuchi. I - Optical observations

Optical observations of the interstellar material in front of Chi Oph are discussed. The main interstellar cloud is made up of several regions with velocities between -6 and -12 km/s (heliocentric). Both CH and CH(+) are found within this feature, but with central velocities which differ by 2 km/s. Another cloud, with a velocity of -26 km/s, contains relatively strong Ca(+) lines. It has a ratio between Ca(+) and Na(0) column densities that is appropriate for 'high-velocity' clouds. Calcium, iron, and sodium column densities are used to estimate an average electron density for the line of sight, as well as for each cloud. The abundances of CH and CH(+), and the absence of CN, are analyzed in terms of current theories about their origin.

Frisch, P. C.↗
NASA NTRS1977

Copernicus studies of interstellar material in the Perseus II complex. III - The line of sight to Zeta Persei

Ultraviolet spectrophotometric data obtained with Copernicus are used to analyze the distribution, composition, density, temperature, and kinematics of the interstellar material along the line of sight to Zeta Persei. The far-UV extinction curve for the star is evaluated along with the kinematics of the interstellar gas, observations of atomic and molecular hydrogen, curves of growth for neutral and ionized species, atomic abundances and depletions, ionization equilibria, and observations of CO and OH lines. The results show that there are apparently three clouds along the line of sight to Zeta Persei: a main cloud at approximately +13 km/s which contains most of the material and forms all the neutral and molecular lines as well as most of the ionic lines, a second component at +22 km/s which must contribute to the strong UV lines of most ions, and a third component at roughly +2 km/s which gives rise to a strong Si III line at 1206 A. It is also found that the UV extinction curve has a somewhat steep far-UV rise, indicating the presence of a substantial number of small grains, and that about 30% of the hydrogen nuclei over the entire line of sight are in molecular form.

Snow, T. P., Jr.↗
NASA NTRS1992

Accurate oscillator strengths for ultraviolet lines of Ar I - Implications for interstellar material

Analysis of absorption from interstellar Ar I in lightly reddened lines of sight provides information on the warm and hot components of the interstellar medium near the sun. The details of the analysis are limited by the quality of the atomic data. Accurate oscillator strengths for the Ar I lines at 1048 and 1067 A and the astrophysical implications are presented. From lifetimes measured with beam-foil spectroscopy, an f-value for 1048 A of 0.257 +/- 0.013 is obtained. Through the use of a semiempirical formalism for treating singlet-triplet mixing, an oscillator strength of 0.064 +/- 0.003 is derived for 1067 A. Because of the accuracy of the results, the conclusions of York and colleagues from spectra taken with the Copernicus satellite are strengthened. In particular, for interstellar gas in the solar neighborhood, argon has a solar abundance, and the warm, neutral material is not pervasive.

Federman, S. R.↗
NASA NTRS2015

Nebular and Interstellar Materials in a Giant Cluster IDP of Probable Cometary Origin

Comets contain a complex mixture of materials with presolar and Solar System origins. Chondritic porous interplanetary dust particles (CP-IDPs) are associated with comets by their fragile nature, unequilibrated anhydrous mineralogy and high abundances of circumstellar grains and isotopically anomalous organic materials. Comet 81P/Wild 2 samples returned by the Stardust spacecraft contain presolar materials as well as refractory 16O-rich Ca-Al-rich inclusion- (CAI), chondrule-, and AOA-like materials. We are conducting coordinated chemical, mineralogical, and isotopic studies of a giant cluster CP-IDP (U2-20-GCA) to determine the proportions of inner Solar System and interstellar materials. We previously found that this IDP contains abundant presolar silicates (approx. 1,800 ppm) and 15N-rich hotspots [6].

Messenger, S.↗
NASA NTRS1993

Optical studies of interstellar material in low density regions of the Galaxy. I - A survey of interstellar Na I and Ca II absorption toward 57 distant stars

We present high-resolution spectra of the Na I D and Ca II K lines toward 57 late-O and early-B stars along extended (d greater than 1 kpc) low-density paths through the Milky Way disk and halo. The sight lines preferentially sample diffuse gas in the interstellar medium (ISM) along interarm, Galactic center, and high latitude directions. We measure equivalent widths, apparent column densities, and absorption component structure. The Ca II to Na I ratios presented as a function of velocity for each sight line exhibit variations due to elemental depletion, ionization, and density enhancements. Absorption along high latitude sight lines is kinematically simpler than it is along interarm and Galactic center sight lines. Galactic rotation noticeably broadens the absorption profiles of distant stars located in these latter directions. Along several sight lines, we see Ca II absorption at velocities corresponding to large distances (/z/ about 1 kpc) from the Galactic plane. The effects of differences in the Ca II and Na I scale heights and nonzero velocity dispersions are readily apparent in the data. Brief notes are given for several sight lines with interesting absorption properties.

Sembach, K. R.↗
NASA NTRS1979

Ortho and parahydrogen in interstellar material

The ortho/para molecular hydrogen ratio in the interstellar medium is considered. It is shown that the ortho/para ratio will be 3:1 in practically all chemical reactions, even at relatively low temperatures. Two examples of exothermic processes that will result in the formation of a 3:1 ortho:para ratio, corresponding to a high-temperature equilibrium, are examined: H2 formation via three-body or surface recombination and catalytic recombination involving electrons and H(-) ions. Gas-phase scrambling ion reactions are also discussed, and it is suggested that virtually all the H2 equilibrated via scrambling reactions involving H(+) and H3(+) ions should exist as parahydrogen in the J ? 0 quantum state. Arguments are given that deuterium cannot interfere with the long scrambling chain that results in parahydrogen formation.

Reeves, R. R.↗
NASA NTRS1986

Interstellar material in the solar system

All the substance of the Earth and other terrestrial planets once existed in the form of interstellar grains and gas. A major aspect of solar system formation (and undoubtedly of star formation generally) is the complex series of processes that converted infalling interstellar grains into planets. A cryptic record of these processes is preserved in certain samples of planetary materials, such as chondritic meteorites, that were preserved in a relatively unchanged form since the beginning. It is to be expected that some of these primitive materials might contain or even consist of preserved presolar interstellar grains. The identification and study of such grains, the ancestors of our planetary system, is a matter of intense interest. Types of primitive material accessible or potentially accessible, and component of or relationship to presolar interstellar grains are discussed.

Wood, J. A.↗
NASA NTRS1976

An analysis of the interstellar material in the line of sight toward Omicron Persei

Chemical abundances and physical conditions in the interstellar gas toward Omicron Per are analyzed using Copernicus UV spectrophotometric data on 69 lines due to ions and atoms as well as 19 lines of H2 and HD. The UV extinction toward the star is determined along with the column densities of atomic and molecular hydrogen, the atomic column densities and temperature in the H I region, and the nature of the ionized regions along the line of sight. It is concluded that: (1) Omicron Per is apparently embedded in the near edge of an extended dense molecular cloud, the outer parts of which give rise to the observed absorption lines; (2) the H I region may consist of more than one cloud; (3) the far-UV extinction rise is unusually steep, indicating a high proportion of small grains; (4) the element depletions are somewhat greater than in Zeta Oph, particularly for sulfur and argon; and (5) the molecular abundances are generally consistent with gas-phase formation models rather than with molecular formation on grain surfaces, unless a substantial amount of small grains is present to increase the available surface area.

Snow, T. P., Jr.↗
NASA NTRS1994

Optical studies of interstellar material in low density regions of the Galaxy

We analyze high-resolution Na I and Ca II interstellar absorption line data obtained in an earlier spectroscopic survey of 57 stars along extended sight lines through the Galactic disk and halo. We find that the Na I lines trace a diffuse cloudy medium and the CA II lines trace both the cloudy medium and a more extended (intercloud) medium. High latitude and interarm sight lines that do not cross spiral arms have clouds that are more diffuse on average than those along sight lines that cross spiral arms. Spiral structure may play an important role in determinating the average absorption properties along extended sight lines and/or interesting physical differences may exist between sight lines that cross spiral arms and those that do not. These might include a harder radiation field and/or higher electron tempertures along the high latitude and 'clean' interarm sight lines. On average, 10% of the Ca II column density occurs at velocities forbidden by the Galactic rotation law by more than 10 km/s. In contrast, only a small precentage of the Na I column density occurs at these velocites. The Ca II to Na I ratio increases by a factor of 15 over forbidden velocities from 0 to 50 km/s and rises rapidly thereafter. A two component model of the Ca II column density per unit velocity over the range l = 325 deg to 360 deg indicates that two distinct distributions exists, one with sigma = 8 km/s and one with sigma = 21 km/s. As much as 60% of the Ca II column density at forbidden velocities may be associated with the faster distribution, which we attribute to warm intercloud material. We estimate expontential scale heights of 0.4-0.5 kpc for the neutral gas traced by the E(B-V), Na I, and H I distributions along the low density sight lines, and we find that Ca II has a larger scale height of 0.8 kpc.

Sembach, K. R.↗
NASA NTRS1980

The interstellar material in front of Chi Ophiuchus. II - Ultraviolet observations

The high-resolution UV spectrometer aboard the Copernicus satellite was used to observe the interstellar gas toward the moderately reddened star Chi Oph. The data are consistent with the hypothesis that the material in both the -6 and -12 km/s blend of gas and the -26 km/s cloud could have been affected by shock front activity, though the signatures of that activity are different in each case. These observations of the blend of gas establish that both low and high density neutral material must be present.

Frisch, P. C.↗
NASA NTRS1987

The local interstellar medium. VII - The local interstellar wind and interstellar material in front of the nearby star Alpha Ophiuchi

IUE observations of Mg I 2852.127 A are used to search for warm interstellar gas in the direction of Alpha Oph. The data on Mg I are first presented, and Mg I as a diagnostic of warm gas is discussed. A cool H I feature found in the direction of Alpha Oph, and which is evidently the origin of most of the observed optical and ultraviolet lines, is discussed, and the cloud geometry is examined.

Frisch, P. C.↗
NASA NTRS1987

Element abundances in the interstellar atomic material

In the interstellar medium, a significant fraction of the free atoms for elements heavier than helium must have condensed into solids, in the form of small, interstellar dust grains. Observations of optical and ultraviolet absorption lines in the spectra of hot stars indicate that the depletions below the cosmic abundances of various elements range from almost none at all to a factor of 0.0001 and seem to be enhanced along lines of sight with higher mean density. Other methods of measuring abundances confirm the absorption line results. The available evidence supports the notion that the grains form in both the atmospheres of cool stars and in dense interstellar clouds, and they are destroyed by shocks which frequently pass through the low density gas.

Jenkins, Edward B.↗
NASA NTRS1995

Laboratory comparisons of organic materials to interstellar dust and the Murchison meteorite

Spectra of objects which lie along several lines of sight through the diffuse interstellar medium (DISM) reveal an absorption feature near 3.4 micrometers, which has been attributed to saturated aliphatic hydrocarbons on interstellar grains. The similarity of the absorption bands near 3.4 micrometers (2950 cm-1) along different lines of sight indicates that the carrier of this band lies in the diffuse dust. Several materials have been proposed as "fits" to the 3.4 micrometers feature over the years. A comparison of these identifications is presented. These comparisons illustrate the need for high resolution, high signal-to-noise observational data as a means of distinguishing between laboratory organics as matches to the interstellar material. Although any material containing hydrocarbons will produce features in the 3.4 micrometers region, the proposed "matches" to the DISM do differ in detail. These differences may help in the analyses of the chemical composition and physical processes which led to the production of the DISM organics, although ISO Observations through the 5-8 micrometers spectral region are essential for a definitive identification. A remarkable similarity between the spectrum of the diffuse dust and an organic extract from the Murchison meteorite suggests that some of the interstellar organic material may be preserved in primitive solar system bodies. The 3.4 micrometers absorption feature (in the rest frame) has recently been detected in external galaxies, indicating the widespread availability of organic material for incorporation into planetary systems.

NASA Center ARC↗
NASA NTRS2002

Cometary Silicates: Interstellar and Nebular Materials

Evidence for interstellar material in comets is deduced from IR spectra, insitu measurements of Halley, and chondritic porous interplanetary dust particles (CP IDPs). IR spectra of comets reveal the spectrally active minerals: amorphous carbon, amorphous silicates, and (in some comets) crystalline silicates. Evidence suggests amorphous silicates are of interstellar origin while crystalline silicates are of nebular origin. 10 microns spectra of comets and submicron amorphous silicate spherules in CP IDPs have shapes similar to lines-of-sight through the ISM. Thermal emission models of cometary IR spectra require Fe-bearing amorphous silicates. Fe-bearing amorphous silicates may be Fe-bearing crystalline silicates formed in AGB outflows that are amorphized through He+ ion bombardment in supernova shocks in the ISM. Crystalline silicates in comets, as revealed by IR spectra, and their apparent absence in the ISM, argues for their nebular origin. The high temperatures (less than l000 K) at which crystals form or are annealed occur in the inner nebula or in nebular shocks in the 5-10 AU region. Oxygen isotope studies of CP IDPs show by mass only 1 % of the silicate crystals are of AGB origin. Together this suggests crystalline silicates in comets are probably primitive grains from the early solar nebula.

Wooden, Diane H.↗
NASA NTRS1993

Evaporation in equilibrium, in vacuum, and in hydrogen gas

Evaporation experiments were conducted for SiO2 in three different conditions: in equilibrium, in vacuum, and in hydrogen gas. Evaporation rate in vacuum is about two orders of magnitude smaller than that in equilibrium, which is consistent with previous works. The rate in hydrogen gas changes depending on hydrogen pressure. The rate at 10 exp -7 bar of hydrogen pressure is as small as that of free evaporation, but at 10 exp -5 bar of hydrogen pressure it is larger than that in equilibrium. In equilibrium and in vacuum, the evaporation rate is limited by decomposition of SiO2 on the crystal surface, but it is limited by a diffusion process for evaporation in hydrogen gas. Therefore, evaporation rate of minerals in the solar nebula can be shown neither by that in equilibrium nor by that in vacuum. The maximum temperature of the solar nebula at the midplane at 2-3 AU where chondrites are believed to have originated is calculated to be as low as 150 K, 1500 K, or in between them. The temperature is, in any case, not high enough for total evaporation of the interstellar materials. Therefore, evaporation of interstellar materials is one of the most important processes for the origin and fractionation of solid materials. The fundamental process of evaporation of minerals has been intensively studied for these several years. Those experiments were carried out either in equilibrium or in vacuum; however, evaporation in the solar nebula is in hydrogen (and much smaller amount of helium) gas. In order to investigate evaporation rate and compositional (including isotopic) fractionation during evaporation, vaporization experiments for various minerals in various conditions are conducted. At first, SiO2 was adopted for a starting material, because thermochemical data and its nature of congruent vaporization are well known. Experiments were carried out in a vacuum furnace system.

Nagahara, Hiroko↗
NASA NTRS1988

Interstellar cloud material in meteorites

In addition to material of apparently circumstellar origin, many primitive meteorites contain material for which an origin in interstellar clouds is indicated. Such material, apparently organic in nature, is revealed by enrichments of deuterium relative to terrestrial material. Astronomical observations have shown that simple organic molecules in dense interstellar clouds have large D/H ratios. The H-isotopic compositions of those molecules are believed to be the result of ion-molecule reactions taking place at low temperatures.

Zinner, Ernst↗