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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Auroral and Non‐Auroral H 3 + Ion Winds at Uranus With Keck‐NIRSPEC and IRTF‐iSHELL

Abstract To date, no investigation has documented ionospheric flows at Uranus. Previous investigations of Jupiter and Saturn have demonstrated that mapping ion winds can be used to understand ionospheric currents and how these connect to magnetosphere‐ionosphere coupling. We present a study of Uranus's near infrared emissions (NIR) using data from the Keck II Telescope's Near InfraRed SPECtrograph (NIRSPEC) and the InfraRed Telescope Facility's iSHELL spectrograph. H 3 + emission lines were used to derive dawn‐to‐dusk intensity, ionospheric temperatures and ion densities to identify auroral emissions, with their Doppler shifts used to measure ion velocities. We confirm the presence of the southern NIR aurora in 2016, driven by elevated H 3 + column densities up to 6.0 × 10 16 m −2 . While no auroral emissions were detected in 2014, we find a 14%–20% super rotation across the planet's disk in 2014 and a 7%–18% super rotation in 2016.

Thomas, Emma M. [Department of Mathematics Physics↗
DOE OSTI2015

Nonlinear plasma experiments in geospace with gigawatts of RF power at HAARP

The ionosphere is the ionized uppermost layer of our atmosphere (from 70 – 500 km altitude) where free electron densities yield peak critical frequencies in the HF (3 – 30 MHz) range. The ionosphere thus provides a quiescent plasma target, stable on timescales of minutes, for a whole host of active plasma experiments. High power RF experiments on ionospheric plasma conducted in the U.S. have been reported since 1970. The largest HF transmitter built to date is the HAARP phased-array HF transmitter near Gakona, Alaska which can deliver up to 3.6 Gigawatts (ERP) of CW RF power in the range of 2.8 – 10 MHz to the ionosphere with microsecond pointing, power modulation, and frequency agility. With an ionospheric background thermal energy in the range of only 0.1 eV, this amount of power gives access to the highest regimes of the nonlinearity (RF intensity to thermal pressure) ratio. HAARP’s unique features have enabled the conduct of a number of unique nonlinear plasma experiments in the interaction region of overdense ionospheric plasma including generation of artificial aurorae, artificial ionization layers, VLF wave-particle interactions in the magnetosphere, parametric instabilities, stimulated electromagnetic emissions (SEE), strong Langmuir turbulence (SLT) and suprathermal electron acceleration. Diagnostics include the Modular UHF Ionospheric Radar (MUIR) sited at HAARP, the SuperDARN-Kodiak HF radar, spacecraft radio beacons, HF receivers to record stimulated electromagnetic emissions (SEE) and telescopes and cameras for optical emissions. We report on short timescale ponderomotive overshoot effects, artificial field-aligned irregularities (AFAI), the aspect angle dependence of the intensity of the HF-enhanced plasma line, and production of suprathermal electrons. One of the primary missions of HAARP, has been the generation of ELF (300 – 3000 Hz) and VLF (3 – 30 kHz) radio waves which are guided to global distances in the Earth-ionosphere waveguide. We review recent efforts to improve the efficiency of the generation ELF/VLF and develop alternative mechanisms that do not require a natural ionospheric current. Applications include the controlled study of ionospheric irregularities affecting spacecraft communication and navigation systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

The effects of the ionosphere on ground-based detection of the global 21 cm signal from the cosmic dawn and the dark ages

Detection of the global H i 21 cm signal from the Cosmic Dawn and the Epoch of Reionization is the key science driver for several ongoing ground-based and future ground-/space-based experiments. The crucial spectral features in the global 21 cm signal (turning points) occur at low radio frequencies ≲100 MHz. In addition to the human-generated radio frequency interference, Earth’s ionosphere drastically corrupts low-frequency radio observations from the ground. In this paper, we examine the effects of time-varying ionospheric refraction, absorption, and thermal emission at these low radio frequencies and their combined effect on any ground-based global 21 cm experiment. It should be noted that this is the first study of the effect of a dynamic ionosphere on global 21 cm experiments. The fluctuations in the ionosphere are influenced by solar activity with flicker noise characteristics. The same characteristics are reflected in the ionospheric corruption to any radio signal passing through the ionosphere. As a result, any ground-based observations of the faint global 21 cm signal are corrupted by flicker noise (or 1/f noise, where f is the dynamical frequency) which scales as ν{sup −2} (where ν is the frequency of radio observation) in the presence of a bright galactic foreground (∝ν{sup −s}, where s is the radio spectral index). Hence, the calibration of the ionosphere for any such experiment is critical. Any attempt to calibrate the ionospheric effects will be subject to the inaccuracies in the current ionospheric measurements using Global Positioning System (GPS) ionospheric measurements, riometer measurements, ionospheric soundings, etc. Even considering an optimistic improvement in the accuracy of GPS–total electron content measurements, we conclude that Earth’s ionosphere poses a significant challenge in the absolute detection of the global 21 cm signal below 100 MHz.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Geomagnetic Storm Effects on Ionospheric Irregularities: Insights from SuperDARN, Madrigal GPS TEC, and ISR Data [Slides]

Geomagnetic disturbances trigger an influx of electrons from the magnetosphere, leading to an increase electron density (even in lower altitudes), amplified ionospheric currents, and subsequently, increased conductance. A surge in the AE index, indicating heightened auroral currents, correlates with a rise in precipitated charged particles, including electrons, into the polar ionosphere. This correlation is detectable through increased parameter values measured by SuperDARN. The downward flow of electron density towards lower altitudes, as observed in PFISR data, potentially obstructs the transmission frequency from radar stations passing through the PFISR location (just like we saw in the KOD station). During the geomagnetic storm, there is increased backscatter power (increased amount of ionospheric irregularities), and the plasma flow draws closer to the radar, suggesting a possible southward shift in the auroral oval as a result of the heightened auroral activity. Increased geomagnetic activity correlates with an elevation in average TEC and induces the occurrence of SED (Storm Enhanced Density).

58 GEOSCIENCES↗
DOE OSTI2021

Numerical Simulations of the Geospace Response to the Arrival of an Idealized Perfect Interplanetary Coronal Mass Ejection

Abstract Previously, Tsurutani and Lakhina (2014, https://doi.org/10.1002/2013GL058825 ) created estimates for a “perfect” interplanetary coronal mass ejection and performed simple calculations for the response of geospace, including . In this study, these estimates are used to drive a coupled magnetohydrodynamic‐ring current‐ionosphere model of geospace to obtain more physically accurate estimates of the geospace response to such an event. The sudden impulse phase is examined and compared to the estimations of Tsurutani and Lakhina (2014, https://doi.org/10.1002/2013GL058825 ). The physics‐based simulation yields similar estimates for Dst rise, magnetopause compression, and equatorial values as the previous study. However, results diverge away from the equator. values in excess of 30 nT/s are found as low as magnetic latitude. Under southward interplanetary magnetic field conditions, magnetopause erosion combines with strong region one Birkeland currents to intensify the response. Values obtained here surpass those found in historically recorded events and set the upper threshold of extreme geomagnetically induced current activity at Earth.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

The two-way relationship between ionospheric outflow and the ring current

It is now well established that the ionosphere, because it acts as a significant source of plasma, plays a critical role in ring current dynamics. However, because the ring current deposits energy into the ionosphere, the inverse may also be true: the ring current can play a critical role in the dynamics of ionospheric outflow. This study uses a set of coupled, first-principles-based numerical models to test the dependence of ionospheric outflow on ring current-driven region 2 field-aligned currents (FACs). A moderate magnetospheric storm event is modeled with the Space Weather Modeling Framework using a global MHD code (Block Adaptive Tree Solar wind Roe-type Upwind Scheme, BATS-R-US), a polar wind model (Polar Wind Outflow Model), and a bounce-averaged kinetic ring current model (ring current atmosphere interaction model with self-consistent magnetic field, RAM-SCB). Initially, each code is two-way coupled to all others except for RAM-SCB, which receives inputs from the other models but is not allowed to feed back pressure into the MHD model. The simulation is repeated with pressure coupling activated, which drives strong pressure gradients and region 2 FACs in BATS-R-US. It is found that the region 2 FACs increase heavy ion outflow by up to 6 times over the non-coupled results. The additional outflow further energizes the ring current, establishing an ionosphere-magnetosphere mass feedback loop. This study further demonstrates that ionospheric outflow is not merely a plasma source for the magnetosphere but an integral part in the nonlinear ionosphere-magnetosphere-ring current system.

58 GEOSCIENCES↗
DOE OSTI2015

The dependence of the strength and thickness of field‐aligned currents on solar wind and ionospheric parameters

Abstract Sheared plasma flows at the low‐latitude boundary layer (LLBL) correlate well with early afternoon auroral arcs and upward field‐aligned currents. We present a simple analytic model that relates solar wind and ionospheric parameters to the strength and thickness of field‐aligned currents (Λ) in a region of sheared velocity, such as the LLBL. We compare the predictions of the model with DMSP observations and find remarkably good scaling of the upward region 1 currents with solar wind and ionospheric parameters in region located at the boundary layer or open field lines at 1100–1700 magnetic local time. We demonstrate that and Λ ∼ L when Λ/ L < 5 where L is the auroral electrostatic scale length. The sheared boundary layer thickness (Δ m ) is inferred to be around 3000 km, which appears to have weak dependence on V sw . J ∥ has dependencies on Δ m , Σ p , n sw , and V sw . The analytic model provides a simple way to organize data and to infer boundary layer structures from ionospheric data.

Johnson, Jay R.↗
DOE OSTI2018

Self-consistent modeling of electron precipitation and responses in the ionosphere: application to low-altitude energization during substorms

Here, we report a new modeling capability that self–consistently couples physics–based magnetospheric electron precipitation with its impact on the ionosphere. Specifically, the ring current model RAM–SCBE is two–way coupled to an ionospheric electron transport model GLOW, representing a significant improvement over previous models, in which the ionosphere is either treated as a 2D spherical boundary of the magnetosphere, or is driven by empirical precipitation models that are incapable of capturing small–scale, transient variations. The new model enables us to study the impact of substorm–associated, spectrum–resolved electron precipitation on the 3D ionosphere. We found that after each substorm injection, a high–energy tail of precipitation is produced in the dawn sector outside the plasmapause, by energetic electrons (10 < E < 100 keV) scattered by whistler–mode chorus waves. Consequently, an ionospheric sub–layer characterized by enhanced Pedersen conductivity arises at unusually low altitude (~85 km), with its latitudinal width of ~5–10° in the auroral zone. The sub–layer structure appears intermittently, in correlation with recurrent substorm injections. It propagates eastward from the nightside to the dayside in the same drift direction of source electrons injected from the plasmasheet, resulting in global impact within the ionosphere. In conclusion, this study demonstrates the model's capability of revealing complex cross–scale interactions in the geospace environment.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Topanga: A kinetic ion plasma code for large-scale ionospheric simulations on magnetohydrodynamic timescales

Topanga is a kinetic ion code developed for simulating large-scale plasma phenomena in the Earth's ionosphere on magnetohydrodynamic timescales. It is a domain-decomposed parallel code that runs on high-performance computing platforms. Features of Topanga include spherical geometry for simplified boundary conditions and computational efficiency; a hybrid plasma model with inertia-less fluid electrons, kinetic ions, and an electric field specified via an Ohm's law; a Maxwell-FDTD (finite difference time domain) plasma model which retains the displacement current in Maxwell's equations and models electron currents in the ionosphere with a tensor conductivity; sponge-layer boundary conditions for absorption of electromagnetic and plasma waves incident on the domain boundaries; and a novel mixed-implicit algorithm for evolving the EM fields inside the Maxwell-FDTD region that is stable over many orders of magnitude in the electron–ion collision frequency. We verify the numerical methods used in Topanga on a pair of test problems. The first test involves modeling a three-dimensional collisionless shock using the hybrid set of equations. The second test involves modeling a spherical TEM mode in vacuum using the Maxwell-FDTD set of equations. Finally, we demonstrate how using the combined set of hybrid and Maxwell-FDTD equations to model the Starfish Prime high-altitude nuclear test recovers a “missing” EM signal on the ground that is not present when using only the hybrid set of equations. The magnitude of this signal in the simulation containing the Maxwell-FDTD region agrees well with the E3a portion of the magnetohydrodynamic electromagnetic pulse from Starfish Prime.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Integration of RAM-SCB into the Space Weather Modeling Framework

We present that numerical simulations of the ring current are a challenging endeavor. They require a large set of inputs, including electric and magnetic fields and plasma sheet fluxes. Because the ring current broadly affects the magnetosphere-ionosphere system, the input set is dependent on the ring current region itself. This makes obtaining a set of inputs that are self-consistent with the ring current difficult. To overcome this challenge, researchers have begun coupling ring current models to global models of the magnetosphere-ionosphere system. This paper describes the coupling between the Ring current Atmosphere interaction Model with Self-Consistent Magnetic field (RAM-SCB) to the models within the Space Weather Modeling Framework. Full details on both previously introduced and new coupling mechanisms are defined. Finally, the impact of self-consistently including the ring current on the magnetosphere-ionosphere system is illustrated via a set of example simulations.

58 GEOSCIENCES↗
DOE OSTI2017

Magnetic Field Observations at Purcell, Oklahoma Field Campaign Report

The campaign “Magnetic Field Observations at Purcell, Oklahoma” installed a ground-based magnetometer at Purcell’s U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility boundary installation at the Kessler Atmospheric and Ecological Field Station, University of Oklahoma, to measure local magnetic field variations. It is a part of the nine stations of the Mid-continent MAgnetoseismic Chain (McMAC) placed as close to the 330° magnetic longitude as possible. This is the meridian in the world where land covers the greatest continuous range in magnetic latitude. Figure 1 shows the map of the magnetometer stations along the 330th magnetic meridian, including the Purcell (PCEL) station. The main scientific objective of the campaign is to detect the field line resonance (FLR) frequencies of the magnetic field line connected to the Purcell station. This magnetic field line extends from Purcell to the outer space at distances as far as 2 Earth radii (RE). To accurately identify FLR frequencies, however, simultaneous measurements at slightly different latitudes along the same meridian are necessary to allow the use of the cross-phase technique. This consideration explains the arrangement to operate magnetometers at the Americus (AMER) and Richardson (RICH) stations nearby. The measured resonant frequency can infer the plasma mass density along the field line through the method of normal-mode magnetoseismology. The magnetometer at the Purcell station can detect many other types of magnetic field fluctuations associated with the changes in the electric currents in the ionosphere and the magnetosphere, which by large are affected by the solar activity. In other words, the magnetic field data collected by this campaign are also useful for understanding space weather phenomena. The magnetometer was installed at Purcell’s ARM boundary facility in March 27, 2006. The construction of the triaxial fluxgate magnetometer used by the campaign, as well as the data processing and analysis, was sponsored by the National Science Foundation. Except during occasional downtimes, the magnetometer collected measurements from June 6, 2006 to July 26, 2016.

47 OTHER INSTRUMENTATION↗
DOE OSTI2015

Theory and observations of upward field‐aligned currents at the magnetopause boundary layer

Abstract The dependence of the upward field‐aligned current density ( J || ) at the dayside magnetopause boundary layer is well described by a simple analytic model based on a velocity shear generator. A previous observational survey confirmed that the scaling properties predicted by the analytical model are applicable between 11 and 17 MLT. We utilize the analytic model to predict field‐aligned currents using solar wind and ionospheric parameters and compare with direct observations. The calculated and observed parallel currents are in excellent agreement, suggesting that the model may be useful to infer boundary layer structures. However, near noon, where velocity shear is small, the kinetic pressure gradients and thermal currents, which are not included in the model, could make a small but significant contribution to J || . Excluding data from noon, our least squares fit returns log( J ||,max_cal ) = (0.96 ± 0.04) log( J ||_obs ) + (0.03 ± 0.01) where J ||,max_cal = calculated J ||,max and J ||_obs = observed J || .

Wing, Simon↗
DOE OSTI2022

Meso-Scale Electrodynamic Coupling of the Earth Magnetosphere-Ionosphere System

Within the fully integrated magnetosphere-ionosphere system, many electrodynamic processes interact with each other. We review recent advances in understanding three major meso-scale coupling processes within the system: the transient field-aligned currents (FACs), mid-latitude plasma convection, and auroral particle precipitation. (1) Transient FACs arise due to disturbances from either dayside or nightside magnetosphere. As the interplanetary shocks suddenly compress the dayside magnetosphere, short-lived FACs are induced at high latitudes with their polarity successively changing. Magnetotail dynamics, such as substorm injections, can also disturb the current structures, leading to the formation of substorm current wedges and ring current disruption. (2) The mid-latitude plasma convection is closely associated with electric fields in the system. Recent studies have unraveled some important features and mechanisms of subauroral fast flows. (3) Charged particles, while drifting around the Earth, often experience precipitating loss down to the upper atmosphere, enhancing the auroral conductivity. Recent studies have been devoted to developing more self-consistent geospace circulation models by including a better representation of the auroral conductance. It is expected that including these new advances in geospace circulation models could promisingly strengthen their forecasting capability in space weather applications. The remaining challenges especially in the global modeling of the circulation system are also discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Effects of EMIC Wave-Driven Proton Precipitation on the Ionosphere

In this report we investigate the proton precipitation caused by electromagnetic ion cyclotron (EMIC) waves and its impact on the ionosphere with the self-consistent ring current-atmosphere interactions model (RAM-SCBE) coupled with an ionospheric particle transport model Global Airglow (GLOW). The EMIC wave diffusion process causes significant precipitation of tens of keV protons, particularly in the afternoon to midnight sector. These precipitating energetic protons further impact the ionosphere-thermosphere and contribute to the ionization in the E/F regions. The integrated auroral conductance is significantly enhanced in the dusk-to-midnight sector. Although the EMIC waves do not directly interact with the ring current electrons, after the EMIC wave scattering included in the model, remarkable changes are found in the global distribution of precipitating electron flux. This means that the addition of proton precipitation driven by EMIC waves results in feedback effects on the ring current electron dynamics through the circulation system. Validation is also conducted by comparing the simulated precipitation flux and ionospheric electron density with observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

A new ionospheric electron precipitation module coupled with RAM-SCB within the geospace general circulation model

Electron precipitation down to the atmosphere due to wave-particle scattering in the magnetosphere contributes significantly to the auroral ionospheric conductivity. In order to obtain the auroral conductivity in global MHD models that are incapable of capturing kinetic physics in the magnetosphere, MHD parameters are often used to estimate electron precipitation flux for the conductivity calculation. Such an MHD approach, however, lacks self-consistency in representing the magnetosphere-ionosphere coupling processes. In this study we improve the coupling processes in global models with a more physical method. We calculate the physics-based electron precipitation from the ring current and map it to the ionospheric altitude for solving the ionospheric electrodynamics. In particular, we use the BATS-R-US (Block Adaptive Tree Scheme-Roe type-Upstream) MHD model coupled with the kinetic ring current model RAM-SCB (Ring current-Atmosphere interaction Model with Self-Consistent Magnetic field (B)) that solves pitch angle-dependent electron distribution functions, to study the global circulation dynamics during the 25–26 January 2013 storm event. Since the electron precipitation loss is mostly governed by wave-particle resonant scattering in the magnetosphere, we further investigate two loss methods of specifying electron precipitation loss associated with wave-particle interactions: (1) using pitch angle diffusion coefficients D αα (E,α) determined from the quasi-linear theory, with wave spectral and plasma density obtained from statistical observations (named as “diffusion coefficient method”) and (2) using electron lifetimes τ(E) independent on pitch angles inferred from the above diffusion coefficients (named as “lifetime method”). We found that both loss methods demonstrate similar temporal evolution of the trapped ring current electrons, indicating that the impact of using different kinds of loss rates is small on the trapped electron population. Furthermore, for the precipitated electrons, the lifetime method hardly captures any precipitation in the large L shell (i.e., 4 < L < 6.5) region, while the diffusion coefficient method produces much better agreement with NOAA/POES measurements, including the spatial distribution and temporal evolution of electron precipitation in the region from the premidnight through the dawn to the dayside. Further comparisons of the precipitation energy flux to DMSP observations indicates that the new physics-based precipitation approach using diffusion coefficients for the ring current electron loss can explain the diffuse electron precipitation in the dawn sector, such as the enhanced precipitation flux at auroral latitudes and flux drop near the subauroral latitudes, but the traditional MHD approach largely overestimates the precipitation flux at lower latitudes.

58 GEOSCIENCES↗
DOE OSTI2021

On the Ion Precipitation due to Field Line Curvature (FLC) and EMIC Wave Scattering and Their Subsequent Impact on Ionospheric Electrodynamics

Both field line curvature (FLC) and electromagnetic ion cyclotron (EMIC) wave scattering are believed to be associated with energetic ion precipitation, but their relative contributions to ionospheric ion precipitation and subsequent effects are still unclear. Here, in this study, by using a kinetic ring current model, we investigate their impact on the ionosphere from two aspects: the global distribution of ion precipitation and resulting ionospheric conductance. Our results show that the intensity and coverage of ion precipitation due to EMIC waves are larger than that due to FLC scattering, while the latter mostly contributes to ion precipitation in outer regions (L > 4–5). We then estimate the conductance with empirical models using the simulated ion precipitation energy flux. When the EMIC wave associated proton precipitation is included, the conductance is significantly enhanced in the dusk-to-midnight sector and has a wide magnetic latitude (MLAT) range from around 52° to 62°, considerably altering the electric potential in the dusk sector, which further influences particle dynamics in the magnetosphere. On the contrary, the proton precipitation caused by FLC scattering only occurs at higher latitudes above MLAT = 60° and the corresponding conductance is slightly enhanced at midnight, with negligible influence on the convective electric potential. Although electron precipitation-associated conductance is predominant globally, the results show that proton precipitation can also play an important role in ionospheric electrodynamics, especially when EMIC wave-associated precipitating proton energy flux exceeds that of electrons in the dusk sector, a region where many subauroral coupling processes occur.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Simultaneous observations of traveling convection vortices: Ionosphere-thermosphere coupling: M-I-T COUPLING OF TCV

We present simultaneous observations of magnetosphere-ionosphere-thermosphere coupling over Svalbard during a traveling convection vortex (TCV) event. Various spaceborne and ground-based instruments made coordinated measurements, including magnetometers, particle detectors, an all-sky camera, European Incoherent Scatter (EISCAT) Svalbard Radar, Super Dual Auroral Radar Network (SuperDARN), and SCANning Doppler Imager (SCANDI). The instruments recorded TCVs associated with a sudden change in solar wind dynamic pressure. The data display typical features of TCVs including vortical ionospheric convection patterns seen by the ground magnetometers and SuperDARN radars and auroral precipitation near the cusp observed by the all-sky camera. Simultaneously, electron and ion temperature enhancements with corresponding density increase from soft precipitation are also observed by the EISCAT Svalbard Radar. The ground magnetometers also detected electromagnetic ion cyclotron waves at the approximate time of the TCV arrival. This implies that they were generated by a temperature anisotropy resulting from a compression on the dayside magnetosphere. SCANDI data show a divergence in thermospheric winds during the TCVs, presumably due to thermospheric heating associated with the current closure linked to a field-aligned current system generated by the TCVs. We conclude that solar wind pressure impulse-related transient phenomena can affect even the upper atmospheric dynamics via current systems established by a magnetosphere-ionosphere-thermosphere coupling process.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Reactions of substituted benzene anions with N and O atoms: Chemistry in Titan’s upper atmosphere and the interstellar medium

The likely existence of aromatic anions in many important extraterrestrial environments, from the atmosphere of Titan to the interstellar medium (ISM), is attracting increasing attention. Nitrogen and oxygen atoms are also widely observed in the ISM and in the ionospheres of planets and moons. In the current work, we extend previous studies to explore the reactivity of prototypical aromatic anions (deprotonated toluene, aniline, and phenol) with N and O atoms both experimentally and computationally. The benzyl and anilinide anions both exhibit slow associative electron detachment (AED) processes with N atom, and moderate reactivity with O atom in which AED dominates but ionic products are also formed. The reactivity of phenoxide is dramatically different; there is no measurable reaction with N atom, and the moderate reactivity with O atom produces almost exclusively ionic products. The reaction mechanisms are studied theoretically by employing density functional theory calculations, and spin conversion is found to be critical for understanding some product distributions. This work provides insight into the rich gas-phase chemistry of aromatic ion-atom reactions and their relevance to ionospheric and interstellar chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗