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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Diagnosis of energy transport in iron buried layer targets using an extreme ultraviolet laser

We demonstrate the use of extreme ultra-violet (EUV) laboratory lasers in probing energy transport in laser irradiated solid targets. EUV transmission through targets containing a thin layer of iron (50 nm) encased in plastic (CH) after irradiation by a short pulse (35 fs) laser focussed to irradiances 3 × 10{sup 16} Wcm{sup −2} is measured. Heating of the iron layer gives rise to a rapid decrease in EUV opacity and an increase in the transmission of the 13.9 nm laser radiation as the iron ionizes to Fe{sup 5+} and above where the ion ionisation energy is greater than the EUV probe photon energy (89 eV). A one dimensional hydrodynamic fluid code HYADES has been used to simulate the temporal variation in EUV transmission (wavelength 13.9 nm) using IMP opacity values for the iron layer and the simulated transmissions are compared to measured transmission values. When a deliberate pre-pulse is used to preform an expanding plastic plasma, it is found that radiation is important in the heating of the iron layer while for pre-pulse free irradiation, radiation transport is not significant.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1980

Thermal iron ions in high speed solar wind streams Detection by the IMP 7/8 energetic particle experiments

The first measurements of the abundance of iron ions in high speed (greater than 600 km/s) solar wind streams have been made with the NOAA/JHU energetic particles experiments (EPE) on IMP 7/8. The identification of iron ions is quantitatively established using 4 years of observations and heavy ion accelerator calibrations of detectors similar to those flown on the spacecraft. Preliminary estimates of the Fe/H ratio are within a factor of 2 of the adopted coronal abundance (0.00005), and there is some evidence that Fe/H may remain approximately constant within a given stream. In the peaks of fast streams (700-800 km/s), about 50 iron ion counts are obtained every 20 s, offering the possibility of studying the Fe/H ratio with approximately 1 m time resolution in high speed streams throughout the decline of Solar Cycle 20 and the rise of Solar Cycle 21.

Mitchell, D. G.↗
DOE OSTI2016

Magnetic study of Fe-doped CdSe nanomaterials

Nanoparticles of pure and iron (50 %) doped cadmium selenide (CdSe) have been synthesized by soft chemical route. EDAX analysis supports the inclusion of Fe into CdSe nanoparticles. The average particle size of pure and doped CdSe is found to be ∼50 nm from scanning electron microscopy (SEM). Magnetization of the samples are measured under the field cooled (FC) and zero field cooled (ZFC) modes in the temperature range from 5K to 300K applying a magnetic field of 500Oe. Field dependent magnetization (M-H) measurement indicates presence of room temperature (RT) paramagnetism and low temperature (5K) ferromagnetism of the sample.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Comparison of the dielectric and magnetocaloric properties of bulk and film of GdFe 0.5 Cr 0.5 O 3

Here, we report a comparison of the magnetic, magnetocaloric, and dielectric properties of 50% iron substituted GdCrO 3 (GdFe 0.5 Cr 0.5 O 3 ) bulk pellet and 960 nm thick film of GdFe 0.5 Cr 0.5 O 3 (GFCO). The 960 nm film was synthesized on a platinized-silicon substrate by chem. soln. deposition and spin-coating methods. The X-ray diffraction scans of the bulk sample and the film as well as the morphology of the film as examined by the field-emission scanning electron microscope indicate phase-pure and polycrystalline nature of these samples. XPS was used to deermine the valence states of Gd, Fe, and Cr. The temp. dependence of the dielectric const. from 225 to 700 K shows peaks at T C = 525 K for the bulk and ≈450 K for the film due to ferroelectric to paraelectric transitions, since elec. polarization vs elec. field hysteresis loops are observed. at room temp. The dielectric studies in the bulk GFCO for T > T C indicate a relaxor-like behavior. The measurements of the magnetization (M) of the samples as a function of temp. (5-350 K) and magnetic field (H) up to 7 T (=70 kOe) depict hysteresis behavior at low temps. due to the canted antiferromagnetic order of Fe 3+ /Cr 3+ below the Néel temp. of ≈275 K. The M vs H isotherms at various temps. are used to det. and compare the magnetic entropy change (-ΔS) and relative cooling power (RCP) of the two samples, yielding (-ΔS) = 30.7 J/kg K (18.8 J/kg K) and RCP = 566.5 J/kg (375 J/kg) for the bulk (960 nm film) samples of GFCO at 7 K and 7 T, resp. The plot of RCP vs T shows that magnetic cooling for this system is most effective for T < 30 K. Comparatively smaller magnitudes of (-ΔS) and RCP for the film vis-a-vis the bulk sample of GFCO scale with its reduced magnetization. This suggests that further improvements in the quality of the films are needed to improve their magnetization and hence their magnetocaloric properties, possibly making them useful for on-chip cooling in miniaturized devices.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Nuclear Data Sheets for A=50

The experimental nuclear structure and decay data are evaluated for all the known nuclides of mass 50 (Cl, Ar, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni). Here, detailed evaluated nuclear structure information are presented in individual decay and reaction datasets and the best values are recommended in the Adopted dataset for level properties, γ and β radiations, and other spectroscopic information. No excited states are known in 50Cl and 50Ni, and limited information is available for 50 Ar, 50 K, 50 Fe and 50 Co. This work supersedes earlier evaluations of A=50 by 2011El01, 1995Bu09, 1990Bu18, 1984Al29, and 1976Au07.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2011

Nuclear Data Sheets for A = 50

The experimental nuclear spectroscopic data for known nuclides of mass number 50 (Cl,Ar,K,Ca,Sc,Ti,V, Cr,Mn,Fe,Co,Ni) have been evaluated and presented together with Adopted properties for levels and {gamma} rays. This evaluation has been carried out about 15 years after the previous one by Thomas Burrows (1995Bu29). Except for {sup 50}Sc and {sup 50}V, extensive new data have become available for all the other nuclides in the intervening years. The data for {sup 50}Sc and {sup 50}V have also been checked again in detail and several changes made. No data are yet available for excited states in {sup 50}Cl, {sup 50}Ar and {sup 50}Ni. This work supersedes earlier evaluations (1995Bu29, 1990Bu18, 1984Al29, 1976Au07) of A=50 nuclides.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2012

Measurement of integrated flux of cosmic ray muons at sea level using the INO-ICAL prototype detector

The India-based Neutrino Observatory (INO) collaboration is planning to set-up a magnetized Iron-CALorimeter (ICAL) to study atmospheric neutrino oscillations with precise measurements of oscillations parameters. The ICAL uses 50 kton iron as target mass and about 28800 Resistive Plate Chambers (RPC) of 2 m × 2 m in area as active detector elements. As part of its R and D program, a prototype detector stack comprising 12 layers of RPCs of 1 m × 1 m in area has been set-up at Tata Institute of Fundamental Research (TIFR) to study the detector parameters using cosmic ray muons. We present here a study of muon flux measurement at sea level and lower latitude. (Site latitude: 18°54'N, longitude: 72°48'E.)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS1985

Relative abundances of sub-iron to iron nuclei in low energy (50-250 MeV/N) cosmic rays as observed in the Skylab experiment

A Lexan polycarbonate detector exposed on the exterior of Skylab-3 for 73 days during a solar quiet period was used to study the relative abundances of calcium to nickel ions in low energy cosmic rays of 50 to 250 MeV/N. The method of charge identification is based on the measurement of conelength (L) and residual range (R) of these particles in various Lexan sheets. Since more than one cone (sometimes as many as five) is observed and is measured, the charge accuracy becomes precise and accurate. The ratio of (calcium to manganese) to (iron and cobalt) obtained at three energy intervals of 50 to 80, 80 to 150, 150 to 250 and 50 to 250 MeV/N are 7.6 plus or minus 3.8, 2.7 plus or minus 0.8, 1.4 plus or minus 0.6 and 3.3 plus or minus 0.7 respectively. These data thus indicate a large increase of this ratio with decreasing energy. The origin of this strong energy dependence is not understood at present.

Durgaprasad, N.↗
DOE OSTI2012

Laboratory Shock Experiments on Basalt - Iron Sulfate Mixes at ~ 40 - 50 GPa and their Relevance to the Martian Reolith Component Present in Shergotties

Basaltic shergottites such as Shergotty, Zagami and EET79001 contain impact melt glass pockets that are rich in Martian atmospheric gases and are known as gas-rich impact-melt (GRIM) glasses. These glasses show evidence for the presence of a Martian regolith component based on Sm and Kr isotopic studies. The GRIM glasses are sometimes embedded with clusters of innumerable micron-sized iron-sulfide blebs associated with minor amounts of iron sulfate particles. These sulfide blebs are secondary in origin and are not related to the primary igneous sulfides occurring in Martian meteorites. The material comprising these glasses arises from the highly oxidizing Martian surface and sulfur is unlikely to occur as sulfide in the Martian regoilith. Instead, sulfur is shown to occur as sulfate based on APXS and Mossbauer results obtained by the Opportunity and Spirit rovers at Meridiani and Gusev. We have earlier suggested that the micron-sized iron sulfide globules in GRIM glasses were likely produced by shock-reduction of iron sulfate occurring in the regolith at the time when the GRIM glasses were produced by the meteoroid impact that launched the Martian meteorites into space. As a result of high energy deposition by shock (~ 40-60 GPa), the iron sulfate bearing phases are likely to melt along with other regolith components and will get reduced to immiscible sulfide fluid under reducing conditions. On quenching, this generates a dispersion of micron-scale sulfide blebs. The reducing agents in our case are likely to be H 2 and CO which were shock-implanted from the Martian atmosphere into these glasses along with the noble gases. We conducted lab simulation experiments in the Lindhurst Laboratory of Experimental Geophysics at Caltech and the Experimental Impact Laboratory at JSC to test whether iron sulfide globules can be produced by impact-driven reduction of iron sulfate by subjecting Columbia River Basalt (CRB) and ferric sulfate mixtures to shock pressures between 40 and 50 GPa under reducing conditions. The experimental products from the recovered samples were analyzed by SEM and microprobe techniques at JSC.

58 GEOSCIENCES↗
DOE OSTI2011

The T{sub z} = -1{yields}T{sub z} =0 beta decays and comparison with Charge Exchange reactions

Gamow-Teller (GT) transitions can be studied in both {beta} decay and charge exchange (CE) reactions. If isospin is a good quantum number, then the Tz = -1{yields}0 and Tz = +1{yields}0GT mirror transitions, are identical. Therefore, a comparison of the results from studies of {beta} decay and CE should shed light on this assumption. Accordingly we have studied the {beta} decay of the Tz = -1 fp-shell nuclei, {sup 54}Ni, {sup 50}Fe, {sup 46}Cr, and {sup 42}Ti, produced in fragmentation and we have compared our results with the spectra from ({sup 3}He, t) measurements on the mirror Tz = +1 target nuclei studied in high resolution at RCNP, Osaka. The {beta} decay experiments were performed as part of the STOPPED beam RISING campaign at GSI.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Fe(III) (oxyhydr)oxide reduction by the thermophilic iron-reducing bacterium Desulfovulcanus ferrireducens

Some thermophilic bacteria from deep-sea hydrothermal vents grow by dissimilatory iron reduction, but our understanding of their biogenic mineral transformations is nascent. Mineral transformations catalyzed by the thermophilic iron-reducing bacterium Desulfovulcanus ferrireducens during growth at 55°C were examined using synthetic nanophase ferrihydrite, akaganeite, and lepidocrocite separately as terminal electron acceptors. Spectral analyses using visible-near infrared (VNIR), Fourier-transform infrared attenuated total reflectance (FTIR-ATR), and Mössbauer spectroscopies were complemented with x-ray diffraction (XRD) and transmission electron microscopy (TEM) using selected area electron diffraction (SAED) and energy dispersive X-ray (EDX) analyses. The most extensive biogenic mineral transformation occurred with ferrihydrite, which produced a magnetic, visibly dark mineral with spectral features matching cation-deficient magnetite. Desulfovulcanus ferrireducens also grew on akaganeite and lepidocrocite and produced non-magnetic, visibly dark minerals that were poorly soluble in the oxalate solution. Bioreduced mineral products from akaganeite and lepidocrocite reduction were almost entirely absorbed in the VNIR spectroscopy in contrast to both parent minerals and the abiotic controls. However, FTIR-ATR and Mössbauer spectra and XRD analyses of both biogenic minerals were almost identical to the parent and control minerals. The TEM of these biogenic minerals showed the presence of poorly crystalline iron nanospheres (50–200 nm in diameter) of unknown mineralogy that were likely coating the larger parent minerals and were absent from the controls. The study demonstrated that thermophilic bacteria transform different types of Fe(III) (oxyhydr)oxide minerals for growth with varying mineral products. These mineral products are likely formed through dissolution-reprecipitation reactions but are not easily predictable through chemical equilibrium reactions alone.

12 reflectance spectroscopy↗
DOE OSTI2011

Is the magnetic anisotropy proportional to the orbital moment?

The relation between orbital moment and magnetic anisotropy is investigated by model calculations, which show that only a part of the spin-orbit coupling contributes to the anisotropy. A large part of the anisotropy energy, about 50% for iron series elements and nearly 100% for rare-earths, is stored in the nonrelativistic part of the Hamiltonian. A feature important for x-ray magnetic circular dichroism is that the orbital moment of heavy atoms rotates with the spin moment, whereas in light atoms, the orbital moment is recreated in each different direction. In the discussion, we consider three examples of current interest in different areas of magnetism, namely, spin-orbit coupling in Gd3+ and Eu2+, surface anisotropy of Nd2Fe14B, and multiferroic magnetization switching using rare-earths. (C) 2011 American Institute of Physics. [doi:10.1063/1.3562445]

Skomski, R↗
DOE OSTI2022

Towards performing high-resolution inelastic X-ray scattering measurements at hard X-ray free-electron lasers coupled with energetic laser drivers

High-resolution inelastic X-ray scattering is an established technique in the synchrotron community, used to investigate collective low-frequency responses of materials. When fielded at hard X-ray free-electron lasers (XFELs) and combined with high-intensity laser drivers, it becomes a promising technique for investigating matter at high temperatures and high pressures. This technique gives access to important thermodynamic properties of matter at extreme conditions, such as temperature, material sound speed, and viscosity. The successful realization of this method requires the acquisition of many identical laser-pump/X-ray-probe shots, allowing the collection of a sufficient number of photons necessary to perform quantitative analyses. Here, a 2.5-fold improvement in the energy resolution of the instrument relative to previous works at the Matter in Extreme Conditions (MEC) endstation, Linac Coherent Light Source (LCLS), and the High Energy Density (HED) instrument, European XFEL, is presented. Some aspects of the experimental design that are essential for improving the number of photons detected in each X-ray shot, making such measurements feasible, are discussed. A careful choice of the energy resolution, the X-ray beam mode provided by the XFEL, and the position of the analysers used in such experiments can provide a more than ten-fold improvement in the photometrics. The discussion is supported by experimental data on 10 µm-thick iron and 50 nm-thick gold samples collected at the MEC endstation at the LCLS, and by complementary ray-tracing simulations coupled with thermal diffuse scattering calculations.

36 MATERIALS SCIENCE↗
NASA NTRS1997

Evaluation of HAN-TEAN Stabilizers using Microcalorimetry

HAN-TEAN (hydroxylammonium nitrate - triethanolammonium nitrate - in water) is being considered for various propellant applications. This propellant has advantages in terms of insensitivity to impact and fire, low vapor pressure and environmentally benign reaction products. One office concerns with HAN-TEAN is its stability and shelf-life, especially when contaminated with trace metals. Stabilizer systems, consisting of anti-oxidants and/or chealating agents were investigated for their ability to control the decomposition of HAN-TEAN. Isothermal microcalorimetry, an ultrasensitive heat measurement technique, was used to monitor the decomposition of HANTEAN at near ambient temperatures. Isothermal microcalorimetry measures the heat flow from a reaction vessel into a surrounding heat sink. Microcalorimetry is approximately 1,000 times more sensitive than accelerating rate calorimetry (ARC) or differential scanning calorimetry (DSC) for measuring heat flow. Samples of HAN-TEAN containing the stabilizers were spiked with 50 ppm iron and the heat evolution monitored for a period of at least 30 days. Ten stabilizer combinations were tested and the rates of HAN-TEAN decomposition were lowered by 74 to 95 percent in the presence of iron.

Hornung, Steven D.↗
NASA NTRS1984

Mossbauer spectroscopy and X-ray diffraction of samples from the Santa Catharina iron meteorite

Conversion electron Mossbauer spectroscopy (CEMS) of samples from the Santa Catharina iron meteorite shows the presence of the ordered iron-nickel phase with 50% Ni, tetrataenite, and of the paramagnetic iron-nickel phase with 25% Ni. The FeNi phase with 50% Ni amounts to 70% of the iron-nickel alloys. Futhermore, the CEM spectra show the presence of small peaks from one or more spinel compounds. These small peaks are more pronounced when regions near the rim of the samples are analyzed. The X-ray diffraction of different areas of the samples, both optically dark and optically light areas, shows the presence of a diffraction pattern from a single f.c.c. lattice with a lattice parameter of a=3.58A This means that the two different Fe-Ni phases seen in the CEMS analysis occupy the same lattice. The X-ray photographs also show the presence of super-structure reflections from the ordered FeNi phase, and that the orientation of the f.c.c. lattice is the same within the whole sample.

Roy-Poulsen, H.↗
DOE OSTI2020

Helical spin structure in iron chains with hybridized boundaries

In this paper, we have compared the magnetic properties of well-controlled ultra-short (≤50 nm) atomic iron (Fe) chains embedded in Fe-phthalocyanine films with those in Fe–hydrogen (H2) phthalocyanine superlattices. Surprisingly, we found that the coercivity of the atomic chains with free boundary conditions is independent of the chain length, whereas the one subject to hybridization of the chain ends exhibits an unexpected length dependence. These findings suggest that ferromagnetism in the free-boundary condition system is caused by an intrinsic indirect exchange. On the other hand, controlled boundary conditions produce a helical spin structure due to an extrinsic indirect exchange, which arises from the interaction between iron atoms at the ends of the chain and the hydrogen in the H 2 phthalocyanine spacer. As a consequence, during magnetic reversal, ultra-short iron chains subject to boundary clamping develop a helical spin structure, leading to increased coercivity. These findings suggest unique insights and ideas for the design of atomic-scale ultra-dense magnetic storage nanodevices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Iron Atom Exchange between Hematite and Aqueous Fe(II)

Aqueous Fe(II) has been shown to exchange with structural Fe(III) in goethite without any significant phase transformation. It remains unclear, however, whether aqueous Fe(II) undergoes similar exchange reactions with structural Fe(III) in hematite, a ubiquitous iron oxide mineral. Here, we use an enriched 57 Fe tracer to show that aqueous Fe(II) exchanges with structural Fe(III) in hematite at room temperature, and that the amount of exchange is influenced by particle size, pH, and Fe(II) concentration. Reaction of 80 nm-hematite (27 m 2 g -1 ) with aqueous Fe(II) at pH 7.0 for 30 days results in ~5% of its structural Fe(III) atoms exchanging with Fe(II) in solution, which equates to about one surface iron layer. Smaller, 50 nm-hematite particles (54 m 2 g -1 ) undergo about 25% exchange (~3× surface iron) with aqueous Fe(II), demonstrating that structural Fe(III) in hematite is accessible to the fluid in the presence of Fe(II). The extent of exchange in hematite increases with pH up to 7.5 and then begins to decrease as the pH progresses to 8.0, likely due to surface site saturation by sorbed Fe(II). Similarly, when we vary the initial amount of added Fe(II), we observe decreasing amounts of exchange when aqueous Fe(II) is increased beyond surface saturation. In conclusion, this work shows that Fe(II) can catalyze iron atom exchange between bulk hematite and aqueous Fe(II), despite hematite being the most thermodynamically stable iron oxide.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗